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    • 21. 发明授权
    • Flexible panel based on electrochromic polymers
    • 基于电致变色聚合物的柔性面板
    • US07826124B2
    • 2010-11-02
    • US12244285
    • 2008-10-02
    • Chunye XuChao MaMinoru Taya
    • Chunye XuChao MaMinoru Taya
    • G02F1/153
    • C07D493/04C08G61/126C08G2261/1424C08G2261/3223C09K9/02G02F1/133305G02F1/1533G02F1/161
    • A flexible electrochromic (EC) panel that is usable for a display device or for other applications in which at least a region of the panel is selectively caused to change opacity. An exemplary EC panel includes an electrochromic working layer or electrode formed of a PProDOT-Me2 polymer film that is deposited on an indium tin oxide (ITO)-coated polyethylene terephthalate (PET) flexible substrate. Similarly, a counter electrode is formed by depositing a vanadium oxide-titanium oxide (V2O5—TiO2) composite film on another ITO PET coated flexible substrate. An ultraviolet light-cured film sealant is employed to seal the flexible panel and also serves as a spacer between the working and counter electrodes. The film sealant is patterned to define a volume for injecting an electrolyte solution through an inlet port provided in the film sealant. The inlet port is then closed. The EC panel can readily be flexed without damage.
    • 一种柔性电致变色(EC)面板,可用于显示设备或其他应用中,其中面板的至少一个区域被选择性地引起改变不透明度。 示例性EC面板包括电沉积工作层或由沉积在氧化铟锡(ITO)涂覆的聚对苯二甲酸乙二醇酯(PET)柔性基底上)的PProDOT-Me2聚合物膜形成的电极。 类似地,通过在另一个ITO PET涂覆的柔性基底上沉积氧化钒 - 氧化钛(V2O5-TiO2)复合膜而形成对电极。 使用紫外光固化膜密封剂来密封柔性板,并且还用作工作电极和对电极之间的间隔件。 图案化膜密封剂以限定用于通过设置在膜密封剂中的入口注入电解质溶液的体积。 然后关闭入口。 EC面板可以轻松地弯曲而不受损坏。
    • 23. 发明授权
    • Electrochromic organic polymer synthesis and devices utilizing electrochromic organic polymers
    • 电致变色有机聚合物合成和利用电致变色有机聚合物的装置
    • US07038828B2
    • 2006-05-02
    • US11008526
    • 2004-12-08
    • Chunye XuMinoru Taya
    • Chunye XuMinoru Taya
    • G02F1/153
    • G02F1/15C09K9/02G02F2001/1502H01L51/0037
    • Large contrast ratio and rapid switching laminated electrochromic (EC) polymer device includes transparent electrode, cathodic EC polymer, gel electrolyte, and counter-electrode. Preferably the cathodic EC polymer is a poly(3,4-propylenedioxythiophene) derivative, PProDOT-Me2. Counter-electrode is a conductive coating deposited on transparent substrate, with preferred coatings including gold and highly conductive carbon. Lithography and sputtering can be employed to pattern a gold layer, while screen printing can be employed to similarly pattern graphite. Empirical studies of preferred device indicate a color change of high contrast ratio of transmittance (>50% T) is rapidly (0.5–1 s) obtained upon applied 2.5V, repeatable to at least 10,000 times, as estimated by electrochemistry. Dual layer EC devices including PProDOT-Me2 are also disclosed, as are methods for synthesizing preferred EC polymers. Preferred synthesis method for obtaining PProDOT-Me2 involves refluxing reagents in toluene in the presence of catalyst, while continually removing methanol byproduct from refluxing solution.
