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    • 21. 发明授权
    • Highly hard material coated articles
    • 高硬度材料涂层制品
    • US4401719A
    • 1983-08-30
    • US258550
    • 1981-04-29
    • Mitsunori KobayashiYoshihiko Doi
    • Mitsunori KobayashiYoshihiko Doi
    • B23B27/14B23P15/28C23C14/06C23C14/32C23C30/00C30B28/12C30B29/36C30B29/38B32B15/04B05D3/06C23C15/00
    • C23C14/32C23C30/00C23C30/005Y10S428/911Y10T428/24983Y10T428/31678
    • This invention relates to a highly hard material coated article which comprises a substrate of tool or part consisting of cermets, cemented carbides, tool steels or stainless steels and at least one highly hard material coated on the surface thereof, selected from the group consisting of carbides, nitrides and carbonitrides of at least one of titanium, zirconium and hafnium and those in which oxygen is dissolved, the coating being formed by an ion plating method wherein the accelerating voltage is high in a short time at the initial stage only, the crystals of the coated film being strongly orientated in the direction of for the surface of the tool or part so that the diffraction intensity ratio of the peak from the {220} plane and the secondly strong diffraction peak in the X-ray diffraction using Cu-K.alpha. ray, that is, the diffraction intensity ratio is 15 or less of the latter to 100 of the former and the half value width of the diffraction peak from the {220} plane of the coating film being 0.8.degree. or more than 2 .theta. scale.
    • 本发明涉及一种高硬度材料涂层制品,其包括由金属陶瓷,硬质合金,工具钢或不锈钢组成的工具或部件的基底,以及涂覆在其表面上的至少一种高硬度材料,其选自碳化物 ,钛,锆和铪中的至少一种的氮化物和碳氮化物以及氧气溶解的氮化物和碳氮化物,通过离子镀法形成涂层,其中仅在初始阶段的短时间内的加速电压高, 该涂膜对于工具或部件的表面以<220°的方向强烈取向,使得在使用Cu的X射线衍射中,来自{220}面的峰与第二强衍射峰的衍射强度比 -Kα射线,也就是说,后者的衍射强度比为15以下,前者的100倍和来自c的{220}面的衍射峰的半值宽度 浇注膜为0.8°或2°以上。
    • 23. 发明授权
    • Recording device and recording method for optical recording medium
    • 光记录介质的记录装置和记录方法
    • US08203923B2
    • 2012-06-19
    • US12952977
    • 2010-11-23
    • Toshio ShojiMitsunori Kobayashi
    • Toshio ShojiMitsunori Kobayashi
    • G11B7/00
    • G11B7/0062G11B7/126
    • It is desired that the overshooting and undershooting of optical pulse waveforms of optical pickups included in optical disk devices be reduced to improve the quality of recording. Among pulses to be recorded, the trailing edge of each last pulse and the leading edge of the subsequent erase top pulse are made to almost coincide with each other. Ratio a/b, where a is the difference between erase top pulse power level Pet and erasing power level Pe and b is the difference between recording power level Pw and the erasing power level Pe, is adjusted to realize an optical pulse waveform with reduced overshooting and undershooting for each of different recording media. Erase top pulse duration Tert is switched according to different recording speeds for different recording media.
    • 期望减少包含在光盘装置中的光学拾取器的光脉冲波形的过冲和下冲以提高记录质量。 在要记录的脉冲中,使每个最后脉冲的后沿和随后的擦除顶部脉冲的前沿彼此几乎一致。 比率a / b,其中a是擦除顶部脉冲功率电平Pet和擦除功率电平Pe之间的差值,b是记录功率电平Pw和擦除功率电平Pe之间的差异,被调整以实现具有减小的超调的光脉冲波形 并且对每个不同的记录媒体进行低估。 擦除顶部脉冲持续时间根据不同记录媒体的不同记录速度切换Tert。
    • 24. 发明申请
    • Optical Disc Apparatus and Method for Recording Information Using the Same
    • 光盘装置及使用其的记录信息的方法
    • US20100020653A1
    • 2010-01-28
    • US12420329
    • 2009-04-08
    • Mitsunori KobayashiTetsuya Fushimi
    • Mitsunori KobayashiTetsuya Fushimi
    • G11B20/10
    • G11B7/1267
    • This invention provides an optical disc apparatus constructed to discriminate a disc ID of an optical disc on which information is to be recorded, then derive, from a strategy pre-registered in the optical disc apparatus, test-recording repetition count information that matches the discriminated disc ID, and after using the derived test-recording repetition count information to assign the number of test-recordings to be conducted upon one specific address within a test-recording area of the optical disc, implement the assigned number of test-recordings and calculate an optimum recording power level for information recording, based upon a read signal generated after the final test-recording. The above construction improves recording power accuracy of information recording on rewritable optical discs.
