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21. 发明授权

US06689724B2 Antioxidants and antioxidant boosters capable of producing hydroperoxyl radicals 失效
标题翻译：能够产生氢过氧基的抗氧化剂和抗氧化剂助剂
公开(公告)号：US06689724B2
公开(公告)日：2004-02-10
申请号：US09855125
申请日：2001-05-14
申请人： Haven S. Aldrich , Richard H. Schlosberg , Stanley J. Brois
发明人： Haven S. Aldrich , Richard H. Schlosberg , Stanley J. Brois
IPC分类号： C10M13348
CPC分类号： C07C233/18 , C07D263/14 , C07D263/52 , C09K15/30 , C10M105/32 , C10M105/38 , C10M105/40 , C10M107/02 , C10M129/76 , C10M133/16 , C10M133/48 , C10M159/12 , C10M159/18 , C10M169/04 , C10M2205/02 , C10M2205/0206 , C10M2207/2805 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/2835 , C10M2207/286 , C10M2207/287 , C10M2207/2875 , C10M2207/288 , C10M2207/2885 , C10M2207/289 , C10M2207/2895 , C10M2207/345 , C10M2215/064 , C10M2215/08 , C10M2215/082 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/227 , C10M2215/28 , C10M2215/30 , C10M2227/09 , C10N2210/01 , C10N2210/03 , C10N2210/04 , C10N2210/08 , C10N2230/08 , C10N2240/00 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/12 , C10N2240/121 , C10N2240/14 , C10N2240/22 , C10N2240/30 , C10N2240/401 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： An antioxidant which comprises a primary aliphatic hydroxyl group linked to an organic backbone such that upon oxidation a hydroperoxyl moiety capable of boosting the efficacy of free radical scavengers and hydroperoxide decomposer type antioxidants is generated in situ. The antioxidant is preferably a high hydroxyl polyol ester having a hydroxyl number ranging from about 30 to about 180 which ester is the reaction product of polyol and an acid which is at least fifty percent branched carboxylic acid, wherein the unconverted hydroxyl group is reacted with a facile leaving group, thereby producing free —CH2OH groups upon hydrolysis or oxidation.
摘要翻译：一种抗氧化剂，其包含与有机主链连接的伯脂肪族羟基，使得在氧化时，原位产生能够提高自由基清除剂和氢过氧化物分解剂型抗氧化剂功效的氢过氧基部分。抗氧化剂优选为羟基数为约30至约180的高羟基多羟基酯，该酯为多元醇与至少50％支化羧酸的酸的反应产物，其中未转化的羟基与从而在水解或氧化时产生游离的-CH 2 OH基团。

22. 发明授权

US06468319B1 Diesel fuel containing ester to reduce emissions 失效
标题翻译：含有柴油的酯油减少排放
公开(公告)号：US06468319B1
公开(公告)日：2002-10-22
申请号：US09615248
申请日：2000-07-13
申请人： Lisa I. Yeh , Richard H. Schlosberg
发明人： Lisa I. Yeh , Richard H. Schlosberg
IPC分类号： C10L118
CPC分类号： C10L1/026
摘要： This invention is a fuel composition comprising a major amount of base fuel and at least 3% w/w of an ester additive mixture derivable by reacting together either (a) (i) a saturated, aliphatic polyhydric alcohol having three or more primary alcohol groups, (ii) a C2-C15 saturated, aliphatic branched chain monohydric alcohol and (iii) a saturated, aliphatic C4-C10 dicarboxylic acid, or (b) a saturated aliphatic polyhydric alcohol having three or more primary alcohol groups with a C6-C15 saturated, aliphatic straight chain or branched chain monocarboxylic acid, or (c) a C2-C15 branched chain saturated aliphatic alcohol with a saturated, aliphatic dicarboxylic acid having 6-10 carbon atoms. The ester additive has a boiling point ≧150° C., a molecular weight ≧200 and an oxygen content ≧13% by weight of said ester additive mixture. The additive significantly reduces particulate emissions from the exhausts of diesel powered engines.
摘要翻译：本发明是一种燃料组合物，其包含主要量的基础燃料和至少3％w / w的酯添加剂混合物，其可以通过使（a）（i）具有三个或更多个伯醇基团的饱和脂肪族多元醇，（ii）C 2 -C 15饱和脂族支链一元醇和（iii）饱和的脂族C 4 -C 10二羧酸，或（b）具有三个或更多个具有C6-C15的伯醇基的饱和脂肪族多元醇饱和的脂族直链或支链一元羧酸，或（c）具有6-10个碳原子的饱和脂族二羧酸的C 2 -C 15支链饱和脂族醇。酯添加剂的沸点> 150℃ 分子量≥200且氧含量> 13重量％的所述酯添加剂混合物。该添加剂显着减少柴油发动机排气的颗粒物排放。

