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    • 26. 发明授权
    • Method for producing thermoshaped substrates coated with a sol-gel lacquer
    • 制备涂有溶胶 - 凝胶漆的热固性基材的方法
    • US06482525B1
    • 2002-11-19
    • US09763521
    • 2001-02-23
    • Reiner KasemannNora KunzeHelmut SchmidtStefan Sepeur
    • Reiner KasemannNora KunzeHelmut SchmidtStefan Sepeur
    • B32B904
    • C08J7/047C08J2483/00C09D4/00Y10T428/31663C08G77/00
    • What is described is a method for producing a thermally shaped substrate coated with a sol-gel coating material, in which the sol-gel coating material comprises one or more hydrolyzable silanes, which may have been hydrolyzed to form a precondensate, and, if desired, a crosslinking agent, at least some of the hydrolyzable silanes containing on a non-hydrolyzable substituent a functional group by way of which crosslinking is possible, and in which A) the sol-gel coating material is applied to a thermally shapable substrate, B) the applied sol-gel coating material is partially precrosslinked and/or dried, C) the substrate coated with the sol-gel coating material is subsequently shaped thermally, and D) during and/or after the thermal shaping the sol-gel coating material is cured completely by means of thermal or photochemical crosslinking.
    • 描述的是制备涂覆有溶胶 - 凝胶涂层材料的热定形基材的方法,其中溶胶 - 凝胶涂层材料包含一种或多种可水解的硅烷,其可以被水解形成预缩合物,如果需要 交联剂,至少一些在不可水解取代基上含有官能团的可水解硅烷,其中交联是可能的,其中A)将溶胶 - 凝胶涂料施加到可热成形的基材上,B) 所施加的溶胶 - 凝胶涂层材料被部分预先交联和/或干燥,C)涂覆有溶胶 - 凝胶涂层材料的基材随后被热成型,并且D)在热成型期间和/或之后,溶胶 - 凝胶涂层材料被固化 完全通过热或光化学交联。
    • 27. 发明授权
    • Process of preserving paper
    • 保存纸张的过程
    • US6071475A
    • 2000-06-06
    • US068905
    • 1998-05-21
    • Helmut SchmidtReiner KasemannStefan SepeurHelmut Duddeck
    • Helmut SchmidtReiner KasemannStefan SepeurHelmut Duddeck
    • D21H25/18
    • D21H25/18
    • A process is disclosed for preserving paper involving the following steps:(a) a plurality of paper layers in contact with one another at least in regions is simultaneously brought into contact with a preservative fluid containing polycondensates based on one or more hydrolytic polycondensation-capable compounds of elements M of main groups III-V and sub-groups II-IV of the Periodic Table; in said polycondensates, at least one organic group (G) with at least two carbon atoms and for each carbon atom at least one atom selected from hydrogen or fluorine and without polar substituents is bound, either directly via one of the carbon atoms or via a connecting group A, to at least 0.1% of the central atoms M; and(b) the paper thus treated with the preservative fluid is dried and/or hardened.
    • PCT No.PCT / EP96 / 05176 Sec。 371日期1998年5月21日 102(e)日期1998年5月21日PCT 1996年11月22日PCT公布。 出版物WO97 / 19224 日期1997年5月29日公开了一种用于保存纸的方法,涉及以下步骤:(a)至少在区域中彼此接触的多个纸层同时与含有缩聚物的防腐液接触,所述防缩液基于一种或多种水解 主要III-V族和元素周期表Ⅱ-Ⅳ族元素M的缩聚能力化合物; 在所述缩聚物中,至少一个具有至少两个碳原子的有机基团(G)和对于每个碳原子,至少一个选自氢或氟并且没有极性取代基的原子直接通过碳原子之一或经由 将A族连接至至少0.1%的中心原子M; 和(b)用防腐剂流体处理的纸被干燥和/或硬化。
    • 28. 发明申请
    • METHOD FOR THE PRODUCTION OF A HIGHLY ABRASION-RESISTANT VEHICLE PAINT, VEHICLE PAINT, AND THE USE THEREOF
    • 生产高耐磨性车辆涂料,车辆涂料及其用途的方法
    • US20110082254A1
    • 2011-04-07
    • US12736181
    • 2009-03-18
    • Stefan SepeurNora LaryeaCarolin ThurnGerd Schlick
    • Stefan SepeurNora LaryeaCarolin ThurnGerd Schlick
    • B05D5/00B05D3/02B05D3/06C09D183/00
    • C09D183/10C08G18/246C08G18/3206C08G18/6225C08G18/6254C08G18/672C08G18/718C08G18/73C08G18/792C09D5/03
    • The invention relates to a method for the production of a highly abrasion-resistant vehicle paint, vehicle paint, and the use thereof.In order to create a vehicle paint having extremely high scratch and chemical resistance, particularly for use in multi-layer coating for OEM series coating (particularly as a clear coat or base cast), the invention proposes a method for the production of a highly abrasion-resistant vehicle paint, comprising the following steps: a. Providing at least one organic monomer, oligomer, prepolymer, or organosilane having one or more organic functional groups, or mixtures thereof; b. Saturating the functional groups described in a. by reacting them with silanes having organic side chains that contain one or more corresponding functional groups, the resultant silane having at least six SiOR groups and a molecular weight exceeding 300; c. Absorbing the resultant macro-molecular silanes in solvent, preferably protic or aprotic solvent, or mixtures thereof; d. Adding reaction partners, particularly acids, Lewis acids, bases or Lewis bases; e. Applying the vehicle paint obtained in this manner onto a substrate, and f. Curing the coating material.
