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11. 发明授权

US5639833A Molding materials comprising polyarylene ethers and copolyamides 失效
标题翻译：包含聚亚芳基醚和共聚酰胺的成型材料
公开(公告)号：US5639833A
公开(公告)日：1997-06-17
申请号：US513631
申请日：1995-08-10
申请人： Martin Weber , Herbert Fisch , Gunter Pipper , Axel Gottschalk
发明人： Martin Weber , Herbert Fisch , Gunter Pipper , Axel Gottschalk
IPC分类号： C08L23/00 , C08L23/16 , C08L51/00 , C08L71/00 , C08L71/08 , C08L71/10 , C08L73/00 , C08L77/00 , C08L77/06 , C08L81/00 , C08L81/06 , C08L87/00
CPC分类号： C08L81/06 , C08L71/00 , C08L77/00 , C08L77/06
摘要： The invention is directed to molding materials containingA) from 1 to 99% by weight of polyarylene ethers having repeating units I ##STR1## where t and q may each be an integer 0, 1, 2 or 3,T, Q and Z may each be a chemical bond or --O--, --S--, --SO.sub.2 --, S.dbd.O, C.dbd.O, --N.dbd.N--, R.sup.a C.dbd.CR.sup.b -- or --CR.sup.c R.sup.d --, with the proviso that at least one of the groups T, Q and Z is --SO.sub.2 -- or C.dbd.O,R.sup.a and R.sup.b,R.sup.c and R.sup.d, andAr and Ar.sup.1 are as defined in the specification,B) from 1 to 99% by weight of copolyamides containingb.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,b.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,b.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine,b.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms andb.sub.5) from 0 to 4 mol % of further polyamide-forming monomers which differ from b.sub.1) to b.sub.4),along with other optional additives.
摘要翻译：本发明涉及含有A）1至99重量％的具有重复单元I（I）的聚亚芳基醚的成型材料，其中t和q可各自为整数0,1,2或3，T，Q 和Z可以各自为化学键或-O - ， - S - ， - SO 2 - ，S = O，C = O，-N = N-，RaC = CRb-或-CRcRd-，条件是至少 T，Q和Z中的一个是-SO 2 - 或C = O，R a和R b，R c和R d，Ar和Ar 1如说明书中所定义，B）1至99重量％的含有b1 ）来自对苯二甲酸的单元为30〜44摩尔％，b2）6〜20摩尔％来自间苯二甲酸的单元，b3）43〜49.5摩尔％的衍生自六亚甲基二胺的单元，b4 ）0.5〜7摩尔％的衍生自6〜30个碳原子的脂肪族环状二胺的单元，b5）0〜4摩尔％的不同于b1）〜b4）的其他聚酰胺形成性单体，以及其它任选的添加剂。

12. 发明授权

US5068308A Continuous preparation of aromatic polycondensates 失效
标题翻译：连续制备芳香族聚氧乙烯
公开(公告)号：US5068308A
公开(公告)日：1991-11-26
申请号：US365130
申请日：1989-06-12
申请人： Gunter Pipper , Gerhard Heinz , Bernd Hisgen
发明人： Gunter Pipper , Gerhard Heinz , Bernd Hisgen
IPC分类号： C08G63/19 , C08G63/60 , C08G63/688 , C08G63/78 , C08G69/32 , C08G69/44 , C08G73/16 , C08G75/26
CPC分类号： C08G75/26 , C08G63/605 , C08G69/32 , C08G69/44
摘要： Aromatic polycondensates are prepared in a continuous process froma) aromatic hydroxy-, thio- and/or amino-carboxylic acids,b) aromatic dihydroxy-, dithio-, diamino- and/or hydroxy-amino compounds,c) urea as an optional component andd) a molar amount equivalent to the sum of components b) and c) of aromatic dicarboxylic acids,by1. reacting components a), b), d) and optionally c) with lower fatty acid anhydrides in excess at from 140.degree. to 280.degree. C. with distillative removal of fatty acids and fatty acid anhydrides,2. passing the oligomer mixture downward through a perpendicular precondensation zone to form a two-phase mixture of prepolymers and vaporous fatty acids,3. separating the prepolymers from the vaporous fatty acids and4. condensing the prepolymer in a condensation zone to give a granulable polycondensate.
摘要翻译：芳香族缩聚物以a）芳族羟基，硫代和/或氨基羧酸，b）芳族二羟基 - ，二硫代 - ，二氨基 - 和/或羟基 - 氨基化合物的连续方法制备，c）作为任选的将组分a），b），d）和任选的c）与140以下的低级脂肪酸酐过量反应，得到芳族二羧酸的组分b）和c）的总和的摩尔量 DEG至280℃，蒸馏除去脂肪酸和脂肪酸酐，2.将低聚物混合物向下通过垂直预缩合区，形成预聚物和汽相脂肪酸的两相混合物，3.将预聚物与蒸气脂肪酸，和4.将预聚物在冷凝区中缩合，得到可颗粒缩聚物。

