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11. 发明授权

US10059648B2 Method for producing fluorine-containing compounds 有权
公开(公告)号：US10059648B2
公开(公告)日：2018-08-28
申请号：US15576398
申请日：2016-05-18
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Shun Ohkubo
IPC分类号： C07C17/25 , C07C17/386 , C07C17/38 , C07C17/383 , C07C17/354
CPC分类号： C07C17/25 , C07B61/00 , C07C17/354 , C07C17/38 , C07C17/383 , C07C17/386 , C07C17/395 , C07C21/18
摘要： Provided is an efficient method for producing a fluorine-containing compound without the need for a rectification column involving numerous stages, extractive distillation, etc. The method for producing a fluorine-containing compound includes the step of supplying a composition containing a mixture to a dehydrohalogenation step, the mixture being at least one member selected from the group consisting of mixtures of at least one fluoroolefin and at least one hydrofluorocarbon, the boiling points of which are close to each other, azeotropic mixtures of at least one fluoroolefin and at least one hydrofluorocarbon, and pseudo-azeotropic compounds of at least one fluoroolefin and at least one hydrofluorocarbon.

12. 发明授权

US09856192B2 Method for preparing 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene 有权
公开(公告)号：US09856192B2
公开(公告)日：2018-01-02
申请号：US15405268
申请日：2017-01-12
申请人： Zhejiang Quzhou Juxin Fluorine Chemical Co., Ltd. , Zhejiang Quhua Fluor-Chemistry Co., Ltd.
发明人： Jun Lei , Aiguo Wang , Bo Yang , Yan Zhang , Huadong Zhou , Yang Zhao , Guoan Liu , Yi Zhu , Gang Su
IPC分类号： C07C17/25 , C07C17/354 , C07C17/383 , C07C17/38
CPC分类号： C07C17/25 , C07C17/354 , C07C17/38 , C07C17/383 , C07C21/18 , C07C19/08
摘要： A method for preparing 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene, including: providing a first reactor including a first section, a second section, and a third section, with each section being filled with different catalysts, preheating hexafluoropropylene and hydrogen, and introducing the hexafluoropropylene and the hydrogen to the first reactor to yield a first mixture including: 1,1,1,2,3-pentafluoropropane, 1,1,1,2,3,3-hexafluoropropane, and hydrogen fluoride; introducing the first mixture to a first distillation column to yield 1,1,1,2,3,3-hexafluoropropane at a top of the first distillation column and 1,1,1,2,3-pentafluoropropane and hydrogen fluoride at a bottom of the first distillation column, recycling the 1,1,1,2,3,3-hexafluoropropane to a lower part of the first section of the first reactor, and introducing the 1,1,1,2,3-pentafluoropropane and the hydrogen fluoride to a second reactor to yield a second mixture including: 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene, hydrogen fluoride, and 1,1,1,2,3-pentafluoropropane; and performing water washing, alkaline washing, drying, and distillation on the second mixture to yield 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene.

13. 发明申请

US20170369403A1 INTEGRATED PROCESS FOR THE PRODUCTION OF Z-1,1,1,4,4,4-HEXAFLUORO-2-BUTENE 审中-公开
公开(公告)号：US20170369403A1
公开(公告)日：2017-12-28
申请号：US15699067
申请日：2017-09-08
申请人： THE CHEMOURS COMPANY FC, LLC
发明人： IVAN SERGEYEVICH BALDYCHEV , STEPHAN M. BRANDSTADTER , PATRICIA CHEUNG , MARIO JOSEPH NAPPA , SHENG PENG , DONALD J. TOTON
IPC分类号： C07C17/25 , C07C17/281 , C07C17/23 , C07C17/354
CPC分类号： C07C17/25 , C07C17/23 , C07C17/281 , C07C17/354 , Y02P20/125 , Y02P20/582 , C07C21/18
摘要： Disclosed is a process for the preparation of cis-1,1,1,4,4,4-hexafluoro-2-butene comprising contacting 1,1,1-trifluorotrichloroethane with hydrogen in the presence of a catalyst comprising ruthenium to produce a product mixture comprising 1316mxx, recovering said 1316mxx as a mixture of Z- and E-isomers, contacting said 1316mxx with hydrogen, in the presence of a catalyst selected from the group consisting of copper on carbon, nickel on carbon, copper and nickel on carbon and copper and palladium on carbon, to produce a second product mixture, comprising E- or Z-CFC-1326mxz, and subjecting said second product mixture to a separation step to provide E- or Z-1326mxz. The E- or Z-1326mxz can be dehydrochlorinated in an aqueous basic solution with an alkali metal hydroxide in the presence of a phase transfer catalyst to produce hexafluoro-2-butyne, which can then be selectively hydrogenated to produce Z-1, 1,1,4,4,4-hexafluoro-2-butene using using either Lindlar's catalyst, or a palladium catalyst further comprising a lantanide element or silver.

