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11. 发明申请

US20110288240A1 NOVEL PHOSPHAZENE-SUPPORTED CATALYST, NOVEL COMPOUND THEREOF AND USE THEREOF 审中-公开
标题翻译：新型磷酸盐载体催化剂，其新颖化合物及其用途
公开(公告)号：US20110288240A1
公开(公告)日：2011-11-24
申请号：US13198397
申请日：2011-08-04
申请人： Naritoshi YOSHIMURA , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
发明人： Naritoshi YOSHIMURA , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
IPC分类号： C08F8/40 , C07C45/45 , C07C41/16 , C07C41/02 , C07F9/06 , C07F9/22
CPC分类号： C08G63/823 , B01J31/0265 , B01J2231/12 , C07F9/065 , C07F9/224
摘要： A phosphazene-supported catalyst in which a support is bonded to a group represented by the general formula (1): wherein n, Zn−, a, b, c, d, R, R1 and D are all defined. The phosphazene-supported catalyst is highly effective to catalyze various organic reactions, and further has no reduction of activity even after recovery and reuse of the catalyst, thus it being economically advantageous. In addition, the polymerization of cyclic monomers, substitution of substituents, carbon-carbon bond forming reactions and the like can be conducted with extremely high efficiency.
摘要翻译：载体与由通式（1）表示的基团键合的磷腈担载催化剂：其中n，Zn-，a，b，c，d，R，R1和D全部定义。磷腈担载的催化剂对于催化各种有机反应是非常有效的，即使在回收和再利用催化剂之后也不会降低活性，因此在经济上是有利的。此外，可以极高效率进行环状单体的聚合，取代基的取代，碳 - 碳键形成反应等。

12. 发明申请

US20080318767A1 Novel Phosphazene-Supported Catalyst, Novel Compound Thereof and Use Thereof 审中-公开
标题翻译：新型磷腈载体催化剂，新型化合物及其用途
公开(公告)号：US20080318767A1
公开(公告)日：2008-12-25
申请号：US11631286
申请日：2005-06-28
申请人： Naritoshi Yoshimura , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
发明人： Naritoshi Yoshimura , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
IPC分类号： C07F9/06 , B01J31/02
CPC分类号： C08G63/823 , B01J31/0265 , B01J2231/12 , C07F9/065 , C07F9/224
摘要： A phosphazene-supported catalyst in which a support is bonded to a group represented by the general formula (1): wherein n, Zn−, a, b, c, d, R, R1 and D are all defined. The phosphazene-supported catalyst is highly effective to catalyze various organic reactions, and further has no reduction of activity even after recovery and reuse of the catalyst, thus it being economically advantageous. In addition, the polymerization of cyclic monomers, substitution of substituents, carbon-carbon bond forming reactions and the like can be conducted with extremely high efficiency.
摘要翻译：载体与由通式（1）表示的基团键合的磷腈担载催化剂：其中n，Zn-，a，b，c，d，R，R1和D全部定义。磷腈担载的催化剂对于催化各种有机反应是非常有效的，即使在回收和再利用催化剂之后也不会降低活性，因此在经济上是有利的。此外，可以极高效率进行环状单体的聚合，取代基的取代，碳 - 碳键形成反应等。