23. 发明授权

US06303827B1 Process for making aromatic aldehydes 失效
标题翻译：制备芳香族醛的方法
公开(公告)号：US06303827B1
公开(公告)日：2001-10-16
申请号：US09393664
申请日：1999-09-10
申请人： Ramzi Yanni Saleh , Christopher L. Becker , Robert C. Michaelson , Richard H. Schlosberg
发明人： Ramzi Yanni Saleh , Christopher L. Becker , Robert C. Michaelson , Richard H. Schlosberg
IPC分类号： C07C4500
CPC分类号： C07C47/542 , C07C7/14858 , C07C45/49 , C07C45/82 , C07C51/235 , C07C51/265 , C07C63/16 , C07C63/26 , C07C63/307 , C07C15/08
摘要： Alkyl aromatic compounds are converted to alkyl aromatic aldehydes by a carbonylation reaction. The carbonylation catalyst can be a high boiling point carbonylation catalyst which allows for the separation of the aldehyde product by selective volatilization. Alternatively, the carbonylation catalyst can be selected from perfluoroalkyl sulfonic acids having 2 to 18 carbon atoms, perfluoroether sulfonic acids having 2 to 18 carbon atoms, BF3(ROH)x wherein R represents CH3 or H and X is a number within the range of from 0.2 to 2, GaBr3, GaCl3, TaF5, NbF5, and NbBr5, with the proviso that when the catalyst is TaF5, NbF5, or NbBr5, then the reaction takes place in the absence of added HF. Preferably, all of the carbonylation reactions take place in the absence of added HF. The alkyl aromatic aldehydes can be oxidized to form an aromatic acid. A mixed xylene feed stock can be converted to a mixture of dimethylbenzaldehydes and then oxidized to form trimellitic acid without the need to separate the xylene or dimethylbenzaldehyde isomers.
摘要翻译：烷基芳族化合物通过羰基化反应转化成烷基芳族醛。羰基化催化剂可以是高沸点羰基化催化剂，其允许通过选择性挥发来分离醛产物。或者，羰基化催化剂可以选自具有2至18个碳原子的全氟烷基磺酸，具有2至18个碳原子的全氟醚磺酸，BF 3（ROH）x其中R表示CH 3或H，X是在 0.2至2，GaBr 3，GaCl 3，TaF 5，NbF 5和NbBr 5，条件是当催化剂为TaF 5，NbF 5或NbBr 5时，则在不加入HF的情况下进行反应。优选地，所有的羰基化反应都在不加入HF的情况下进行。烷基芳族醛可被氧化形成芳族酸。混合二甲苯原料可以转化成二甲基苯甲醛的混合物，然后氧化形成偏苯三酸，而不需要分离二甲苯或二甲基苯甲醛异构体。

