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    • 24. 发明授权
    • 6-Substituted 2,4-diamino-1,3,5-triazine derivatives having at least two asymmetrically substituted carbon atoms, the production thereof, and their use as herbicides
    • 具有至少两个不对称取代的碳原子的6-取代的2,4-二氨基-1,3,5-三嗪衍生物,其制备及其作为除草剂的用途
    • US06358886B1
    • 2002-03-19
    • US09623612
    • 2000-11-03
    • Hans-Jochem RiebelStefan LehrKatharina VoigtMarkus DollingerMark Wilhelm DrewesIngo WetcholowskyRandy Allen MyersYukiyoshi WatanabeToshio Goto
    • Hans-Jochem RiebelStefan LehrKatharina VoigtMarkus DollingerMark Wilhelm DrewesIngo WetcholowskyRandy Allen MyersYukiyoshi WatanabeToshio Goto
    • C07D25118
    • C07D405/12A01N43/68C07D251/48C07D409/12
    • The invention relates to novel substituted optically active aminotriazines having at least two asymmetrically substituted carbon atoms of the formula (I), in which A represents a single bond or represents in each case straight-chain or branched alkanediyl or oxaalkanediyl having in each case up to 6 carbon atoms, Z represents certain carbocyclic or heterocyclic radicals and the substituents R1, R2, R3, R4 and Y are as defined in the description,  with the proviso that in each individual case R2, R3 and Y are different from one another and that the substituents at the two carbon atoms to which R2 and R3 or R4 are attached are configured as follows: (a) R configuration at the carbon atom to which R2 and R3 are attached and R configuration at the carbon atom to which R4 is attached (“R,R-diastereomers”), (b) R configuration at the carbon atom to which R2 and R3 are attached and S configuration at the carbon atom to which R4 is attached (“R,S-diastereomers”), (c) S configuration at the carbon atom to which R2 and R3 are attached and R configuration at the carbon atom to which R4 is attached (“S,R-diastereomers”), (d) S configuration at the carbon atom to which R2 and R3 are attached and S configuration at the carbon atom to which R4 is attached (“S,S-diastereomers”), (e) R configuration at the carbon atom to which R2 and R3 are attached and racemic configuration at the carbon atom to which R4 is attached (“R,racdiastereomers”), (f) S configuration at the carbon atom to which R2 and R3 are attached and racemic configuration at the carbon atom to which R4 is attached (“S,rac-diastereomers”), and to a process for preparing the compounds of the formula (I) and to their use as herbicides.
    • 本发明涉及具有式(I)的至少两个不对称取代的碳原子的新的取代的光学活性氨基三嗪,其中A表示单键或表示在每种情况下为直链或支链烷二基或氧杂烷二基,在每种情况下最多为6 碳原子,Z表示某些碳环或杂环基团,并且取代基R 1,R 2,R 3,R 4和Y如说明书中所定义,条件是在各个别情况下,R 2,R 3和Y彼此不同, R2和R3或R4连接的两个碳原子上的取代基配置如下:(a)R 2和R 3连接的碳原子上的R构型,R 4连接的碳原子上的R构型(“ R,R非对映异构体“),(b)R 2和R 3连接的碳原子上的R构型,R 4连接的碳原子上的S构型(”R,S-非对映异构体“),(c)S 配置在碳ato m与R 2相连的碳原子上的R构型(“S,R-非对映异构体”),(d)在R2和R3所连接的碳原子上的S构型, R 4连接的碳原子(“S,S-非对映异构体”),(e)R 2和R 3所连接的碳原子上的R构型,R 4连接的碳原子上的外消旋构型(“R” 外消旋异构体“),(f)R 2和R 3所连接的碳原子上的S构型以及与R4连接的碳原子上的外消旋构型(”S,外消旋 - 非对映体“),以及制备该化合物的方法 的式(I)和它们作为除草剂的用途。
    • 30. 发明授权
    • Herbicidal aminoguanidinoazines
    • 除草氨基胍基嗪
    • US5211740A
    • 1993-05-18
    • US840358
    • 1992-02-24
    • Christa FestRolf KirstenJoachim KluthKlaus-Helmut MullerHans-Jochem RiebelHans-Joachim SantelRobert R. SchmidtHarry Strang
    • Christa FestRolf KirstenJoachim KluthKlaus-Helmut MullerHans-Jochem RiebelHans-Joachim SantelRobert R. SchmidtHarry Strang
    • C07D521/00
    • C07D521/00
    • Herbicidal aminoguanidinoazines of the formula ##STR1## in which R.sup.1 stands for an optionally substituted radical from the series comprising alkyl, aralkyl, aryl and hetaryl,R.sup.2 stands for hydrogen, halogen, hydroxyl, alkyl, halogenoalkyl, alkoxyalkyl, alkoxy, halogenoalkoxy, alkylthio, halogenoalkylthio, amino, alkylamino or dialkylamino,X stands for nitrogen or a --CH group,Y stands for nitrogen or a --CR.sup.3 group whereR.sup.3 stands for hydrogen, halogen, cyano, alkyl, formyl, alkyl-carbonyl or alkoxy-carbonyl, andZ stands for nitrogen or a --CR.sup.4 group whereR.sup.4 stands for hydrogen, halogen, hydroxyl, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, alkylthio, alkylamino or dialkylaminoand their salts,with the exception of the compounds N'-(4,6-dimethyl-pyrimidin-2-yl)-N"-amino-N'"-(2-diethylaminosulphonyl-phenylsulphonyl)-guanidine, N'-(4,6-dimethyl-pyrimidin-2-yl)-N"-amino-N'"-(2-methoxycarbonyl-phenylsulphonyl)-guanidine and N'-(4,6-dimethyl-pyrimidin-2-yl)-N"-amino-N'"-(2-methoxycarbonyl-thiophen-3-yl-sulphonyl)-guanidine and their salts.
    • 式(I)的除草氨基胍基嗪其中R1代表包含烷基,芳烷基,芳基和杂芳基的系列中任意取代的基团,R 2代表氢,卤素,羟基,烷基,卤代烷基,烷氧基烷基,烷氧基,卤代烷氧基 ,烷硫基,卤代烷硫基,氨基,烷基氨基或二烷基氨基,X表示氮或-CH基,Y表示氮或-CR 3基,其中R3表示氢,卤素,氰基,烷基,甲酰基, 羰基,Z代表氮或-CR 4基团,其中R4代表氢,卤素,羟基,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基氨基或二烷基氨基及其盐,除了化合物N' - (4 ,6-二甲基 - 嘧啶-2-基)-N“ - 氨基-N” - (2-二乙基氨基磺酰基 - 苯基磺酰基) - 胍,N' - (4,6-二甲基 - 嘧啶-2-基) -N' - 氨基-N“ - (2-甲氧基羰基 - 庚基磺酰基) - 胍和N' - (4,6-二甲基 - 嘧啶-2-基)-N” - 氨基-N“ - (2-甲基 - 氧羰基 - 噻吩-3-基 - 磺酰基) - 胍及其盐。