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21. 发明授权

US4369094A Method of preventing the entry of air into the housing of a charging device which conveys coal 失效
标题翻译：防止空气进入输送煤的充电装置的壳体中的方法
公开(公告)号：US4369094A
公开(公告)日：1983-01-18
申请号：US329565
申请日：1981-12-10
申请人： Claus Flockenhaus , Gunter Gabriel , Gunter Ziolkowski, deceased , Paul-Heinz Heesen , Joachim F. Meckel , Manfred Galow
发明人： Claus Flockenhaus , Gunter Gabriel , Gunter Ziolkowski, deceased , Paul-Heinz Heesen , Joachim F. Meckel , Manfred Galow
IPC分类号： C10B31/02 , C10B31/04 , C10B31/00 , C10B41/00
CPC分类号： C10B31/04
摘要： Superheated steam is continuously made to flow through the housing of a device which conveys coal from a bunker to the charging holes of coke ovens. While no charging takes place, the steam is vented from the housing and condensed. When charging does take place, the steam enters the coke oven with the coal, is then discharged from the coke oven, and thereupon condensed. The pressure of the steam in the housing may be greater than ambient atmospheric pressure and/or the pressure of the coking gas in the oven, to reliably prevent the entry of the air and/or the gas into the housing and thus to avoid the formation of dangerous gas mixtures therein.
摘要翻译：过热蒸汽被连续地流过设备的壳体，该设备将煤从煤仓输送到焦化炉的充气孔。当不发生充电时，蒸汽从壳体排出并冷凝。当进行充电时，蒸汽与煤炭一起进入焦炉，然后从焦炉中排出，然后冷凝。壳体中的蒸汽的压力可以大于环境大气压力和/或炉中焦化气体的压力，以可靠地防止空气和/或气体进入壳体并因此避免形成的危险气体混合物。

22. 发明授权

US4950473A Method for reducing nitrogen oxides in flue gas 失效
标题翻译：减少烟气中氮氧化物的方法
公开(公告)号：US4950473A
公开(公告)日：1990-08-21
申请号：US263470
申请日：1988-10-27
申请人： Claus Flockenhaus , Manfred Galow , Klaus Merkel , Hans-Eugen Buhler , Hartmut Kainer
发明人： Claus Flockenhaus , Manfred Galow , Klaus Merkel , Hans-Eugen Buhler , Hartmut Kainer
IPC分类号： B01D53/56 , F23J15/00
CPC分类号： B01D53/56 , F23J15/003 , F23J2215/10
摘要： Apparatus and method for reducing nitrogen oxides in flue gas within a flue gas duct includes a number of distributor tubes for the injection of a reducing agent into the flue gas within the duct. Each distributor tube includes a control valve to be able to set an appropriate injection of the reducing agent to respond to different concentrations of the nitrogen oxides within the flue gas over the cross section of the flue gas duct. Each distributor tube comprises at least two parallel distributor tube segments which extend from opposite sides of the flue gas duct to the center of the flue gas duct. The two parallel distribution tube segments include a plurality of openings along the lengths thereof to supply the reducing agent generally evenly throughout their aligned portions of the cross section. The control valve is employed to adjust the reducing agent to provide the proper quantity thereof which corresponds to the particular concentration of nitrogen oxides within the flue gas at each corresponding portion of the entire cross section.
摘要翻译：用于还原烟气管道内的烟气中的氮氧化物的装置和方法包括用于将还原剂注入管道内的烟道气中的多个分配管。每个分配器管包括一个控制阀，以便能够设定合适的还原剂的注入，以响应烟道气中的氮氧化物在烟道气管道的横截面上的不同浓度。每个分配器管包括至少两个平行的分配器管段，其从烟道气管道的相对侧延伸到烟气管道的中心。两个平行的分配管段包括沿其长度的多个开口，以在整个横截面的整个对齐部分中大致均匀地供给还原剂。使用控制阀来调节还原剂以提供适当的量，这对应于在整个横截面的每个对应部分处的烟道气中氮氧化物的特定浓度。

