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    • 11. 发明授权
    • Method for treatment of aluminum dross oxides
    • 铝浮渣氧化物处理方法
    • US4434142A
    • 1984-02-28
    • US426200
    • 1982-09-28
    • John A. Huckabay
    • John A. Huckabay
    • C01F7/02C01F7/46
    • C01F7/46C01F7/021C01P2004/50
    • There is disclosed a method for the treatment of aluminum dross oxides which contain aluminum metal, aluminum carbide, aluminum nitride and salts such as potassium and sodium chloride. The method comprises the thermal treatment of an aqueous suspension of the dross oxides with agitation in the presence of a particulate grinding medium. The method is practiced in a stirred reactor vessel which contains a bed of refractory, ceramic balls that are agitated with a slurry to provide a sufficient abrading action on the aluminum metal particles to remove the aluminum hydroxide coating and continually expose the aluminum metal for reaction with the water. This invention comprises the introduction of a purge gas into the suspension, preferably air, during its thermal treatment to reduce the formation of foam during the treatment and to assist in liberation of ammonia formed by the decomposition of the aluminum nitride.
    • 公开了一种处理包含铝金属,碳化铝,氮化铝和盐如氯化钾和氯化钠的铝渣的氧化物的方法。 该方法包括在颗粒研磨介质的存在下搅拌,热处理浮渣氧化物的水悬浮液。 该方法在搅拌的反应器容器中实施,该容器包含耐火材料床,陶瓷球用浆料搅拌以对铝金属颗粒提供足够的研磨作用以除去氢氧化铝涂层并连续暴露铝金属以与 水。 本发明包括在其热处理期间将吹扫气体引入悬浮液,优选空气中,以减少处理过程中泡沫的形成并帮助释放由氮化铝分解形成的氨。
    • 12. 发明授权
    • Removal of oxalate from bayer process liquor
    • 从拜耳处理液中除去草酸盐
    • US4275043A
    • 1981-06-23
    • US114286
    • 1980-01-22
    • Bohdan Gnyra
    • Bohdan Gnyra
    • C01F7/47C01F7/06C01F7/46
    • C01F7/473
    • Sodium oxalate is supersaturated solution in Bayer spent liquor stabilized by the presence of humic material is precipitated by the treatment with an adsorbent which adsorbs the humic material to give an insoluble product, thus removing it from solution and destabilizing the solution with respect to precipitation of sodium oxalate. The preferred adsorbent is activated carbon. The activated carbon can be dispersed in the spent liquor as a fine powder or the spent liquor can be passed through a column of particulate carbon. Precipitation of sodium oxalate can be expidited by addition to seed crystals and/or addition of sodium oxalate solution which is supersaturated at a temperature higher than that of the spent liquor.
    • 草酸钠是过饱和溶液,通过腐殖质存在而稳定的拜耳废液中,通过用吸附腐殖质的吸附剂进行沉淀,得到不溶性产物,从而从溶液中除去溶液并使溶液不稳定 草酸盐。 优选的吸附剂是活性炭。 活性炭可以作为细粉末分散在废液中,或者废料可以通过颗粒碳柱。 草酸钠的沉淀可以通过加入晶种和/或在高于废液的温度下过饱和的草酸钠溶液的添加来消除。