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21. 发明授权

US5310942A Pyridone dyes and thermal transfer thereof 失效
标题翻译：吡啶酮染料及其热转移
公开(公告)号：US5310942A
公开(公告)日：1994-05-10
申请号：US764194
申请日：1991-09-23
申请人： Volker Bach , Ruediger Sens , Karl-Heinz Etzbach
发明人： Volker Bach , Ruediger Sens , Karl-Heinz Etzbach
IPC分类号： C09B57/00 , B41M5/26 , B41M5/39 , C07D213/90 , C07D401/12 , C07D413/12 , C07D417/12 , C09B53/00 , D06P5/13
CPC分类号： B41M5/39 , C09B53/00
摘要： Pyridone transfer dyes have the formula ##STR1## where Q.sup.1 is hydrogen, fluorine, chlorine, methyl or a substituted amino radical,Q.sup.2 is hydrogen, fluorine or chlorine or Q.sup.1 and Q.sup.2 together with the carbon atoms to which they are attached form an aromatic carbocyclic or heterocyclic ring,x is a heterocyclic radical, a carboxylic or carboxamide radical or substituted amino radical andK is an aromatic radical.
摘要翻译：吡啶酮转移染料具有通式“IMAGE”，其中Q1是氢，氟，氯，甲基或取代的氨基，Q2是氢，氟或氯，或者Q1和Q2与它们所连接的碳原子一起形成芳族碳环或杂环，x是杂环基，羧基或羧酰胺基或取代的氨基，K是芳族基。

22. 发明授权

US5132438A Bichromophoric methine and azamethine dyes and process for transferring them 失效
标题翻译：双氯甲烷和氨基甲酸染料及其转移方法
公开(公告)号：US5132438A
公开(公告)日：1992-07-21
申请号：US650219
申请日：1991-02-04
申请人： Volker Bach , Karl-Heinz Etzbach , Ruediger Sens
发明人： Volker Bach , Karl-Heinz Etzbach , Ruediger Sens
IPC分类号： B41M5/385 , B41M5/26 , B41M5/388 , B41M5/39 , C09B23/00 , C09B23/10 , C09B53/00 , C09B53/02 , C09B55/00 , D06P5/13
CPC分类号： B41M5/385 , C09B23/105 , C09B53/02 , C09B55/009 , B41M5/3854 , B41M5/3856 , B41M5/39
摘要： Bichromophoric methine and azamethine transfer dyes have the formulaZ.sup.2 --Z.sup.1 --LY.sup.1 --Y.sup.2whereL is a bridge member which does not permit any conjugation of .pi.-electrons between Z.sup.1 and Y.sup.1,Y.sup.1 and Z.sup.1 are each independently of the other aminophenylene, which may be benzofused, or heterocyclyl andY.sup.2 and Z.sup.2 are each independently of the other benzoquinoeiminyl, which may be benzofused, or heterocyclyl.
摘要翻译：色氨酸次甲基和氮代甲基转移染料具有式Z2-Z1-LY1-Y2，其中L是不允许在Z1和Y1之间的π电子的任何共轭的桥接元件，Y1和Z1各自独立于另一个氨基亚苯基，或者是杂环基，Y 2和Z 2各自独立地是苯醌基，可以是苯并稠合的或杂环基。

23. 发明授权

US5312926A Indonaphthol dyes and thermal transfer thereof 失效
标题翻译：吲哚萘酚染料及其热转移
公开(公告)号：US5312926A
公开(公告)日：1994-05-17
申请号：US677291
申请日：1991-03-29
申请人： Volker Bach , Karl-Heinz Etzbach , Ruediger Sens
发明人： Volker Bach , Karl-Heinz Etzbach , Ruediger Sens
IPC分类号： B41M5/035 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , C09B23/00 , C09B23/04 , C09B53/00 , C09B53/02 , D06P5/13 , C07D277/46
CPC分类号： B41M5/3856 , C09B53/00 , B41M5/3854 , B41M5/39
摘要： Indonaphthol thermal transfer dyes have the formula ##STR1## where X is nitrogen or the radical CH,R.sup.1 and R.sup.2 are each independently of the other C.sub.1 -C.sub.6 -alkyl, which may be substituted, C.sub.1 -C.sub.6 -monooxaalkyl or -dioxaalkyl or allyl,R.sup.3 and R.sup.4 are each independently of the other hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkanoylamino, andR.sup.5 is five-membered hetaryl which is not benzofused and has two or more hetero atoms,with the proviso that R.sup.1 and R.sup.2 are not both unsubstituted C.sub.1 -C.sub.6 -alkyl at one and the same time.
摘要翻译：吲哚萘酚热转印染料具有式（I），其中X为氮或基团CH，R 1和R 2各自独立地为可被取代的C 1 -C 6 - 单氧烷基或 - 二氧杂环烷基或烯丙基的其它C 1 -C 6烷基， R 3和R 4各自独立地为另一个氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷酰基氨基，R 5为未被苯并且具有两个或多个杂原子的五元杂芳基，条件是R1和R2不是同时是未取代的C 1 -C 6烷基。

