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11. 发明申请

US20040122083A1 Antitubulin assembly and cell growth inhibitor denominated "dioxostatin" 审中-公开
标题翻译：抗微管蛋白装配和细胞生长抑制剂称为“二氧化diox抑素”
公开(公告)号：US20040122083A1
公开(公告)日：2004-06-24
申请号：US10275789
申请日：2003-03-31
发明人： George R Pettit , John W Lippert
IPC分类号： C07D323/02
CPC分类号： C07D317/22
摘要： A new inhibitor of microtubule assembly (IC50 0.59 nullM); with antineoplastic properties, denominated nulldioxostatinnull, has been synthesized and its effectiveness against human cancer and murine P388 lymphocytic leukemia cell lines demonstrated. Dioxostatin hs the following structure (I). 1
摘要翻译：一种新的微管组装抑制剂（IC500.59μM）; 已经合成了具有抗肿瘤性质，称为“二氧化二砷”，证明了其对人类癌症和鼠P388淋巴细胞白血病细胞株的有效性。 Dioxostatin具有以下结构（I）。

12. 发明申请

US20040059137A1 Method for producing compounds having a cf2o bridge 失效
标题翻译：生产具有cf2o桥的化合物的方法
公开(公告)号：US20040059137A1
公开(公告)日：2004-03-25
申请号：US10450266
申请日：2003-06-12
发明人： Peer Kirsch , Andreas Taugerbeck , Alexander Hahn
IPC分类号： C07D323/02 , C07D319/06
CPC分类号： C07D317/72 , C07B41/04 , C07C45/59 , C07C45/60 , C07C49/753 , C07D319/14 , C07D321/10 , C07D339/08 , C07D409/06 , C09K19/3066 , C09K19/42 , C09K19/588 , C09K2019/3408 , C09K2019/3425 , C09K2019/3433 , C09K2019/3438
摘要： The invention relates to a process for the preparation of compounds containing at least one nullCF2nullOnull bridge in the molecule, in which a) an acid is added onto at least one ketene dithioketal, b) the resultant bis(alkylthio)carbenium salt is reacted with at least one compound having at least one hydroxyl group in the presence of a base, c) and subsequently, preferably in situ, the resultant dithioorthoester is subjected to oxidative fluorodesulfurisation using a fluorinating agent and an oxidant to give the compound containing at least one nullCF2nullOnull bridge in the molecule.
摘要翻译：本发明涉及在分子中制备含有至少一个-CF 2 -O-桥的化合物的方法，其中a）将酸加入到至少一种烯酮二硫酮缩酮上，b）得到的双（烷硫基）碳鎓盐与至少一种在碱存在下具有至少一个羟基的化合物反应，c）并且随后优选在原位使用氟化剂和氧化剂进行氧化氟代脱硫，得到含有分子中至少有一个-CF2-O-桥。

13. 发明申请

US20030199572A1 Alkyl-dihalogenophenyl-substituted ketoenols 失效
标题翻译：烷基 - 二卤代苯基取代的酮戊二醇
公开(公告)号：US20030199572A1
公开(公告)日：2003-10-23
申请号：US10017695
申请日：2001-12-14
发明人： Folker Lieb , Hermann Hagemann , Arno Widdig , Michael Ruther , Reiner Fischer , Thomas Bretschneider , Christoph Erdelen , Ulrike Wachendorff-Neumann , Peter Dahmen , Markus Dollinger , Hans-Joachim Santel , Alan Graff , Wolfram Andersch , Norbert Mencke , Andreas Turberg
IPC分类号： A01N043/16 , A01N043/08 , C07D323/02
CPC分类号： C07D333/50 , A01N43/10 , A01N43/12 , A01N43/16 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/90 , A01N47/02 , A01N47/06 , A01N53/00 , C07C69/757 , C07C323/56 , C07D207/38 , C07D209/54 , C07D307/94 , C07D309/08 , C07D309/36 , C07D311/46 , C07D333/32 , C07D333/38 , C07D491/10 , C07D493/10
摘要： The present invention relates to new compounds of the formula (I) 1 in which X represents halogen, Y represents halogen or alkyl and Z represents halogen or alkyl, with the proviso that always one of the radicals Y and Z represents halogen while the other represents alkyl, and Het represents one of the groups 2 3 in which A, B, D and G have the meanings given in the description, to a plurality of processes for their preparation and to their use as pesticides and herbicides.
摘要翻译：本发明涉及式（I）的新化合物，其中X表示卤素，Y表示卤素或烷基，Z表示卤素或烷基，条件是基团Y和Z中的任何一个表示卤素，而另一个表示烷基并且Het代表A，B，D和G具有本说明书中给出的含义的组之一，其制备方法和用作农药和除草剂的多种方法。