23. 发明授权

US4433066A Method for the preparation of high-caloric gases, particularly methane, by means of a catalyst fluidized bed 失效
标题翻译：通过催化剂流化床制备高热量气体，特别是甲烷的方法
公开(公告)号：US4433066A
公开(公告)日：1984-02-21
申请号：US340738
申请日：1982-01-19
申请人： Erich Hackler , Claus Flockenhaus , Werner Lommerzheim
发明人： Erich Hackler , Claus Flockenhaus , Werner Lommerzheim
IPC分类号： B01J8/00 , B01J8/28 , C07C1/04
CPC分类号： B01J8/28 , B01J8/006 , C07C1/0485 , B01J2208/0007 , B01J2208/00132 , B01J2208/00141 , B01J2208/00539 , B01J2208/00548
摘要： A method for the production of high-caloric content gases is disclosed wherein feed gases containing CO and H.sub.2 are passed through at least two consecutive catalytic fluidized bed stages having cooling elements wherein, the feed gases being introduced to the first stage under pressure and to the subsequent stages under a pressure which is less than the pressure of the next preceding stage, and the gas produced from each preceding stage is fed to the next stage as a diluting gas. As a result of using the method of the present invention, one can avoid the necessity of compression of the feed gases in the subsequent reaction stages, thereby decreasing the cost as well as the technical difficulties encountered in the process.
摘要翻译：公开了一种用于生产高热量含量气体的方法，其中包含CO和H 2的进料气体通过至少两个具有冷却元件的连续的催化流化床阶段，其中在压力下将进料气体引入第一阶段，在低于下一级的压力的压力下的后续阶段，并且从每个前一级产生的气体作为稀释气体被供给到下一阶段。作为使用本发明的方法的结果，可以避免后续反应阶段中进料气体压缩的必要性，从而降低成本以及在该方法中遇到的技术难题。

24. 发明授权

US4407974A Method of and apparatus for catalytic conversion of gases 失效
标题翻译：催化转化气体的方法和装置
公开(公告)号：US4407974A
公开(公告)日：1983-10-04
申请号：US371265
申请日：1982-04-23
申请人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
发明人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
IPC分类号： B01J8/18 , C07C1/00 , C07C1/04 , C07C9/04 , C07C67/00 , C10K3/04
CPC分类号： C07C1/042 , B01J8/1836 , C07C1/048 , Y02P20/131
摘要： A method of catalytic conversion of feed gases, particularly of a low-sulphur gas mixture rich in carbon monoxide and hydrogen, into a product gas mixture containing methane and/or higher hydrocarbons under high pressure includes the step of removing heat of reaction from the catalytic conversion from a reaction zone by feeding both water and steam to form a cooling medium through a pipe coil in the reaction zone. This forms superheated steam in the pipe coil and the superheated steam is then converted into another form of energy, for example in a turbo-generator. Preferably the reaction zone is a fluidized bed. For carrying out this method a reactor is used, which is preferably a fluidized bed reactor and in this reactor the piping system forming the superheater is disposed in the lower part of the reaction zone. The superheater is connected to a feedwater line and to a steam inlet line and a steam turbine is connected to a steam output line leading from the superheater.
摘要翻译：将含有一氧化碳和氢的低硫气体混合物的进料气体特别是在高压下含有甲烷和/或高级烃的产物气体混合物的催化转化方法包括从催化剂中除去反应热的步骤通过进料水和蒸汽从反应区转化成通过反应区中的管线形成冷却介质。这在管线圈中形成过热蒸汽，然后将过热蒸汽转化成另一形式的能量，例如在涡轮发电机中。优选地，反应区是流化床。为了实施该方法，使用反应器，其优选为流化床反应器，并且在该反应器中，形成过热器的管道系统设置在反应区的下部。过热器连接到给水管线和蒸汽入口管线，蒸汽轮机连接到从过热器引出的蒸汽输出管线。

25. 发明授权

US4352618A Method of, and apparatus for preventing the unintended charging of coke oven chambers 失效
标题翻译：用于防止焦炉室意外充电的方法和装置
公开(公告)号：US4352618A
公开(公告)日：1982-10-05
申请号：US145766
申请日：1980-04-30
申请人： Claus Flockenhaus , Horst Joseph , Joachim Meckel
发明人： Claus Flockenhaus , Horst Joseph , Joachim Meckel
IPC分类号： C10B31/00 , C10B31/04
CPC分类号： C10B41/005 , C10B31/04
摘要： A method and an apparatus are described for preventing the unintentional introduction of coal from a supply into a coke oven which already contains a charge of coal or coke. An obstruction sensor is lowered through a charging hole in the ceiling of the oven; if it encounters an obstruction, such as a charge of coal or coke in the oven, it triggers a signal which blocks any discharge of coal through the charging hole into the oven.
摘要翻译：描述了一种方法和装置，用于防止煤炭从供应中无意地引入已经含有煤或焦炭的焦炉中。阻塞传感器通过烤箱天花板中的充电孔降低; 如果它遇到阻塞物，例如炉子中的煤或焦炭，它会触发一个信号，阻止任何煤气通过充电孔进入烤箱。

