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    • 12. 发明授权
    • Method of preparing hybrid polymers for phase change ink
    • 相变油墨混合聚合物的制备方法
    • US06376611B1
    • 2002-04-23
    • US09426379
    • 1999-10-25
    • Michael D. Matzinger
    • Michael D. Matzinger
    • C08L3300
    • C09D11/34
    • Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20° C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise: (a) from about 0.1% to about 30% of one or more colorants; and (b) from about 0.1 to about 99.9% of one or more hybrid polymers. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention contemplates the hybrid polymers which are the reaction product of a first polymer and a second polymer which, if added to the ink composition individually, would result in an incompatible ink composition, as well as methods for the preparation of the hybrid polymers.
    • 用于相变(热熔)喷墨记录装置的相变(热熔)油墨组合物,其中通过在高于环境温度(20℃)的温度下热熔化油墨进行记录,以提供具有高 公开了高质量图像,耐擦伤性,耐磨性,低温储存稳定性和柔韧性,抗偏移和粘合性以及其它所需性能,包括:(a)约0.1%至约30%的一种或多种着色剂; 和(b)约0.1至约99.9%的一种或多种杂化聚合物。除了上述以外列出的组分可以包括在油墨组合物中以实现特定的打印机,基材或最终用途要求。 此外,本发明考虑了作为第一聚合物和第二聚合物的反应产物的杂化聚合物,如果单独加入到油墨组合物中,将导致不相容的油墨组合物,以及制备混合物的方法 聚合物。
    • 13. 发明授权
    • ABS compositions having improved combinations of properties
    • 具有改进的性能组合的ABS组合物
    • US06727319B2
    • 2004-04-27
    • US10242991
    • 2002-09-13
    • Herbert Eichenauer
    • Herbert Eichenauer
    • C08L3300
    • C08L51/04C08L2666/24
    • A thermoplastic molding composition having an improved profile of properties is disclosed. The composition contains A) a graft rubber that is a product of free-radical emulsion polymerization of vinyl monomers in the presence of rubber a) that is present in latex form and having a glass transition temperature below 0° C., using at least one peroxydisulfate compound as an initiator, and B) a graft rubber that is a product of free-radical emulsion polymerization of vinyl monomers in the presence of at least one rubber b) that is present in latex form and having a glass transition temperature below 0° C., using at least one redox system as an initiator, and C) at least one graft polymer, that is a product of solution, bulk or suspension polymerization of a grafted phase that contains a member selected from the group consisting of styrene and acrylonitrile in a weight ratio of 90:10 to 50:50 therebetween, in the presence of a rubber, and wherein the weight ratio of introduced graft monomers to introduced rubber is 50:50 to 97:3.
    • 公开了具有改进的特性轮廓的热塑性模塑组合物。 组合物包含A)在橡胶存在下乙烯基单体的自由基乳液聚合的产物的接枝橡胶a),其以胶乳形式存在并且玻璃化转变温度低于0℃,使用至少一种 过氧化二硫酸酯化合物作为引发剂,和B)在至少一种橡胶b)存在下乙烯基单体的自由基乳液聚合的产物的接枝橡胶,b)以胶乳形式存在并且玻璃化转变温度低于0° 使用至少一种氧化还原体系作为引发剂,和C)至少一种接枝聚合物,其是接枝相的溶液,本体或悬浮聚合的产物,其含有选自苯乙烯和丙烯腈的成员 在橡胶存在下,其重量比为90:10至50:50,其中引入的接枝单体与引入的橡胶的重量比为50:50至97:3。
    • 14. 发明授权
    • Marine paint compositions
    • 海洋油漆成分
    • US06710117B2
    • 2004-03-23
    • US10204491
    • 2003-01-13
    • Michel GillardMarcel VosJos G. M. Prinsen
    • Michel GillardMarcel VosJos G. M. Prinsen
    • C08L3300
    • C09D5/1668C08L39/00C09D143/00C08L2666/04C08L2666/28
    • Marine paint composition comprising: a first polymer comprising from 20 to 70 wt % of monomer units A of at least one hydrolysable either tin or silicium ester of an olefinically unsaturated carboxylic acid or salt of copper, zinc, calcium of an olefinically unsaturated carboxylic acid, the balance being monomer units C selected from the group consisting of esters of ethylenically unsaturated carboxylic acids with C1-C18 alcohols, styrene, alpha-methyl styrene, vinyl toluenes, and mixtures thereof; a second polymer comprising from 5 to 40 wt % of at least one monomer B selected from the group consisting of the N-vinyl lactam monomers of general formula CH2═CH—NR′″″—CO—R′, the N-vinyl amides of general formula CH2═CH—N—CO—R″, the monomer of general formula CH2═CR′″—COO—R″″—NR′″″—CO—R′, the monomers of general formula CH2═CR′″—COO—R″″—N—CO—R″, 2-pyrrolidone-1-isoprenyl ketone, and mixtures thereof, wherein R′ is a n-alkylidene radical having 2 to 8 carbon atoms, R″ is selected from the group consisting of alkyl, cycloalkyl, aryl, alkylaryl and arylalkyl radicals having a maximum of 18 carbon atoms, R′″ is H or CH3, R″″ is a n-alkylidene radical having from 1 to 8 carbon atoms, R′″″ is H or R″, the balance being monomer units C selected from the group consisting of esters of ethylenically unsaturated carboxylic acids with C1-C18 alcohols, styrene, alpha-methyl styrene, vinyl toluenes, and mixtures thereof; at least one antifoulant; the ratio of the first polymer comprising monomer units A to the second polymer comprising monomer units B being of from 95:5 to 10:90.
