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    • 9. 发明授权
    • Method of forming berryllium bearing metallic glass
    • 形成带圆柱形金属玻璃的方法
    • US5368659A
    • 1994-11-29
    • US198873
    • 1994-02-18
    • Atakan PekerWilliam L. Johnson
    • Atakan PekerWilliam L. Johnson
    • C22C9/00C22C14/00C22C16/00C22C45/00C22C45/06C22C45/10
    • C22C45/10
    • Alloys which form metallic glass upon cooling below the glass transition temperature at a rate appreciably less than 10.sup.6 K/s comprise beryllium in the range of from 2 to 47 atomic percent and at least one early transition metal in the range of from 30 to 75% and at least one late transition metal in the range of from 5 to 62%. A preferred group of metallic glass alloys has the formula (Zr.sub.1-x Ti.sub.x).sub.a (Cu.sub.1-y Ni.sub.y).sub.b Be.sub.c. Generally, a is in the range from 30 to 75% and the lower limit increases with increasing x. When x is in the range of from 0 to 0.15, b is in the range of from 5 to 62%, and c is in the range of from 6 to 47%. When x is in the range of from 0.15 to 0.4, b is in the range of from 5 to 62%, and c is in the range of from 2 to 47%. When x is in the range of from 0.4 to 0.6, b is in the range of from 5 to 62%, and c is in the range of from 2 to 47%. When x is in the range of from 0.6 to 0.8, b is in the range of from 5 to 62%, and c is in the range of from 2 to 42%. When x is in the range of from 0.8 to 1, b is in the range of from 5 to 62%, and c is in the range of from 2 to 30%. Other elements may also be present in the alloys in varying proportions.
    • 在低于玻璃化转变温度的玻璃化转变温度下以大大低于106K / s的速率冷却形成金属玻璃的合金包括2至47原子%的铍和至少一种在30至75%范围内的早期过渡金属, 和至少一种5至62%的后期过渡金属。 优选的一组金属玻璃合金具有式(Zr1-xTix)a(Cu1-yNiy)bBec。 通常,a在30〜75%的范围内,下限随着x的增加而增加。 当x在0至0.15的范围内时,b在5至62%的范围内,c在6至47%的范围内。 当x在0.15至0.4的范围内时,b在5至62%的范围内,c在2至47%的范围内。 当x在0.4至0.6的范围内时,b在5至62%的范围内,c在2至47%的范围内。 当x在0.6至0.8的范围内时,b在5至62%的范围内,c在2至42%的范围内。 当x在0.8至1的范围内时,b在5至62%的范围内,c在2至30%的范围内。 其他元素也可以以不同比例存在于合金中。