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21. 发明授权

US4720376A Process for the removal of nitrogen oxides and soot from exhaust gases of machines and combustion installations burning heavy fuel oil 失效
标题翻译：从燃烧重型燃油的机器和燃烧设备的废气中除去氮氧化物和烟灰的过程
公开(公告)号：US4720376A
公开(公告)日：1988-01-19
申请号：US860306
申请日：1986-05-06
申请人： Karl H. Laue , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein , Hans-Eugen Buhler
发明人： Karl H. Laue , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein , Hans-Eugen Buhler
IPC分类号： B01D53/86 , B01D53/94 , F01N3/02 , F01N3/023 , F01N3/20 , F01N3/28 , B01J37/00
CPC分类号： F01N3/36 , B01D53/8625 , B01D53/8646 , B01D53/9409 , F01N3/02 , F01N3/0205 , F01N3/0231 , F01N3/2066 , F01N3/2882 , F01N2610/02 , F01N2610/14 , Y02T10/24
摘要： A process for the removal of nitrogen oxides and soot from exhaust gases from machines and combustion installations burning heavy fuel oil by means of free-passage catalysts at increased temperatures with the addition of ammonia into the exhaust gas stream ahead of the catalysts. To make the process mre effective, the soot adhering to the catalyst surfaces is removed by burning it off and/or by friction resulting from the admixture of sand, ash or similar abrasive mixtures into the exhaust gas stream ahead of the catalysts.
摘要翻译：一种用于从机器和燃烧装置的废气中除去氮氧化物和烟灰的方法，通过在升高的温度下通过自由通道催化剂燃烧重质燃料燃料，在催化剂之前的排气流中加入氨。为了使该方法有效，粘附到催化剂表面上的烟灰通过将其从脱硫和/或由砂，灰或类似的研磨混合物混合物引起的摩擦物排出到催化剂前面的排气流中来除去。

22. 发明授权

US4433066A Method for the preparation of high-caloric gases, particularly methane, by means of a catalyst fluidized bed 失效
标题翻译：通过催化剂流化床制备高热量气体，特别是甲烷的方法
公开(公告)号：US4433066A
公开(公告)日：1984-02-21
申请号：US340738
申请日：1982-01-19
申请人： Erich Hackler , Claus Flockenhaus , Werner Lommerzheim
发明人： Erich Hackler , Claus Flockenhaus , Werner Lommerzheim
IPC分类号： B01J8/00 , B01J8/28 , C07C1/04
CPC分类号： B01J8/28 , B01J8/006 , C07C1/0485 , B01J2208/0007 , B01J2208/00132 , B01J2208/00141 , B01J2208/00539 , B01J2208/00548
摘要： A method for the production of high-caloric content gases is disclosed wherein feed gases containing CO and H.sub.2 are passed through at least two consecutive catalytic fluidized bed stages having cooling elements wherein, the feed gases being introduced to the first stage under pressure and to the subsequent stages under a pressure which is less than the pressure of the next preceding stage, and the gas produced from each preceding stage is fed to the next stage as a diluting gas. As a result of using the method of the present invention, one can avoid the necessity of compression of the feed gases in the subsequent reaction stages, thereby decreasing the cost as well as the technical difficulties encountered in the process.
摘要翻译：公开了一种用于生产高热量含量气体的方法，其中包含CO和H 2的进料气体通过至少两个具有冷却元件的连续的催化流化床阶段，其中在压力下将进料气体引入第一阶段，在低于下一级的压力的压力下的后续阶段，并且从每个前一级产生的气体作为稀释气体被供给到下一阶段。作为使用本发明的方法的结果，可以避免后续反应阶段中进料气体压缩的必要性，从而降低成本以及在该方法中遇到的技术难题。