24. 发明授权

US5281572A Bichromorphic methine and azamethine dyes and process for transferring them 失效
标题翻译：双重染色体次甲基和azamethine染料及其转移过程
公开(公告)号：US5281572A
公开(公告)日：1994-01-25
申请号：US971598
申请日：1992-11-05
申请人： Volker Bach , Karl-Heinz Etzbach , Ruediger Sens
发明人： Volker Bach , Karl-Heinz Etzbach , Ruediger Sens
IPC分类号： B41M5/035 , B41M5/385 , B41M5/39 , C09B23/10 , C09B53/02 , C09B55/00 , B41M5/38
CPC分类号： B41M5/385 , C09B23/105 , C09B53/02 , C09B55/009 , B41M5/3854 , B41M5/3856 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： Bichromophoric methine and azamethine transfer dyes have the formulaZ.sup.2 --Z.sup.1 --LY.sup.1 --Y.sup.2whereinL is a bridge member which does not permit any conjugation of .pi.-electrons between Z.sup.1 and Y.sup.1,Y.sup.1 and Z.sup.1 are each independently of the other aminophenylene, which may be benzofused, or heterocyclyl andY.sup.2 and Z.sup.2 are each independently of the other benzoquinoneiminyl, which may be benzofused, or heterocyclyl.
摘要翻译：色氨酸次甲基和azamethine转移染料具有式Z2-Z1-LY1-Y2，其中L是不允许Z1和Y1之间的（pi）电子的任何共轭的桥接元件，Y1和Z1各自独立于另一个氨基亚苯基，其可以是苯并稠合的，或杂环基，并且Y 2和Z 2各自独立地为可以是苯并稠合的其它苯醌基或杂环基。

25. 发明授权

US5225548A Indophenol dyes and thermal transfer thereof 失效
标题翻译：吲哚酚染料及其转印
公开(公告)号：US5225548A
公开(公告)日：1993-07-06
申请号：US763272
申请日：1991-09-20
申请人： Volker Bach , Karl-Heinz Etzbach , Ruediger Sens
发明人： Volker Bach , Karl-Heinz Etzbach , Ruediger Sens
IPC分类号： C09B53/02 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , C09B53/00 , D06P5/13
CPC分类号： B41M5/3856 , C09B53/00 , B41M5/3854 , B41M5/39
摘要： Indophenol dyes of the formula ##STR1## where X is nitrogen or the radical CH,Q is a five-membered heterocyclic radical, andK is a radical of an aniline, aminonaphthalene, aminoquinoline or aminothiazole derivative, andthe radical A can be benzofused,are useful for thermal transfer processes.
摘要翻译：其中X是氮或基团CH，Q是五元杂环基团，K是苯胺，氨基萘，氨基喹啉或氨基噻唑衍生物的基团，并且基团A可以是苯并稠合的式IMAMA的吲哚酚染料，可用于热转印过程。

26. 发明授权

US5139997A Transfer of bichromophoric cyano-containing methine dyes 失效
标题翻译：含二茂铁的含有甲基染料的转染
公开(公告)号：US5139997A
公开(公告)日：1992-08-18
申请号：US650430
申请日：1991-02-04
申请人： Volker Bach , Karl-Heinz Etzbach , Ruediger Sens
发明人： Volker Bach , Karl-Heinz Etzbach , Ruediger Sens
IPC分类号： B41M5/385 , B41M5/035 , B41M5/132 , B41M5/26 , B41M5/30 , B41M5/388 , B41M5/39 , C09B23/00 , D06P5/13
CPC分类号： B41M5/3854 , Y10S428/913 , Y10S428/914
摘要： Bichromophoric methine transfer dyes of the formula ##STR1## where L is a bridge member which does not permit any conjugation of .pi.-electrons between Z and Y,X is cyano, C.sub.1 -C.sub.6 -alkoxycarbonyl or C.sub.1 -C.sub.6 -monoalkylcarbamoyl, wherein alkyl may in each case be interrupted by oxygen atoms, or is C.sub.5 -C.sub.7 -cycloalkoxycarbonyl, C.sub.5 -C.sub.7 -monocycloalkylcarbamoyl, phenoxycarbonyl or monophenylcarbamoyl,Y and Z are each independently of the other aminophenylene, which may be benzo-fused, or heterocyclyl,are transferable from a transfer to a sheet of plastic-coated paper with the aid of an energy source.
摘要翻译：其中L是不允许π电子在Z和Y之间任意共轭的桥接元件，X是氰基，C 1 -C 6 - 烷氧基羰基或C 1 -C 6 - 单烷基氨基甲酰基，其中烷基可以是在每种情况下都被氧原子中断，或者是C5-C7-环烷氧基羰基，C5-C7-单环烷基氨基甲酰基，苯氧基羰基或单苯基氨基甲酰基，Y和Z各自独立地是可以被苯并稠合或杂环基转移的另一氨基亚苯基从能量源的转移到一张塑料涂层纸。

