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21. 发明申请

US20090308752A1 Electrochemical Pump 有权
标题翻译：电化学泵
公开(公告)号：US20090308752A1
公开(公告)日：2009-12-17
申请号：US12546826
申请日：2009-08-25
申请人： Christine E. Evans , Forrest W. Payne , Carl A. Koval , Richard D. Noble , Mya A. Norman
发明人： Christine E. Evans , Forrest W. Payne , Carl A. Koval , Richard D. Noble , Mya A. Norman
IPC分类号： C25B13/00 , F04B37/02 , F16K31/02 , C25B9/00
CPC分类号： A61M5/145 , A61M5/14526 , A61M2005/14204 , A61M2005/14513 , A61M2205/0244 , F04B17/00
摘要： The invention provides electrochemically-based methods and devices for producing fluid flow and/or changes in fluid pressure. In the methods and devices of the invention, current passes through a divided electrochemical cell. Adjacent compartments of the cell are divided by an ionically conducting separator. Each compartment includes an electrode and an electrolyte solution or ionic liquid. The electrolyte solution(s) or ionic liquid(s) and the ionically conducting separator are selected to obtain the desired relationship between the current through the cell and the fluid flowrate and/or change in fluid pressure.
摘要翻译：本发明提供用于产生流体流动和/或流体压力变化的基于电化学的方法和装置。在本发明的方法和装置中，电流通过分隔的电化学电池。细胞的相邻隔室被离子导电分离器分开。每个隔室包括电极和电解质溶液或离子液体。选择电解质溶液或离子液体和离子导电分离器以获得通过电池的电流与流体流速之间的期望关系和/或流体压力的变化。

22. 发明授权

US07074734B2 Isomorphously substituted molecular sieve membranes 失效
标题翻译：同晶取代分子筛膜
公开(公告)号：US07074734B2
公开(公告)日：2006-07-11
申请号：US10868553
申请日：2004-06-15
申请人： Tuan Anh Vu , Richard D. Noble , John L. Falconer
发明人： Tuan Anh Vu , Richard D. Noble , John L. Falconer
IPC分类号： B01J29/06
CPC分类号： B01D71/028 , B01D61/362 , B01D63/06 , B01D63/063 , B01D67/0069 , B01D69/10 , B01D2323/08 , B01D2323/24 , B01D2323/40 , B01J29/06 , B01J29/061 , B01J29/86
摘要： Zeolite membranes that can be used to continuously separate components of mixtures are disclosed. The zeolite membranes are prepared by isomorphous substitution, which allows systematic modification of the zeolite surface and pore structure. Through proper selection of the basic zeolite framework structure and compensating cations, isomorphous substitution permits high separation selectivity without many of the problems associated with zeolite post-synthesis treatments. The inventive method for preparing zeolite membranes is alkali-free and is much simpler than prior methods for making acid hydrogen zeolite membranes, which can be used as catalysts in membrane reactors.
摘要翻译：公开了可用于连续分离混合物组分的沸石膜。沸石膜通过同晶取代制备，其允许系统地改性沸石表面和孔结构。通过适当选择碱性沸石骨架结构和补偿阳离子，同晶取代允许高分离选择性，而不需要与沸石后合成处理相关的许多问题。用于制备沸石膜的本发明方法是无碱的，并且比制备酸性氢沸石膜的现有方法简单得多，其可以用作膜反应器中的催化剂。