23. 发明授权

US4407974A Method of and apparatus for catalytic conversion of gases 失效
标题翻译：催化转化气体的方法和装置
公开(公告)号：US4407974A
公开(公告)日：1983-10-04
申请号：US371265
申请日：1982-04-23
申请人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
发明人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
IPC分类号： B01J8/18 , C07C1/00 , C07C1/04 , C07C9/04 , C07C67/00 , C10K3/04
CPC分类号： C07C1/042 , B01J8/1836 , C07C1/048 , Y02P20/131
摘要： A method of catalytic conversion of feed gases, particularly of a low-sulphur gas mixture rich in carbon monoxide and hydrogen, into a product gas mixture containing methane and/or higher hydrocarbons under high pressure includes the step of removing heat of reaction from the catalytic conversion from a reaction zone by feeding both water and steam to form a cooling medium through a pipe coil in the reaction zone. This forms superheated steam in the pipe coil and the superheated steam is then converted into another form of energy, for example in a turbo-generator. Preferably the reaction zone is a fluidized bed. For carrying out this method a reactor is used, which is preferably a fluidized bed reactor and in this reactor the piping system forming the superheater is disposed in the lower part of the reaction zone. The superheater is connected to a feedwater line and to a steam inlet line and a steam turbine is connected to a steam output line leading from the superheater.
摘要翻译：将含有一氧化碳和氢的低硫气体混合物的进料气体特别是在高压下含有甲烷和/或高级烃的产物气体混合物的催化转化方法包括从催化剂中除去反应热的步骤通过进料水和蒸汽从反应区转化成通过反应区中的管线形成冷却介质。这在管线圈中形成过热蒸汽，然后将过热蒸汽转化成另一形式的能量，例如在涡轮发电机中。优选地，反应区是流化床。为了实施该方法，使用反应器，其优选为流化床反应器，并且在该反应器中，形成过热器的管道系统设置在反应区的下部。过热器连接到给水管线和蒸汽入口管线，蒸汽轮机连接到从过热器引出的蒸汽输出管线。

24. 发明授权

US4352618A Method of, and apparatus for preventing the unintended charging of coke oven chambers 失效
标题翻译：用于防止焦炉室意外充电的方法和装置
公开(公告)号：US4352618A
公开(公告)日：1982-10-05
申请号：US145766
申请日：1980-04-30
申请人： Claus Flockenhaus , Horst Joseph , Joachim Meckel
发明人： Claus Flockenhaus , Horst Joseph , Joachim Meckel
IPC分类号： C10B31/00 , C10B31/04
CPC分类号： C10B41/005 , C10B31/04
摘要： A method and an apparatus are described for preventing the unintentional introduction of coal from a supply into a coke oven which already contains a charge of coal or coke. An obstruction sensor is lowered through a charging hole in the ceiling of the oven; if it encounters an obstruction, such as a charge of coal or coke in the oven, it triggers a signal which blocks any discharge of coal through the charging hole into the oven.
摘要翻译：描述了一种方法和装置，用于防止煤炭从供应中无意地引入已经含有煤或焦炭的焦炉中。阻塞传感器通过烤箱天花板中的充电孔降低; 如果它遇到阻塞物，例如炉子中的煤或焦炭，它会触发一个信号，阻止任何煤气通过充电孔进入烤箱。

25. 发明授权

US4289585A Method and apparatus for the wet quenching of coke 失效
标题翻译：焦炭湿法淬火的方法和装置
公开(公告)号：US4289585A
公开(公告)日：1981-09-15
申请号：US112439
申请日：1980-01-16
申请人： Dietrich Wagener , Claus Flockenhaus , Manfred Blase
发明人： Dietrich Wagener , Claus Flockenhaus , Manfred Blase
IPC分类号： C10B39/08 , C10B39/10
CPC分类号： C10B39/08
摘要： A method and apparatus for the wet quenching of coke is disclosed wherein hot coke is sprayed from above with quenching water, the steam generated by the heat of the coke is condensed by a spray of condensation water from the top of the quenching tower, and the hot condensate-water mixture is collected at the bottom of the quenching tower and recirculating to the top of the tower where it is sprayed between quenching operations to be cooled by a counterflowing stream of air. The cooled condensate-water mixture is suitable for reuse as the condensation spray water.
摘要翻译：公开了一种用于冷焦的焦炭的方法和装置，其中用焦炭从上方喷射热焦炭，焦炭热量产生的蒸汽通过来自淬火塔顶部的冷凝水喷雾而冷凝，在冷凝塔的底部收集热的冷凝水混合物，并且再循环到塔的顶部，在其顶部喷洒淬火操作之间，以便由逆流的空气流冷却。冷凝水冷却水混合物适合作为冷凝喷水的再利用。

