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    • 11. 发明授权
    • De-foamer and processes for its production
    • 脱泡剂及其生产工艺
    • US4696761A
    • 1987-09-29
    • US860686
    • 1986-05-02
    • Karlheinz HaubennestelDaniela BreilAlfred BubatWerner Spratte
    • Karlheinz HaubennestelDaniela BreilAlfred BubatWerner Spratte
    • B01D19/00B01D19/04C07C273/18C07C275/14B01D17/04
    • C07C273/1827B01D19/0413
    • To produce a de-foamer, mono- and/or poly-functional isocyanate is reacted with mono- and/or polyfunctional amines, preferably in equivalent ratio 0.5:1 up to 1:0.2, in an organic carrier media, to form urea sols at temperatures which lie below the melting temperature of the resulting urea, the organic carrier medium not being a true solvent for the urea. The prepared ureas are represented by the general Formula 1: ##STR1## wherein r=C.sub.4 -C.sub.30 -alkyl; R'=C2-C.sub.12 -alkylene, phenylene or naphthalene with or without substitution by one or more C.sub.1 -C.sub.9 -alkyl groups, or cycloalkylene; R'--H or CH.sub.3 ; R"--H or methyl; and x=0 to 1, and are prepared by reacting isocyanates with amines in organic carrier media to form ureas of Formula 1, at temperatures lying below the melting temperature of the resulting urea, the organic carrier media not being true solvents for the urea.
    • 为了生产脱泡剂,单 - 和/或多官能异氰酸酯与有机载体介质中的单 - 和/或多官能胺优选以0.5:1至高达1:0.2的当量比反应,形成尿素溶胶 在低于所得尿素的熔融温度的温度下,有机载体介质不是尿素的真正溶剂。 制备的尿素由通式1表示:其中r = C 4 -C 30 - 烷基; R'= C2-C12-亚烷基,亚苯基或萘,有或没有被一个或多个C 1 -C 9 - 烷基或亚环烷基取代; R'-H或CH3; R“ - H或甲基; 并且x = 0至1,并且通过在有机载体介质中使异氰酸酯与胺反应以在低于所得尿素的熔融温度的温度下形成式1的脲来制备,有机载体介质不是尿素的真正溶剂。
    • 13. 发明授权
    • Levelling agents for surface coatings
    • 流平剂表面涂层
    • US06710127B2
    • 2004-03-23
    • US09967499
    • 2001-09-28
    • Karlheinz HaubennestelAlfred BubatAlbert Frank
    • Karlheinz HaubennestelAlfred BubatAlbert Frank
    • C08L7900
    • C08F290/04C08F283/12C08F290/06C08F290/061C08F290/068C09D7/47
    • The invention relates to levelling agents for surface coatings having a weight-average molecular weight of from 5000 to 100,000. The levelling agent is a branched polymer comprising a free-radically or ionically polymerized base molecule into which macromonomeric units containing at one end a monomeric unit which has an ethylenically unsaturated bond and possessing a weight-average molecular weight of from 1000 to 30,000 have been incorporated by free-radical or ionic copolymerization, the weight fraction of the macromonomeric units, based on the total weight of the branched polymer, being from 1 to 60% by weight. The invention further relates to the use of appropriate polymers as levelling agents for coating formulations and to coating formulations comprising the levelling agents of the invention.