    • 本发明提供了一种光盘装置,其被构造为鉴别要记录信息的光盘的盘ID,然后从预先登记在光盘装置中的策略导出与被识别的信息相匹配的测试记录重复计数信息 光盘ID,并且在使用导出的测试记录重复计数信息来分配在光盘的测试记录区域内的一个特定地址上进行的测试记录的数量,实现分配的测试记录数量并计算 基于在最终测试记录之后产生的读取信号,用于信息记录的最佳记录功率电平。 上述结构提高了可重写光盘上的信息记录的记录功率精度。
    • 25. 发明授权
    • Plate type member for semiconductor device package and package
    • 半导体器件和封装的板型元件
    • US5990548A
    • 1999-11-23
    • US671058
    • 1996-06-27
    • Mitsunori KobayashiAkira FukuiKouichi Takashima
    • Mitsunori KobayashiAkira FukuiKouichi Takashima
    • C22C27/04H01L21/48H01L23/14H01L23/373H01L23/492H01L23/10H01L23/48H01L23/52
    • H01L23/3736H01L21/4871H01L23/4922H01L2924/15312
    • A plate type member of a Cu--W and/or Mo alloy can be bonded to a ceramic member or the like to form a semiconductor device package without problems, because the degree of warping of the plate type member during a heating step in its fabrication is suppressed. In the plate type member consisting of a Cu--W and/or Mo alloy, including a small amount of alkaline earth metal impurity the difference between alkaline earth metal contents in upper and lower halves of the member along the thickness direction is not more than 10 ppm, or delete "an alkaline earth" preferably not more than 5 ppm relative to the content of W and/or Mo. This plate type member is manufactured by reducing the alkaline earth metal content in W and/or Mo raw material powder, or standing a skeleton vertically upright on a refractory plate for carryiing out Cu infiltration, and performing homogeneous heating and cooling replace during the manufacturing thereby preventing maldistribution of the alkaline earth metal.
    • 由于在其制造中的加热步骤期间板型构件的翘曲程度,Cu-W和/或Mo合金的板状构件可以被接合到陶瓷构件等以形成半导体器件封装, 被压制 在由包含少量碱土金属杂质的Cu-W和/或Mo合金构成的板状部件中,沿着厚度方向的部件的上下半部分的碱土金属含量之差不大于10 ppm,或相对于W和/或Mo的含量,删除“碱土”,优选不大于5ppm。该板型构件通过降低W和/或Mo原料粉末中的碱土金属含量来制造,或 竖立竖立在耐火板上的骨架,以进行Cu渗透,并且在制造过程中进行均匀的加热和冷却替换,从而防止碱土金属的分布不均。
    • 26. 发明授权
    • Coated cemented carbide member
    • 涂覆硬质合金构件
    • US5914181A
    • 1999-06-22
    • US885982
    • 1997-06-30
    • Katsuya UchinoToshio NomuraMitsunori KobayashiMasuo Chudo
    • Katsuya UchinoToshio NomuraMitsunori KobayashiMasuo Chudo
    • C22C29/02C22C29/06C23C30/00
    • C22C29/06C22C29/02C23C30/005B22F2998/00Y10T407/27Y10T428/24942Y10T428/24975Y10T428/265Y10T428/31714
    • A coated cemented carbide member includes a cemented carbide base material containing a binder metal of at least one iron family metal and a hard phase, and a coating layer provided on the surface of the cemented carbide base material. The hard phase contains at least one metal component selected from carbides, nitrides, carbo-nitrides and carbonic nitrides of Zr and/or Hf and WC. A layer consisting of only WC and an, iron family metal or a binder phase enriched layer or a low hardness layer is provided on an outermost surface of each insert edge portion of the cemented carbide base material. The coating layer is a single or multiple layer consisting of at least one metal component selected from carbides, nitrides, carbo-nitrides, oxides and borides of metals belonging to the groups IVB, VB and VIB of the periodic table. Due to this structure, it is possible to improve chipping resistance with no deterioration of wear resistance in the coated cemented carbide member to be used, for example, as a cutting tool.
