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21. 发明授权

US06465589B2 Paint composition 失效
标题翻译：油漆组成
公开(公告)号：US06465589B2
公开(公告)日：2002-10-15
申请号：US09726446
申请日：2000-12-01
申请人： Hiroshi Inukai , Eiichi Okazaki , Kunihiko Mizutani , Akihito Iida
发明人： Hiroshi Inukai , Eiichi Okazaki , Kunihiko Mizutani , Akihito Iida
IPC分类号： C08L3700
CPC分类号： C09D133/062 , C08F220/14 , C08F220/18 , C09D143/04 , C08F2220/1825 , C08F2220/281 , C08F220/06 , C08F220/36 , C08F2222/404 , C08F230/08 , C08F222/40 , C08F220/28
摘要： A paint composition is provided, which comprises a copolymer comprising the following constitutional units (A), (B), and (C) as essential components: (A) a (meth)acrylate monomer unit having a straight-chain, branched-chain, or cyclic alkyl group; (B) at least one monomer unit selected from the group consisting of a monomer unit having an unsaturated double bond and a hydroxyalkyl group, a monomer unit having an unsaturated double bond and an epoxy group, and a monomer unit having an unsaturated double bond and an alkoxysilyl group; and (C) a monomer unit having an unsaturated double bond and a maleimide group. The paint composition is excellent in weatherability and coating gloss. The composition may be contained in an organic solvent such as cyclic ethers, aromatic hydrocarbons, esters, and ketones. The organic solvent may be one that comprises 40% or more of a saturated hydrocarbon. In this case, it is preferred that a (meth)acrylic ester monomer having an alkyl group of 8 to 20 carbon atoms accounts for 5 to 50% by weight of the total amount of the constitutional units of the copolymer.
摘要翻译：提供了一种涂料组合物，其包含作为必要组分的包含以下结构单元（A），（B）和（C）的共聚物：（A）具有直链，支链的（甲基）丙烯酸酯单体单元或环状烷基; （B）选自由具有不饱和双键和羟烷基的单体单元，具有不饱和双键的单体单元和环氧基组成的组中的至少一种单体单元和具有不饱和双键的单体单元和烷氧基甲硅烷基; 和（C）具有不饱和双键和马来酰亚胺基团的单体单元。涂料组合物的耐候性和涂料光泽性优异。组合物可以包含在有机溶剂如环醚，芳烃，酯和酮中。有机溶剂可以是含有40％以上饱和烃的溶剂。在这种情况下，优选碳原子数为8〜20的（甲基）丙烯酸酯单体占共聚物的结构单元总量的5〜50重量％。