    • 大对比度和快速切换叠层电致变色(EC)聚合物器件包括透明电极,阴极EC聚合物,凝胶电解质和对电极。 优选地,阴极EC聚合物是聚(3,4-亚丙二氧基噻吩)衍生物,PProDOT-Me 2。 反电极是沉积在透明基底上的导电涂层,优选的涂层包括金和高导电性碳。 可以使用平版印刷和溅射来图案化金层,而丝网印刷可以用于类似地图案化石墨。 对优选装置的实证研究表明,如通过电化学估算的,施加2.5V时获得的透射率(> 50%T)的高对比度的颜色变化快速(0.5-1s),可重复至少10,000次。 还公开了包括PProDOT-Me 2 2的双层EC装置,以及用于合成优选的EC聚合物的方法。 优选的用于获得PProDOT-Me 2的合成方法包括在催化剂存在下在甲苯中回流试剂,同时从回流溶液中持续除去甲醇副产物。
    • 24. 发明申请
    • Tactile sensors
    • 触觉传感器
    • US20090165569A1
    • 2009-07-02
    • US12330396
    • 2008-12-08
    • Minoru TayaJin WangChunye XuYasuo Kuga
    • Minoru TayaJin WangChunye XuYasuo Kuga
    • G01D7/00
    • G01D5/14G01L1/005G01L5/228G06F3/0338Y10T29/49007
    • An electroactive polymer is used to produce a tactile sensor. The electroactive polymer (EAP) includes a sheet of an ion-exchange membrane having opposite surfaces on which are plated gold electrodes. The EAP is formed to have a dome-shape with a plurality of sensing electrodes circumferentially disposed around an outer surface of the dome. A flexible polymer underlying the EAP supports it and prevents a force applied to the tactile sensor from inverting the dome. The sensor electrodes produce separate output signals indicative of different vector components of an applied force acting on the tactile sensor, so that a direction of the force can be determined. Vias provided in the electrodes are electrically coupled to a flexible circuit that conveys the output signals externally from the sensing electrodes for use and further processing. A plurality of the tactile sensors can be formed as an array on an ion-exchange membrane.
    • 电活性聚合物用于产生触觉传感器。 电活性聚合物(EAP)包括具有相对表面的离子交换膜片,其上镀有金电极。 EAP形成为具有围绕圆顶的外表面周向设置的多个感测电极的圆顶形状。 EAP下面的柔性聚合物支撑它,并且防止施加到触觉传感器的力反转圆顶。 传感器电极产生指示作用在触觉传感器上的施加力的不同矢量分量的分离的输出信号,从而可以确定力的方向。 设置在电极中的通孔电耦合到柔性电路,其将来自感测电极的输出信号从外部传送以用于和进一步处理。 多个触觉传感器可以形成为离子交换膜上的阵列。
    • 25. 发明申请
    • FLEXIBLE PANEL BASED ON ELECTROCHROMIC POLYMERS
    • 基于电致发光聚合物的柔性面板
    • US20090052006A1
    • 2009-02-26
    • US12244285
    • 2008-10-02
    • Chunye XuChao MaMinoru Taya
    • Chunye XuChao MaMinoru Taya
    • G02F1/161B29D11/00
    • C07D493/04C08G61/126C08G2261/1424C08G2261/3223C09K9/02G02F1/133305G02F1/1533G02F1/161
    • A flexible electrochromic (EC) panel that is usable for a display device or for other applications in which at least a region of the panel is selectively caused to change opacity. An exemplary EC panel includes an electrochromic working layer or electrode formed of a PProDOT-Me2 polymer film that is deposited on an indium tin oxide (ITO)-coated polyethylene terephthalate (PET) flexible substrate. Similarly, a counter electrode is formed by depositing a vanadium oxide-titanium oxide (V2O5-TiO2) composite film on another ITO PET coated flexible substrate. An ultraviolet light-cured film sealant is employed to seal the flexible panel and also serves as a spacer between the working and counter electrodes. The film sealant is patterned to define a volume for injecting an electrolyte solution through an inlet port provided in the film sealant. The inlet port is then closed. The EC panel can readily be flexed without damage.