    • 涂覆的硬质合金构件包括含有至少一种铁族金属和硬质相的粘合剂金属的硬质合金基体材料和设置在硬质合金基体材料的表面上的涂层。 硬相包含至少一种选自Zr和/或Hf和WC的碳化物,氮化物,碳氮化物和碳氮化物的金属组分。 在硬质合金基材的每个嵌入件边缘部分的最外表面上设置仅由WC和铁族金属或粘结剂相富集层或低硬度层组成的层。 涂层是由选自元素周期表的IVB,VB和VIB族金属的碳化物,氮化物,碳氮化物,氧化物和硼化物中的至少一种金属组分组成的单层或多层。 由于这种结构,可以在所使用的涂覆硬质合金构件例如作为切削工具的情况下,不会劣化耐磨损性而提高抗碎裂性。
    • 27. 发明授权
    • Diamond-coated hard material and a process for the production thereof
    • 金刚石涂层硬质材料及其制造方法
    • US5370944A
    • 1994-12-06
    • US30260
    • 1993-04-27
    • Naoya OmoriMitsunori KobayashiToshio Nomura
    • Naoya OmoriMitsunori KobayashiToshio Nomura
    • C22C1/05C23C30/00B22F7/07B22F7/06C23C16/22
    • C23C30/005C22C1/051Y10T428/12021Y10T428/12028Y10T428/12049Y10T428/12056Y10T428/12146
    • This invention relates to a diamond-coated hard material and a process for the production of the same. The feature of the diamond-coated hard material consists in that in a diamond-coated hard material comprising a substrate of a tungsten carbide-based cemented carbide having a diamond-coated layer provided on the surface of the substrate, a surface-modified layer containing no binder phase or containing a binder phase in a proportion of less than in the interior part of the substrate is present on the outermost surface of the substrate. This hard material can be produced by converting the substrate material into a sintered or heat treated surface or skin and then coating with diamond. The diamond-coated hard material of the present invention has such a high wear resistance and excellent bonding strength to the substrate that it can favorably be applied to various tools, parts, grinding wheels, etc.
    • PCT No.PCT / JP92 / 00919 Sec。 371日期:1993年4月27日 102(e)日期1993年4月27日PCT提交1992年7月17日PCT公布。 出版物WO93 / 020222 日期:1993年2月4日。本发明涉及金刚石涂层硬质材料及其制造方法。 金刚石涂覆的硬质材料的特征在于,在金刚石涂覆的硬质材料中,其包含设置在基材表​​面上的具有金刚石涂层的碳化钨基硬质合金的基材,含有 在基板的最外表面上不存在粘结相或者比基板内部少的粘结相。 这种硬质材料可以通过将基底材料转变成烧结或热处理的表面或皮肤,然后用金刚石涂覆来制备。 本发明的金刚石涂层硬质材料具有如此高的耐磨性和对基材的优异的粘结强度,可有利地应用于各种工具,零件,砂轮等。
    • 29. 发明授权
    • Process of physical vapor deposition
    • 物理气相沉积过程
    • US4507189A
    • 1985-03-26
    • US316906
    • 1981-10-30
    • Yoshihiko DoiYoshiki MaedaMitsunori Kobayashi
    • Yoshihiko DoiYoshiki MaedaMitsunori Kobayashi
    • C23F4/00B23P15/28C23C14/02C23C14/06C23C14/08C23C30/00C23C15/00
    • B23P15/28C23C14/022C23C30/005
    • The present invention relates to a process of physical vapor deposition which homogeneously and tightly coats hard compounds on the surface of cutting tools, parts requiring wear resistance or ornaments such as a watch case and the like in order to improve wear resistance, heat resistance, corrosion resistance, appearance and the like of said tools, parts or ornaments.The present invention can provide a method of physically coating a solid solution consisting of at least one compound selected from the group consisting of carbides, nitrides or oxides of metals belonging to IVb, Vb and VIb groups of the Periodic Table and/or aluminum oxide and zirconium oxide on the surface of said tools, parts or ornaments in the form of a single layer or multiple-layers, wherein the surface of said tools and the like is subjected to sputter cleaning in the atmosphere of hydrogen or the gaseous mixture of hydrogen and inert gas wherein hydrogen is present at 20% by volume or more, to homogeneously clean said surface of said tools and the like and as a result, the adhesion of the coating consisting of said compounds on said tools and the like is improved and equalized. Thus the above-mentioned properties of said tools and the like is further improved.
    • 本发明涉及一种物理气相沉积方法,其在切削工具的表面上均匀且紧密地涂覆硬化合物,需要耐磨性的部件或诸如表壳等的装饰品,以改善耐磨性,耐热性,腐蚀性 所述工具,零件或装饰品的阻力,外观等。 本发明可以提供一种物理地涂覆由至少一种选自元素周期表的IVb,Vb和VIb族的金属的碳化物,氮化物或氧化物的化合物组成的固溶体的方法和/或氧化铝,以及 所述工具的表面上的氧化锆,单层或多层形式的零件或装饰品,其中所述工具等的表面在氢气气氛或氢气的气体混合物中进行溅射清洗 惰性气体,其中氢以20体积%以上存在,以均匀地清洁所述工具等的所述表面,结果,由所述化合物组成的涂层在所述工具等上的粘附性得到改善和均衡。 因此,进一步提高了所述工具等的上述特性。