13. 发明授权

US6077930A Preparation process of polymer 失效
标题翻译：聚合物的制备工艺
公开(公告)号：US6077930A
公开(公告)日：2000-06-20
申请号：US79230
申请日：1998-05-15
申请人： Tadahito Nobori , Shinji Kiyono , Takaomi Hayashi , Usaji Takaki
发明人： Tadahito Nobori , Shinji Kiyono , Takaomi Hayashi , Usaji Takaki
IPC分类号： C08G63/82 , C08G65/26 , C08G69/20 , C08G77/08 , C08G63/08
CPC分类号： C08G69/20 , C08G63/823 , C08G65/2675 , C08G77/08
摘要： A preparation process of a polymer comprising conducting ring-opening polymerization of a 4- to 10-membered ring-opening polymerizable cyclic monomer in the presence of a phosphazenium salt of an active hydrogen compound represented by the chemical formula (1): ##STR1## wherein n is an integer of 1 to 8 and indicates the number of phosphazenium cations, Z.sup.n- is an anion of a n-valent active hydrogen compound derived by releasing n protons from an active hydrogen compound having a maximum of 8 active hydrogen atoms, a, b, c and d are individually a positive integer or 0 and are not all 0 at the same time, R's are the same or different hydrocarbons having 1 to 10 carbon atoms, and two R's located on each common nitrogen atom may be coupled together to form a ring structure; or in the presence of the phosphazenium salt of the active hydrogen compound and the active hydrogen compound is disclosed. The process can prepare polymer by ring-opening polymerization of a 4- to 10-membered ring-opening polymerizable cyclic monomer in the presence of an initiator which causes no specific problem or preparation and handling, contains quite no installic ingredient and has no residual odor.
摘要翻译：一种聚合物的制备方法，包括在由化学式（1）表示的活性氢化合物的磷氮烯基鏻盐的存在下进行4-至10-元可开环聚合的环状单体的开环聚合：其中n为 1〜8的整数，表示磷氮烯基鏻阳离子的数量，Zn-是通过从具有最多8个活性氢原子的活性氢化合物释放n个质子得到的n价活性氢化合物的阴离子，a，b， c和d分别为正整数或0并且同时不全部为0，R为相同或不同的碳原子数为1〜10的烃，并且位于每个常见氮原子上的两个R可以连接在一起形成环结构; 或在活性氢化合物的磷腈鎓盐和活性氢化合物的存在下进行。该方法可以通过在不引起特定问题或制备和处理的引发剂的存在下开环聚合4-至10-元可开环聚合的环状单体来制备聚合物，其中不含安装成分并且没有残留气味。

14. 发明授权

US06664365B2 Process for producing poly(alkylene oxide) in the presence of a phosphazenium salt or compound 有权
标题翻译：在磷氮烯基鏻盐或化合物存在下制备聚（环氧烷）的方法
公开(公告)号：US06664365B2
公开(公告)日：2003-12-16
申请号：US09366046
申请日：1999-09-03
申请人： Tadahito Nobori , Masahiro Kouno , Toshiaki Suzuki , Kazumi Mizutani , Shinji Kiyono , Yoshiho Sonobe , Usaji Takaki
发明人： Tadahito Nobori , Masahiro Kouno , Toshiaki Suzuki , Kazumi Mizutani , Shinji Kiyono , Yoshiho Sonobe , Usaji Takaki
IPC分类号： C08G6510
CPC分类号： C07F9/065 , C07F9/067 , C08G65/2675
摘要： The present invention provides a novel salt useful as an active species in an organic reaction and represented by the following chemical formula (1): wherein n stands for an integer of from 1 to 8, Zn− represents an n-valent anion of an active hydrogen compound, a, b, c and d each stands for a positive integer, and Rs represent the same or different hydrocarbon groups. Also disclosed is a simple and efficient process for producing a poly(alkylene oxide) by polymerizing an alkylene oxide compound in the presence of the salt represented by the chemical formula (1).
摘要翻译：本发明提供了可用作有机反应中的活性物质的新型盐，其由以下化学式（1）表示：其中n表示1至8的整数，Z n表示n价阴离子的活性氢化合物，a，b，c和d分别表示正整数，Rs表示相同或不同的烃基。还公开了通过在化学式（1）表示的盐的存在下聚合烯化氧化合物来制备聚（环氧烷）的简单和有效的方法。