27. 发明授权

US5580980A N-aminopyridone dyes 失效
标题翻译： N-氨基吡啶酮染料
公开(公告)号：US5580980A
公开(公告)日：1996-12-03
申请号：US140021
申请日：1993-11-01
申请人： Karl-Heinz Etzbach , Ernst Schefczik , Ruediger Sens , Matthias Wiesenfeldt
发明人： Karl-Heinz Etzbach , Ernst Schefczik , Ruediger Sens , Matthias Wiesenfeldt
IPC分类号： B41M5/385 , B41M5/26 , B41M5/388 , B41M5/39 , C07B57/00 , C07D213/89 , C07D265/36 , C09B23/00 , C09B23/02 , C09B23/04 , C09B53/00 , C09B55/00 , C09B57/00 , C07D215/38 , C07D277/38
CPC分类号： B41M5/3856 , C09B23/02 , C09B23/04 , C09B55/009 , B41M5/3854 , B41M5/39
摘要： Pyridone dyes useful for thermal transfer have the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, Y, X and Z are defined in the specification.
摘要翻译： PCT No.PCT / EP92 / 00505 Sec。 371日期：1993年11月1日 102（e）1993年11月1日PCT PCT。出版物WO92 / 19684 日期：1992年11月12日可用于热转移的吡啶酮染料具有式（I）其中R1，R2，R3，Y，X和Z在本说明书中定义。

28. 发明授权

US5302577A Transfer of anthraquinone dyes 失效
标题翻译：转移蒽醌染料
公开(公告)号：US5302577A
公开(公告)日：1994-04-12
申请号：US038867
申请日：1993-03-29
申请人： Ruediger Sens , Thomas Werner , Karl-Heinz Etzbach
发明人： Ruediger Sens , Thomas Werner , Karl-Heinz Etzbach
IPC分类号： B41M5/385 , B41M5/035 , B41M5/26 , B41M5/382 , B41M5/388 , B41M5/39 , B41M5/50 , B41M5/52 , C09B1/26 , D06P5/13 , B41M5/38
CPC分类号： B41M5/3852 , Y10S428/913 , Y10S428/914
摘要： Anthraquionone dyes are transferred by diffusion or sublimation from a carrier to a plastic-coated substrate with the aid of an energy source by using a carrier on which one or more anthraquinone dyes I ##STR1## where X is hydrogen or cyano,R.sup.1, R.sup.2 and R.sup.3 independently of one another are each hydrogen,alkyl, alkanoyloxyalkyl, alkoxycarbonyloxyalkyl or alkoxycarbonylalkyl, each of which may be of up to 20 carbon atoms and may be substituted by halogen, hydroxyl or cyano,phenyl or benzyl, each of which may be substituted by C.sub.1 -C.sub.15 -alkyl or C.sub.1 -C.sub.15 -alkoxy anda radical of the formula II[--W--O]n--R.sup.4 IIwhereW is identical or different C.sub.2 -C.sub.6 -alkylene radicals,n is from 1 to 6 andR.sup.4 is C.sub.1 -C.sub.4 -alkyl or unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted or C.sub.1 -C.sub.4 -alkoxy-substituted phenyl, are present.
摘要翻译：通过使用其上X是氢或氰基的一种或多种蒽醌染料I（* CHEMICAL STRUCTURE *）I的载体，借助能量源，通过扩散或升华将载体扩散或升华从载体转移到塑料涂覆的基材上， R 1，R 2和R 3彼此独立地各自为氢，烷基，烷酰氧基烷基，烷氧基羰氧基烷基或烷氧基羰基烷基，其各自可以具有至多20个碳原子，并且可以被卤素，羟基或氰基，苯基或苄基取代，可以被C 1 -C 15 - 烷基或C 1 -C 15 - 烷氧基和式II（-WO）n -R 4 ii的基团取代，其中W是相同或不同的C 2 -C 6亚烷基，n是1至6，R 4 是C1-C4烷基或未取代的或C1-C4-烷基取代或C1-C4-烷氧基取代的苯基。