24. 发明授权

US5698722A Functionalization of polymers based on Koch chemistry and derivatives thereof 失效
标题翻译：基于Koch化学及其衍生物的聚合物的功能化
公开(公告)号：US5698722A
公开(公告)日：1997-12-16
申请号：US469561
申请日：1995-06-06
申请人： Joseph Victor Cusumano , William Daniel Diana , Jacob Emert , Keith Raymond Gorda , Richard H. Schlosberg , David A. Young , William Bernard Eckstrom , Edris Eileen Manry , Michael John Keenan
发明人： Joseph Victor Cusumano , William Daniel Diana , Jacob Emert , Keith Raymond Gorda , Richard H. Schlosberg , David A. Young , William Bernard Eckstrom , Edris Eileen Manry , Michael John Keenan
IPC分类号： C10M159/12 , B01J10/00 , B01J19/24 , C07C51/14 , C07C67/38 , C08F8/00 , C08F8/10 , C08F8/32 , C08F8/34 , C08L23/26 , C08L101/00 , C08L101/06 , C10L1/14 , C10L1/18 , C10L1/195 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/2383 , C10L1/24 , C10L1/26 , C10L1/28 , C10L1/30 , C10L10/00 , C10M129/95 , C10M133/06 , C10M133/52 , C10M133/54 , C10M133/56 , C10M143/00 , C10M145/12 , C10M149/06 , C10M159/18 , C10N20/04 , C10N30/04 , C07C59/255
CPC分类号： C10M159/18 , B01J19/2415 , B01J19/242 , C07C51/14 , C07C67/38 , C08F8/00 , C08F8/10 , C08F8/14 , C08F8/18 , C08F8/32 , C08F8/34 , C10L1/143 , C10L1/1817 , C10L1/195 , C10L1/198 , C10L1/206 , C10L1/221 , C10L1/236 , C10L1/238 , C10L1/2383 , C10L1/2475 , C10L1/2493 , C10L1/2691 , C10L1/285 , C10L1/303 , C10L10/04 , C10M129/95 , C10M133/06 , C10M133/52 , C10M133/54 , C10M133/56 , C10M143/00 , C10M145/12 , C10M149/06 , B01J2219/00094 , C08F2800/20 , C10L1/208 , C10L1/2387 , C10L1/2683 , C10L1/30 , C10M2207/023 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/289 , C10M2209/00 , C10M2209/02 , C10M2209/082 , C10M2209/10 , C10M2215/04 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/22 , C10M2215/221 , C10M2215/224 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/28 , C10M2215/30 , C10M2217/024 , C10M2217/046 , C10M2217/06 , C10M2219/062 , C10M2227/061 , C10M2227/09 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2210/05 , C10N2210/06 , C10N2210/07 , C10N2210/08 , C10N2240/00 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/22 , C10N2240/30 , C10N2240/40 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2270/02
摘要： A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.
摘要翻译：作为至少一种数均分子量为至少500且每个聚合物链至少烯属双键的聚合物与一氧化碳和亲核捕集剂的反应产物的Koch官能化产物。本发明包括官能化聚合物，其衍生物及其制备方法。

25. 发明授权

US5691422A Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof 失效
标题翻译：具有末端醛或羟基取代基的饱和聚烯烃及其衍生物
公开(公告)号：US5691422A
公开(公告)日：1997-11-25
申请号：US662835
申请日：1996-06-12
申请人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
发明人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
IPC分类号： C08F8/00 , C08F8/32 , C08F210/16 , C08F210/18 , C10L1/198 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10M133/54 , C10M133/58
CPC分类号： C10M133/58 , C08F210/18 , C08F8/00 , C08F8/32 , C10L1/198 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/18 , C10M133/54 , C08F210/16 , C10M2215/04 , C10M2215/042 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06
摘要： A saturated polymer having a terminal aldehyde or hydroxy substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the saturated polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical, and wherein the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.
摘要翻译：具有末端醛或羟基取代基的饱和聚合物，其可以直接或以衍生形式用作燃料和润滑油组合物的分散剂，其中饱和聚合物的Mn为约300至10,000，并且衍生自聚烯烃其衍生自式H2C = CHR4的单体，其中R4是氢或直链或支链烷基，并且其中聚烯烃具有至少约30％的末端亚乙烯基不饱和键。特别理想的胺衍生物可以通过单步氨基甲基化方法或两步加氢甲酰化和还原胺化方法形成。