23. 发明授权

US5433857A Convective electrohydrodynamic fluid membranes 失效
标题翻译：对流电动力学流体膜
公开(公告)号：US5433857A
公开(公告)日：1995-07-18
申请号：US963480
申请日：1992-10-16
申请人： Richard D. Noble , Noel A. Clark
发明人： Richard D. Noble , Noel A. Clark
IPC分类号： B01D53/32 , B01D61/38
CPC分类号： B01D61/38 , B01D53/326
摘要： A fluid membrane is described, termed the electroconvective liquid crystal membrane (ECLCM), comprised of a sandwich-like configuration in which a fluid layer is contained within a structure. The structure containing the fluid layer separates distinct regions having different concentrations of one or more diffusant species and is capable of being accessed by the diffusant species. The fluid layer is comprised of any fluid in which an electrohydrodynamic (EHD) flow can be induced, including liquid crystals and liquid crystal-like fluids. The ECLCM includes means for applying an electric field to the fluid layer such that an EHD flow is induced within the fluid layer. The EHD flow alters the passage of the diffusant species across the ECLCM. The fluid layer may be modified by the addition of other components which act as carriers to the passage of selected diffusants. These additional components move in the EHD flow and can be chemically bonded to the fluid layer, added as dopants into the fluid layer, or may be separate solid or liquid phases of other materials not soluble in the fluid layer. The membrane of the present invention can function in an electrochemically modulated complexation (EMC) process wherein a complexing agent is added to the fluid layer and electrolyzed to high and low affinity redox states for separation of different molecular species. The present invention includes a method for separating and purifying molecules.
摘要翻译：描述了称为电对流液晶膜（ECLCM）的流体膜，其包括其中流体层包含在结构内的夹心状构造。包含流体层的结构分离具有不同浓度的一种或多种扩散物质的不同区域，并且能够被扩散物质接近。流体层由其中可以诱导电动力学（EHD）流的任何流体组成，包括液晶和液晶状流体。 ECLCM包括用于向流体层施加电场的装置，使得在流体层内诱导EHD流动。 EHD流量改变扩散物种通过ECLCM。流体层可以通过添加作为载体的其它成分而被修饰，以使所选择的扩散剂通过。这些附加组件在EHD流中移动并且可化学键合到流体层，作为掺杂剂添加到流体层中，或者可以是不溶于流体层的其它材料的分离的固体或液相。本发明的膜可以在电化学调制的络合（EMC）方法中起作用，其中将络合剂加入到流体层中并电解成用于分离不同分子种类的高和低亲和性氧化还原状态。本发明包括分离和分离分子的方法。

24. 发明授权

US5417832A Enhancing performance of perfluorinated ionomer membranes via dopant incorporation, method of making thereof and the membrane 失效
标题翻译：通过掺杂掺杂提高全氟化离聚物膜的性能，制备方法和膜
公开(公告)号：US5417832A
公开(公告)日：1995-05-23
申请号：US935016
申请日：1992-08-25
申请人： John Pellegrino , Richard D. Noble , Robert Rabago , Carl Koval
发明人： John Pellegrino , Richard D. Noble , Robert Rabago , Carl Koval
IPC分类号： B01D53/22 , B01D67/00 , B01D69/14 , B01D71/32 , C08J5/22 , H01M8/10 , C25B13/08
CPC分类号： B01D67/0013 , B01D53/228 , B01D67/0011 , B01D69/141 , B01D71/32 , C08J5/225 , H01M8/1023 , H01M8/1039 , H01M8/1051 , H01M8/1081 , B01D2323/12 , C08J2327/12 , Y02C10/10 , Y02P70/56
摘要： The present invention describes a perfluorinated ionomer membrane having a improved transport characteristics. A surfactant species is added to a polymer mixture prior to film casting. The resulting membranes have a measurably altered membrane microstructure and improved transport characteristics over prior art membranes. The present invention describes the method of producing the improved membranes. The membranes of the present invention are useful in a number of separation processes, including the separation of NH.sub.3 from gaseous and liquid mixtures, in the production of NaOH and Cl.sub.2 gas from the electrolytic dissolution of NaCl, in the separation of toxic and radioactive metals from aqueous streams, and in solid polymer electrolyte H.sub.2 /O.sub.2 fuel cells.
摘要翻译：本发明描述了具有改善的运输特性的全氟化离聚物膜。在成膜前，将表面活性剂物质加入到聚合物混合物中。所得到的膜具有可测量地改变的膜微结构并且改善了传统特性。本发明描述了制备改良膜的方法。本发明的膜可用于许多分离过程，包括从气体和液体混合物中分离NH 3，在从NaCl的电解溶解产生的NaOH和Cl 2气体中分离毒性和放射性金属，水溶液和固体高分子电解质H 2 / O 2燃料电池。

25. 发明授权

US5084169A Stationary magnetically stabilized fluidized bed for protein separation and purification 失效
公开(公告)号：US5084169A
公开(公告)日：1992-01-28
申请号：US409616
申请日：1989-09-19
申请人： Richard D. Noble , Carl A. Koval , Lori Nixon , Geoffrey F. Slaff
发明人： Richard D. Noble , Carl A. Koval , Lori Nixon , Geoffrey F. Slaff
IPC分类号： B01D15/08 , G01N30/58
CPC分类号： B01D15/08 , G01N30/58 , Y10S210/905
摘要： Magnetically stabilized fluidized bed technology is utilized in conjunction with ion-exchange adsorption/desorption processes in a method and system for isolating proteins from cell lysate. The invention also includes a magnetizable, porous, ion-exchange particle, and a method for producing the same, for use with the stationary magnetically stabilized fluidized bed protein isolation process.