14. 发明申请

US20020042524A1 Process for cis-1{2-[4-(6-methoxy-2-phenyl-1,2,3,4-tetrahydronaphthalen-1-yl)phenoxy] ethyl}pyrrolidine 有权
标题翻译：顺式-1 {2- [4-（6-甲氧基-2-苯基-1,2,3,4-四氢萘-1-基）苯氧基]乙基}吡咯烷
公开(公告)号：US20020042524A1
公开(公告)日：2002-04-11
申请号：US09974309
申请日：2001-10-09
发明人： Charles K.F. Chiu
IPC分类号： C07D323/02 , C07D207/04
CPC分类号： C07D295/088 , C07C43/215 , C07C45/48 , C07C45/59 , C07C49/84 , C07C2602/10 , C07D317/22 , C07D317/26
摘要： This invention provides an improved process for cis-1-null2-null4-(6-methoxy-2-phenyl-1,2,3,4-tetrahydronaphthalen-1-yl)phenoxynullethylnullpyrrolidine which is an intermediate for the preparation of (null)cis-6-phenyl-5-null4-(2-pyrrolidin-1-yl-ethoxy)-phenylnull-5,6,7,8-tetrahydronaphthalene-2-ol which is useful for the treatment of osteoporosis.
摘要翻译：本发明提供了顺式-1- {2- [4-（6-甲氧基-2-苯基-1,2,3,4-四氢萘-1-基）苯氧基]乙基}吡咯烷的改进方法，其为制备（ - ）顺式-6-苯基-5- [4-（2-吡咯烷-1-基 - 乙氧基） - 苯基] -5,6,7,8-四氢萘-2-醇，其可用于治疗骨质疏松症。

15. 发明授权

US4485250A Perfluorodioxole and its polymers 失效
标题翻译：全氟二恶唑及其聚合物
公开(公告)号：US4485250A
公开(公告)日：1984-11-27
申请号：US421824
申请日：1982-09-23
申请人： Edward N. Squire
发明人： Edward N. Squire
IPC分类号： C07D317/42 , C08F34/02 , C08F214/26 , C07D317/00 , C07D323/02
CPC分类号： C07D317/42 , C08F214/262 , C08F34/02
摘要： Perfluoro-1,3-dioxole is a useful monomer, which polymerizes to either amorphous or liquid homopolymers and copolymerizes with tetrafluoroethylene as well as with other monomers to both crystalline and amorphous copolymers having one or more such comonomers incorporated therein. Amorphous homopolymers and copolymers of perfluoro-1,3-dioxole are useful in such applications as glazing for reactors for hydrogen fluoride reactions. Amorphous homopolymers and amorphous or crystalline copolymers form self-supporting films and can be used for coatings and linings which are inert to most chemicals and are stain and weather resistant and as dielectrics for electrical and electronic equipment. Liquid homopolymers can be used as hydraulic fluids and heat exchange media.
摘要翻译：全氟-1,3-二氧杂环戊烯是一种有用的单体，其可以与无定形或液体均聚物聚合，并与四氟乙烯以及其它单体与具有一个或多个这样的共聚单体并入其中的结晶和无定形共聚物共聚。全氟-1,3-二氧杂环戊烯的无定形均聚物和共聚物可用于诸如用于氟化氢反应的反应器的玻璃的应用。无定形均聚物和无定形或结晶共聚物形成自支撑膜，并且可用于对大多数化学品是惰性的并且具有耐污染和耐候性以及用于电气和电子设备的电介质的涂层和衬里。液体均聚物可用作液压油和热交换介质。