26. 发明授权

US4282068A Apparatus for the transfer and quenching of coke 失效
标题翻译：用于焦炭转移和淬火的装置
公开(公告)号：US4282068A
公开(公告)日：1981-08-04
申请号：US108008
申请日：1979-12-28
申请人： Claus Flockenhaus , Manfred Galow , Joachim F. Meckel , Horst G. Joseph
发明人： Claus Flockenhaus , Manfred Galow , Joachim F. Meckel , Horst G. Joseph
IPC分类号： C10B33/00 , C10B39/04 , C10B39/08 , C10B45/00
CPC分类号： C10B33/003
摘要： In the process of transferring coke from a coke oven chamber in a battery of coke ovens to a quenching car, the coke is quenched by a water spray from above. The resulting steam is collected in a hood located above and movable with the quenching car and is either exhausted from the hood and conveyed to a condenser or is condensed in the hood with the condensate being collected, cooled and recirculated to provide the water for the quenching and condensing sprays. The apparatus and method of this invention provides for transferring and quenching the coke without emitting harmful gases and dust to the atmosphere.
摘要翻译：在将焦炭从炼焦炉电炉中的焦炉转移到淬火车的过程中，焦炭通过上面的喷水骤冷。所产生的蒸汽被收集在位于上方并且可以与淬火车一起移动的罩中，并且从发动机罩排出并被输送到冷凝器或在发动机罩中冷凝，冷凝物被收集，冷却和再循环以提供用于淬火的水并凝结喷雾。本发明的装置和方法提供了转移和淬火焦炭，而不会向大气中排放有害气体和灰尘。

27. 发明授权

US4751212A Process for the manufacture of a catalyst for the reduction of nitrogen oxides in exhaust gases 失效
标题翻译：用于制造用于还原废气中的氮氧化物的催化剂的方法
公开(公告)号：US4751212A
公开(公告)日：1988-06-14
申请号：US938525
申请日：1986-12-05
申请人： Claus Flockenhaus , Erich Hackler , Karl H. Laue , Klaus Merkel , Arnold Max , Werner Stender , Johann Jansen , Hartmut Kainer , Daniel Grimm , Blagoje Levkov
发明人： Claus Flockenhaus , Erich Hackler , Karl H. Laue , Klaus Merkel , Arnold Max , Werner Stender , Johann Jansen , Hartmut Kainer , Daniel Grimm , Blagoje Levkov
IPC分类号： B01D53/86 , B01J23/745 , B01J23/74 , B01J27/053 , C01B21/00
CPC分类号： B01J23/745 , B01D53/8628
摘要： The invention relates to a process for the manufacture of a catalyst for the reduction of nitrogen oxides in exhaust gases. The catalyst contains a metal oxide. The catalyst is preferably used for catalytic reduction with ammonia. The process comprises screening a natural goethite iron ore to the required grain size and then treating the ore with sulfuric acid. Subsequently, the goethite iron ore is heated to a temperature which approximately equals the temperature at which it will be used in the catalytic reaction.
摘要翻译：本发明涉及制备用于还原废气中的氮氧化物的催化剂的方法。催化剂含有金属氧化物。该催化剂优选用于用氨催化还原。该方法包括将天然针铁矿铁矿筛选成所需的粒度，然后用硫酸处理矿石。随后，将针铁矿铁矿石加热到与催化反应中使用的温度大致相等的温度。

28. 发明授权

US4539016A Method of and apparatus for adjusting and maintaining constant the temperature during methanizing of a charge gas 失效
标题翻译：用于调节和维持充电气体甲烷化期间温度恒定的方法和装置
公开(公告)号：US4539016A
公开(公告)日：1985-09-03
申请号：US257352
申请日：1981-04-24
申请人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
发明人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
IPC分类号： C10K3/02 , B01J8/18 , C07C1/04 , C10K3/04
CPC分类号： B01J8/1836 , C07C1/048 , B01J2208/00132 , B01J2208/00256 , B01J2208/00274
摘要： In methanizing CO and H.sub.2 containing charge gases, the charge gas is passed upwardly through a vertically extending fluidized bed reactor flowing, in turn, through a fluidized bed zone, a dust bed zone and a separation zone. From the separation zone, the gas is conveyed out of the reactor to a point of use. Coolant tubes are positioned in the reactor passing vertically through the fluidized bed zone, the dust bed zone and the separation zone for removing the heat generated in the reaction. An evaporable coolant, preferably water, is circulated through the coolant tubes. In a separate steam drum, the vapor pressure of the coolant is set for maintaining constant the temperature of the vaporizing coolant.
摘要翻译：在甲烷化含CO和H 2的充电气体中，充电气体向上通过一个垂直延伸的流化床反应器，反应器又流过流化床区域，灰尘床区域和分离区域。从分离区，将气体从反应器输送到使用点。冷却剂管定位在反应器中垂直通过流化床区域，灰尘床区域和分离区域，以除去反应中产生的热量。可蒸发的冷却剂，优选水，循环通过冷却剂管。在单独的蒸汽鼓中，设置冷却剂的蒸汽压力以保持汽化冷却剂的温度恒定。

