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    • 25. 发明授权
    • Herbicidal method employing meta-anilide urea compounds
    • 使用间苯二胺脲化合物的除草方法
    • US3890133A
    • 1975-06-17
    • US39625573
    • 1973-09-07
    • STAUFFER CHEMICAL CO
    • TEACH EUGENE G
    • C07C273/18C07D307/52A01N9/20
    • C07C273/1827C07D307/52
    • Meta-anilide urea compositions have the formula:

      IN WHICH X and Y are, independently, oxygen and sulfur; R1 is hydrogen or lower alkyl; R2 and R3 are, independently, hydrogen, alkyl, lower alkoxy, haloalkyl, lower alkenyl, cycloalkyl having from 3 to 6 carbon atoms, inclusive, carbalkoxyalkyl, furfuryl, naphthyl, phenyl or substituted-phenyl, inclusive, in which the substituents are halogen, nitro, or lower alkoxy; R4 is hydrogen or lower alkyl; R5 is hydrogen, alkyl, ethyl cycloalkyl, lower alkenyl, halogenated lower alkyl, cycloalkyl having 3 to 6 carbon atoms, inclusive, pinonoyl 2,4-dichlorophenoxymethylene, benzyl, phenyl, or substituted-phenyl in which the substituents are halogen, nitro, lower alkyl, lower alkoxy or trihalomethyl; Z is halogen, lower alkyl, nitro, amino or trifluoromethyl, and m is an integer having a value from 0 to 4, inclusive, provided that when R1, R2, R3 and R4 are each hydrogen, X and Y are each oxygen and m is O, then R5 is other than methyl or ethyl. The compounds are useful as herbicides and they exhibit both preemergence and post-emergence activity. Representative compounds are: 1-(3''isobutyramidophenyl)-3-methyl urea, 1-cyclohexyl-3-(3''propionamidophenyl)urea, 1-butyl-3-(3''-propionamidophenyl) urea, 1-butyl-3-(3''-isobutyramidophenyl)urea, 1-(3''-nitrophenyl)-3-(3''isobutyramidophenyl) urea, 1-N,N-dimethyl-3(pivalamidophenyl)urea, 1-(3''-propionamidophenyl)-3-n-butyl thiourea, and 1-(3''-pestafluoropropionamido phenyl)3,3-dimethyl urea.
    • 元苯胺尿素组合物具有下式:
    • 29. 发明授权
    • Insecticidal active geranyl and citronyl amine derivatives and their epoxides
    • 杀虫活性香叶基和香on胺衍生物及其环氧化物
    • US3886148A
    • 1975-05-27
    • US35602473
    • 1973-04-30
    • STAUFFER CHEMICAL CO
    • PALLOS FERENC MMENN JULIUS J
    • C07D303/34C07D303/36C09B23/00C07D1/22
    • C07D303/36C07D303/34
    • Compounds having the formula

      WHEREIN R can be selected from the group consisting of alkyl, alkenyl, alkynyl, alicyclic, ketoalkyl, alkoxyalkyl, alkylthioalkyl, carbalkoxy, carboxamido, dialkylaminoalkyl, cyanoalkyl, haloalkyl, aryl, aralkyl, and substituted aryl and aralkyl, wherein said substituents can be selected from halogen, alkyl, alkoxy and alkylthio; R1 can be selected from hydrogen, alkyl, alkoxyalkyl, alkylthioalkyl, cyanoalkyl, alkenyl and alkynyl; R2 can be selected from the group consisting of

      WHEREIN R3, R4 and R5 are independently selected from methyl and ethyl. These compounds are active in blocking normal development and/or reproduction of insect species which can be applied at certain stages of insect development.
    • 具有式WHEREIN R的化合物可以选自烷基,烯基,炔基,脂环族,酮基烷基,烷氧基烷基,烷硫基烷基,烷氧基烷氧基,甲酰胺基,二烷基氨基烷基,氰基烷基,卤代烷基,芳基,芳烷基和取代的芳基和芳烷基,其中所述 取代基可以选自卤素,烷基,烷氧基和烷硫基; R 1可以选自氢,烷基,烷氧基烷基,烷基硫代烷基,氰基烷基,烯基和炔基; R 2可以选自下列基团:其中R 3,R 4和R 5独立地选自甲基和乙基。 这些化合物在阻断昆虫物种的正常发育和/或繁殖方面是有活性的,可以在昆虫发育的某些阶段施用。