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11. 发明授权

US5595575A Blue disperse dye mixture 失效
标题翻译：蓝色分散染料混合物
公开(公告)号：US5595575A
公开(公告)日：1997-01-21
申请号：US555171
申请日：1995-11-08
申请人： Kiyoshi Himeno , Toshio Hihara , Ryouichi Sekioka
发明人： Kiyoshi Himeno , Toshio Hihara , Ryouichi Sekioka
IPC分类号： C09B67/22 , D06P3/54
CPC分类号： C09B67/0051 , C09B67/0046 , Y10S8/922
摘要： A blue disperse dye mixture comprising a monoazo dye of the following formula (1) and at least one azo dye selected from the group consisting of dyes of the following formulas (2), (3), (4) and (5): ##STR1## wherein each of the variables is defined in the specification.
摘要翻译：包含下式（1）的单偶氮染料和至少一种选自下式（2），（3），（4）和（5）的染料的偶氮染料的蓝色分散染料混合物：GE （4）（5）其中每个变量在说明书中定义。

12. 发明授权

US5332404A Disperse dye mixtures 失效
标题翻译：分散染料混合物
公开(公告)号：US5332404A
公开(公告)日：1994-07-26
申请号：US988813
申请日：1992-12-10
申请人： Kiyoshi Himeno , Toshio Hihara , Hirotsugu Tsumura , Yoshiharu Hamano
发明人： Kiyoshi Himeno , Toshio Hihara , Hirotsugu Tsumura , Yoshiharu Hamano
IPC分类号： C09B67/22 , C09B67/38 , D06P1/18 , D06P3/54
CPC分类号： C09B67/0051 , C09B67/008 , D06P1/18 , Y10S8/922
摘要： A disperse dye mixture comprising a monoazo dye of the following formula (1) and a monoazo dye of the following formula (2) blended thereto in an amount of from 0.1 to 10 times by weight of the dye of the formula (1): ##STR1## wherein each of X.sup.1 and X.sup.2 which are independent of each other, is nitro, cyano, sulfomethyl or halogen, each of Y.sup.1, Y.sup.2, Z.sup.1 and Z.sup.2 which are independent of one another, is hydrogen, cyano, nitro, trifluoromethyl, halogen or sulfomethyl, each of W.sup.1 and W.sup.2 which are independent of each other, is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl or alkoxy, and each of R.sup.1 and R.sup.2 which are independent of each other, is C.sub.1 -C.sub.4 alkyl, or C.sub.2 -C.sub.4 alkyl which is substituted by cyano, halogen, hydroxy, hydroxyalkoxy, C.sub.1 -C.sub.4 alkyl, hydroxyalkoxyalkoxy, acyloxyalkoxy, acyloxyalkoxyalkoxy or alkoxyalkoxy.
摘要翻译：一种分散染料混合物，其包含下式（1）的单偶氮染料和下式（2）的单偶氮染料，其量为式（1）染料的0.1-10倍重量：（1）其中X1和X2各自独立的是硝基，氰基，磺基甲基或卤素，Y1，Y2，Z1和Z2各自独立地是氢，氰基，硝基，三氟甲基，卤素或磺基甲基各自独立地为氢，卤素，C 1 -C 2烷基或烷氧基，R 1和R 2各自独立地为 C 1 -C 4烷基或被氰基，卤素，羟基，羟基烷氧基，C 1 -C 4烷基，羟基烷氧基烷氧基，酰氧基烷氧基，酰氧基烷氧基烷氧基或烷氧基烷氧基取代的C 2 -C 4烷基。