22. 发明授权

US09403990B2 Curing-type coating-agent composition 有权
标题翻译：固化型包衣剂组合物
公开(公告)号：US09403990B2
公开(公告)日：2016-08-02
申请号：US14343323
申请日：2012-08-27
申请人： Hiroaki Takashima , Kyoko Kumagai , Hidetaka Hayashi , Tetsuya Mitsuoka , Naoharu Ueda , Hisashi Muramatsu , Kazumasa Inata , Takeshi Fujita , Yasuyuki Sanai , Eiichi Okazaki , Satoshi Yoneda , Naomasa Furuta
发明人： Hiroaki Takashima , Kyoko Kumagai , Hidetaka Hayashi , Tetsuya Mitsuoka , Naoharu Ueda , Hisashi Muramatsu , Kazumasa Inata , Takeshi Fujita , Yasuyuki Sanai , Eiichi Okazaki , Satoshi Yoneda , Naomasa Furuta
IPC分类号： C09D4/00 , C09D7/12 , C08G18/67 , C08G18/79 , C08F290/06 , C09D175/16 , C08K9/06
CPC分类号： C09D4/00 , C08F290/067 , C08G18/672 , C08G18/673 , C08G18/792 , C08K9/06 , C09D7/63 , C09D175/16
摘要： A curing-type coating-agent composition according to the present invention contains: Component (A) (e.g., an isocyanuric ring-containing urethane (meth)acrylate compound) in an amount of from 20 to 80 parts by mass; Component (B) (e.g., an isocyanuric ring-containing tri(meth)acrylate compound free from any urethane bond) in an amount of from 10 to 70 parts by mass; Component (C-1) (e.g., a reaction compound between a colloidal silica and an alkoxysilane compound having a maleimide group) in amount of from 1 to 35 parts by mass, or Component (C-2) (e.g., a specific organosilicon compound) in an amount of from 5 to 35 parts by mass; a radical-polymerization initiator serving as Component (D) in an amount of from 0.1 to 10 parts by mass; an ultraviolet absorber serving as Component (E) in an amount of from 1 to 12 parts by mass; and an organic solvent serving as Component (F) in an amount of from 10 to 1,000 parts by mass; with respect to a sum of the Component (A), the Component (B), and the Component (C-1) or the Component (C-2) being taken as 100 parts by mass. The aforementioned composition demonstrates excellent wear resistance and weatherability as a coating agent for plastic substrate, or the like, which is employed outside.
摘要翻译：本发明的固化型涂布剂组合物含有20〜80质量份的成分（A）（例如异氰脲酸环的氨基甲酸酯（甲基）丙烯酸酯化合物））; 组分（B）（例如，不含任何氨基甲酸酯键的含异氰脲酸酯的三（甲基）丙烯酸酯化合物）的量为10〜70质量份; 组分（C-1）（例如，胶体二氧化硅和具有马来酰亚胺基团的烷氧基硅烷化合物之间的反应化合物）为1〜35质量份，或成分（C-2）（例如，特定的有机硅化合物）为5〜35质量份; 作为组分（D）的自由基聚合引发剂的量为0.1至10质量份; 作为组分（E）的紫外线吸收剂的量为1至12质量份; 和作为成分（F）的有机溶剂的量为10〜1000质量份; 相对于成分（A），成分（B）和成分（C-1）或成分（C-2）的合计为100质量份。上述组合物表现出作为外部使用的塑料基材等的涂布剂的优异的耐磨性和耐候性。

23. 发明申请

US20150044477A1 MEMBER FOR VEHICLE AND MANUFACTURING PROCESS FOR THE SAME 有权
标题翻译：车辆及其制造工艺的成员
公开(公告)号：US20150044477A1
公开(公告)日：2015-02-12
申请号：US14343336
申请日：2012-08-27
申请人： Hiroaki Takashima , Kyoko Kumagai , Hidetaka Hayashi , Tetsuya Mitsuoka , Naoharu Ueda , Hisashi Muramatsu , Kazumasa Inata , Takeshi Fujita , Yasuyuki Sanai , Eiichi Okazaki , Satoshi Yoneda , Naomasa Furuta
发明人： Hiroaki Takashima , Kyoko Kumagai , Hidetaka Hayashi , Tetsuya Mitsuoka , Naoharu Ueda , Hisashi Muramatsu , Kazumasa Inata , Takeshi Fujita , Yasuyuki Sanai , Eiichi Okazaki , Satoshi Yoneda , Naomasa Furuta
IPC分类号： C09D133/14 , C08K5/3492
CPC分类号： C09D133/14 , C08J3/243 , C08J7/045 , C08J2433/06 , C08J2475/16 , C08J2483/02 , C08K5/3492 , Y10T428/31547
摘要： A member for vehicle according to the present invention includes a resinous substrate, and a protective film being formed on a surface of the resinous substrate partially at least. The protective film is made by curing a curing-type coating-agent composition containing: Component (A) (e.g., an isocyanuric ring-containing urethane(meth)acrylate compound) in an amount of from 20 to 80 parts by mass; Component (B) (e.g., anisocyanuricring-containing urethane(meth)acrylate compound free from any urethane bond) in an amount of from 10 to 70 parts by mass; Component (C) including a specific organosilicon compound in an amount of from 5 to 35 parts by mass; a radical-polymerization initiator serving as Component (D) in an amount of from 0.1 to 10 parts by mass; an ultraviolet absorber serving as Component (E) in an amount of from 1 to 12 parts by mass; and an organic solvent serving as Component (F) in an amount of from 10 to 1,000 parts by mass; with respect to a sum of the Component (A), the Component (B), and the Component (C) being taken as 100 parts by mass. Said protective film demonstrates excellent wear resistance and weatherability.
摘要翻译：根据本发明的车辆用部件包括树脂基板和至少部分地形成在树脂基板的表面上的保护膜。保护膜通过固化含有20〜80质量份的组分（A）（例如，含异氰脲酸酯环的氨基甲酸酯（甲基）丙烯酸酯化合物））的固化型包衣剂组合物来制备; 组分（B）（例如不含任何氨基甲酸酯键的含异氰脲酸酯的氨基甲酸酯（甲基）丙烯酸酯化合物）的量为10〜70质量份; 含有5〜35质量份的特定有机硅化合物的成分（C）作为组分（D）的自由基聚合引发剂的量为0.1至10质量份; 作为组分（E）的紫外线吸收剂的量为1至12质量份; 和作为成分（F）的有机溶剂的量为10〜1000质量份; 相对于成分（A），成分（B）和成分（C）的总和为100质量份。所述保护膜具有优异的耐磨性和耐候性。