    • 本发明涉及生产高耐磨性车漆,车漆及其用途的方法。 为了制造具有极高的耐划痕和耐化学性的车漆,特别是用于OEM系列涂层(特别是透明涂层或基底铸件)的多层涂层中,本发明提出了一种制造高度磨损的方法 耐车辆涂料,包括以下步骤:a。 提供至少一种有机单体,低聚物,预聚物或具有一个或多个有机官能团的有机硅烷,或其混合物; b。 饱和a中描述的官能团。 通过使它们与具有含有一个或多个相应官能团的有机侧链的硅烷反应,得到的硅烷具有至少六个SiOR基团并且分子量超过300; C。 将所得的大分子硅烷在溶剂中,优选质子或非质子溶剂或其混合物中吸收; d。 添加反应伴侣,特别是酸,路易斯酸,碱或路易斯碱; e。 将以这种方式获得的车漆施用到基材上,f。 固化涂料。
    • 29. 发明申请
    • METHOD FOR THE PRODUCTION OF A COATING MATERIAL
    • 涂料的生产方法
    • US20100092686A1
    • 2010-04-15
    • US12451131
    • 2008-04-28
    • Nora LaryeaCarolin ThurnStefan Sepeur
    • Nora LaryeaCarolin ThurnStefan Sepeur
    • B05D1/04C09D183/04C09D189/00C23C16/44B05D3/06
    • C09D183/04C08G18/3206C08G18/3812C08G18/4854C08G18/718C09D4/00C09D175/04C09D183/06C09D183/08C08G77/00C08G77/26
    • The invention relates to a method for producing a coating material as well as the use of the coating material.In order to provide a method for producing a novel coating material with which scratchproof coatings can be fabricated and which may also be used as coating powder, it is proposed within the scope of the invention that one or more organic molecules, oligomers or polymers comprising at least one functional group react with one or more silanes comprising at least one functional organic group on an organic side chain to form a covalent bond between the organic molecule, oligomer or polymer and the silane, thus resulting in a high-molecular-weight silane which can be cured directly by means of a catalyst.Surprisingly, it has been found that by reacting organically functionalized silanes, e.g. silanes that have an NCO— functional group (and are, at the most, slightly pre-crosslinked), with suitable reaction partners, a novel class of compounds can be produced which, in the form of coating powders, high-solids binders or 100 percent resins, may be used as coating material.
    • 本发明涉及涂料的制造方法以及涂料的使用。 为了提供一种制备可以制造防刮涂层并且也可以用作涂层粉末的新型涂料的方法,在本发明的范围内提出了一种或多种有机分子,低聚物或聚合物,其包含在 至少一个官能团与一个或多个包含有机侧链上的至少一个官能有机基团的硅烷反应,以在有机分子,低聚物或聚合物与硅烷之间形成共价键,从而得到高分子量硅烷, 可以通过催化剂直接固化。 令人惊奇的是,已经发现通过使有机官能化的硅烷例如 具有NCO-官能团(并且最多略微预先交联的)的硅烷与合适的反应伴侣可以生产出一类新颖的化合物,其以涂层粉末的形式,高固体粘合剂或100 百分比的树脂可以用作涂料。
    • 30. 发明申请
    • Silane coating material and a process to preduce silane coating
    • 硅烷涂层材料和一种减少硅烷涂层的工艺
    • US20090326146A1
    • 2009-12-31
    • US12311064
    • 2007-09-10
    • Stefan SepeurNora LaryeaCarolin ThurnGerd Schlick
    • Stefan SepeurNora LaryeaCarolin ThurnGerd Schlick
    • C08L83/06B05D3/10
    • C09D4/00C08G77/00C08G77/26
    • The invention relates to a silane coating material and a process to produce silane coating.To produce a silane coating material according to the preamble, in which the above-mentioned drawbacks are avoided, according to the invention a process to produce a silane coating is proposed where one or several silanes, which are not or only minimally pre-condensed, are charged with a reactant and the thus created coating material is applied onto a substrate and then hardened.Surprisingly it has been shown that, through the reaction involving higher-molecular and only slightly pre-cross-linked silanes with a suitable reactant, a new class of coating materials can be created. According to the current state of the art, silanes are processed in sol-gel processes, where pre-condensated species are assumed. The approach according to the invention is advantageous insofar as the restrictions with respect to pot time no longer exist and, in addition, better features of the coating material are obtained, especially a high scratch-resistance.
    • 本发明涉及一种硅烷涂层材料和一种生产硅烷涂层的方法。 为了制备根据前言的硅烷涂层材料,其中避免了上述缺点,根据本发明,提出了一种制备硅烷涂层的方法,其中一种或几种不是或仅最初预缩合的硅烷, 装入反应物,将由此产生的涂料施加到基材上然后硬化。 令人惊奇的是,已经表明,通过涉及具有合适反应物的较高分子和仅略微预交联的硅烷的反应,可以产生新类型的涂料。 根据目前的现有技术,硅烷在溶胶 - 凝胶法中被处理,其中假定了预缩合的物质。 根据本发明的方法是有利的,只要相对于加入时间的限制不再存在,并且另外获得涂层材料的更好的特征,特别是高耐划伤性。