13. 发明授权

US4841029A Diazo colors and dyeing method using the same 失效
标题翻译：重氮颜色和染色方法使用相同
公开(公告)号：US4841029A
公开(公告)日：1989-06-20
申请号：US186656
申请日：1988-04-19
申请人： Yoshiaki Kato , Toshio Hihara
发明人： Yoshiaki Kato , Toshio Hihara
IPC分类号： C09B62/513 , C07D251/70 , C09B62/44 , D06P1/38 , D06P3/82 , D06P3/84 , D06P3/85 , D06P3/872
CPC分类号： D06P1/38 , C09B62/4415
摘要： A disazo color having three triazine rings, one of which is substituted with a reactive group of --NR.sup.1 --A--SO.sub.2 C.sub.2 H.sub.4 OSO.sub.3 M, wherein R.sup.1 represents a hydrogen atom or a lower alkyl group; A represents a substituted or unsubstituted phenylene or naphthylene group; and M represents a hydrogen atom or an alkali metal. The disazo color is capable of dyeing cellulose-containing fibers under conditions conventionally employed for dyeing polyester fibers with a disperse dye, making it possible to dye mixed fibers of cellulose fiber and polyester fiber in a single-bath through one step.
摘要翻译：具有三个三嗪环的二重色，其中一个被-NR1-A-SO2C2H4OSO3M的反应性基团取代，其中R1表示氢原子或低级烷基; A表示取代或未取代的亚苯基或亚萘基; M表示氢原子或碱金属。双色调能够在通常用于用分散染料染色聚酯纤维的条件下染色含纤维素纤维，使得可以通过一步将单纤维素纤维和聚酯纤维的混合纤维染色。

14. 发明申请

US20070271710A1 Disperse Dyes for Poly(Lactic Acid) Based Fibers 审中-公开
标题翻译：分散染料用于聚（乳酸）基纤维
公开(公告)号：US20070271710A1
公开(公告)日：2007-11-29
申请号：US11630496
申请日：2005-06-17
申请人： Daisuke Hosoda , Koichi Fujisaki , Toshio Hihara
发明人： Daisuke Hosoda , Koichi Fujisaki , Toshio Hihara
IPC分类号： D06P3/54 , D06P3/82
CPC分类号： D06P3/8276 , D06P3/54
摘要： The present invention relates to the use of a yellow and/or a red and/or a blue component of disperse dyes for dyeing poly(lactic acid) fibers or poly(lactic acid) based fibers.
摘要翻译：本发明涉及分散染料的黄色和/或红色和/或蓝色成分用于染色聚（乳酸）纤维或聚（乳酸）基纤维的用途。

15. 发明授权

US5734028A Blue type disperse dye mixture 失效
标题翻译：蓝色分散染料混合物
公开(公告)号：US5734028A
公开(公告)日：1998-03-31
申请号：US732723
申请日：1996-10-18
申请人： Kiyoshi Himeno , Toshio Hihara , Ryouchi Sekioka
发明人： Kiyoshi Himeno , Toshio Hihara , Ryouchi Sekioka
IPC分类号： C09B67/22 , D06P1/18 , D06P1/20 , D06P3/54
CPC分类号： C09B67/0041 , D06P1/18 , D06P1/20 , Y10S534/01
摘要： A blue type disperse dye mixture comprising a monoazo dye of the formula (1) in an amount of 1.0 part by weight and at least one of anthraquinone dyes of the formulae (2) to (4) in a total amount of from 0.2 to 3.0 parts by weight: ##STR1##
摘要翻译：一种蓝色分散染料混合物，其包含1.0重量份的式（1）的单偶氮染料和至少一种式（2）至（4）的蒽醌染料，其总量为0.2-3.0 （1）（2）（3）（4）