15. 发明授权

US06936684B2 Poly (alkylene oxide) prepared in the presence of a phosphazenium salt or compound 失效
标题翻译：在磷氮烯基鏻盐或化合物存在下制备的聚（环氧烷）
公开(公告)号：US06936684B2
公开(公告)日：2005-08-30
申请号：US10458689
申请日：2003-06-11
申请人： Tadahito Nobori , Masahiro Kouno , Toshiaki Suzuki , Kazumi Mizutani , Shinji Kiyono , Yoshiho Sonobe , Usaji Takaki
发明人： Tadahito Nobori , Masahiro Kouno , Toshiaki Suzuki , Kazumi Mizutani , Shinji Kiyono , Yoshiho Sonobe , Usaji Takaki
IPC分类号： C07F9/06 , C08G65/26 , C08G65/28 , C08G65/04 , C08K5/5399
CPC分类号： C07F9/065 , C07F9/067 , C08G65/2675
摘要： A salt useful as an active species in an organic reaction and represented by the following chemical formula (1): wherein n stands for an integer of from 1 to 8, Zn− represents an n-valent anion of an active hydrogen compound, a, b, c and d each stands for a positive integer, and Rs represent the same or different hydrocarbon groups. In addition, a simple and efficient process is provided for producing a poly(alkylene oxide) by polymerizing an alkylene oxide compound in the presence of the salt represented by the chemical formula (1).
摘要翻译：用作有机反应中的活性物质并由下列化学式（1）表示的盐：其中n表示1至8的整数，Z 表示n价阴离子的活性氢化合物，a，b，c和d分别表示正整数，Rs表示相同或不同的烃基。此外，通过在化学式（1）表示的盐的存在下聚合烯化氧化合物，提供简单有效的方法来制备聚（环氧烷）。

16. 发明授权

US5990352A Phosphazenium salt and preparation process thereof, and process for producing poly(alkylene oxide) 失效
标题翻译：磷腈鎓盐及其制备方法，以及制备聚（环氧烷）
公开(公告)号：US5990352A
公开(公告)日：1999-11-23
申请号：US796893
申请日：1997-02-05
申请人： Tadahito Nobori , Masahiro Kouno , Toshiaki Suzuki , Kazumi Mizutani , Shinji Kiyono , Yoshiho Sonobe , Usaji Takaki
发明人： Tadahito Nobori , Masahiro Kouno , Toshiaki Suzuki , Kazumi Mizutani , Shinji Kiyono , Yoshiho Sonobe , Usaji Takaki
IPC分类号： C07F9/06 , C08G65/26 , C08G65/28 , C07F9/02 , C07D207/46 , C07D211/92 , C07D223/04
CPC分类号： C07F9/065 , C07F9/067 , C08G65/2675
摘要： A salt useful as an active species in an organic reaction and represented by the following chemical formula (1): ##STR1## wherein n stands for an integer of from 1 to 8, Z.sup.n- represents an n-valent anion of an active hydrogen compound, a, b, c and d each stands for a positive integer, and Rs represent the same or different hydrocarbon groups. In addition, a simple and efficient process is provided for producing a poly(alkylene oxide) by polymerizing an alkylene oxide compound in the presence of the salt represented by the chemical formula (1).
摘要翻译：用作有机反应中的活性物质并由以下化学式（1）表示的盐：其中n表示1至8的整数，Zn表示活性氢化合物的n价阴离子， b，c和d分别表示正整数，Rs表示相同或不同的烃基。此外，通过在化学式（1）表示的盐的存在下聚合烯化氧化合物，提供简单有效的方法来制备聚（环氧烷）。