26. 发明申请

US20140154499A1 Method and Membrane for Nanoporous, Bicontinuous Cubic Lyotropic Liquid Crystal Polymer Membranes that Enable Facile Film Processing and Pore Size Control 审中-公开
标题翻译：用于纳米多孔，双连续立方溶致液晶聚合物膜的方法和膜，其实现易于制膜和孔径控制
公开(公告)号：US20140154499A1
公开(公告)日：2014-06-05
申请号：US14234362
申请日：2012-07-22
申请人： Douglas L. Gin , Blaine M. Carter , Brian R. Wiesenauer , Evan S. Hatakeyama , Richard D. Noble , John L. Barton
发明人： Douglas L. Gin , Blaine M. Carter , Brian R. Wiesenauer , Evan S. Hatakeyama , Richard D. Noble , John L. Barton
IPC分类号： C08J5/00 , C08F26/06
CPC分类号： C08J5/00 , B01D67/00 , B01D69/10 , B01D71/06 , B01D71/58 , B01D71/82 , C08F26/06 , C09K19/02 , C09K2019/525 , C09K2019/528 , C09K2219/03 , Y10T428/249981
摘要： A method of forming a nanoporous membrane includes preparing a solution of a gemini Imidazolium Lyotropic Liquid Crystal (LLC) monomer, a polar low-volatility organic solvent, and a radical photo-initiator in a volatile organic solvent; solvent-casting the solution onto a porous material, evaporating the volatile organic solvent; heating such that the gemini imidazolium monomer forms a Q-phase material and photopolymerizing the imidazolium monomer by exposing the radical photo-initiator to UV light; and exchanging the polar low-volatility organic solvent. Also disclosed is a membrane composed of polymerized gemini imidazolium LLC monomers, and a thin-film composite membrane having the Q-phase material supported on a porous supporting membrane.
摘要翻译：形成纳米多孔膜的方法包括在挥发性有机溶剂中制备双子咪唑溶致液晶（LLC）单体，极性低挥发性有机溶剂和自由基光引发剂的溶液; 将溶液溶剂浇铸到多孔材料上，蒸发挥发性有机溶剂; 加热，使得双子咪唑单体形成Q相材料并通过将自由基光引发剂暴露于UV光而使咪唑单体光聚合; 并交换极性低挥发性有机溶剂。还公开了由聚合的双子咪唑鎓LLC单体组成的膜和具有支撑在多孔支撑膜上的Q相材料的薄膜复合膜。

27. 发明授权

US08679227B2 High flux SAPO-34 membranes for CO2/CH4 separation and template removal method 失效
标题翻译：高通量SAPO-34膜用于CO2 / CH4分离和模板去除方法
公开(公告)号：US08679227B2
公开(公告)日：2014-03-25
申请号：US13096225
申请日：2011-04-28
申请人： John L. Falconer , Richard D. Noble , Begum Tokay , Yanfeng Zhang
发明人： John L. Falconer , Richard D. Noble , Begum Tokay , Yanfeng Zhang
IPC分类号： B01D53/22 , B01D71/02 , B05D3/02
CPC分类号： B01D71/028 , B01D53/228 , B01D67/0051 , B01D2323/00 , B01D2323/24 , Y02C10/10 , Y02C20/20
摘要： The present invention provides methods for making improved zeolite and crystalline silicoaluminophosphate (SAPO) membranes, in particular SAPO-34 membranes, on a porous support through improved removal of the organic structure-directing templating agent. A calcining step is performed in an oxygen free atmosphere, such as under a vacuum or inert gas, to remove the organic templating agent. By removing the templating agent in the absence of oxygen, the calcination step can remove a greater amount of the templating agent than comparable template removal steps conducted in the presence of oxygen and the calcination step can be conducted at significantly lower temperatures. The membranes of the present invention provide increased permeance while maintaining comparable selectivity for gas separations, particularly carbon dioxide (CO2) and methane (CH4) separations and separations at high temperatures.
摘要翻译：本发明提供了通过改进去除有机结构导向模板剂在多孔载体上制备改进的沸石和结晶硅铝磷酸盐（SAPO）膜，特别是SAPO-34膜的方法。煅烧步骤在无氧气氛下，例如在真空或惰性气体下进行，以除去有机模板剂。通过在不存在氧的情况下除去模板剂，煅烧步骤可以除去在氧气存在下进行的可比模板除去步骤的更大量的模板剂，并且煅烧步骤可以在显着较低的温度下进行。本发明的膜提供增加的渗透性，同时保持气体分离，特别是在高温下的二氧化碳（CO 2）和甲烷（CH 4）分离和分离的可比选择性。

