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    • 25. 发明授权
    • Polymers containing polyene-based second-order nonlinear optical chromophores and devices incorporating the same
    • 含有多烯基二级非线性光学发色团的聚合物和包含其的装置
    • US06652779B1
    • 2003-11-25
    • US09679937
    • 2000-10-05
    • Cheng ZhangHarold R. FettermanWilliam SteierJoseph Michael
    • Cheng ZhangHarold R. FettermanWilliam SteierJoseph Michael
    • F21V900
    • C08K5/0041C09B23/0066C09B23/0075C09B23/0091C09B23/145G02F1/065G02F1/225G02F1/3611G02F1/3612G02F1/3613G02F1/3614G02F1/3615G02F1/3617G02F2001/212
    • Polymers containing polyene-bridged second-order nonlinear optical chromophores and devices incorporating the same are disclosed. The chromophores are functionalized and incorporated into a series of polymers ranging from linear polyesters, linear poly[ester-imide]s, chain-crosslinked polyesters/poly[ester-imide]s, to crosslinked star-shaped/dendritic macromolecules. An exemplary preferred polymer is a linear chain polymer formed from a dihydroxy-functionalized polyene-bridged chromophore, a diacid or diacid dichloride, and a diol. In a preferred embodiment, the diol structure also includes at least one imide group. Another exemplary preferred polymer is a crosslinked polymer comprised of a linear chain polymer formed from a dihydroxy-functionalized polyene-bridged chromophore, a diacid or diacid dichloride and a diol. The crosslinking is realized by thermally induced cyclolization of trifluorovinylethers which are attached to the diol co-monomer and/or chromophore in the linear chain polymer chain. In a preferred embodiment, the diol structure also includes at least one imide group. Another exemplary preferred polymer is a crosslinked polymer made from crosslinkable star-shaped high molecular weight (larger than 2,000) structure containing polyene-bridged chromophores. In a preferred embodiment, the crosslinking groups are multiple trifluorovinylether groups located at the periphery of the star-shaped structure. Another exemplary preferred polymer is a crosslinked polymer made from crosslinkable dendritic structure having a chromophore core and one or more dendrons. In a preferred embodiment, the crosslinking groups are multiple trifluorovinylether groups located at the periphery of the dendritic structure.
    • 公开了含有多烯桥接二级非线性光学发色团的聚合物和结合其的装置。 发色团被官能化并且并入一系列聚合物中,从线性聚酯,线性聚[酯 - 酰亚胺],链交联聚酯/聚[酯 - 酰亚胺]到交联的星形/树枝状大分子。 示例性的优选聚合物是由二羟基官能化的多烯桥接发色团,二酸或二酰氯和二醇形成的线性链聚合物。 在优选的实施方案中,二醇结构还包括至少一个酰亚胺基团。 另一个优选的优选聚合物是由二羟基官能化的多烯桥接发色团,二酸或二酰氯和二醇形成的直链聚合物组成的交联聚合物。 通过在线性链聚合物链中连接到二醇共聚单体和/或发色团上的三氟乙烯基的热诱导环化来实现交联。 在优选的实施方案中,二醇结构还包括至少一个酰亚胺基团。 另一个典型的优选聚合物是由含有多烯桥接的发色团的可交联的星形高分子量(大于2,000)结构制成的交联聚合物。 在优选的实施方案中,交联基团是位于星形结构周边的多个三氟乙烯基基团。 另一个示例性的优选聚合物是由具有发色团核心和一个或多个树枝状结构的可交联树枝状结构制成的交联聚合物。 在优选的实施方案中,交联基团是位于树枝状结构周边的多个三氟乙烯基醚基团。
    • 26. 发明授权
    • Organohybrid-based damping material, method for producing the same, and method for damping using the same
    • 有机混合阻尼材料及其制造方法以及使用其的阻尼方法
    • US06566431B1
    • 2003-05-20
    • US09668351
    • 2000-09-25
    • Cheng ZhangTadashi MiuraMasao Sumita
    • Cheng ZhangTadashi MiuraMasao Sumita
    • C08K513
    • C08K5/13
    • The present invention provides a damping composite material, exhibiting more stable and functional damping effects than the conventional one based on the viscous or frictional mechanism to convert mechanical vibrational energy into thermal energy, and also provide a method for producing the same. The damping material of the present invention comprises at least a material showing piezoelectric, dielectric and electroconductive effects, and an organic polymer matrix material, wherein the material showing piezoelectric, dielectric and electroconductive effects is a compound containing a phenolic group, and the method of the present invention for producing the damping material comprises two steps, one uniformly mixing the material showing piezoelectric, dielectric and electroconductive effects with the organic polymer matrix material at normal temperature or higher, and the other forming the mixture by pressing or drawing at high temperature. The materials showing piezoelectric, dielectric and electroconductive effects, and useful for the present invention, include 4,4′-thio-bis(3-methyl-6-tertiary butylphenol) and 2,2′-methylene-bis(4-ethyl-6-tertiary butylphenol), and the organic polymer matrix materials useful for the present invention include polyurethane and acrylic rubber. The damping material of the present invention may be formed into sheet, fiber or expanded shapes, which may be laminated or composited.
    • 本发明提供了一种阻尼复合材料,其表现出比常规的阻尼复合材料更为稳定和功能的阻尼效果,其基于将机械振动能转换成热能的粘性或摩擦机理,并且还提供了制造该阻尼复合材料的阻尼材料。 本发明至少包括显示压电,电介质和导电效应的材料和有机聚合物基质材料,其中显示压电,电介质和导电效应的材料是含有酚基的化合物,以及本发明的制备方法 阻尼材料包括两个步骤,一个在常温或更高温度下均匀混合显示压电,电介质和导电效应的材料与有机聚合物基体材料,另一个通过在高温下压制或拉伸而形成混合物。显示压电, 电介质a 对于本发明有用的导电效果包括4,4'-硫代 - 双(3​​-甲基-6-叔丁基苯酚)和2,2'-亚甲基 - 双(4-乙基-6-叔丁基苯酚), 并且可用于本发明的有机聚合物基质材料包括聚氨酯和丙烯酸橡胶。本发明的阻尼材料可以形成为片材,纤维或膨胀形状,其可以层压或复合。