13. 发明授权

US5030709A Continuous preparation of copolyamides 失效
标题翻译：连续制备共聚酰胺
公开(公告)号：US5030709A
公开(公告)日：1991-07-09
申请号：US501034
申请日：1990-03-29
申请人： Gunter Pipper , Eckhard M. Koch
发明人： Gunter Pipper , Eckhard M. Koch
IPC分类号： C08G69/26 , C08G69/28 , C08G69/36
CPC分类号： C08G69/265 , C08G69/28 , C08G69/36
摘要： Copolyamides which contain units of the formula --NH--(CH.sub.2).sub.4 --NH are prepared by a continuous process in whicha) an aqueous solution of from 5 to 80% by weight of a salt of 1,4-diaminobutane, and dicarboxylic acids and from 20 to 95% by weight of further polyamide-forming starting materials are heated to a temperature above the melting point of the copolyamide, with the addition of diamines and with vaporization of water, under superatmospheric pressure,b) the vapor phase and prepolymer are brought into intimate contact with one another,c) the prepolymer is separated from the vapor phase and the polymer is discharged after a total residence time of not more than 30 minutes, andd) diamines are separated off from the vapor phase and recycled to a).
摘要翻译：包含式-NH-（CH 2）4 -NH的单元的共聚酰胺通过连续方法制备，其中a）5-80重量％的1,4-二氨基丁烷的盐和二羧酸的水溶液和20至95重量％的另外的聚酰胺形成原料在超大气压下加热至高于共聚酰胺熔点的温度，加入二胺并蒸发水，b）气相和预聚物彼此紧密接触，c）将预聚物与气相分离，聚合物在总停留时间不超过30分钟后排出，并且d）将二胺从气相中分离并再循环至一个）。

14. 发明授权

US4816557A Removal of caprolactam and oligomers thereof from nylon granules containing same 失效
标题翻译：从含有它们的尼龙颗粒中除去己内酰胺及其低聚物
公开(公告)号：US4816557A
公开(公告)日：1989-03-28
申请号：US167250
申请日：1988-03-11
申请人： Gunter Pipper , Claus Cordes
发明人： Gunter Pipper , Claus Cordes
IPC分类号： C08G69/16 , C08G69/46
CPC分类号： C08G69/46
摘要： Caprolactam and oligomers thereof are removed from nylon granules containing same in a process wherein(a) nylon granules are introduced at not less than 100.degree. C. at the top of a substantially upright treatment zone,(b) nylon granules are passed downward through the treatment zone while being heated to from 130.degree. to 210.degree. C.,(c) superheated steam is passed at from 130.degree. to 210.degree. C. upward through the treatment zone,(d) dry nylon granules are withdrawn at the bottom end of the treatment zone and steam containing caprolactam and oligomers thereof is withdrawn at the top of the treatment zone,(e) the caprolactam and oligomers thereof containing steam thus obtained is passed through a column giving an aqueous solution of caprolactam and oligomers thereof as bottom product and virtually caprolactam-free steam as overhead product.
摘要翻译：在其中（a）尼龙颗粒在基本上直立的处理区的顶部不低于100℃引入尼龙颗粒的过程中，己内酰胺及其低聚物从含有其的尼龙颗粒中除去，（b）尼龙颗粒向下通过处理区，同时加热至130℃至210℃，（c）过热蒸汽从130℃升至210℃，向上通过处理区，（d）干燥的尼龙颗粒在处理区和含有己内酰胺及其低聚物的蒸汽在处理区的顶部排出，（e）将含有这样得到的蒸汽的己内酰胺及其低聚物通过柱，得到己内酰胺及其低聚物的水溶液作为底部产物，实际上无己内酰胺的蒸汽作为塔顶产品。

