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    • 23. 发明授权
    • Bleach additive and bleaching compositions having glycine anhydride
activators
    • 漂白添加剂和具有甘氨酸酐活化剂的漂白组合物
    • US5879409A
    • 1999-03-09
    • US606124
    • 1996-02-23
    • Kevin Lee KottAlan David Willey
    • Kevin Lee KottAlan David Willey
    • C11D3/28C11D3/39C11D3/395C11D17/08C11D7/54D06L3/02
    • C11D3/3947C11D3/392
    • Bleach-additives and bleaching compositions comprising glycine anhydride activators are provided. The activators have the general formulas of: ##STR1## wherein R.sub.1 and R.sub.2 can be the same or different and are a substituted or unsubstituted C.sub.1 -C.sub.9 alkyl or aryl residue; or ##STR2## where n is 0 to 50, R.sub.3 is a linear or branched alkyl, aryl, or alkaryl or arylalk with C.sub.1 -C.sub.25, --H, --OH, --OR.sub.5, --COOM, or SO.sub.3 M, where M is H or alkali metal or alkaline earth metal; R.sub.4 is a linear or branched alkylene, arylene, or alkylarylene or arylalkylene with C.sub.1 -C.sub.25 ; and, R.sub.5 is a linear or branched alkyl, aryl, or alkaryl or arylalk with C.sub.1 -C.sub.25. The compositions display low soil resistivity and are formulated to provide in-use pH values of from 7 to about 9.5. Additional ingredients may include detersive surfactants, emulsifiers, chelants, and nonsoap pH reducing ingredients. Both granular and liquid compositions are provided.
    • 提供了含有甘氨酸酐活化剂的漂白剂和漂白组合物。 活化剂具有以下通式:其中R 1和R 2可以相同或不同,并且是取代或未取代的C 1 -C 9烷基或芳基残基; 或其中n为0至50,R 3为具有C 1 -C 25,-H,-OH,-OR 5,-COOM或SO 3 M的直链或支链烷基,芳基或烷芳基或芳基烷基,其中M为H或 碱金属或碱土金属; R4是具有C1-C25的直链或支链亚烷基,亚芳基或烷基亚芳基或芳基亚烷基; R5是具有C1-C25的直链或支链烷基,芳基或烷芳基或芳基。 组合物显示出低的土壤电阻率,并且被配制成提供从7至约9.5的使用中的pH值。 另外的成分可以包括去污表面活性剂,乳化剂,螯合剂和非皂的pH降低成分。 提供了颗粒和液体组合物。
    • 29. 发明授权
    • Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof
    • 清洁产品,包括通过亚乙烯基烯烃制备的改进的烷基芳基磺酸盐表面活性剂及其制备方法
    • US06566319B1
    • 2003-05-20
    • US09478906
    • 2000-01-07
    • Jeffrey John ScheibelKevin Lee KottThomas Anthony CripeDaniel Stedman ConnorJames Charles Theophile Roger Burckett-St. Laurent
    • Jeffrey John ScheibelKevin Lee KottThomas Anthony CripeDaniel Stedman ConnorJames Charles Theophile Roger Burckett-St. Laurent
    • C11D1700
    • C07C303/08C07C303/06C11D1/22C11D11/04C07C309/31
    • Cleaning compositions, especially laundry detergents and the like, comprising (i) modified alkylarylsulfonate surfactants, e.g., modified alkylbenzenesulfonates, which are the product of particular processes and (ii) cleaning adjuncts such as enzymes and bleaches. Processes for making the cleaning products, including processes comprising vinylidene olefin production, alkylation of arenes, sulfonation and domestic cleaning product formulation. VO production is used to introduce particular limited branching into an alpha-olefinic feedstock which, converted to dimer form, has from about 10 to about 16, preferably from about 12 to about 14 carbon atoms. Preferred processes maximize the amount of vinylidene olefin useful for detergent manufacture, and minimize deep internal olefin production. Further, an alkylation step, preferably having an internal isomer selectivity of from 0 to no more than about 40 is used, in which the VO monoalkylates arenes such as benzene, in presence of an alkylation catalyst preferably comprising an at least partially crystalline, porous zeolite-containing solid, the zeolite being at least partially acidic and having intermediate pore size. Preferred alkylation catalysts include at least partially dealuminized acidic mordenites.
    • 清洁组合物,特别是衣物洗涤剂等,其包含(i)改性的烷基芳基磺酸盐表面活性剂,例如改性烷基苯磺酸盐,其是特定方法的产物和(ii)清洁助剂如酶和漂白剂。 用于制造清洁产品的方法,包括包含亚乙烯基烯烃生产,芳烃烷基化,磺化和家用清洁产品配方的方法。 VO生产用于将特定有限的支化物引入α-烯烃原料中,其转化为二聚体形式具有约10至约16个,优选约12至约14个碳原子。 优选的方法使用于洗涤剂制造的亚乙烯基烯烃的量最大化,并使内部烯烃的生产最小化。 此外,使用优选具有0至不大于约40的内部异构体选择性的烷基化步骤,其中在烷基化催化剂存在下,优选包含至少部分结晶的多孔沸石的VO单烷基化物芳烃如苯 所述沸石至少部分为酸性且具有中等孔径。 优选的烷基化催化剂包括至少部分脱铝的酸性丝光沸石。