24. 发明授权

US08900712B2 Member for vehicle and manufacturing process for the same 有权
标题翻译：车辆和制造工艺的成员也是一样的
公开(公告)号：US08900712B2
公开(公告)日：2014-12-02
申请号：US13697159
申请日：2011-05-24
申请人： Tetsuya Mitsuoka , Toshihisa Shimo , Kyoko Kumagai , Hidetaka Hayashi , Hiroaki Takashima , Naoharu Ueda , Kazumasa Inata , Takeshi Fujita , Yasuyuki Sanai , Eiichi Okazaki , Satoshi Yoneda
发明人： Tetsuya Mitsuoka , Toshihisa Shimo , Kyoko Kumagai , Hidetaka Hayashi , Hiroaki Takashima , Naoharu Ueda , Kazumasa Inata , Takeshi Fujita , Yasuyuki Sanai , Eiichi Okazaki , Satoshi Yoneda
IPC分类号： B32B27/40 , C09D133/14 , C09D133/04
CPC分类号： C09D133/14 , C08G18/672 , C08G18/673 , C08G18/755 , C08J7/047 , C08J2369/00 , C08J2475/16 , C08K9/06 , C09D4/00 , C09D139/04 , Y10T428/31547 , Y10T428/31551
摘要： A member for vehicle according to the present invention is equipped with a resinous substrate, and a protective film being formed on a surface of the resinous substrate partially at least. The protective film is made by curing a curing-type coating-agent composition that includes: Component (A) including a urethane adduct compound exhibiting weatherability in an amount of from 99 to 65 parts by mass; Component (B) comprising a reaction product between a colloidal silica and an alkoxysilane compound having a maleimide group in an amount of from 1 to 35 parts by mass; a radical-polymerization initiator serving as Component (C) in an amount of from 0.1 to 10 parts by mass; an ultraviolet absorber serving as Component (D) in an amount of from 1 to 12 parts by mass; and an organic solvent serving as Component (E) in an amount of from 10 to 1,000 parts by mass; with respect to a sum of Component (A) and Component (B) being taken as 100 parts by mass. The member for vehicle according to the present invention exhibits excellent wear resistance and weatherability.
摘要翻译：根据本发明的车辆用部件配备有树脂基板，并且至少部分地形成在树脂基板的表面上的保护膜。保护膜是通过固化固化型涂布剂组合物制成的，该组合物包括：包含99至65质量份耐候性的氨基甲酸酯加合物的组分（A）组分（B）包含胶体二氧化硅和马来酰亚胺基团的烷氧基硅烷化合物之间的反应产物，其量为1〜35质量份; 作为组分（C）的自由基聚合引发剂的量为0.1至10质量份; 用作组分（D）的紫外线吸收剂的量为1至12质量份; 和作为组分（E）的有机溶剂的量为10至1,000质量份; 相对于成分（A）和成分（B）的总和为100质量份。根据本发明的车辆用构件表现出优异的耐磨性和耐候性。