29. 发明授权

US5208210A Thermal transfer printing 失效
标题翻译：热转印
公开(公告)号：US5208210A
公开(公告)日：1993-05-04
申请号：US763638
申请日：1991-09-23
申请人： Ruediger Sens , Karl-Heinz Etzbach
发明人： Ruediger Sens , Karl-Heinz Etzbach
IPC分类号： B41M5/385 , B41M5/035 , B41M5/26 , B41M5/388 , B41M5/39 , C09B1/51 , D06P5/13
CPC分类号： B41M5/3852 , Y10S428/913 , Y10S428/914
摘要： Anthraquinone dyes I useful for thermal transfer printing have the formula ##STR1## where R is alkyl, alkoxyalkyl, aryloxyalkyl, alkanoyloxyalkyl, alkoxycarbonyloxyalkyl or alkoxycarbonylalkyl, which may each contain up to 20 carbon atoms and whose carbon chains may be interrupted by form one to four oxygen atoms in ether function, or is C.sub.5 -C.sub.8 -cycloalkyl or phenyl which may each be substituted by C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy.
摘要翻译：可用于热转移印刷的蒽醌染料I具有式Ia：其中R是烷基，烷氧基烷基，芳氧基烷基，烷酰氧基烷基，烷氧基羰氧基烷基或烷氧基羰基烷基，其各自含有至多20个碳原子，并且其碳链可以被一个四个氧原子在醚中起作用，或者是C 5 -C 8 - 环烷基或苯基，其各自可被C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基取代。

30. 发明授权

US5162045A Transferring dyes for thermal printing 失效
标题翻译：转印用于热敏印刷的染料
公开(公告)号：US5162045A
公开(公告)日：1992-11-10
申请号：US606840
申请日：1990-10-31
申请人： Bernhard Albert , Karl-Heinz Etzbach , Ruediger Sens
发明人： Bernhard Albert , Karl-Heinz Etzbach , Ruediger Sens
IPC分类号： B41M5/26 , B41M5/385 , B41M5/388 , C09B29/03 , C09B29/033 , D06P5/13
CPC分类号： B41M5/385 , B41M5/3854 , B41M5/388 , Y10S8/922
摘要： Dyes are transferred from a carrier by sublimation/vaporization to plastic-coated papers by a process in which the dyes used are of the general formula (I) ##STR1## where A is D--N=N-- or ##STR2## R.sup.1 and R.sup.2 are each hydrogen, alkyl, alkoxy, alkylthio or halogen and R.sup.1 and R together may furthermore form a 5-membered or 6-membered heterocyclic ring, and R and R' independently of one another are each hydrogen, phenyl which is unsubstituted or substituted by methyl or methoxy, or C.sub.5 - or C.sub.6 -cycloalkyl or C.sub.1 -C.sub.6 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.2 -C.sub.5 -alkanoyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyloxy, C.sub.1 -C.sub.4 -alkoxy-C.sub.2 - or C.sub.3 -alkoxycarbonyloxy, hydroxyl, cyano, halogen, phenyl or C.sub.5 - or C.sub.6 cycloalkyl, or ##STR3## is a 5-membered or 6-membered saturated heterocyclic ring where D is a radical of a diazo component of the thiophene, thiazole, isothiazole or 1,2,4-thiadiazole series and R.sup.3 is hydrogen or CN.In the process, the dyes (I) give strong dyeings which have good light fastness and are resistant to chemical substances.
摘要翻译：染料通过升华/蒸发从载体转移到塑料涂布的纸上，其中使用的染料具有通式（I）的化合物（I），其中A是DN = N-或R1和 R 2各自为氢，烷基，烷氧基，烷硫基或卤素，R 1和R可以另外形成5元或6元杂环，R和R'彼此独立地为氢，未取代或取代的苯基 C 1 -C 4 - 烷氧羰基，C 2 -C 5 - 烷酰氧基，C 1 -C 4 - 烷氧基羰基氧基，C 1 -C 4 - 烷氧基羰基氧基，C 1 -C 4 - C 4 - 烷氧基-C 2 - 或C 3 - 烷氧基羰基氧基，羟基，氰基，卤素，苯基或C 5 - 或C 6环烷基，或者IMAGE是5元或6元饱和杂环，其中D是重氮组分噻吩，噻唑，异噻唑或1,2,4-噻二唑系列，R3为氢或CN。在此过程中，染料（I）产生强烈的染色，耐光性好，耐化学物质。

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