14. 发明申请

US20170166517A1 Process for Preparing N-(4-Cyclohexyl-3-trifluoromethyl-benzyloxy)-acetimidic Acid Ethyl Ester 审中-公开
公开(公告)号：US20170166517A1
公开(公告)日：2017-06-15
申请号：US15432213
申请日：2017-02-14
申请人： Novartis AG
发明人： Fabrice GALLOU , Joerg Matthias SEDELMEIER , Caspar VOGEL
IPC分类号： C07C251/52 , C07C47/546 , C07C22/08 , C07C17/35 , C07C249/04 , C07C17/04 , C07C51/15 , C07C29/44 , C07C249/12 , C07C25/18 , C07C17/354
CPC分类号： C07C251/52 , C07C17/04 , C07C17/12 , C07C17/14 , C07C17/26 , C07C17/35 , C07C17/354 , C07C22/08 , C07C25/18 , C07C29/14 , C07C29/147 , C07C29/44 , C07C33/50 , C07C45/27 , C07C47/546 , C07C47/55 , C07C49/82 , C07C51/15 , C07C249/04 , C07C249/12 , C07C259/04 , C07C2601/14 , C07C2601/16 , C07D205/04
摘要： This invention relates to novel processes for synthesizing N-(4-cyclohexyl-3-trifluoromethyl-benzyloxy)-acetimidic acid ethyl ester and to the compound of formula I below and other intermediates that are used in such processes.

15. 发明授权

US09428429B2 Method for producing fluorine-containing alkane 有权
标题翻译：含氟烷烃的生产方法
公开(公告)号：US09428429B2
公开(公告)日：2016-08-30
申请号：US13634047
申请日：2011-02-18
申请人： Yuko Shiotani , Kakeru Hanabusa , Takehiro Chaki , Kazuhiro Takahashi
发明人： Yuko Shiotani , Kakeru Hanabusa , Takehiro Chaki , Kazuhiro Takahashi
IPC分类号： C07C17/354 , C07C17/23
CPC分类号： C07C17/23 , C07C17/354 , C07C19/08
摘要： The present invention provides a method for producing a fluorine-containing alkane, which comprises reacting at least one fluorine-containing compound selected from the group consisting of chlorine-containing fluoroalkanes and fluorine-containing alkenes with hydrogen gas in the presence of catalysts, wherein two or more catalysts having different catalytic activities are used, and the fluorine-containing compound and hydrogen gas, which are starting materials, are sequentially brought into contact with the catalysts in the order of the catalyst having a lower catalytic activity followed by the catalyst having a higher catalytic activity. According to the present invention, in the method for producing a fluorine-containing alkane by using chlorine-containing fluoroalkane or fluorine-containing alkene as a starting material, and subjection it to a reduction reaction or a hydrogen addition reaction, the objective fluorine-containing alkane can be produced with high productivity.
摘要翻译：本发明提供一种含氟烷烃的制造方法，其特征在于，在催化剂存在下，使选自含氟的氟代烷烃和含氟烯烃的至少一种含氟化合物与氢气反应，使用具有不同催化活性的催化剂或更多的催化剂，并且作为起始原料的含氟化合物和氢气按催化剂的顺序依次与催化剂接触，催化剂的催化活性低于催化剂，其后催化剂具有更高的催化活性。根据本发明，在使用含氯氟烷烃或含氟烯烃作为起始原料的含氟烷烃的制造方法中，将其置于还原反应或氢加成反应中，目标含氟可以高生产率生产烷烃。