26. 发明授权

US4751212A Process for the manufacture of a catalyst for the reduction of nitrogen oxides in exhaust gases 失效
标题翻译：用于制造用于还原废气中的氮氧化物的催化剂的方法
公开(公告)号：US4751212A
公开(公告)日：1988-06-14
申请号：US938525
申请日：1986-12-05
申请人： Claus Flockenhaus , Erich Hackler , Karl H. Laue , Klaus Merkel , Arnold Max , Werner Stender , Johann Jansen , Hartmut Kainer , Daniel Grimm , Blagoje Levkov
发明人： Claus Flockenhaus , Erich Hackler , Karl H. Laue , Klaus Merkel , Arnold Max , Werner Stender , Johann Jansen , Hartmut Kainer , Daniel Grimm , Blagoje Levkov
IPC分类号： B01D53/86 , B01J23/745 , B01J23/74 , B01J27/053 , C01B21/00
CPC分类号： B01J23/745 , B01D53/8628
摘要： The invention relates to a process for the manufacture of a catalyst for the reduction of nitrogen oxides in exhaust gases. The catalyst contains a metal oxide. The catalyst is preferably used for catalytic reduction with ammonia. The process comprises screening a natural goethite iron ore to the required grain size and then treating the ore with sulfuric acid. Subsequently, the goethite iron ore is heated to a temperature which approximately equals the temperature at which it will be used in the catalytic reaction.
摘要翻译：本发明涉及制备用于还原废气中的氮氧化物的催化剂的方法。催化剂含有金属氧化物。该催化剂优选用于用氨催化还原。该方法包括将天然针铁矿铁矿筛选成所需的粒度，然后用硫酸处理矿石。随后，将针铁矿铁矿石加热到与催化反应中使用的温度大致相等的温度。

27. 发明授权

US4695559A Catalyst for the selective reduction of nitrogen oxides in waste gases and process for the manufacture of such a catalyst 失效
标题翻译：用于选择性还原废气中的氮氧化物的催化剂和用于制造这种催化剂的方法
公开(公告)号：US4695559A
公开(公告)日：1987-09-22
申请号：US831142
申请日：1986-02-19
申请人： Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Biagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein , Hans-Eugen Buhler , Horst Kalfa , Johann Jansen , Werner Stender , Arnold Max
发明人： Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Biagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein , Hans-Eugen Buhler , Horst Kalfa , Johann Jansen , Werner Stender , Arnold Max
IPC分类号： B01D53/94 , B01D53/86 , B01J23/86 , B01J37/04 , B01J21/18 , B01J27/053 , B01J27/18
CPC分类号： B01J37/04 , B01D53/8628 , B01J23/862
摘要： A catalyst for use with ammonia for the selective reduction of nitrogen oxides in waste gases. The catalyst comprises a mixture of substances which has high activity and selectivity with regard to nitrogen oxide conversion and high sorption capabilities with regard to ammonia, but low oxidation capabilities with regard to sulfur dioxide, ammonia, or similar substances. The invention also provides a process for the manufacture and use of such catalysts.
摘要翻译：用于氨的催化剂用于选择性还原废气中的氮氧化物。催化剂包括对于氮氧化物转化和对氨具有高吸附能力而具有高活性和选择性的物质的混合物，但对于二氧化硫，氨或类似物质的氧化能力低。本发明还提供了制备和使用这种催化剂的方法。

28. 发明授权

US4539016A Method of and apparatus for adjusting and maintaining constant the temperature during methanizing of a charge gas 失效
标题翻译：用于调节和维持充电气体甲烷化期间温度恒定的方法和装置
公开(公告)号：US4539016A
公开(公告)日：1985-09-03
申请号：US257352
申请日：1981-04-24
申请人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
发明人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
IPC分类号： C10K3/02 , B01J8/18 , C07C1/04 , C10K3/04
CPC分类号： B01J8/1836 , C07C1/048 , B01J2208/00132 , B01J2208/00256 , B01J2208/00274
摘要： In methanizing CO and H.sub.2 containing charge gases, the charge gas is passed upwardly through a vertically extending fluidized bed reactor flowing, in turn, through a fluidized bed zone, a dust bed zone and a separation zone. From the separation zone, the gas is conveyed out of the reactor to a point of use. Coolant tubes are positioned in the reactor passing vertically through the fluidized bed zone, the dust bed zone and the separation zone for removing the heat generated in the reaction. An evaporable coolant, preferably water, is circulated through the coolant tubes. In a separate steam drum, the vapor pressure of the coolant is set for maintaining constant the temperature of the vaporizing coolant.
摘要翻译：在甲烷化含CO和H 2的充电气体中，充电气体向上通过一个垂直延伸的流化床反应器，反应器又流过流化床区域，灰尘床区域和分离区域。从分离区，将气体从反应器输送到使用点。冷却剂管定位在反应器中垂直通过流化床区域，灰尘床区域和分离区域，以除去反应中产生的热量。可蒸发的冷却剂，优选水，循环通过冷却剂管。在单独的蒸汽鼓中，设置冷却剂的蒸汽压力以保持汽化冷却剂的温度恒定。