16. 发明授权

US5368612A Method of dyeing a fiber mixture with water-insoluble naphthalic acid imide dyestuffs 失效
标题翻译：用水不溶性萘二甲酰亚胺染料染色纤维混合物的方法
公开(公告)号：US5368612A
公开(公告)日：1994-11-29
申请号：US100294
申请日：1993-08-02
申请人： Kiyoshi Himeno , Toshio Hihara
发明人： Kiyoshi Himeno , Toshio Hihara
IPC分类号： C09B62/02 , D06P1/382
CPC分类号： C09B62/021 , Y10S8/922 , Y10S8/924 , Y10S8/926
摘要： Water-insoluble naphthalic acid imide dyestuffs of the following formula: ##STR1## wherein D is ##STR2## wherein R.sup.1 is C.sub.1 -C.sub.8 alkyl which may be substituted, R.sup.2 is hydrogen, halogen, lower alkyl, lower alkoxy or cyano, X is oxygen or sulfur, and m is 0 or 1; A is phenylene, alkylene, aralkylene or --C.sub.2 H.sub.4 OC.sub.2 H.sub.4 --; B is oxygen, sulfur or ##STR3## wherein R.sup.3 is hydrogen or lower alkyl; Y is a 6-membered nitrogen-containing heterocyclic ring having at least one active halogen atom; and n is 0 or 1.
摘要翻译：下式的水不溶性萘二甲酰亚胺染料：其中D是其中R 1是可被取代的C 1 -C 8烷基，R 2是氢，卤素，低级烷基，低级烷氧基或氰基， X是氧或硫，m是0或1; A是亚苯基，亚烷基，亚芳基或-C 2 H 4 OC 2 H 4 - ; B是氧，硫或者其中R 3是氢或低级烷基; Y是具有至少一个活性卤素原子的6元含氮杂环; n为0或1。

17. 发明授权

US4707546A Reactive monoazo dyestuffs 失效
标题翻译：活性单偶氮染料
公开(公告)号：US4707546A
公开(公告)日：1987-11-17
申请号：US822680
申请日：1986-01-23
申请人： Toshio Niwa , Kiyoshi Himeno , Toshio Hihara
发明人： Toshio Niwa , Kiyoshi Himeno , Toshio Hihara
IPC分类号： C09B62/085 , C09B62/343 , D06P1/382 , D06P3/85
CPC分类号： C09B62/085
摘要： A reactive monoazo dyestuff of the general formula [I]: ##STR1## wherein R.sup.1 and R.sup.2 each represents substituted or unsubstituted alkyl, cyclohexyl, aralkyl or substituted or unsubstituted aryl, Z represents hydrogen, chlorine, methyl or acylamino, (A) represents substituted or unsubstituted alkylene, (B) represents oxygen or --NH--, X represents fluorine or chlorine, and Y represents --NR.sup.4 R.sup.5 or --OR.sup.6 wherein R.sup.4, R.sup.5 and R.sup.6 each represents hydrogen, substituted or unsubstituted alkyl, alkenyl, cyclohexyl, aryl or aralkyl, or --NR.sup.4 R.sup.5 represents a 5- or 6-membered nitrogen-containing heterocyclic ring formed by combining R.sup.4 and R.sup.5.
摘要翻译：通式[I]的反应性单偶氮染料：其中R 1和R 2各自表示取代或未取代的烷基，环己基，芳烷基或取代或未取代的芳基，Z表示氢，氯，甲基或酰氨基，（A ）表示取代或未取代的亚烷基，（B）表示氧或-NH-，X表示氟或氯，Y表示-NR4R5或-OR6，其中R4，R5和R6各自表示氢，取代或未取代的烷基，烯基，环己基，芳基或芳烷基，或-NR4R5表示通过组合R4和R5形成的5-或6-元含氮杂环。