16. 发明授权

US3868392A Method and apparatus for the production of peroxide derivatives of high purity ozonides, by ozonization of the corresponding olefins, and subsequent treatments 失效
标题翻译：用于生产高纯度臭氧化物的过氧化物衍生物的方法和装置，通过相应的烯烃的臭氧化和随后的处理
公开(公告)号：US3868392A
公开(公告)日：1975-02-25
申请号：US22720372
申请日：1972-02-17
申请人： SNIA VISCOSA
发明人： SICLARI FRANCESCO , ROSSI PIETRO PAOLO
IPC分类号： C07C45/40 , C07C51/34 , C07C227/08 , C07D323/02 , C07C75/00
CPC分类号： C07D323/02 , C07C45/40 , C07C51/34 , C07C227/08 , C07C59/153 , C07C59/147
摘要： A method is disclosed for the production of peroxide-like derivatives of ozonides by ozonization of the correspoding olefins, comprising the step of placing an olefin in the presence of ozone in solution in a solvent mixture which comprises at least a nonpolar solvent (inert with respect to the olefin concerned) and at least a polar solvent, in which the as formed ozonide is reactively dissolved, a heavy weight phase being formed which contains the peroxide-like derivative. The derivative in question is removed from the reaction environment so as to substract it from superoxidation and polymerization effects.
摘要翻译：公开了通过相应的烯烃的臭氧化来生产臭氧化物的过氧化物类衍生物的方法，包括将臭氧存在于溶液中的溶剂中的烯烃在包含至少非极性溶剂的惰性溶剂（惰性的与所述烯烃相关）和至少一种其中形成的臭氧化物被反应性溶解的极性溶剂，形成含有过氧化物衍生物的重质相。所述衍生物从反应环境中除去，以将其从超氧化和聚合效应中减去。

17. 发明授权

US3347766A Method of contacting slag with a reducing arc atmosphere to reduce the metal oxides contained therein 失效
标题翻译：使渣与还原电弧气氛接触以减少其中所含的金属氧化物的方法
公开(公告)号：US3347766A
公开(公告)日：1967-10-17
申请号：US31290063
申请日：1963-10-01
申请人： UNION CARBIDE CORP
发明人： DEATH FRANK S , MORCIO JOSEPH A
IPC分类号： B01J19/08 , C01B3/34 , C01B13/11 , C07C2/80 , C07C45/33 , C07C45/40 , C07D323/02 , C08F2/52 , C10G15/00 , C21B13/12 , C21C5/52 , C22B4/00 , C22B9/05 , C22B11/02 , C22B15/00 , C22B34/32 , F17C13/02 , G10L21/00 , H01J37/32 , H03G5/20 , H04B1/66 , H05H1/32 , H05H1/42
CPC分类号： H05H1/42 , B01J19/088 , C01B3/342 , C01B13/11 , C01B2201/10 , C01B2201/14 , C01B2201/60 , C01B2201/66 , C07C2/80 , C07C45/33 , C07C45/40 , C07D323/02 , C10G15/00 , C21B13/125 , C21C5/52 , C22B4/005 , C22B9/05 , C22B11/02 , C22B15/006 , C22B34/32 , F17C13/02 , F17C2201/0109 , F17C2201/0119 , F17C2203/0629 , G10L21/00 , H01J37/32 , H01J37/32009 , H01J37/32055 , H03G5/20 , H04B1/66 , H05H1/32 , Y02E60/321 , Y02P10/136 , Y02P10/143 , Y02P10/216 , C07C11/24
摘要： A continuous reaction is effected in a gas stream by an electric discharge at a point in the stream where the flow has been made supersonic and the pressure and temperature lowered by a substantially adiabatic expansion. Various forms of apparatus for carrying out such a process are described. The apparatus may be used for the production of ozone which is used to convert ethylene and tetramethyl-ethylene fed into the apparatus into the corresponding ozonides. On leaving the apparatus the ozonides are converted in the presence of water into formaldehyde and acetone respectively.ALSO:A continuous reaction is effected in a gas stream by an electric discharge at a point in the stream where the flow has been made supersonic and the pressure and temperature lowered by a substantially adiabatic expansion. One form of apparatus, Fig. 1, comprises a supersonic nozzle 1, a pressure reducing chamber 17 for starting the action of the nozzle and a recompression chamber 13. Gas from an inlet pipe 6 passes along a cylindrical chamber 5 to a convergent part 2 of the nozzle 1 and then expands in a divergent part 4. A hollow electrode 8 supported by insulators 9 and 10 in the chamber 5 produces a discharge at the outlet 7 of the nozzle 1. The recompression chamber 13 comprises a convergent part 14, a cylindrical part 15 and a divergent part 16. This apparatus may be used for the production of acetylene and hydrogen from methane gas, or for the cracking of other hydrocarbons. An alternative form of apparatus is described in which the electrode 8 is extended to the part 16 of the chamber 13 and is closed at the end, but is provided with side vents for the injection of methane into the part 15 of the chamber 13. Two discharges are set up, the first at the end of the nozzle 1 for producing ozone, and the second in the chamber 13 for partially oxidizing the methane.