25. 发明授权

US08642178B2 Vehicle member and process for producing the same 有权
标题翻译：车辆及其制造方法
公开(公告)号：US08642178B2
公开(公告)日：2014-02-04
申请号：US13502911
申请日：2010-10-13
申请人： Tetsuya Mitsuoka , Hidetaka Hayashi , Toshihisa Shimo , Kyoko Kumagai , Naoharu Ueda , Kazumasa Inata , Takeshi Fujita , Yasuyuki Sanai , Eiichi Okazaki , Hiroshi Suzuki , Naomasa Furuta
发明人： Tetsuya Mitsuoka , Hidetaka Hayashi , Toshihisa Shimo , Kyoko Kumagai , Naoharu Ueda , Kazumasa Inata , Takeshi Fujita , Yasuyuki Sanai , Eiichi Okazaki , Hiroshi Suzuki , Naomasa Furuta
IPC分类号： B32B27/40 , B32B27/30 , C08J7/04
CPC分类号： B60J1/2094 , C08F2230/085 , C08G18/673 , C08G18/8175 , C08G77/20 , C09D175/16 , C09D183/06 , Y10T428/31547 , Y10T428/31663
摘要： Disclosed is a vehicle member comprising a resin substrate and a protective film formed on at least a part of the surface of the resin substrate. The protective film is produced by curing a curable coating agent composition, wherein the curable coating agent composition comprises 95 to 65 parts by mass of a component (A) comprising an urethane adduct compound having weather resistance, 5 to 35 parts by mass of a component (B) comprising a specific organosilicon compound, 0.1 to 10 parts by mass of a component (C) which is a radical polymerization initiator, 1 to 12 parts by mass of a component (D) which is an ultraviolet ray absorber, and 10 to 1,000 parts by mass of a component (E) which is an organic solvent, with respect to 100 parts by mass of the components (A) and (B) in total.
摘要翻译：公开了一种车辆构件，其包括树脂基板和形成在树脂基板的表面的至少一部分上的保护膜。保护膜是通过固化可固化涂层剂组合物而制备的，其中可固化涂层剂组合物包含95至65质量份包含耐候性的氨基甲酸酯加合物的组分（A），5-35质量份的组分（B）含有特定的有机硅化合物，0.1〜10质量份作为自由基聚合引发剂的成分（C），1〜12质量份作为紫外线吸收剂的成分（D），10〜相对于100质量份的（A）成分和（B）成分，作为有机溶剂的成分（E）1000质量份。