18. 发明授权

US4623719A Disazo dyestuffs having a monofluorotriazinyl group 失效
标题翻译：具有单氟三嗪基的双偶氮染料
公开(公告)号：US4623719A
公开(公告)日：1986-11-18
申请号：US843927
申请日：1986-03-24
申请人： Toshio Niwa , Kiyoshi Himeno , Toshio Hihara
发明人： Toshio Niwa , Kiyoshi Himeno , Toshio Hihara
IPC分类号： C09B31/14 , C09B62/09 , D06P1/382 , C07C107/06
CPC分类号： D06P1/382 , C09B62/09
摘要： This invention relates to disazo dyestuffs for cellulose or cellulose-containing fibers represented by the formula: ##STR1## wherein R.sup.1 represents a hydrogen atom, a nitro group, a halogen atom, an alkyl group of 1 or 2 carbon atoms or an acetylamino group; R.sup.2 and R.sup.3 each represents a hydrogen atom, an alkyl group of 1 or 2 carbon atoms, and alkoxy group or an acetylamino group; Y.sup.1 and Y.sup.2 each represents a hydrogen atom or an alkyl group, and alkenyl group, a cyclohexyl group, an aryl group or an aralkyl group which group ma optionally be substituted by cyano, hydroxyl, lower alkoxy or dialkylamino, or NY.sup.1 Y.sup.2 represents a 5-membered or 6-membered nitrogen-containing heretocyclic ring formed by combination of Y.sup.1 and Y.sup.2, and the total carbon atoms in Y.sup.1 and Y.sup.2 is 18 or less.
摘要翻译：本发明涉及由下式表示的纤维素或含纤维素纤维的双偶氮染料：其中R1表示氢原子，硝基，卤素原子，1或2个碳原子的烷基或乙酰氨基; R2和R3各自表示氢原子，1或2个碳原子的烷基和烷氧基或乙酰氨基; Y1和Y2各自表示氢原子或烷基，以及基团任选被氰基，羟基，低级烷氧基或二烷基氨基取代的烯基，环己基，芳基或芳烷基，或者NY1Y2表示5- 通过Y1和Y2的组合形成的6-元或6元含氮杂环，Y1和Y2中的总碳原子数为18以下。

19. 发明授权

US4515716A 2,6-Diaminopyridine-based azo dyes for cellulose-containing fibers 失效
标题翻译：用于含纤维素纤维的2,6-二氨基吡啶类偶氮染料
公开(公告)号：US4515716A
公开(公告)日：1985-05-07
申请号：US414733
申请日：1982-09-03
申请人： Toshio Niwa , Toshio Hihara
发明人： Toshio Niwa , Toshio Hihara
IPC分类号： C09B62/08 , D06P1/382 , D06P3/60 , C09B62/06 , C09B62/085 , C09B62/09
CPC分类号： C09B62/08 , D06P1/382 , D06P3/6041
摘要： Diaminopyridine-based azo dyes for cellulose-containing fibers, represented by the following formula: ##STR1## and the other is hydrogen, phenyl, benzyl, allyl, or alkyl which are unsubstituted or substituted by hydroxyl or lower alkoxy(whereinA is methylene, ethylene, propylene, or 1,3-butylene;n is 0 or 1;Y.sup.1 and Y.sup.2, which are the same or different, are hydrogen, alkyl, alkenyl, cyclohexyl, aryl, or aralkyl which are unsubstituted or substituted by cyano, hydroxy, lower alkoxy, or dialkylamino, or Y.sup.1 and Y.sup.2 together form a 5- or 6-membered heterocyclic ring (NY.sup.1 Y.sup.2) containing one nitrogen, the total number of carbon atoms of Y.sup.1 and Y.sup.2 being 18 or less;R.sup.1 is nitro, cyano, methylsulfonyl, phenylsulfonyl, mono-lower alkylaminosulfonyl, di-lower alkylaminosulfonyl, acetyl, or benzoyl;R.sup.2 and R.sup.3, which are the same or different, are hydrogen, trifluoromethyl, halogen, or cyano;R.sup.4 is hydrogen, lower alkyl, mono- or di-lower alkylaminosulfonyl, mono/or di-lower alkylcarbamoyl, or acetylamino;R.sup.5 and R.sup.6, which are the same or different, are hydrogen, halogen, or lower alkyl;R.sup.7 is lower alkyl;R.sup.8 is trifluoromethyl, or halogen; andR.sup.9 is hydrogen, or halogen).The dyes are useful for dyeing cellulose-containing fibers, particularly cellulose fibers and mixed fibers of polyester fibers and cellulose fibers in from orange to blue.
摘要翻译：用于含纤维素的纤维的二氨基吡啶类偶氮染料，由下式表示：另一种是氢，苯基，苄基，烯丙基或未被羟基或低级烷氧基取代的烷基（其中A为亚甲基，亚乙基，亚丙基或1,3-亚丁基; n为0或1; Y1和Y2相同或不同，为氢，未取代或被氰基，羟基，低级烷氧基或二烷基氨基取代的烷基，链烯基，环己基，芳基或芳烷基，或Y1和Y2一起形成含有一个氮的5-或6-元杂环（NY1Y2） Y1和Y2的碳原子数为18以下; R1为硝基，氰基，甲基磺酰基，苯基磺酰基，单低级烷基氨基磺酰基，二低级烷基氨基磺酰基，乙酰基或苯甲酰基; R2和R3相同或不同，是氢，三氟甲基，卤素或氰基; R 4是氢，低级烷基，一或二低级烷基氨基磺酰基，一或二低级烷基氨基甲酰基或乙酰氨基; R 5和R 6相同或不同，为氢，卤素或低级烷基; R7是低级烷基; R8是三氟甲基或卤素; 和R9是氢或卤素）。染料可用于将含纤维素的纤维，特别是纤维素纤维和聚酯纤维和纤维素纤维的混合纤维从橙色到蓝色染色。