    • 一种柔性电致变色(EC)面板,可用于显示设备或其他应用中,其中面板的至少一个区域被选择性地引起改变不透明度。 示例性EC面板包括电沉积工作层或由沉积在氧化铟锡(ITO)涂覆的聚对苯二甲酸乙二醇酯(PET)柔性基底上)的PProDOT-Me2聚合物膜形成的电极。 类似地,通过在另一个ITO PET涂覆的柔性基底上沉积氧化钒 - 氧化钛(V2O5-TiO2)复合膜而形成对电极。 使用紫外光固化膜密封剂来密封柔性板,并且还用作工作电极和对电极之间的间隔件。 膜密封剂被图案化以限定用于通过设置在膜密封剂中的入口注入电解质溶液的体积。 然后关闭入口。 EC面板可以轻松地弯曲而不受损坏。
    • 26. 发明授权
    • Electrochromic organic polymer synthesis and devices utilizing electrochromic organic polymers
    • 电致变色有机聚合物合成和利用电致变色有机聚合物的装置
    • US07002722B2
    • 2006-02-21
    • US10755433
    • 2004-01-12
    • Chunye XuMinoru Taya
    • Chunye XuMinoru Taya
    • G02F1/153
    • G02F1/15C09K9/02G02F2001/1502H01L51/0037
    • Large contrast ratio and rapid switching laminated electrochromic (EC) polymer device includes transparent electrode, cathodic EC polymer, gel electrolyte, and counter-electrode. Preferably the cathodic EC polymer is a poly(3,4-propylenedioxythiophene) derivative, PProDOT-Me2. Counter-electrode is a conductive coating deposited on transparent substrate, with preferred coatings including gold and highly conductive carbon. Lithography and sputtering can be employed to pattern a gold layer, while screen printing can be employed to similarly pattern graphite. Empirical studies of preferred device indicate a color change of high contrast ratio of transmittance (>50% T) is rapidly (0.5–1s) obtained upon applied 2.5V, repeatable to at least 10,000 times, as estimated by electrochemistry. Dual layer EC devices including PProDOT-Me2 are also disclosed, as are methods for synthesizing preferred EC polymers. Preferred synthesis method for obtaining PProDOT-Me2 involves refluxing reagents in toluene in the presence of catalyst, while continually removing methanol byproduct from refluxing solution.
    • 大对比度和快速切换叠层电致变色(EC)聚合物器件包括透明电极,阴极EC聚合物,凝胶电解质和对电极。 优选地,阴极EC聚合物是聚(3,4-亚丙二氧基噻吩)衍生物,PProDOT-Me 2。 反电极是沉积在透明基底上的导电涂层,优选的涂层包括金和高导电性碳。 可以使用平版印刷和溅射来图案化金层,而丝网印刷可以用于类似地图案化石墨。 对于优选装置的实证研究表明,如通过电化学估算的,施加2.5V时获得的透射率(> 50%T)的高对比度的颜色变化快速(0.5-1s),可重复至少10,000次。 还公开了包括PProDOT-Me 2 2的双层EC装置,以及用于合成优选的EC聚合物的方法。 优选的用于获得PProDOT-Me 2的合成方法包括在催化剂存在下在甲苯中回流试剂,同时从回流溶液中持续除去甲醇副产物。
    • 27. 发明授权
    • Electrochromic organic polymer synthesis and devices utilizing electrochromic organic polymers
    • 电致变色有机聚合物合成和利用电致变色有机聚合物的装置
    • US06747780B2
    • 2004-06-08
    • US10180222
    • 2002-06-25
    • Chunye XuMinoru Taya
    • Chunye XuMinoru Taya
    • G02F115
    • G02F1/15C09K9/02G02F2001/1502H01L51/0037
    • Large contrast ratio and rapid switching laminated electrochromic (EC) polymer device includes transparent electrode, cathodic EC polymer, gel electrolyte, and counter-electrode. Preferably the cathodic EC polymer is a poly(3,4-propylenedioxythiophene) derivative, PProDOT-Me2. Counter-electrode is a conductive coating deposited on transparent substrate, with preferred coatings including gold and highly conductive carbon. Lithography and sputtering can be employed to pattern a gold layer, while screen printing can be employed to similarly pattern graphite. Empirical studies of preferred device indicate a color change of high contrast ratio of transmittance (>50% T) is rapidly (0.5-1s) obtained upon applied 2.5V, repeatable to at least 10,000 times, as estimated by electrochemistry. Dual layer EC devices including PProDOT-Me2 are also disclosed, as are methods for synthesizing preferred EC polymers. Preferred synthesis method for obtaining PProDOT-Me2 involves refluxing reagents in toluene in the presence of catalyst, while continually removing methanol byproduct from refluxing solution.