28. 发明申请

US20130047849A1 Organic Porous Materials Comprising Shape-Persistent Three-Dimensional Molecular Cage Building Blocks 有权
标题翻译：有机多孔材料包括形状持续三维分子笼构件
公开(公告)号：US20130047849A1
公开(公告)日：2013-02-28
申请号：US13635882
申请日：2011-03-18
申请人： Wei Zhang , Richard D. Noble , Yinghua Jin , Bret A. Voss
发明人： Wei Zhang , Richard D. Noble , Yinghua Jin , Bret A. Voss
IPC分类号： C07C211/43 , B01D53/04 , C07C209/60
CPC分类号： B01D53/02 , B01D2253/20 , B01D2253/202 , B01D2257/504 , B01J20/267 , B01J20/28007 , B01J20/28045 , B01J20/3212 , B01J20/3236 , B82Y30/00 , Y02C10/08
摘要： Porous bulk materials formed of shape-persistent, non-collapsible, three-dimensional molecular cage building blocks are presented that are useful for a variety of applications including gas separation/storage, sensing, and catalysis.
摘要翻译：提出了由形状持久的，不可塌陷的三维分子笼构建块形成的多孔体材料，其可用于多种应用，包括气体分离/储存，感测和催化。

29. 发明授权

US08067327B2 Membranes for highly selective separations 失效
标题翻译：用于高度选择性分离的膜
公开(公告)号：US08067327B2
公开(公告)日：2011-11-29
申请号：US12894562
申请日：2010-09-30
申请人： Shiguang Li , Sara A. Arvidson , John L. Falconer , Richard D. Noble
发明人： Shiguang Li , Sara A. Arvidson , John L. Falconer , Richard D. Noble
IPC分类号： B01J20/28
CPC分类号： B01D71/028 , B01D53/228 , B01D67/0051 , B01D67/0093 , B01D69/10 , B01D2253/108 , B01D2257/504 , B01D2325/20 , B01J20/28033 , C07C7/144 , C10L3/10 , C10L3/102 , Y02C10/10 , Y02P20/152 , C07C9/04
摘要： The present invention provides modified molecular sieve membranes with improved CO2/CH4 separation selectivity and methods for making such membranes. The molecular sieve membranes are modified by adsorption of a modifying agent, such as ammonia, within and/or on the membrane.
摘要翻译：本发明提供具有改进的CO 2 / CH 4分离选择性的改性分子筛膜和制备这种膜的方法。分子筛膜通过在膜内和/或膜上吸附改性剂例如氨来修饰。

30. 发明授权

US07604129B2 Lyotropic liquid crystal nanofiltration membranes 有权
标题翻译：溶致液晶纳滤膜
公开(公告)号：US07604129B2
公开(公告)日：2009-10-20
申请号：US10529409
申请日：2003-10-03
申请人： Douglas L. Gin , Meijuan Zhou , Richard D. Noble
发明人： Douglas L. Gin , Meijuan Zhou , Richard D. Noble
IPC分类号： B01D39/00 , B01D29/00 , C25D1/08
CPC分类号： B01D69/125 , B01D67/0006 , B01D69/02 , B01D69/142 , B01D71/28 , B01D71/40 , B01D71/44 , B01D2323/18 , B01D2323/30 , B01D2325/02 , B01D2325/021 , B01D2325/04
摘要： The invention provides composite nanofiltration membranes (FIG. 5) with lyotropic liquid crystal (LLC) polymer porous membranes (30) attached to a porous support (20). The LLC membranes are prepared from LLC monomers which form the inverted hexagonal or bicontinuous cubic phase. The arrangement, size, and chemical properties of the pores can be tailored on the molecular level. The composite membrane of the invention is useful for separation processes involving aqueous and nonaqueous solutions as well as gases. Methods for making and using the composite nanofiltration membranes of the inventions are also provided.
摘要翻译：本发明提供了复合纳滤膜（图5），其具有连接到多孔载体（20）上的溶致液晶（LLC）聚合物多孔膜（30）。 LLC膜由形成倒六角或双连续立方相的LLC单体制备。毛孔的布置，尺寸和化学性质可以在分子水平上进行调整。本发明的复合膜可用于涉及水和非水溶液以及气体的分离方法。还提供了制备和使用本发明的复合纳滤膜的方法。

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