20. 发明授权

US5608042A Benzothiazolemonoazo dyes 失效
标题翻译：苯并噻唑单偶氮染料
公开(公告)号：US5608042A
公开(公告)日：1997-03-04
申请号：US594487
申请日：1996-01-31
申请人： Kiyoshi Himeno , Toshio Hihara , Ryouichi Sekioka
发明人： Kiyoshi Himeno , Toshio Hihara , Ryouichi Sekioka
IPC分类号： C09B29/00 , C09B29/08 , D06P3/54 , C09B29/045 , C09B29/09
CPC分类号： C09B29/0813 , C09B29/0088 , D06P3/54 , Y10S8/922
摘要： A monoazo dye of the following formula (I): ##STR1## wherein R is phenyl, phenoxy or benzyl, and D is a group of the formula (D1), (D2), (D3) or (D4): ##STR2## wherein each of X.sup.1, X.sup.2 and X.sup.3, which are independent of one another, is hydrogen or chlorine, X.sup.4 is hydrogen, chlorine, methyl or --NHCOR.sup.1, wherein R.sup.1 is C.sub.1-4 alkyl or phenyl; ##STR3## wherein X.sup.4 is as defined above, Y.sup.1 is hydrogen, chlorine or C.sub.1-4 alkoxy; ##STR4## wherein X.sup.5 is hydrogen, halogen, methyl or --NHZ, wherein Z is C.sub.1-4 alkylsurfonyl, C.sub.1-4 alkylcarbonyl, phenylsulfonyl, phenylcarbonyl, C.sub.1-2 alkoxy C.sub.1-2 alkylcarbonyl or aminocarbonyl, Y.sup.2 is hydrogen, methyl or C.sub.1-2 alkoxy, and Q.sup.1 is cyano or C.sub.1-4 alkylcarbonyl; ##STR5## wherein P is formyl, nitro or cyano, Q.sup.2 is cyano or nitro, T is halogen, methyl, phenyl or methylsulfonyl, X.sup.5 is as defined above, and Y.sup.3 is hydrogen or C.sub.1-2 alkoxy.
摘要翻译：下式（I）的单偶氮染料：其中R是苯基，苯氧基或苄基，D是式（D1），（D2），（D3）或（D4）的基团：（D1）其中X 1，X 2和X 3彼此独立地为氢或氯，X 4为氢，氯，甲基或-NHCOR 1，其中R 1为C 1-4烷基或苯基; （D2）其中X4如上所定义，Y 1是氢，氯或C 1-4烷氧基; （D3）其中X5是氢，卤素，甲基或-NHZ，其中Z是C1-4烷基磺酰基，C1-4烷基羰基，苯基磺酰基，苯基羰基，C1-2烷氧基C1-2烷基羰基或氨基羰基，Y2是氢，甲基或C 1-2烷氧基，Q 1为氰基或C 1-4烷基羰基; （D4）其中P是甲酰基，硝基或氰基，Q2是氰基或硝基，T是卤素，甲基，苯基或甲基磺酰基，X5如上所定义，Y 3是氢或C 1-2烷氧基。

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