26. 发明申请

US20120244361A1 VEHICLE MEMBER AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：车辆会员及其制造方法
公开(公告)号：US20120244361A1
公开(公告)日：2012-09-27
申请号：US13502911
申请日：2010-10-13
申请人： Tetsuya Mitsuoka , Hidetaka Hayashi , Toshihisa Shimo , Kyoko Kumagai , Naoharu Ueda , Kazumasa Inata , Takeshi Fujita , Yasuyuki Sanai , Eiichi Okazaki , Hiroshi Suzuki , Naomasa Furuta
发明人： Tetsuya Mitsuoka , Hidetaka Hayashi , Toshihisa Shimo , Kyoko Kumagai , Naoharu Ueda , Kazumasa Inata , Takeshi Fujita , Yasuyuki Sanai , Eiichi Okazaki , Hiroshi Suzuki , Naomasa Furuta
IPC分类号： B32B27/40 , C08F2/50 , C08J7/04
CPC分类号： B60J1/2094 , C08F2230/085 , C08G18/673 , C08G18/8175 , C08G77/20 , C09D175/16 , C09D183/06 , Y10T428/31547 , Y10T428/31663
摘要： Disclosed is a vehicle member comprising a resin substrate and a protective film formed on at least a part of the surface of the resin substrate. The protective film is produced by curing a curable coating agent composition, wherein the curable coating agent composition comprises 95 to 65 parts by mass of a component (A) comprising an urethane adduct compound having weather resistance, 5 to 35 parts by mass of a component (B) comprising a specific organosilicon compound, 0.1 to 10 parts by mass of a component (C) which is a radical polymerization initiator, 1 to 12 parts by mass of a component (D) which is an ultraviolet ray absorber, and 10 to 1,000 parts by mass of a component (E) which is an organic solvent, with respect to 100 parts by mass of the components (A) and (B) in total.
摘要翻译：公开了一种车辆构件，其包括树脂基板和形成在树脂基板的表面的至少一部分上的保护膜。保护膜是通过固化可固化涂层剂组合物而制备的，其中可固化涂层剂组合物包含95至65质量份包含耐候性的氨基甲酸酯加合物的组分（A），5-35质量份的组分（B）含有特定的有机硅化合物，0.1〜10质量份作为自由基聚合引发剂的成分（C），1〜12质量份作为紫外线吸收剂的成分（D），10〜相对于100质量份的（A）成分和（B）成分，作为有机溶剂的成分（E）1000质量份。

27. 发明申请

US20110319582A1 CURABLE COMPOSITION COMPRISING INORGANIC OXIDE MICROPARTICLES THAT ARE SURFACE-MODIFIED WITH MALEIMIDE GROUPS 有权
标题翻译：包含用马来酰亚胺基团修饰的无机氧化物微生物的可固化组合物
公开(公告)号：US20110319582A1
公开(公告)日：2011-12-29
申请号：US13139200
申请日：2009-12-11
申请人： Kazumasa Inata , Eiichi Okazaki
发明人： Kazumasa Inata , Eiichi Okazaki
IPC分类号： C08F222/40 , B32B3/00 , C07F7/18
CPC分类号： G02B1/14 , C08F283/12 , C08F290/06 , C08F290/062 , C08F290/068 , C08F292/00 , C08G73/12 , C08G73/125 , C08K3/22 , C08K9/06 , C08L51/10 , C09D7/62 , C09D7/67 , C09D7/68 , G02B1/10 , Y10T428/2982 , C08L2666/02 , C08F222/1006 , C08L71/02
摘要： To provide a curable composition that has excellent smoothness when a plastic substrate is coated therewith and dried, causes hardly any warp after curing or swarf when cutting, and has excellent scratch resistance, transparency, adhesion, and UV resistance and, furthermore, to provide an active energy beam-curable composition that can be cured without using a photopolymerization initiator or with the use of a small amount thereof.A curable composition containing a reaction product (A) obtained by reacting an alkoxysilane compound (a1) represented by Formula (1) below and inorganic oxide microparticles (a2) in the presence of water and an organic solvent. (P—SiO3/2)1-a(P—Si(R0)O2/2)a(O1/2R3)z (1) In Formula (1), P denotes a maleimide-containing group, R3 denotes a hydrogen atom or a monovalent organic group, R0 denotes a monovalent organic group, a is 0 or a positive number and satisfies 0≦a
摘要翻译：为了提供一种在将塑料基材涂布并干燥时具有优异的平滑性的固化性组合物，在切割时固化或切割后几乎不发生翘曲，并且具有优异的耐刮擦性，透明性，粘合性和耐紫外线性，并且还提供活性能量束固化性组合物，其可以在不使用光聚合引发剂的情况下固化，也可以少量使用。一种含有在水和有机溶剂的存在下使由下式（1）表示的烷氧基硅烷化合物（a1）和无机氧化物微粒（a2）反应得到的反应产物（A）的固化性组合物。（P-SiO 3/2）1-a（P-Si（R 0）O 2/2）a（O 1 / 2R 3）z（1）在式（1）中，P表示含马来酰亚胺的基团，R3表示氢原子或一价有机基团，R 0表示一价有机基团，a为0或正数，满足0＆nlE; a <1，z为正数，满足0.1＆nlE; z＆nlE; 2。