18. 发明授权

US3083209A Ozonidation process 失效
标题翻译：臭氧化过程
公开(公告)号：US3083209A
公开(公告)日：1963-03-26
申请号：US82425559
申请日：1959-07-01
申请人： EXXON RESEARCH ENGINEERING CO
发明人： HABIB AUSTIN G , RYAN JOHN F
IPC分类号： C07D323/02
CPC分类号： C07D323/02

19. 发明授权

US11845903B2 High yield jet fuel and chemicals from ozonolysis of triglycerides 有权
公开(公告)号：US11845903B2
公开(公告)日：2023-12-19
申请号：US17930468
申请日：2022-09-08
申请人： ExxonMobil Technology and Engineering Company
发明人： Patrick L. Hanks
IPC分类号： C10G69/02 , C07D323/02 , C07C51/34 , C10G3/00 , C11C1/04 , B01J10/00 , B01D3/14 , B01J19/24 , C07C1/20 , C07C1/207 , C07C1/24 , C07C1/22
CPC分类号： C10G69/02 , B01D3/14 , B01J10/00 , B01J19/245 , C07C1/20 , C07C1/207 , C07C1/22 , C07C1/24 , C07C51/34 , C07D323/02 , C10G3/50 , C11C1/04 , B01J2219/0004 , C10G2300/1011 , C10G2400/08
摘要： A method for producing jet range hydrocarbons may include reacting at least a portion a fatty acid stream comprising C18:1 free fatty acid with ozone in an ozonolysis unit to form at least a C18:1 ozonide intermediate; introducing the C18:1 ozonide intermediate into a reactor, wherein at least a portion of the C18:1 ozonide intermediate is reacted with a reductive agent to produce oxidized products comprising azelaic acid and nonanoic acid; and introducing the oxidized products into a hydrotreating unit, wherein at least a portion of the oxidized products is hydrotreated to produce a paraffin product comprising nonane.

20. 发明申请

US20230136255A1 HIGH YIELD JET FUEL AND CHEMICALS FROM OZONOLYSIS OF TRIGLYCERIDES 有权
公开(公告)号：US20230136255A1
公开(公告)日：2023-05-04
申请号：US17930468
申请日：2022-09-08
申请人： ExxonMobil Technology and Engineering Company
发明人： Patrick L. Hanks
IPC分类号： C10G69/02 , C07D323/02 , C07C51/34 , C10G3/00 , C11C1/04 , B01J19/24 , B01J10/00 , B01D3/14
摘要： A method for producing jet range hydrocarbons may include reacting at least a portion a fatty acid stream comprising C18:1 free fatty acid with ozone in an ozonolysis unit to form at least a C18:1 ozonide intermediate; introducing the C18:1 ozonide intermediate into a reactor, wherein at least a portion of the C18:1 ozonide intermediate is reacted with a reductive agent to produce oxidized products comprising azelaic acid and nonanoic acid; and introducing the oxidized products into a hydrotreating unit, wherein at least a portion of the oxidized products is hydrotreated to produce a paraffin product comprising nonane.

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