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    • 11. 发明授权
    • Method of forming berryllium bearing metallic glass
    • 形成带圆柱形金属玻璃的方法
    • US5368659A
    • 1994-11-29
    • US198873
    • 1994-02-18
    • Atakan PekerWilliam L. Johnson
    • Atakan PekerWilliam L. Johnson
    • C22C9/00C22C14/00C22C16/00C22C45/00C22C45/06C22C45/10
    • C22C45/10
    • Alloys which form metallic glass upon cooling below the glass transition temperature at a rate appreciably less than 10.sup.6 K/s comprise beryllium in the range of from 2 to 47 atomic percent and at least one early transition metal in the range of from 30 to 75% and at least one late transition metal in the range of from 5 to 62%. A preferred group of metallic glass alloys has the formula (Zr.sub.1-x Ti.sub.x).sub.a (Cu.sub.1-y Ni.sub.y).sub.b Be.sub.c. Generally, a is in the range from 30 to 75% and the lower limit increases with increasing x. When x is in the range of from 0 to 0.15, b is in the range of from 5 to 62%, and c is in the range of from 6 to 47%. When x is in the range of from 0.15 to 0.4, b is in the range of from 5 to 62%, and c is in the range of from 2 to 47%. When x is in the range of from 0.4 to 0.6, b is in the range of from 5 to 62%, and c is in the range of from 2 to 47%. When x is in the range of from 0.6 to 0.8, b is in the range of from 5 to 62%, and c is in the range of from 2 to 42%. When x is in the range of from 0.8 to 1, b is in the range of from 5 to 62%, and c is in the range of from 2 to 30%. Other elements may also be present in the alloys in varying proportions.
    • 在低于玻璃化转变温度的玻璃化转变温度下以大大低于106K / s的速率冷却形成金属玻璃的合金包括2至47原子%的铍和至少一种在30至75%范围内的早期过渡金属, 和至少一种5至62%的后期过渡金属。 优选的一组金属玻璃合金具有式(Zr1-xTix)a(Cu1-yNiy)bBec。 通常,a在30〜75%的范围内,下限随着x的增加而增加。 当x在0至0.15的范围内时,b在5至62%的范围内,c在6至47%的范围内。 当x在0.15至0.4的范围内时,b在5至62%的范围内,c在2至47%的范围内。 当x在0.4至0.6的范围内时,b在5至62%的范围内,c在2至47%的范围内。 当x在0.6至0.8的范围内时,b在5至62%的范围内,c在2至42%的范围内。 当x在0.8至1的范围内时,b在5至62%的范围内,c在2至30%的范围内。 其他元素也可以以不同比例存在于合金中。
    • 13. 发明授权
    • Amorphous metal alloys in the beryllium-titanium-zirconium system
    • 铍钛锆体系中的无定形金属合金
    • US4050931A
    • 1977-09-27
    • US709028
    • 1976-07-27
    • Lee Elliot TannerRanjan RayCarl F. Cline
    • Lee Elliot TannerRanjan RayCarl F. Cline
    • C22C45/06C22C45/10C22C14/00C22C16/00
    • C22C45/06C22C45/10
    • Amorphous metal alloys are prepared from compositions in the beryllium-titanium-zirconium system. The compositions, in the form of long, continuous ribbon, are defined within an area on a ternary diagram having as its coordinates in atom percent beryllium, atom percent titanium, and atom percent zirconium, the area being defined by a polygon having at its corners the 10 points defined byA. 40% Be, 58% Ti, 2% ZrB. 35% Be, 57% Ti, 8% ZrC. 30% Be, 55% Ti, 15% ZrD. 30% Be, 20% Ti, 50% ZrE. 35% Be, 0% Ti, 65% ZrF. 45% Be, 0% Ti, 55% ZrG. 55% Be, 15% Ti, 30% ZrH. 55% Be, 20% Ti, 25% ZrI. 50% Be, 35% Ti, 15% ZrJ. 43% Be, 53% Ti, 4% Zr.These alloys evidence high strength, low density, a specific strength of at least about 33 .times. 10.sup.5 cm and good ductility. The alloys are useful in applications requiring a high strength-to-weight ratio.
    • 无定形金属合金由铍钛锆体系中的组合物制备。 形式为长连续带的组合物定义在三元图上的以原子百分比铍,原子百分比钛和原子百分比锆为坐标的区域内,该面积由多角形限定在其角上 由A. 40%Be,58%Ti,2%Zr B. 35%Be,57%Ti,8%Zr C. 30%Be,55%Ti,15%Zr D. 30%Be, 20%Ti,50%Zr E. 35%Be,0%Ti,65%Zr F. 45%Be,0%Ti,55%Zr G. 55%Be,15%Ti,30%Zr H. 55% Be,20%Ti,25%Zr I. 50%Be,35%Ti,15%Zr J. 43%Be,53%Ti,4%Zr。