29. 发明授权

US4322269A Method for the wet quenching of coke 失效
标题翻译：焦炭湿法淬火方法
公开(公告)号：US4322269A
公开(公告)日：1982-03-30
申请号：US263354
申请日：1981-05-14
申请人： Dietrich Wagener , Claus Flockenhaus , Manfred Blase
发明人： Dietrich Wagener , Claus Flockenhaus , Manfred Blase
IPC分类号： C10B39/08
CPC分类号： C10B39/08
摘要： A method and apparatus for the wet quenching of coke is disclosed wherein hot coke is sprayed from above with quenching water, the steam generated by the heat of the coke is condensed by a spray of condensation water from the top of the quenching tower, and the hot condensate-water mixture is collected at the bottom of the quenching tower and recirculating to the top of the tower where it is sprayed between quenching operations to be cooled by a counterflowing stream of air. The cooled condensate-water mixture is suitable for reuse as the condensation spray water.
摘要翻译：公开了一种用于冷焦的焦炭的方法和装置，其中用焦炭从上方喷射热焦炭，焦炭热量产生的蒸汽通过来自淬火塔顶部的冷凝水喷雾而冷凝，在冷凝塔的底部收集热的冷凝水混合物，并且再循环到塔的顶部，在其顶部喷洒淬火操作之间，以便由逆流的空气流冷却。冷凝水冷却水混合物适合作为冷凝喷水的再利用。

30. 发明授权

US4258006A Apparatus for fluid catalytic conversion of gases 失效
标题翻译：用于流体催化转化气体的装置
公开(公告)号：US4258006A
公开(公告)日：1981-03-24
申请号：US59522
申请日：1979-07-23
申请人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
发明人： Claus Flockenhaus , Erich Hackler , Werner Lommerzheim
IPC分类号： B01J8/18 , C07C1/00 , C07C1/04 , C07C9/04 , C07C67/00 , C10K3/04 , B01J8/24
CPC分类号： C07C1/042 , B01J8/1836 , C07C1/048 , Y02P20/131
摘要： A method of catalytic conversion of feed gases, particularly of a low-sulphur gas mixture rich in carbon monoxide and hydrogen, into a product gas mixture containing methane and/or higher hydrocarbons under high pressure includes the step of removing heat of reaction from the catalytic conversion from a reaction zone by feeding both water and steam to form a cooling medium through a pipe coil in the reaction zone. This forms superheated steam in the pipe coil and the superheated steam is then converted into another form of energy, for example in a turbo-generator. Preferably the reaction zone is a fluidized bed. The apparatus for carrying out this method comprises a reactor, which is preferably a fluidized bed reactor and in this reactor the piping system forming the superheater is disposed in the lower part of the reaction zone. The superheater is connected to a feedwater line and to a steam inlet line and a steam turbine is connected to a steam output line leading from the superheater.
摘要翻译：将含有一氧化碳和氢的低硫气体混合物的进料气体特别是在高压下含有甲烷和/或高级烃的产物气体混合物的催化转化方法包括从催化剂中除去反应热的步骤通过进料水和蒸汽从反应区转化成通过反应区中的管线形成冷却介质。这在管线圈中形成过热蒸汽，然后将过热蒸汽转化成另一形式的能量，例如在涡轮发电机中。优选地，反应区是流化床。用于实施该方法的装置包括反应器，其优选为流化床反应器，并且在该反应器中，形成过热器的管道系统设置在反应区的下部。过热器连接到给水管线和蒸汽入口管线，蒸汽轮机连接到从过热器引出的蒸汽输出管线。

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