    • 海洋涂料组合物,其包含:包含20至70重量%的至少一种可水解的烯属不饱和羧酸的锡或硅酸酯或烯属不饱和羧酸的铜,锌,钙的盐的单体单元A的第一聚合物, 余量为选自烯键式不饱和羧酸与C 1 -C 18醇的酯,苯乙烯,α-甲基苯乙烯,乙烯基甲苯及其混合物的单体单元C; 包含5至40重量%的至少一种单体B的第二聚合物,所述单体选自通式为CH 2 = CH-NR“' - CO-R'的N-乙烯基内酰胺单体,N- 通式为CH2 = CH-N-CO-R“的乙烯基酰胺,通式CH 2 = CR”'-COO-R“' - NR”' - CO-R'的单体, 通式CH 2 = CR“' - COO-R”' - N-CO-R“,2-吡咯烷酮-1-异戊二烯基酮及其混合物的单体,其中R'是具有 2至8个碳原子,R“选自具有最多18个碳原子的烷基,环烷基,芳基,烷基芳基和芳基烷基,R”'是H或CH 3,R“'是 具有1至8个碳原子的正亚烷基,R“”是H或R“,余量为选自烯键式不饱和羧酸与C 1 -C 18醇的酯,苯乙烯 ,α-甲基苯乙烯,乙烯基甲苯及其混合物; 至少一种防污剂; 包含单体单元A的第一聚合物与包含单体单元B的第二聚合物的比例为95:5至10:90。
    • 15. 发明授权
    • Wet-stick adhesives
    • 湿粘胶
    • US06441092B1
    • 2002-08-27
    • US09367510
    • 1999-08-13
    • Melinda B. Gieselman
    • Melinda B. Gieselman
    • C08L3300
    • A61L15/58C08L33/064C08L2666/04C09J133/08C09J2201/606Y10T428/1452Y10T428/1462Y10T428/2887Y10T428/2891C08L33/06
    • A wet-skin adhesive includes a pressure-sensitive adhesive component that includes at least one monoethylenically unsaturated (meth)acrylic acid ester comprising an alkyl group having at least 4 carbons on average and at least one monoethylenically unsaturated reinforcing monomer; and a film-forming component that includes at least one monoethylenically unsaturated (meth)acrylic acid ester comprising an alkyl group having less than 4 carbons on average and at least one hydrophilic acidic monomer, wherein the wet-stick pressure-sensitive adhesive has an initial wet skin adhesion of at least about 0.8 N/dm. Advantageously, the wet-stick adhesive has an initial wet skin adhesion that is at least about 65% of an initial dry skin adhesion.
    • 湿皮粘合剂包括压敏粘合剂组分,其包含至少一种包含平均具有至少4个碳的烷基和至少一种单烯属不饱和增强单体的单烯属不饱和(甲基)丙烯酸酯; 和含有平均具有少于4个碳原子的烷基和至少一个亲水性酸性单体的至少一种单烯键式不饱和(甲基)丙烯酸酯的成膜组分,其中该湿粘压敏粘合剂具有初始 湿皮肤粘附力为至少约0.8N / dm 2。 有利地,湿粘粘合剂具有初始的湿皮肤粘附,其为初始干燥皮肤粘附的至少约65%。