    • 本发明涉及重均分子量为5000至100,000的表面涂层流平剂。 流平剂是包含自由基或离子聚合的碱分子的支链聚合物,其中含有一端具有烯键式不饱和键并具有1000至30,000重均分子量的单体单元的大分子单体已经被引入 通过自由基或离子共聚,基于支化聚合物的总重量,大分子单元的重量分数为1至60重量%。 本发明还涉及合适的聚合物作为流平剂用于涂布制剂和包含本发明的流平剂的包衣制剂的用途。
    • 16. 发明授权
    • Polyester group containing polysiloxanes for lacquers and molding
compositions
    • 含聚硅氧烷的聚酯基团用于漆和模塑组合物
    • US4812518A
    • 1989-03-14
    • US913302
    • 1986-09-30
    • Karlheinz HaubennestelAlfred Bubat
    • Karlheinz HaubennestelAlfred Bubat
    • C08L101/00C08G18/46C08G18/61C08G77/382C08G77/445C08J5/16C09D5/00C09D7/00C09D7/12C09D183/04C09D183/10C09D201/00C08F8/00C08G77/04
    • C09D183/10C08G18/4692C08G18/61C08G77/382C08G77/445C08G2125/00C08G2150/20
    • Lacquers and molding compositions containing an anti-adhesive character producing and lubricity increasing amount of a polyester-containing polysiloxane corresponding to the formula ##STR1## wherein A, B and D each represent --CH.sub.3 or --Z--R--Q; Z represents an alkylene group with 1 to 11 carbon atoms, --(CH.sub.2).sub.2 SCH.sub.2 --or --(CH.sub.2).sub.3 NHCO--; R represents an aliphatic, cycloaliphatic or aromatic group containing at least 3 carboxylate ester groups and having an average molecular weight Mn of 300 to 3,000; Q represents a reactive group capable of chemically reacting with a resin component of the lacquer or molding composition; x represents a number from 4 to 150; y represents a number from 1 to 6, in which an average molecule contains at least one group --Z--R--Q and the ratio of the number of --Z--R--Q groups to the number x is from 1:3 to 1:30. A process for imparting anti-adhesive character and increasing lubricity of lacquers and molding compositions by incorporating such polyester-containing polysiloxanes into the compositions as additives is also disclosed.
    • 含有对应于式(I)的含聚酯的聚硅氧烷的抗粘合特性产生和润滑性增加的提花和模塑组合物,其中A,B和D各自表示-CH 3或-Z-R-Q; Z表示具有1至11个碳原子的亚烷基, - (CH 2)2 SCH 2 - 或 - (CH 2)3 NHCO-; R表示含有至少3个羧酸酯基并且平均分子量&< 300和3,000的脂族,脂环族或芳族基团; Q表示能够与漆或模塑组合物的树脂组分化学反应的反应性基团; x表示4〜150的数; y表示1〜6的数,其中平均分子含有至少一个基团-Z-R-Q,并且-Z-R-Q基团数与x数之比为1:3至1:30。 还公开了通过将这种含聚酯的聚硅氧烷掺入组合物中作为添加剂来赋予涂料和模塑组合物的抗粘性和增加润滑性的方法。
    • 18. 发明授权
    • Terminal unsaturated, glycidol-based macromonomers, polymers obtainable therefrom, preparation and use
    • 末端不饱和,缩水甘油基大分子单体,可从其获得的聚合物,制备和用途
    • US08987410B2
    • 2015-03-24
    • US13379303
    • 2010-06-04
    • Wojciech JaunkyAlbert FrankAlfred BubatJürgen Omeis
    • Wojciech JaunkyAlbert FrankAlfred BubatJürgen Omeis
    • C07C231/12C07C41/03C07C233/20C07C43/178C08G65/26C08G65/00C08G65/22
    • C08G65/2609C08G65/00C08G65/22C08G65/2612
    • Process for preparing a macromonomer, in which a starting compound H2C═CR1—C6H4-s(R4)s—R3—OH or H2C═CR2—CO—NH—R3—OH, where R1 and R2 are each H or a linear or branched alkyl radical having from 1 to 4 carbon atoms, R3 is a linear or branched alkylene, aralkylene radical which has from 1 to 20 carbon atoms and can contain one or more hydroxy groups and the radicals R4 are each, independently of one another, a linear or branched alkyl, aralkyl, alkoxy or aralkoxy radical having from 1 to 20 carbon atoms and s=0-4, is, after partial deprotonation, reacted with at least one hydroxy-functional oxirane compound in the presence of an inhibitor of free-radical polymerization with opening of the oxirane ring, where the molar ratio of the molar amounts used n(starting compound):n(oxirane compound) is in the range from 1:100 to 1:1.Macromonomers which can be obtained by the process, polymers which can be obtained therefrom and their use as additives in coating compositions, plastics and cosmetics.
