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    • 12. 发明授权
    • Process for preparing polyolefins
    • 聚烯烃的制备方法
    • US4410670A
    • 1983-10-18
    • US45961
    • 1979-06-06
    • Yoshio TajimaKazuo MatsuuraNobuyuki KurodaMituji Miyoshi
    • Yoshio TajimaKazuo MatsuuraNobuyuki KurodaMituji Miyoshi
    • C08F10/00C08F4/66
    • C08F10/00
    • This invention provides a process for preparing polyolefins using a new catalyst. According to this invention, .alpha.-olefins can be polymerized or copolymerized to have good stereoregularity and at a high activity by the use of such new catalyst. The new catalyst used in this invention consists of [A] a solid component obtained by contacting (1) a magnesium oxide, (2) an aluminum trihalide, (3) a hydroxy compound represented by the general formula ROH wherein R is an organic radical having 1 to 20 carbon atoms and (4) a titanium halide and/or an addition product of a titanium halide and an aromatic carboxylic acid ester, and [B] an organometallic compound and/or an addition product of an organometallic compound and an aromatic carboxylic acid ester; or it consists of the solid component of the above [A], the organometallic compound and/or the addition product of an organometallic compound and an aromatic carboxylic acid ester of the above [B], and [C] an aromatic carboxylic acid ester. The said catalyst is prepared, in one of the most preferred embodiments thereof, by using the solid component of the above [A] which is obtained by first co-pulverizing the compounds of the above (1),(2) and (3), then washing the co-pulverized product with an aromatic compound, separating the liquid phase to give a solid substance (a) and contacting the latter with the compound and/or the addition product of the above (4).
    • 本发明提供使用新催化剂制备聚烯烃的方法。 根据本发明,通过使用这种新的催化剂,α-烯烃可以聚合或共聚以具有良好的立构规整性和高活性。 本发明中使用的新型催化剂由[A]一种固体组分组成,该固体组分通过使(1)氧化镁,(2)三卤化铝,(3)由通式ROH表示的羟基化合物,其中R是有机基团 具有1至20个碳原子和(4)卤化钛和/或卤化钛和芳族羧酸酯的加成产物,和[B]有机金属化合物和/或有机金属化合物和芳族化合物的加成产物 羧酸酯; 或者由上述[A]的固体组分,有机金属化合物和/或上述[B]的有机金属化合物和芳族羧酸酯的加成产物和[C]芳族羧酸酯组成。 所述催化剂在其最优选的实施方案之一中,通过使用上述[A]的固体成分,其是通过首先共混上述(1),(2)和(3)的化合物而获得的, ,然后用芳族化合物洗涤共粉碎产物,分离液相,得到固体物质(a),并使其与上述(4)的化合物和/或加成产物接触。
    • 16. 发明授权
    • Process for preparing polyolefins
    • 聚烯烃的制备方法
    • US4088812A
    • 1978-05-09
    • US752003
    • 1976-12-20
    • Kazuo MatuuraMasaomi MatsuzakiHumiaki OshimiNobuyuki KurodaMituji Miyoshi
    • Kazuo MatuuraMasaomi MatsuzakiHumiaki OshimiNobuyuki KurodaMituji Miyoshi
    • C08F4/02C08F4/62C08F10/00C08F10/02
    • C08F10/00
    • This invention discloses an improved catalyst for the polymerization or copolymerization of olefins, and a process for preparing polyolefins which comprises polymerizing or copolymerizing olefins using the said catalyst. According to the invention there is provided a process for preparing polyolefins by polymerizing or copolymerizing olefins using as a catalyst at least one compound selected from the group consisting of a titanium compound and a vanadium compound supported on a solid carrier, and an organometallic compound, said solid carrier comprising a product obtained by treatment with SO.sub.3 of at least one member selected from the group consisting of an oxide of Group II-IV metals of the Periodic Table and a double oxide of the said oxide and other oxide, which other oxide may be another oxide of Group II-IV metals of the Periodic Table or may be an oxide of other Group metals of the same Table.
    • 本发明公开了一种用于烯烃聚合或共聚的改进催化剂,以及一种制备聚烯烃的方法,该方法包括使用所述催化剂聚合或共聚烯烃。 根据本发明,提供了一种通过使用至少一种选自负载在固体载体上的钛化合物和钒化合物和有机金属化合物的化合物作为催化剂聚合或共聚烯烃的方法,所述方法 固体载体,其包含通过用SO 3处理由选自元素周期表中的II-IV族金属的氧化物和所述氧化物和其它氧化物的二氧化物中的至少一种获得的产物,其它氧化物可以是 元素周期表第II-Ⅳ族金属的另一种氧化物,或者可以是同一表中其他族金属的氧化物。