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    • 21. 发明授权
    • Radiation absorbing polymer, composition for radiation absorbing coating, radiation absorbing coating and application thereof as anti-reflective coating
    • 辐射吸收聚合物,用于辐射吸收涂层的组合物,辐射吸收涂层及其作为抗反射涂层的应用
    • US06468718B1
    • 2002-10-22
    • US09244358
    • 1999-02-04
    • Wen-Bing KangMunirathna PadmanabanHatsuyuki TanakaKen KimuraTakanori KudoGeorg Pawlowski
    • Wen-Bing KangMunirathna PadmanabanHatsuyuki TanakaKen KimuraTakanori KudoGeorg Pawlowski
    • G03C173
    • C09D4/00C08F246/00G03F7/091C08F220/26C08F220/58C08F212/00
    • A radiation absorbing polymer having chemically bonded thereto a radiation absorbing dye, which has high absorption at a predetermined wavelength radiation, which shows good adhesion to a substrate and good thin film-forming, which has no dependence upon resists, which is soluble in a solvent for photoresists but becomes insoluble after being baked; a composition for radiation absorbing coating containing this polymer, and a radiation absorbing coating such as an anti-reflective coating formed from this composition are disclosed. The radiation absorbing polymer comprises a copolymer containing at least both a recurring unit composed of a monomer containing a keto group and a divalent group (preferably a methylene group) in its side chain and a recurring unit composed of a monomer containing an organic chromophore bonded directly or through a linkage group to the main chain. This radiation absorbing polymer is dissolved in a solvent such as alcohol, aromatic hydrocarbon, ketone, ester, etc., and the resulting solution is applied to a wafer and baked to form a radiation absorbing coating such as an anti-reflective coating. On this coating is coated, for example, a chemically amplified resist. This coated substrate is then exposed to deep UV rays and is developed to form a fine resist pattern excluding the influence of standing wave.
    • 一种辐射吸收聚合物,其化学键合有辐射吸收染料,该辐射吸收染料在预定波长辐射下具有高吸收性,其对基底具有良好的粘附性,并且与溶于溶剂的抗蚀剂无关的良好的薄膜形成 用于光致抗蚀剂,但在烘烤后变得不溶; 公开了含有这种聚合物的辐射吸收涂层用组合物和由该组合物形成的抗反射涂层等吸收辐射涂层。 辐射吸收聚合物包括共聚物,其至少包含由侧链中含有酮基和二价基团(优选亚甲基)的单体构成的重复单元,以及由含有直接键合的有机发色团的单体构成的重复单元 或通过连接组到主链。 将这种辐射吸收聚合物溶于醇,芳族烃,酮,酯等溶剂中,将所得溶液施加到晶片上并烘烤以形成抗辐射涂层等吸收辐射的涂层。 在该涂层上涂覆例如化学放大抗蚀剂。 然后将该涂覆的基材暴露于深紫外线,并显影以形成除了驻波的影响之外的精细抗蚀剂图案。