    • 制备大分子单体的方法,其中起始化合物H2C = CR1-C6H4-s(R4)s-R3-OH或H2C = CR2-CO-NH-R3-OH,其中R1和R2各自为H或直链或 具有1至4个碳原子的支链烷基,R3是具有1至20个碳原子并且可以含有一个或多个羟基的基团的直链或支链亚烷基,亚芳基,并且基团R 4各自彼此独立地为 具有1至20个碳原子且s = 0-4的直链或支链烷基,芳烷基,烷氧基或芳烷氧基是在部分去质子化后与至少一种羟基官能的环氧乙烷化合物在游离 - 使用n(起始化合物):n(环氧乙烷化合物)的摩尔量的摩尔比为1:100〜1:1的环氧乙烷环的开环自由基聚合。 可以通过该方法获得的大分子单体,可从其获得的聚合物及其作为涂料组合物,塑料和化妆品中的添加剂的用途。
    • 20. 发明申请
    • TERMINAL UNSATURATED, GLYCIDOL-BASED MACROMONOMERS, POLYMERS OBTAINABLE THEREFROM, PREPARATION AND USE
    • 端基不饱和,基于甘氨酸的麦芽糖,可获得的聚合物,制备和使用
    • US20120165414A1
    • 2012-06-28
    • US13379303
    • 2010-06-04
    • Wojciech JaunkyAlbert FrankAlfred BubatJürgen Omeis
    • Wojciech JaunkyAlbert FrankAlfred BubatJürgen Omeis
    • A61K8/81C07C231/12C07C43/178C09D125/08C08F220/58C08F216/14C09D133/26C07C41/03C07C233/20
    • C08G65/2609C08G65/00C08G65/22C08G65/2612
    • Process for preparing a macromonomer, in which a starting compound H2C═CR1—C6H4-s(R4)s—R3—OH or H2C═CR2—CO—NH—R3—OH, where R1 and R2 are each H or a linear or branched alkyl radical having from 1 to 4 carbon atoms, R3 is a linear or branched alkylene, aralkylene radical which has from 1 to 20 carbon atoms and can contain one or more hydroxy groups and the radicals R4 are each, independently of one another, a linear or branched alkyl, aralkyl, alkoxy or aralkoxy radical having from 1 to 20 carbon atoms and s=0-4, is, after partial deprotonation, reacted with at least one hydroxy-functional oxirane compound in the presence of an inhibitor of free-radical polymerization with opening of the oxirane ring, where the molar ratio of the molar amounts used n(starting compound):n(oxirane compound) is in the range from 1:100 to 1:1.Macromonomers which can be obtained by the process, polymers which can be obtained therefrom and their use as additives in coating compositions, plastics and cosmetics.
    • 制备大分子单体的方法,其中起始化合物H2C = CR1-C6H4-s(R4)s-R3-OH或H2C = CR2-CO-NH-R3-OH,其中R1和R2各自为H或直链或 具有1至4个碳原子的支链烷基,R3是具有1至20个碳原子并且可以含有一个或多个羟基的基团的直链或支链亚烷基,亚芳基,并且基团R 4各自彼此独立地为 具有1至20个碳原子且s = 0-4的直链或支链烷基,芳烷基,烷氧基或芳烷氧基是在部分去质子化后与至少一种羟基官能的环氧乙烷化合物在游离 - 使用n(起始化合物):n(环氧乙烷化合物)的摩尔量的摩尔比为1:100〜1:1的环氧乙烷环的开环自由基聚合。 可以通过该方法获得的大分子单体,可从其获得的聚合物及其作为涂料组合物,塑料和化妆品中的添加剂的用途。