28. 发明授权

US07399574B2 Curable resin for photo-patterning, process for producing the same, curable resin composition, color filter, liquid crystal panel substrate, and liquid crystal panel 有权
标题翻译：光刻图案用固化树脂，其制造方法，固化性树脂组合物，滤色器，液晶面板基板，液晶面板
公开(公告)号：US07399574B2
公开(公告)日：2008-07-15
申请号：US10255353
申请日：2002-09-26
申请人： Shinji Hayashi , Shunsuke Sega , Hiromu Taguchi , Mitsutaka Hasegawa , Eiichi Okazaki , Keiji Maeda
发明人： Shinji Hayashi , Shunsuke Sega , Hiromu Taguchi , Mitsutaka Hasegawa , Eiichi Okazaki , Keiji Maeda
IPC分类号： G03C1/73 , G03F7/027
CPC分类号： G03F7/0388 , G02F1/133514 , G02F1/13394 , G03F7/0007 , G03F7/033 , Y10T428/1036 , Y10T428/1059
摘要： Provided are a curable resin and a curable resin composition which have alkali-solubility and curability that can freely be adjusted and a high sensitivity, a liquid crystal panel substrate which can maintain an even cell gap, and a liquid crystal panel using the liquid crystal panel substrate to exhibit a superior display quality. A curable resin composition comprising an imide-containing copolymer having a molecular structure wherein a constitutional unit at least the following units are connected: a constitutional unit having a cyclic imide group represented by the formula (1), a constitutional unit having an acid functional group such as a carboxyl group; and a constitutional unit having a photopolymerizing functional group. In a liquid crystal panel substrate (color filter 103), plural spacers (column-shaped spacers 12) are disposed in a non-display region on a substrate 5.
摘要翻译：提供一种可以自由调节和高灵敏度的碱溶性和固化性的可固化树脂和固化性树脂组合物，能够保持均匀单元间隙的液晶面板基板和使用液晶面板的液晶面板底物显示出优异的显示质量。一种包含具有分子结构的含酰亚胺共聚物的固化性树脂组合物，其中至少具有以下单元的结构单元连接：具有式（1）表示的环状酰亚胺基的结构单元，具有酸官能团的结构单元如羧基; 和具有光聚合官能团的结构单元。在液晶面板基板（彩色滤光片103）中，在基板5的非显示区域配置多个间隔物（柱状间隔物12）。

29. 发明授权

US06329443B1 Acrylates and actinic radiation-curable compositions containing them 有权
标题翻译：含有它们的丙烯酸酯和光化辐射固化组合物
公开(公告)号：US06329443B1
公开(公告)日：2001-12-11
申请号：US09446370
申请日：1999-12-20
申请人： Eiichi Okazaki , Tetsuji Jitsumatsu
发明人： Eiichi Okazaki , Tetsuji Jitsumatsu
IPC分类号： C08F246
CPC分类号： C07D209/48 , C08F20/36 , C09D4/00 , C08F220/36
摘要： New imido(meth) acrylates of general formula (1), wherein R1, R2 and R3 may be the same or different and each represents H or CH3; R4 to R7 may be the same or different and each represents H or CmH2m+1 (in which m is 1 to 6); and n represents 1 to 4, and radiation-curable compositions prepared from them, easily cured by the irradiation with radiations, particularly ultraviolet rays, to form cured compositions excellent in weather resistance, abrasion resistance and adhesion to a base, and free from the problem of odor.
摘要翻译：新的通式（1）的酰亚胺基（甲基）丙烯酸酯，其中R 1，R 2和R 3可以相同或不同，各自表示H或CH 3; R 4至R 7可以相同或不同，各自表示H或C m H 2n + 1（其中m为1至6）; n表示1〜4，由它们制备的可辐射固化组合物通过辐射特别是紫外线照射容易固化，以形成耐候性，耐磨性和与基材的粘附性优异的固化组合物，并且不存在问题的气味

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