29. 发明授权

US4258006A Apparatus for fluid catalytic conversion of gases 失效
标题翻译：用于流体催化转化气体的装置
公开(公告)号：US4258006A
公开(公告)日：1981-03-24
申请号：US59522
申请日：1979-07-23
申请人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
发明人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
IPC分类号： B01J8/18 , C07C1/00 , C07C1/04 , C07C9/04 , C07C67/00 , C10K3/04 , B01J8/24
CPC分类号： C07C1/042 , B01J8/1836 , C07C1/048 , Y02P20/131
摘要： A method of catalytic conversion of feed gases, particularly of a low-sulphur gas mixture rich in carbon monoxide and hydrogen, into a product gas mixture containing methane and/or higher hydrocarbons under high pressure includes the step of removing heat of reaction from the catalytic conversion from a reaction zone by feeding both water and steam to form a cooling medium through a pipe coil in the reaction zone. This forms superheated steam in the pipe coil and the superheated steam is then converted into another form of energy, for example in a turbo-generator. Preferably the reaction zone is a fluidized bed. The apparatus for carrying out this method comprises a reactor, which is preferably a fluidized bed reactor and in this reactor the piping system forming the superheater is disposed in the lower part of the reaction zone. The superheater is connected to a feedwater line and to a steam inlet line and a steam turbine is connected to a steam output line leading from the superheater.
摘要翻译：将含有一氧化碳和氢的低硫气体混合物的进料气体特别是在高压下含有甲烷和/或高级烃的产物气体混合物的催化转化方法包括从催化剂中除去反应热的步骤通过进料水和蒸汽从反应区转化成通过反应区中的管线形成冷却介质。这在管线圈中形成过热蒸汽，然后将过热蒸汽转化成另一形式的能量，例如在涡轮发电机中。优选地，反应区是流化床。用于实施该方法的装置包括反应器，其优选为流化床反应器，并且在该反应器中，形成过热器的管道系统设置在反应区的下部。过热器连接到给水管线和蒸汽入口管线，蒸汽轮机连接到从过热器引出的蒸汽输出管线。

30. 发明授权

US4178150A Process and installation for drying and heating coal 失效
标题翻译：干燥加热煤的加工和安装
公开(公告)号：US4178150A
公开(公告)日：1979-12-11
申请号：US863795
申请日：1977-12-23
申请人： Claus Flockenhaus , Horst Fach , Gunter Gabriel , Manfred Galow , Joachim Meckel
发明人： Claus Flockenhaus , Horst Fach , Gunter Gabriel , Manfred Galow , Joachim Meckel
IPC分类号： C10B57/10 , C10B57/08 , C10F5/00 , C10L9/08 , F26B17/10 , F27B15/00
CPC分类号： C10B57/08
摘要： Coal is passed in a two-stage process through a drying and heating zone. The coal coming from the drying zone is separated from the heat carrier gas which is then passed into the atmosphere after going through an electrodust separator. The dried coal is delivered into the heating zone. The hot gas for the heating zone is furnished by a combustion device. The exhaust gas from the heating zone is separated from the heated coal which is recovered while the exhaust gas is passed back into the drying zone. Part of the hot combustion gas coming from the combustion chamber is branched off and passed into the exhaust gas coming out of the drying zone either directly behind the drying zone or behind the separator for separating the dried coal from the exhaust gas. The temperature of the exhaust gas from the drying zone is thus prevented from sinking below the sulfuric acid dewpoint or water vapor dewpoint which might result in corrosive damage to the apparatus, particularly to the electrodust separator.
摘要翻译：煤通过干燥和加热区在两阶段过程中通过。来自干燥区的煤与热载体分离，然后通过电极分离器后将其通入大气中。干燥的煤被输送到加热区。加热区的热气由燃烧装置提供。来自加热区域的废气与废气再次返回到干燥区域中被回收的加热煤分离。来自燃烧室的热燃烧气体的一部分被分支并且从干燥区域直接排出干燥区域的废气或分离器之后的废气中，从而将干燥的煤与废气分离。因此，防止来自干燥区域的废气的温度低于硫酸露点或水蒸气露点，这可能导致对设备，特别是电极分离器的腐蚀性损坏。

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