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    • 12. 发明授权
    • Magnetic recording material
    • 磁记录材料
    • US4657817A
    • 1987-04-14
    • US558673
    • 1983-12-06
    • Tsutomu OkitaKyoichi NaruoNobuo TsujiTeruo NakagawaKiyoshi MuraseTakahisa Ogasawara
    • Tsutomu OkitaKyoichi NaruoNobuo TsujiTeruo NakagawaKiyoshi MuraseTakahisa Ogasawara
    • C08F290/00C08F299/06C08G18/42C08G18/67C08L75/16C09D5/23C09D175/04C09D175/14G11B5/702G11B5/70
    • G11B5/7026C08G18/42C08G18/672C08L75/16G11B5/7021Y10S428/90Y10T428/31609
    • There is provided a magnetic recording material produced by coating on a support a magnetic coating composition which contains as main components a magnetic powder and a binder, the binder comprising an urethane acrylate synthesized using a polyester polyol having a particular structure, and by irradiating the resulting magnetic coat with electron beams to harden it. The polyester polyol contains polyhydric alcohol component, 50 mole % or more of which is a dihydric alcohol selected from the class (A) described below, and/or polybasic acid component, 50 mole % or more of which is a dibasic acid selected from the class (B) described below. The urethane acrylate is synthesized under such a condition that it may have two or more of (meth)acryloyl groups per molecule. Thus, improvements in electromagnetic properties and in durability are attained.Class (A): Alkyl-substituted aliphatic dihydric alcohols, alicyclic dihydric alcohols, and dihydric alcohols made by addition of alkylene oxides to alicyclic or aromatic dihydric alcohols.Class (B): Alicyclic dicarboxylic acids and aromatic dicarboxylic acids.
    • 提供了一种通过在载体上涂覆磁性涂料组合物而制备的磁记录材料,磁性涂料组合物含有作为主要组分的磁性粉末和粘合剂,所述粘合剂包含使用具有特定结构的聚酯多元醇合成的聚氨酯丙烯酸酯,并且通过照射所得到的 磁性涂层用电子束硬化。 聚酯多元醇含有多元醇成分,其中50摩尔%以上是选自下述(A)的二元醇,和/或多元酸成分,50摩尔%以上的二元酸选自 (B)类。 氨基甲酸酯丙烯酸酯在每分子可以具有两个以上(甲基)丙烯酰基的条件下合成。 因此,获得了电磁特性和耐久性的改善。 (A)类:烷基取代的脂族二元醇,脂环族二元醇和通过将环氧烷烃加成到脂环族或芳族二元醇中制得的二元醇。 类(B):脂环族二羧酸和芳族二羧酸。
    • 17. 发明授权
    • Layers used to prevent reticulation in photographic elements
    • US4056396A
    • 1977-11-01
    • US578069
    • 1975-05-16
    • Ikutaro HorieTakushi MiyazakoShinji SakaguchiNobuo TsujiNagao Kameji
    • Ikutaro HorieTakushi MiyazakoShinji SakaguchiNobuo TsujiNagao Kameji
    • G03C1/04C08F16/00C08F16/14C08F20/00C08F20/52G03C1/053G03C1/76G03C3/00
    • G03C1/7614G03C1/053
    • A photographic light-sensitive material including a support, a non-light sensitive uppermost layer consisting of at least one organic synthetic high polymer compound as a film forming material and at least one light-sensitive layer between the support and the uppermost layer, said organic high polymer compound being selected from the group consisting of the following polymers (A) to (F):polymer (A) comprising repeating units a.sub.1 and a.sub.2 ;______________________________________ a.sub.1 : ##STR1## 80 - 97 mol% a.sub.2 : ##STR2## 3 - 20 mol% ______________________________________ Wherein M represents a cation, and m represents 0, 3 or 4;Polymer (B) comprising repeating units b.sub.1, b.sub.2 and b.sub.3 ;______________________________________ b.sub.1 : ##STR3## 5 - 30 mol% b.sub.2 : ##STR4## 5 - 75 mol% b.sub.3 : ##STR5## 20 - 65 mol% ______________________________________ Wherein R.sub.1 and R.sub.2 each represents --CH.sub.3 or --C.sub.2 H.sub.5, R.sub.3 and R.sub.5 each represents --H or --CH.sub.3, and R.sub.4 represents --CH.sub.3, --C.sub.2 H.sub.5, --C.sub.3 H.sub.7 or --C.sub.4 H.sub.9 ;polymer (C) comprising repeating units c.sub.1 and c.sub.2 ;______________________________________ c.sub.1 : ##STR6## 10 - 40 mol% c.sub.2 : ##STR7## 60 - 90 mol% ______________________________________ Wherein R.sub.6 represents --H or --CH.sub.3, and Z represents --COOH, --COOCH.sub.3, --COOC.sub.2 H.sub.5, --COOC.sub.3 H.sub.7, --COOC.sub.4 H.sub.9 or --CONH.sub.2 ;polymer (D) comprising repeating units d.sub.1 and d.sub.2 ;______________________________________ d.sub.1 : ##STR8## 10 - 40 mol% d.sub.2 : ##STR9## 60 - 90 mol% ______________________________________ Wherein R.sub.7 represents --H or --CH.sub.3 ;polymer (E) comprising repeating units e.sub.1 and e.sub.2 ;______________________________________ e.sub.1 : ##STR10## 20 - 60 mol% e.sub.2 : ##STR11## 40 - 80 mol% ______________________________________ wherein R.sub.8 and R.sub.9 each represents --H or --CH.sub.3, and X represents --CH.sub.3, --C.sub.2 H.sub.5, --C.sub.3 H.sub.7 or --C.sub.4 H.sub.9 ; andpolymer (F) comprising repeating unit f.sub.1 ;______________________________________ f.sub.1 : ##STR12## wherein Y represents --CH.sub.3 or --COCH.sub.3, R.sub.10 represents --H or --C.sub.n H.sub.2n+1, n being an integer of 1 to 12, said organic synthetic high polymer compound being insoluble to a processing solutions