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    • 17. 发明授权
    • Process for preparing novel high solids non-aqueous polymer compositions
    • 制备新型高固体非水性聚合物组合物的方法
    • US6110995A
    • 2000-08-29
    • US273688
    • 1994-07-12
    • Wood E. HunterKevin W. FrederickRandy J. Loeffler
    • Wood E. HunterKevin W. FrederickRandy J. Loeffler
    • C08J3/00C08F6/20C08J3/09C08J3/11
    • C08J3/09C08F6/20C08J2300/14
    • The use of falling-film evaporation and a concentration means such as centrifugal separation to dehydrate and concentrate a water-in-oil polymer emulsion or suspension is disclosed. In a preferred embodiment, a water-in-oil polymer composition containing less than about 25% active polymer solids is dehydrated in falling-film evaporator to produce an evaporator concentrate containing less than about 5.0% water. The evaporator concentrate then flows to a separation device such as a centrifuge, wherein oil is removed to produce a composition that is substantially a polymer and emulsifying surfactant-in-oil composition containing in excess of about 60 weight % polymer solids. The centrifuge raffinate may optionally be treated in a second separation means to capture additional polymer solids, with optional recycle of the oil-rich raffinate. The concentrated polymer composition is preferably stabilized with a steric stabilizer to produce a free flowing liquid product.
    • 公开了使用降膜蒸发和诸如离心分离的浓缩装置来使油包水聚合物乳液或悬浮液脱水并浓缩。 在优选的实施方案中,包含少于约25%活性聚合物固体的油包水聚合物组合物在降膜蒸发器中脱水以产生含有少于约5.0%水的蒸发浓缩物。 蒸发器浓缩物然后流到分离装置,例如离心机,其中除去油,以产生基本上是含有超过约60重量%聚合物固体的聚合物和乳化表面活性剂 - 油组合物的组合物。 离心萃余液可以任选地在第二分离装置中处理以捕获另外的聚合物固体,并且富油萃取液的任选循环。 浓缩的聚合物组合物优选用空间稳定剂稳定以产生自由流动的液体产物。
    • 18. 发明授权
    • Method for remediating sites contaminated with toxic waste
    • 修复受有毒废物污染的场所的方法
    • US6049021A
    • 2000-04-11
    • US248879
    • 1999-02-11
    • Gerry D. GetmanJon E. RogersWood E. Hunter
    • Gerry D. GetmanJon E. RogersWood E. Hunter
    • A62D3/00A62D3/32A62D3/34A62D3/36A62D101/06A62D101/20A62D101/22A62D101/24A62D101/26A62D101/28B01D11/00B01J8/00B09B3/00B09C1/02B09C1/08C02F1/70G21F20060101G21F9/00G21F9/28
    • B09C1/08G21F9/001G21F9/30
    • Methods for decontaminating toxic waste, particularly solid carrier materials, such as soil contaminated with a toxin, or solid mixed wastes are more efficiently decontaminated with solvated electrons by first extracting the toxin from the carrier with a nitrogenous base at elevated temperatures, followed by a temperature reduction before initiating chemical reduction of the toxin with solvated electrons. Pre-extraction of the toxin at elevated temperatures followed by temperature reduction minimizes competing side reactions, improves selectivity of solvated electrons for the toxin and improves the economics of the process with more efficient metal utilization. The process can be performed without separation of the toxin from the extraction vessel holding the solid carrier material. Alternatively, elevated temperatures can be used to perform one or more extractions of toxin with nitrogenous base followed by reduction with solvated electrons by performing the reaction in a separate reactor. The processes of the invention are useful in the destruction of virtually any chemically reducible hazardous substance.
    • 用有毒废物,特别是固体载体材料(如毒素污染的土壤)或固体混合废物进行净化的方法,通过首先在高温下用含氮碱从载体中提取毒素,再用溶剂化电解进行更有效的净化,然后加入温度 在用溶剂化电子开始化学还原毒素之前还原。 在升高的温度下预先提取毒素,随后进行温度降低,使竞争性副反应最小化,提高溶剂化电子对毒素的选择性,并通过更有效的金属利用来改善该方法的经济性。 该过程可以在不将毒素从保持固体载体材料的萃取容器中分离的情况下进行。 或者,升高的温度可用于用含氮碱进行一次或多次毒素提取,然后通过在单独的反应器中进行反应而用溶剂化电子还原。 本发明的方法可用于几乎任何化学还原性有害物质的破坏。