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    • 13. 发明授权
    • Method for forming a sequence of crosslinked pigmented coatings on ceramic substrates
    • 在陶瓷基板上形成交联着色涂层序列的方法
    • US06214414B1
    • 2001-04-10
    • US09359471
    • 1999-07-22
    • Robert H. TangYingchao ZhangLouis J. NehmsmannAlan E. WangGeorge D. MorrisRobert A. Montague
    • Robert H. TangYingchao ZhangLouis J. NehmsmannAlan E. WangGeorge D. MorrisRobert A. Montague
    • B05D136
    • C03C17/3405C03C2217/445C03C2217/485
    • A method comprising heating to elevated temperature a ceramic substrate having thereon a sequence of coatings of pigmented coating compositions wherein each of said pigmented coating compositions comprises: (a) reactive organic resin which is polyhydroxy-functional, polyepoxy-functional, or both epoxy-functional and hydroxy-functional; (b) reactive wax; (c) color-imparting pigment; and (d) blocked polyisocyanate; wherein: (e) the pigmented coating composition of at least one coating of the sequence is substantially free of amino-functional curing agent; and (f) the pigmented coating composition of at least one other coating of the sequence further comprises amino-functional curing agent; to crosslink all of the pigmented coating compositions of the coatings of the sequence and to adhere the sequence to the ceramic substrate. The preferred ceramic substrates are glass bottles.The outermost coating of the sequence may optionally be overlain with a coating of substantially clear overcoating composition which comprises reactive organic resin which is polyhydroxy-functional, polyepoxy-functional, or both epoxy-functional and hydroxy-functional. Upon heating to the elevated curing temperature, the substantially clear overcoating composition is crosslinked together with the pigmented coating compositions.
    • 一种方法,包括将具有着色涂料组合物涂层序列的陶瓷基材加热到高温,其中每种所述着色涂料组合物包含:(a)反应性有机树脂,其为多羟基官能团,聚环氧官能团或环氧官能团 和羟基官能团; (b)活性蜡; (c)赋颜色剂; 和(d)封端的多异氰酸酯; 其中:(e)所述序列的至少一种涂层的着色涂料组合物基本上不含氨基官能的固化剂; 和(f)该序列的至少一种其它涂层的着色涂料组合物还包含氨基官能的固化剂; 以使所述序列的涂层的所有着色涂料组合物交联并将该序列粘附到陶瓷基材上。 优选的陶瓷基材是玻璃瓶。该顺序的最外涂层可以任选地与基本上透明的涂层组合物的涂层重叠,该涂层组合物包含反应性有机树脂,其是多羟基官能的,聚环氧官能的或环氧官能的和羟基官能的 。 加热至升高的固化温度后,基本上透明的外涂层组合物与着色涂料组合物一起交联。