    • 大对比度和快速切换叠层电致变色(EC)聚合物器件包括透明电极,阴极EC聚合物,凝胶电解质和对电极。 阴极EC聚合物优选为聚(3,4-亚丙基二氧噻吩)衍生物PProDOT-Me2。 反电极是沉积在透明基底上的导电涂层,优选的涂层包括金和高导电性碳。 可以使用平版印刷和溅射来图案化金层,而丝网印刷可以用于类似地图案化石墨。 对于优选装置的实证研究表明,如通过电化学估算的,施加2.5V时获得的透射率(> 50%T)的高对比度的颜色变化快速(0.5-1s),可重复至少10,000次。 还公开了包括PProDOT-Me2的双层EC装置,以及用于合成优选的EC聚合物的方法。 获得PProDOT-Me2的优选合成方法包括在催化剂存在下在甲苯中回流试剂,同时从回流溶液中持续除去甲醇副产物。
    • 30. 发明申请
    • DESIGN OF SHAPE MEMORY ALLOY FIBERS AND SHAPE MEMORY POLYMER FIBERS AND FILMS AND THEIR COMPOSITES FOR REVERSIBLE SHAPE CHANGES
    • 形状记忆合金纤维和形状记忆聚合物纤维和膜的设计及其可逆形状变化的复合材料
    • US20090130391A1
    • 2009-05-21
    • US12264178
    • 2008-11-03
    • Minoru Taya
    • Minoru Taya
    • B05D3/00B32B25/02B32B3/00B05D1/18B28B1/52
    • B29C61/0608B29L2031/22F03G7/065Y10T428/24612Y10T428/249922Y10T428/2925Y10T428/31678
    • A plurality of reversible active composite materials are disclosed, including composites based on a shape memory alloy member (SMA) and a shape memory polymer member (SMP), as well as composites based on two different SMP members. Each different member (SMA or SMP) will be trained to remember a specific shape at a specific temperature. Where two different SMP members are employed, the members exhibit different glass transition temperatures. Such composite materials can be implemented in many form factors, including two generally planar members, a single generally planar SMP member with SMA fibers distributed throughout the SMP, and a SMA fiber/wire coated with a SMP coating. In particular, the SMA fiber/wire coated with a SMP layer can be used to form helical coils that can be used in paired hinges to achieve reversible bending of a structure into which such paired hinges are incorporated.
    • 公开了多种可逆活性复合材料,包括基于形状记忆合金构件(SMA)和形状记忆聚合物构件(SMP)的复合材料,以及基于两种不同SMP构件的复合材料。 将训练每个不同的成员(SMA或SMP)以记住特定温度下的特定形状。 当使用两种不同的SMP构件时,构件表现出不同的玻璃化转变温度。 这种复合材料可以以许多形状因子实现,包括两个通常为平面的构件,具有分布在整个SMP中的SMA纤维的单个大体平坦的SMP构件和涂覆有SMP涂层的SMA纤维/线。 特别地,涂覆有SMP层的SMA纤维/线可以用于形成螺旋线圈,其可以用于成对的铰链中,以实现将这种成对的铰链结合到其中的结构的可逆弯曲。