26. 发明授权

US4277327A Treatment of phenol-containing feed streams 失效
标题翻译：处理含苯酚的进料流
公开(公告)号：US4277327A
公开(公告)日：1981-07-07
申请号：US95642
申请日：1979-11-19
申请人： Richard H. Schlosberg , Martin L. Gorbaty
发明人： Richard H. Schlosberg , Martin L. Gorbaty
IPC分类号： C07C41/01 , C10G29/20 , C10G19/08 , C07C41/00
CPC分类号： C10G29/205 , C07C41/16
摘要： Phenol-containing streams are treated by an oxygen-alkylation process to convert substantially all of the phenol groups to ether groups. The oxygen-alkylation process comprises contacting the phenol-containing stream, preferably a coal liquid, with (a) a basic solution comprising one or more oxides or hydroxides of a metal selected from the group consisting of alkali and alkaline-earth metals; and (b) an alkylating agent represented by the formula RX where R is a C.sub.1 to C.sub.18 alkyl, allyl, cycloalkyl, haloalkyl, benzyl or arylalkyl group provided X is located on the alkyl portion of the compound and X is sulfate or a halide selected from the group consisting of chlorine, bromine and iodine.
摘要翻译：含有苯酚的物流通过氧 - 烷基化方法处理，将基本上所有的苯酚基团转化为醚基团。氧 - 烷基化方法包括使含苯酚的物流，优选煤液体与（a）包含一种或多种选自碱金属和碱土金属的金属的一种或多种氧化物或氢氧化物的碱性溶液接触; 和（b）由式RX表示的烷基化剂，其中R是C1至C18烷基，烯丙基，环烷基，卤代烷基，苄基或芳烷基，提供X位于化合物的烷基部分上，X为硫酸酯或选择卤化物由氯，溴和碘组成的组。

27. 发明授权

US4277326A Oxygen alkylation of phenol-containing hydrocarbonaceous streams 失效
标题翻译：含苯酚的含烃物流的氧烷基化
公开(公告)号：US4277326A
公开(公告)日：1981-07-07
申请号：US95641
申请日：1979-11-19
申请人： Richard H. Schlosberg , Charles G. Scouten
发明人： Richard H. Schlosberg , Charles G. Scouten
IPC分类号： C07C41/01 , C10G29/20 , C10G19/08 , C07C41/00
CPC分类号： C10G29/205 , C07C41/16
摘要： Process for improving properties of phenol-containing hydrocarbonaceous streams such as a coal liquid by contacting stream with (a) a multivalent metal composition selected from the group consisting of oxides and/or hydroxides of multivalent metals capable of forming hydroxy metal phenates with the phenols of the stream; and (b) one or more alkylating agents represented by the formula RX where R is a C.sub.1 to C.sub.18 group selected from the group consisting of alkyl, allyl, cycloalkyl, haloalkyl, benzyl, and arylalkyl, provided X is located on the alkyl portions of the alkylating agent and X is sulfate or a halide.
摘要翻译：通过使物流与（a）选自能够形成羟基金属酚盐的多价金属的氧化物和/或氢氧化物的多价金属组合物与酚的酚类化合物流; 和（b）一种或多种由式RX表示的烷基化剂，其中R是选自烷基，烯丙基，环烷基，卤代烷基，苄基和芳基烷基的C1至C18基团，条件是X位于烷基化剂和X是硫酸盐或卤化物。