16. 发明授权

US09255047B2 Process for the preparation of fluorinated compounds 有权
标题翻译：氟化合物的制备方法
公开(公告)号：US09255047B2
公开(公告)日：2016-02-09
申请号：US12602707
申请日：2009-08-19
申请人： Anne Pigamo , Michel Devic , Laurent Wendlinger
发明人： Anne Pigamo , Michel Devic , Laurent Wendlinger
IPC分类号： C07C17/354 , C07C17/25 , C07C21/18
CPC分类号： C07C17/25 , C07C17/354 , C07C21/18 , Y02P20/582 , C07C19/08
摘要： A subject-matter of the invention is a process for the preparation of 2,3,3,3-tetrafluoro-1-propene which comprises the following stages: (i) hydrogenation of hexafluoropropylene to give 1,1,1,2,3,3-hexafluoropropane; (ii) dehydrofluorination of the 1,1,1,2,3,3-hexafluoropropane obtained in the preceding stage to give 1,2,3,3,3-pentafluoro-1-propene; (iii) hydrogenation of the 1,2,3,3,3-pentafluoro-1-propene obtained in the preceding stage to give 1,1,1,2,3-pentafluoropropane; and (iv) dehydrofluorination of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage to give 2,3,3,3-tetrafluoro-1-propene. Stages (ii) and (iv) are carried out using a water and potassium hydroxide mixture with the potassium hydroxide representing between 58 and 86% by weight of the mixture and at a temperature of between 110 and 180° C.
摘要翻译：本发明的主题是制备2,3,3,3-四氟-1-丙烯的方法，其包括以下步骤：（i）六氟丙烯的氢化，得到1,1,1,2,3 ，3-六氟丙烷; （ii）前段得到的1,1,1,2,3,3-六氟丙烷的脱氟化氢，得到1,2,3,3,3-五氟-1-丙烯; （iii）在前一阶段获得的1,2,3,3,3-五氟-1-丙烯的氢化，得到1,1,1,2,3-五氟丙烷; 和（iv）前一阶段获得的1,1,1,2,3-五氟丙烷的脱氟化氢，得到2,3,3,3-四氟-1-丙烯。阶段（ii）和（iv）使用氢氧化钾与氢氧化钾混合物进行，其中氢氧化钾占混合物重量的58-86％，在110-180℃的温度下进行。

17. 发明申请

US20160023969A1 Process for the Preparation of 2,3,3,3-Tetrafluoropropene 有权
标题翻译：制备2,3,3,3-四氟丙烯的方法
公开(公告)号：US20160023969A1
公开(公告)日：2016-01-28
申请号：US14876090
申请日：2015-10-06
申请人： MEXICHEM AMANCO HOLDING S.A. DE C.V.
发明人： JOHN W. SMITH , CLAIRE MCGUINESS , ANDREW P. SHARRATT , ANDREW M. TAYLOR
IPC分类号： C07C17/25 , C07C17/354
CPC分类号： C07C17/25 , C07C17/354 , C07C21/18 , C07C19/08
摘要： The invention provides a process for the preparation of 1234yf comprising (a) contacting 1,1,2,3,3,3-hexafluoropropene (1216) with hydrogen in the presence of a hydrogenation catalyst to produce 1,1,2,3,3,3-hexafluoropropane (236ea); (b) dehydrofluorinating 236ea to produce 1,2,3,3,3-pentafluoropropene (1225ye); (c) contacting 1225ye with hydrogen in the presence of a hydrogenation catalyst to produce 1,2,3,3,3-pentafluoropropane (245eb); and (d) dehydrofluorinating 245eb to produce 1234yf.
摘要翻译：本发明提供了一种制备1234yf的方法，其包括（a）在氢化催化剂存在下使1,1,2,3,3,3-六氟丙烯（1216）与氢气接触以产生1,1,2,3， 3,3-六氟丙烷（236ea）; （b）脱氢氟化236ea以制备1,2,3,3,3-五氟丙烯（1225ye）; （c）在氢化催化剂存在下使1225ye与氢气接触以产生1,2,3,3,3-五氟丙烷（245eb）; 和（d）脱氢氢化245eb以产生1234yf。