15. 发明授权

US5936045A Biodegradable polymers, the preparation thereof, and the use thereof for producing biodegradable moldings 失效
标题翻译：生物可降解聚合物及其制备方法及其生产可降解模制品的用途
公开(公告)号：US5936045A
公开(公告)日：1999-08-10
申请号：US894240
申请日：1997-08-14
申请人： Volker Warzelhan , Gunter Pipper , Ursula Seeliger , Peter Bauer , Dieter Bernhard Beimborn , Motonori Yamamoto
发明人： Volker Warzelhan , Gunter Pipper , Ursula Seeliger , Peter Bauer , Dieter Bernhard Beimborn , Motonori Yamamoto
IPC分类号： C08J9/04 , C08G63/66 , C08G63/672 , C08G63/91 , C08L3/00 , C08L67/00 , C08L101/16 , C09J167/00 , D21H19/28
CPC分类号： C08G63/914 , C08G63/672
摘要： Biodegradable polymers comprising a polyether ester P1 obtained by reactinga first mixture of20-95 mol% of adipic acid or ester-forming derivatives thereof or mixtures thereof,5-80 mol% of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and0-5 mol% of a compound containing sulfonate groups,and a second mixture of15-99.8 mol% of a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,85-0.2 mol% of a dihydroxy compound IHO--�(CH.sub.2).sub.n --O!.sub.m --H(n=2, 3 or 4, m=2-250)with0-5 mol%, based on the first mixture, of a compound D having at least three groups capable of ester formation,and a bisoxazoline C1, their preparation and their use in the manufacture of biodegradable molding materials.
摘要翻译： PCT No.PCT / EP96 / 00458 Sec。 371日期1997年8月14日 102（e）日期1997年8月14日PCT提交1996年2月3日PCT公布。公开号WO96 / 25448 日期1996年8月22日可生物降解的聚合物包括通过使20-95mol％己二酸或其成酯衍生物或其混合物的第一混合物5-80mol％的对苯二甲酸或酯形成衍生物或其混合物，和0-5mol％的含有磺酸盐基团的化合物，以及15-99.8mol％选自C 2 -C 6烷二醇和C 5 -C 10 - 环烷二醇的二羟基化合物的第二混合物， 85-0.2摩尔％的二羟基化合物IHO - [（CH 2）n O] m H（n = 2,3或4，m = 2-250），基于第一混合物，0-5摩尔％的化合物D 具有至少三个能够形成酯的基团，以及双恶唑啉C1，它们的制备及其在制造可生物降解的成型材料中的用途。

