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    • 28. 发明申请
    • PROCESS AND APPARATUS FOR CONTINUOUS PURIFICATION OF A SOLID MIXTURE BY FRACTIONAL SUBLIMATION/DESUBLIMATION
    • 通过分层次/连续连续固化固体混合物的方法和装置
    • US20110278276A1
    • 2011-11-17
    • US13146487
    • 2010-01-25
    • Markus LinsenbuehlerBernd SachwehJoerg HalpapMartin KarchesReinhold Rieger
    • Markus LinsenbuehlerBernd SachwehJoerg HalpapMartin KarchesReinhold Rieger
    • H05B1/00B01D7/00
    • B01D7/00C09B67/0096
    • A process is proposed for continuously purifying a solid mixture comprising a sublimable product of value and components with lower and higher sublimation temperatures by fractional sublimation/desublimation in a hot wall tubular oven (1) with supply of the solid mixture together with an inert gas stream, into which the solid mixture is dispersed by means of a dispersing unit (2), at one end of the hot wall tubular oven (1), heating the dispersed solid mixture in the hot wall tubular oven (1) at a temperature at which the product of value sublimes to obtain a gas mixture comprising components with a higher sublimation temperature than the product of value as solid particles, passing the gas mixture comprising components with a higher sublimation temperature than the product of value as solid particles through a hot gas filter (3) with a suitable pore size in order to retain the solid particles with a higher sublimation temperature than the product of value, cooling the gas mixture from which the components with a higher sublimation temperature than the product of value have been removed to a temperature at which the product of value desublimes, and at which the components with a lower sublimation temperature than the product of value are yet to desublime, to obtain a gas mixture comprising the particulate product of value and separating the purified particulate product of value from the cooled gas mixture.
    • 提出了一种通过在热壁管式烘箱(1)中通过分数升华/蒸发来连续纯化含有具有较低升华温度和升华升温温度的具有升华值的组分的可升华产物的固体混合物的方法,该固体混合物与惰性气体流 ,其中通过分散单元(2)将固体混合物分散在其中,在热壁管式烘箱(1)的一端处,在热壁管式烘箱(1)的一个温度下加热分散的固体混合物, 值得升值的产品以获得包含具有比作为固体颗粒的值高的升华温度的组分的气体混合物的气体混合物,使包含具有比作为固体颗粒的值高的升华温度的组分的气体混合物通过热气体过滤器 (3)具有合适的孔径,以便保持具有比值乘积更高的升华温度的固体颗粒,将气体混合物从 其中具有比值的乘积更高的升华温度的组分已经被去除到值均匀的产物的温度,并且具有低于值的产物的较低升华温度的组分尚未到时间的温度,以获得 气体混合物,其包含有价值的颗粒产物,并且将经纯化的颗粒产物与冷却的气体混合物分离。