28. 发明授权

US4256568A Removal of phenols from phenol-containing streams 失效
标题翻译：从含苯酚流中除去酚
公开(公告)号：US4256568A
公开(公告)日：1981-03-17
申请号：US95640
申请日：1979-11-19
申请人： Richard H. Schlosberg , Charles G. Scouten
发明人： Richard H. Schlosberg , Charles G. Scouten
IPC分类号： C07C37/86 , B01J23/00 , B01J23/74 , B01J23/755 , C07C27/00 , C07C37/00 , C07C39/04 , C07C67/00 , C10G19/073 , C10G29/16 , C10G1/00 , C07C19/08 , C07C37/68 , C10G19/08
CPC分类号： C07C37/005 , C10G19/073 , C10G29/16
摘要： Process for removing phenols from phenol-containing streams such as coal liquids by contacting the stream with a multivalent metal composition selected from the group consisting of oxides and/or hydroxides of one or more multivalent metals capable of forming a hydroxy metal phenate with the phenols of the stream; separating the hydroxy metal phenate from the treated stream; and heating the hydroxy metal phenate to its decomposition temperature, thereby forming phenols and oxides of the multivalent metal.
摘要翻译：通过使物流与多价金属组合物接触，从含酚物流如煤液中除去酚的方法，该多价金属组合物选自一种或多种能形成羟基金属酚盐的多价金属的氧化物和/或氢氧化物，流; 从处理的流中分离羟基金属酚盐; 并将羟基金属酚盐加热至其分解温度，从而形成多价金属的酚和氧化物。

29. 发明授权

US4092235A Treatment of coal by alkylation or acylation to increase liquid products from coal liquefaction 失效
标题翻译：通过烷基化或酰化处理煤，以增加煤液化产物
公开(公告)号：US4092235A
公开(公告)日：1978-05-30
申请号：US635706
申请日：1975-11-26
申请人： Richard H. Schlosberg , Peter S. Maa , Richard C. Neavel
发明人： Richard H. Schlosberg , Peter S. Maa , Richard C. Neavel
IPC分类号： C10G1/00 , C10G1/06
CPC分类号： C10G1/065 , C10G1/00 , Y10S208/951
摘要： The production of liquid hydrocarbons from coal is significantly enhanced by alkylating or acylating the coal prior to subjecting the coal to liquefaction conditions. The introduction of aliphatic hydrocarbon radicals or acyl radicals, including carbon monoxide, into the coal structure is believed to permit more of the coal to undergo liquefaction at suitable liquefaction conditions. The alkylation or acylation reactions can be conducted in the presence or absence of added or extraneous catalysts.
摘要翻译：在煤经历液化条件之前，通过烷化或酰化煤，显着提高了来自煤的液体烃的生产。据信，在煤结构中引入脂族烃基或酰基，包括一氧化碳，允许更多的煤在合适的液化条件下经历液化。烷基化或酰化反应可以在存在或不存在加入的或外来的催化剂的情况下进行。

30. 发明授权

US10519380B2 Hydrocarbon extraction of oil from oil sand 有权
公开(公告)号：US10519380B2
公开(公告)日：2019-12-31
申请号：US13273003
申请日：2011-10-13
申请人： Edward L. Diefenthal , Richard D. Jordan , Richard H. Schlosberg
发明人： Edward L. Diefenthal , Richard D. Jordan , Richard H. Schlosberg
IPC分类号： C10G1/04
摘要： This invention provides a process for producing a crude oil composition from oil sand using a solvent comprised of a hydrocarbon mixture to extract or remove only a portion of the bitumen on the oil sand. The solvent type and the manner by which the extraction process is carried out has substantial impact on the quality of the extracted oil component. The solvent is designed so that it has the desired Hansen solubility parameters that enable the partial extraction of the desired oil composition. The solvent is further designed so that it can be comprised of multiple hydrocarbons having the appropriate boiling point ranges that enable the solvent to be easily recovered and recycle, without the need to externally provide for solvent make-up.

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