16. 发明授权

US5710216A Thermoplastic molding materials based on partly aromatic polyamides and polymethacrylamides 失效
标题翻译：基于部分芳族聚酰胺和聚甲基丙烯酰胺的热塑性成型材料
公开(公告)号：US5710216A
公开(公告)日：1998-01-20
申请号：US572039
申请日：1995-12-14
申请人： Martin Weber , Herbert Fisch , Gunter Pipper , Axel Gottschalk
发明人： Martin Weber , Herbert Fisch , Gunter Pipper , Axel Gottschalk
IPC分类号： C08L33/24 , C08L77/00 , C08L77/06 , C08L33/10
CPC分类号： C08L33/24 , C08L77/00 , C08L77/06
摘要： Thermoplastic molding materials contain A) from 1 to 98.5% by weight of a partly aromatic copolyamide, B) from 1 to 98.5% by weight of a polymethacrylimide, C) from 0.5 to 30% by weight of a polymeric component having OH groups, D) from 0 to 60% by weight of fibrous or particulate fillers or mixtures thereof, E) from 0 to 40% by weight of rubber impact modifiers and F) from 0 to 40% by weight of conventional additives and processing assistants.
摘要翻译：热塑性成型材料包含A）1至98.5重量％的部分芳族共聚酰胺，B）1至98.5重量％的聚甲基丙烯酰亚胺，C）0.5至30重量％的具有OH基团的聚合物组分，D ）0至60重量％的纤维或颗粒填料或其混合物，E）0至40重量％的橡胶冲击改性剂和F）0至40重量％的常规添加剂和加工助剂。

17. 发明授权

US5128442A Catalytic, solid state process for the preparation of linear polyamides 失效
标题翻译：用于制备线性聚氨酯的催化，固态过程
公开(公告)号：US5128442A
公开(公告)日：1992-07-07
申请号：US681255
申请日：1991-04-08
申请人： Gunter Pipper , Wolfgang F. Mueller , Harald Dauns
发明人： Gunter Pipper , Wolfgang F. Mueller , Harald Dauns
IPC分类号： C08G69/30 , C08G69/28
CPC分类号： C08G69/28
摘要： A process for the preparation of a linear polyamide by reacting the appropriate dicarboxylic acid and diamine in a liquid reaction medium with the addition of a catalytically effective phosphorus compound, removing the reaction medium to give a solid salt, precondensing the latter in the solid phase at a temperature of from 140.degree. C. to 5.degree. C. below the melting point of the salt and continuing condensation at a temperature above that used for the precondensation until the desired degree of condensation is reached.
摘要翻译：通过在液体反应介质中使合适的二羧酸和二胺与添加催化有效的磷化合物反应来制备线性聚酰胺的方法，除去反应介质以得到固体盐，将固相的预冷凝温度低于盐的熔点为140℃至5℃，并在高于用于预缩合直到达到所需缩合度的温度下继续冷凝。

18. 发明授权

US4578455A Process and apparatus for removing volatile constituents from polymer melts or pastes 失效
标题翻译：从聚合物熔体或糊状物中除去挥发性成分的方法和设备
公开(公告)号：US4578455A
公开(公告)日：1986-03-25
申请号：US724500
申请日：1985-04-18
申请人： Gunter Pipper , Siegfried Riegger , Josef G. Floss
发明人： Gunter Pipper , Siegfried Riegger , Josef G. Floss
IPC分类号： C08G69/00 , B29C48/76 , C08F6/00 , C08G85/00 , C08F6/28
CPC分类号： B29C47/767 , B29C47/763 , C08F6/00 , C08G85/002 , B29C47/0009
摘要： A process for removing volatile constituents from polymer melts or pastes, wherein the polymer or paste containing the volatile constituents is passed, with continuous formation of fresh surfaces, through one or more zones in which the volatile constituents evaporate, and the volatile constituents are removed from the zone or zones in which they evaporate through, in each case, a plurality of porous orifices, and an apparatus for carrying out said process.
摘要翻译：从聚合物熔体或糊状物中除去挥发性成分的方法，其中含有挥发性成分的聚合物或糊料连续形成新鲜表面，通过其中挥发性成分蒸发的一个或多个区域，并且挥发性成分从其中它们蒸发的区域或每个区域在每种情况下都是多个多孔孔，以及用于执行所述方法的装置。

