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11. 发明授权

US10526282B2 Fluorine-based compound for brancher, polymer using same, and polymer electrolyte membrane using same 有权
公开(公告)号：US10526282B2
公开(公告)日：2020-01-07
申请号：US15515007
申请日：2015-10-28
申请人： LG CHEM, LTD.
发明人： Hyun Woog Ryu , Sehee Jung , Joong Jin Han , Yong Jin Jang , Youngjea Kim , Esder Kang
IPC分类号： C07C323/09 , C08L71/12 , C08G65/40 , C07C43/29 , C08G75/02 , C07C317/12 , H01M8/10 , C07C43/275 , H01M8/18 , B01J39/19 , C08G75/0245 , C08G75/12 , H01M8/1039 , H01M8/1018
摘要： The present specification relates to a fluorine-based compound for a brancher, a polymer using the same, a polymer electrolyte membrane using the same, a fuel cell using the same, and a redox flow battery including the same.

12. 发明授权

US10300477B2 Terminally-crosslinked methyl morpholinium-functionalized block copolymers, and anion exchange membranes using the same 有权
公开(公告)号：US10300477B2
公开(公告)日：2019-05-28
申请号：US15694980
申请日：2017-09-04
申请人： INCHEON UNIVERSITY INDUSTRY ACADEMIC COOPERATION FOUNDATION
发明人： Tae Hyun Kim , So Hyun Kwon
IPC分类号： C08G75/23 , B01J41/13 , B01J47/12 , C08J5/22 , C08G75/0245 , C08G81/00 , B29C71/02 , C08J3/24 , C08J7/12 , H01M8/1027 , H01M8/1081 , B01D71/80 , B01D67/00 , B01J41/04 , C08G65/40 , B01D71/82 , B01D61/42 , B01D71/68
摘要： The present disclosure herein relates to a terminally-crosslinked methyl morpholinium-functionalized block copolymer, and an anion exchange membrane using the same, and more particularly, to a terminally-crosslinked block copolymer which has a novel structure, and in which, in a poly(arylene ether sulfone) multiblock copolymer (MM-PES) having methyl morpholinium as a conducting group, an azide compound may be used as a crosslinking agent so that crosslinking only occurs at ends of the polymer chains (xMM-PES), thereby minimizing conductivity loss, significantly increasing mechanical and chemical stability, attaining additional conductivity resulting from the three-dimensional structure of morpholinium, and reducing water uptake while enhancing water retention capacity, uses thereof as an alkaline fuel cell anion exchange membrane (AEM), and a method for conveniently preparing the same through simple heat-treatment.

13. 发明申请

US20190077918A1 SULFIDE-BASED POLYMER, FILM COMPRISING SAME AND METHOD FOR PREPARING SAME 审中-公开
公开(公告)号：US20190077918A1
公开(公告)日：2019-03-14
申请号：US15741642
申请日：2017-07-07
申请人： LG CHEM, LTD.
发明人： Sanggon KIM , Hyungsam CHOI , Duk Hun JANG
IPC分类号： C08G75/0245 , C08G75/0227 , C08G75/20 , C08J5/18
CPC分类号： C08G75/0245 , C08G75/0204 , C08G75/0209 , C08G75/0227 , C08G75/0236 , C08G75/20 , C08J5/18 , C08J2381/02 , C08J2381/06 , C08L81/02 , C08L81/06
摘要： The present disclosure provides a sulfide-based polymer, a film comprising the same, and a method for preparing the same.

14. 发明授权

US4785057A Para-phenylene sulfide block copolymer, process for the production of the same 失效
标题翻译：对亚苯基硫醚嵌段共聚物，生产过程相同
公开(公告)号：US4785057A
公开(公告)日：1988-11-15
申请号：US858851
申请日：1986-04-30
申请人： Zenya Shiiki , Takayuki Katto , Yo Iizuka , Takao Iwasaki , Toshitaka Kouyama
发明人： Zenya Shiiki , Takayuki Katto , Yo Iizuka , Takao Iwasaki , Toshitaka Kouyama
IPC分类号： C08G75/0254 , C08G75/0245 , H01B3/30 , H05K1/03 , C08G75/14 , C08G75/16
CPC分类号： H01B3/301 , C08G75/0231 , C08G75/0245 , C08G75/0254 , D01F6/765 , D01F6/78 , H05K1/0333 , Y10S428/901 , Y10T428/24909 , Y10T428/24917 , Y10T428/31533
摘要： A para-phenylene sulfide block copolymer consisting essentially of a recurring unit (A) ##STR1## and a recurring unit (B) ##STR2## said recurring units (A) being present in the form of a block of 20 to 5,000 units of (A) on the average in the molecular chain, the mol fraction of the recurring units (A) being in the range of 0.50 to 0.98, the block copolymer having a melt viscosity (.eta.*) of 50 to 100,000 poise as determined at 310.degree. C. at a shear rate of 200 sec.sup.-1 and having: (a) a glass transition temperature (Tg) of 20.degree. to 80.degree. C., (b) a crystalline melting point (Tm) of 250.degree. to 285.degree. C., and (c) a crystallization index (Ci) of 15 to 45, this value being that of the heat-treated, but not stretch-oriented copolymer, which block copolymer is preferably produced by a process comprising a first step of heating an aprotic polar organic solvent containing a dihaloaromatic compound consisting essentially of a m-dihalobenzene and an alkali metal sulfide to form a reaction liquid (E) containing a m-phenylene sulfide polymer consisting essentially of recurring units (B) ##STR3## and a second step of adding a p-dihalobenzene to the reaction liquid (E) and heating the mixture in the presence of an alkali metal sulfide and an aprotic polar organic solvent to form a block copolymer consisting essentially of the recurring units (B) and recurring units (A) ##STR4##
摘要翻译：基本上由重复单元（A）＆lt; IMAGE＆gt;和重复单元（B）＆lt; IMAGE＆gt;组成的对亚苯基硫醚嵌段共聚物表示重复单元（A）以20-5,000单位（ A）平均分子链中，重复单元（A）的摩尔分数在0.50〜0.98范围内，嵌段共聚物的熔体粘度（η）为50〜100,000泊，在310℃下测定（a）玻璃化转变温度（Tg）为20〜80℃，（b）结晶熔点（Tm）为250〜285℃ ，（c）15〜45的结晶指数（Ci），该值为热处理而不是拉伸取向共聚物的值，该嵌段共聚物优选通过包括加热第含有主要由间二卤代苯和碱金属硫化物组成的二卤代芳族化合物的非质子极性有机溶剂形成反应液（E），其包含基本上由重复单元（B）组成的间苯硫醚聚合物，第二步是将对二卤代苯加入到反应液（E）中，并在碱金属硫化物存在下加热混合物和非质子极性有机溶剂以形成基本上由重复单元（B）和重复单元（A）组成的嵌段共聚物。

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