18. 发明申请

US20150336862A1 CATALYTIC HYDROGENATION USING COMPLEXES OF BASE METALS WITH TRIDENTATE LIGANDS 有权
标题翻译：使用三元配体的碱金属复合物进行催化氢化
公开(公告)号：US20150336862A1
公开(公告)日：2015-11-26
申请号：US13587717
申请日：2012-08-16
申请人： Kalyan V. Vasudevan , Guoqi Zhang , Susan K. Hanson
发明人： Kalyan V. Vasudevan , Guoqi Zhang , Susan K. Hanson
IPC分类号： C07C29/17 , C07F15/06 , C07F5/04 , C07C67/303 , C07C51/36 , C07D211/46 , C07C41/20 , C07C41/18 , C07C29/145 , C07C41/01 , C07C17/354 , C07C45/62 , C07C209/52 , C07C5/03 , C07C5/05 , B01J31/24 , C07F15/04
CPC分类号： B01J31/2295 , B01J31/189 , B01J31/2476 , B01J2231/643 , B01J2231/645 , B01J2231/646 , B01J2531/0244 , B01J2531/845 , B01J2531/847 , C07C5/03 , C07C5/05 , C07C17/354 , C07C29/141 , C07C29/145 , C07C29/172 , C07C29/175 , C07C41/01 , C07C41/18 , C07C41/20 , C07C41/26 , C07C45/62 , C07C51/36 , C07C67/303 , C07C209/52 , C07C209/70 , C07C2531/14 , C07C2531/22 , C07C2531/28 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2602/08 , C07C2602/42 , C07C2603/12 , C07C2603/18 , C07D211/02 , C07D211/46 , C07F5/04 , C07F15/04 , C07F15/045 , C07F15/06 , C07F15/065 , Y02P20/52 , C07C43/23 , C07C33/20 , C07C33/22 , C07C33/24 , C07C35/38 , C07C69/24 , C07C53/126 , C07C31/125 , C07C33/46 , C07C43/04 , C07C35/32 , C07C43/205 , C07C49/403 , C07C211/27 , C07C211/48 , C07C25/13 , C07C15/073 , C07C15/02 , C07C15/085 , C07C11/02 , C07C13/26 , C07C13/64 , C07C13/20
摘要： Complexes of cobalt and nickel with tridentate ligand PNHPR are effective for hydrogenation of unsaturated compounds. Cobalt complex [(PNHPCy)Co(CH2SiMe3)]BArF4 (PNHPCy=bis[2-(dicyclohexylphosphino)ethyl]amine, BArF4=B(3,5-(CF3)2C6H3)4)) was prepared and used with hydrogen for hydrogenation of alkenes, aldehydes, ketones, and imines under mild conditions (25-60° C., 1-4 atm H2). Nickel complex [(PNHPCy)Ni(H)]BPh4 was used for hydrogenation of styrene and 1-octene under mild conditions. (PNPCy)Ni(H) was used for hydrogenating alkenes.
摘要翻译：钴和镍与三齿配体PNHPR的配合物对于不饱和化合物的氢化是有效的。钴配合物[（PNHPCy）Co（CH2SiMe3）] BArF4（PNHPCy =双[2-（二环己基膦基）乙基]胺，BArF 4 = B（3,5-（CF 3）2 C 6 H 3）4）的烯烃，醛，酮和亚胺在温和条件下（25-60℃，1-4atm H 2）。镍络合物[（PNHPCy）Ni（H）] BPh4用于在温和条件下苯乙烯和1-辛烯的氢化。（PNPCy）Ni（H）用于氢化烯烃。

19. 发明申请

US20150126785A1 Process for the Preparation of 1,1,1-Trifluoropropane 有权
标题翻译： 1,1,1-三氟丙烷的制备方法
公开(公告)号：US20150126785A1
公开(公告)日：2015-05-07
申请号：US14233868
申请日：2012-07-18
申请人： Andrew P. Sharratt , Claire Elizabeth Mcguinness , Emma Jane Hodgson
发明人： Andrew P. Sharratt , Claire Elizabeth Mcguinness , Emma Jane Hodgson
IPC分类号： C07C17/354 , C07C17/25
CPC分类号： C07C17/354 , C07C17/23 , C07C17/25 , C07C19/08
摘要： The invention provides a process comprising contacting (1243zf) or (253fb) with hydrogen in the presence of a hydrogenation catalyst to produce a composition comprising 1,1,1-trifluoropropane (263fb).
摘要翻译：本发明提供了一种方法，其包括在氢化催化剂存在下使（1243zf）或（253fb）与氢气接触以产生包含1,1,1-三氟丙烷（263fb）的组合物。

20. 发明授权

US08912370B2 Method for producing hexafluoropropane 有权
标题翻译：生产六氟丙烷的方法
公开(公告)号：US08912370B2
公开(公告)日：2014-12-16
申请号：US13377159
申请日：2010-05-05
申请人： Michel Devic , Nicolas Doucet , Laurent Wendlinger , Geraldine Cavallini
发明人： Michel Devic , Nicolas Doucet , Laurent Wendlinger , Geraldine Cavallini
IPC分类号： C07C17/354 , C07C19/08 , C07C21/18
CPC分类号： C07C17/354 , C07C19/08 , C07C21/18 , Y02P20/582
摘要： The present invention relates to a method for producing 1,1,1,2,3,3-hexaafluoropropane, involving reacting gaseous phase hexafluoropropene with hydrogen in a superstoichimetric amount in the presence of a hydrogenation catalyst in a reactor, and recirculating a part of the gaseous effluent from the reactor.
摘要翻译：本发明涉及一种生产1,1,1,2,3,3-六氟丙烷的方法，其包括在反应器中在加氢催化剂存在下使超过一定量的气相六氟丙烯与氢反应，并将一部分来自反应器的气态流出物。

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