19. 发明授权

US4540772A Continuous preparation of nylon from aqueous salt solution in precondensation zone having baffles 失效
标题翻译：从具有挡板的预缩合区域的盐水溶液中连续制备尼龙
公开(公告)号：US4540772A
公开(公告)日：1985-09-10
申请号：US620837
申请日：1984-06-15
申请人： Gunter Pipper , Franz Schmidt , Rainer Theysohn , Siegfried Riegger , Eduard Heil , Hermann Fischer , Richard Thoma , Paul Matthies
发明人： Gunter Pipper , Franz Schmidt , Rainer Theysohn , Siegfried Riegger , Eduard Heil , Hermann Fischer , Richard Thoma , Paul Matthies
IPC分类号： C08G69/00 , C08G69/26 , C08G69/28 , C08L77/00
CPC分类号： C08G69/28
摘要： Nylons are prepared by a continuous process in which, in a precondensation zone, an aqueous solution of a salt of a dicarboxylic acid of 6 to 18 carbon atoms and a diamine of 6 to 18 carbon atoms is heated to 250.degree.-300.degree. C. under superatmospheric pressure, with simultaneous vaporization of water and formation of a prepolymer, the prepolymer and the vapor are separated, and the former is fed into a polycondensation zone and condensed under superatmospheric pressure of from 1 to 10 bar and at from 250.degree. to 300.degree. C., wherein the aqueous salt solution is condensed under superatomspheric pressure of from 1 to 10 bar in the first third of the tubular precondensation zone provided with baffles, until the degree of conversion is not less than 93%, and the prepolymer and the vapor phase are brought into intimate contact with one another in the remaining two thirds of the precondensation zone.
摘要翻译：尼龙通过连续方法制备，其中在预缩合区中将6至18个碳原子的二羧酸盐和6至18个碳原子的二胺的水溶液加热至250-300℃。在超大气压下，同时蒸发水和形成预聚物，将预聚物和蒸气分离，将前者加入缩聚区，并在1至10巴和250至300的超大气压下冷凝 ℃，其中盐水溶液在具有挡板的管状预缩合区的第一三分之一中在1至10巴的超大体压力下冷凝，直到转化率不低于93％，并且预聚物和气相在预缩合区的剩余三分之二处彼此紧密接触。

20. 发明授权

US4537949A Continuous preparation of nylon with diamine recycling 失效
标题翻译：连续制备尼龙与二胺回收
公开(公告)号：US4537949A
公开(公告)日：1985-08-27
申请号：US620563
申请日：1984-06-14
申请人： Franz Schmidt , Gunter Pipper , Josef G. Floss , Franz Zahradnik
发明人： Franz Schmidt , Gunter Pipper , Josef G. Floss , Franz Zahradnik
IPC分类号： C08G69/26 , C08G69/00 , C08G69/28 , C08L77/00
CPC分类号： C08G69/28
摘要： Nylons are prepared by a continuous process in which, in an evaporator zone, an aqueous solution of a salt of a dicarboxylic acid of 6 to 18 carbon atoms and a diamine of 6 to 18 carbon atoms is heated to 250.degree.-300.degree. C. under superatmospheric pressure, with simultaneous vaporization of water and formation of a prepolymer, the prepolymer and the vapors are separated continuously, the vapors are rectified and the entrained diamines are recycled, and the prepolymer is fed to a polycondensation zone and subjected to polycondensation under superatmospheric pressure of from 1 to 10 bar and at from 250.degree. to 300.degree. C., wherein the aqueous salt solution is heated under superatmospheric pressure of from 1 to 10 bar during a residence time of less than 60 seconds, with the proviso that, on leaving the evaporator zone, the degree of conversion is not less than 93% and the water content of the prepolymer is not more than 7% by weight.
摘要翻译：尼龙通过连续方法制备，其中在蒸发器区中将6至18个碳原子的二羧酸盐和6至18个碳原子的二胺的水溶液加热至250-300℃。在超大气压下，随着水的蒸发和预聚物的形成，预聚物和蒸气被连续分离，蒸气被精馏，夹带的二胺被再循环，并将预聚物进料到缩聚区，并在超大气压下进行缩聚压力为1至10巴，在250至300℃，其中在低于60秒的停留时间内，盐水溶液在1至10巴的超大气压下加热，条件是在离开蒸发区，转化度不低于93％，预聚物的含水量不超过7重量％。

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