17. 发明授权

US4831158A Preparation process indoles 失效
标题翻译：制备过程吲哚
公开(公告)号：US4831158A
公开(公告)日：1989-05-16
申请号：US117904
申请日：1987-11-02
申请人： Tomoyuki Ueno , Tadatoshi Honda , Takashi Jimbo , Makoto Kotani , Kazuhiro Terada , Shinji Kiyono
发明人： Tomoyuki Ueno , Tadatoshi Honda , Takashi Jimbo , Makoto Kotani , Kazuhiro Terada , Shinji Kiyono
IPC分类号： C07D209/04 , B01J23/90 , C07D209/08
CPC分类号： C07D209/08 , B01J23/90 , Y02P20/584
摘要： In a process for preparing an indole by reacting an aniline with a diol, a catalyst the activity of which has been reduced through its use in the reaction is brought into contact with an inert gas containing 5 vol. % or less of oxygen so that the catalyst is regenerated for its repeated utilization. The activity of the regenerated catalyst is enhanced further when it is subjected to a reducing treatment for activation upon its reutilization.
摘要翻译：在通过使苯胺与二醇反应制备吲哚的方法中，其活性通过其在反应中的使用而降低的催化剂与含有5体积％的惰性气体接触。氧气的百分比以下，使得催化剂被再生以便重复使用。再生催化剂的活性在其再利用时进行还原处理以进行活化时进一步增强。

18. 发明申请

US20130197270A1 METHOD FOR PRODUCING TRANS-1,4-BIS(AMINOMETHYL) CYCLOHEXANE 有权
标题翻译：生产反式-1,4-双（氨基甲基）环己酮的方法
公开(公告)号：US20130197270A1
公开(公告)日：2013-08-01
申请号：US13878090
申请日：2011-10-05
申请人： Naritoshi Yoshimura , Shinji Kiyono , Tetsuya Hamada , Eiji Watanabe , Saiko Sawada
发明人： Naritoshi Yoshimura , Shinji Kiyono , Tetsuya Hamada , Eiji Watanabe , Saiko Sawada
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , B01J23/44 , B01J25/00 , B01J25/02 , C07B2200/09 , C07C253/22 , C07C253/34 , C07C2601/14 , C07C255/46 , C07C211/18
摘要： A method for producing trans-1,4-bis(aminomethyl)cyclohexane includes a nuclear hydrogenation step of producing a hydrogenated terephthalic acid or terephthalic acid derivative by nuclear hydrogenation of a terephthalic acid or terephthalic acid derivative, the terephthalic acid or terephthalic acid derivative being at least one selected from the group consisting of terephthalic acid, terephthalic acid ester, and terephthalic acid amide; a cyanation step of treating the hydrogenated terephthalic acid or terephthalic acid derivative with ammonia, thereby producing 1,4-dicyanocyclohexane, and producing trans-1,4-dicyanocyclohexane from the obtained 1,4-dicyanocyclohexane; and an aminomethylation step of treating the trans-1,4-dicyanocyclohexane with hydrogen, thereby producing trans-1,4-bis(aminomethyl)cyclohexane.Metal oxide is used as a catalyst in the cyanation step, and the obtained trans-1,4-dicyanocyclohexane has a metal content of 3000 ppm or less.
摘要翻译：反式-1,4-双（氨基甲基）环己烷的制造方法包括通过对苯二甲酸或对苯二甲酸衍生物的核氢化制造氢化对苯二甲酸或对苯二甲酸衍生物的核氢化工序，对苯二甲酸或对苯二甲酸衍生物为选自对苯二甲酸，对苯二甲酸酯和对苯二甲酸酰胺中的至少一种; 用氨处理氢化对苯二甲酸或对苯二甲酸衍生物的氰化步骤，从而得到1,4-二氰基环己烷，由所得的1,4-二氰基环己烷生产反式-1,4-二氰基环己烷; 和用氢处理反式-1,4-二氰基环己烷的氨基甲基化步骤，从而产生反式-1,4-双（氨基甲基）环己烷。在氰化步骤中使用金属氧化物作为催化剂，得到的反式-1,4-二氰基环己烷的金属含量为3000ppm以下。

19. 发明授权

US08865939B2 Method for producing trans-1,4-bis(aminomethyl) cyclohexane 有权
标题翻译：反式-1,4-双（氨基甲基）环己烷的制备方法
公开(公告)号：US08865939B2
公开(公告)日：2014-10-21
申请号：US13878090
申请日：2011-10-05
申请人： Naritoshi Yoshimura , Shinji Kiyono , Tetsuya Hamada , Eiji Watanabe , Saiko Sawada
发明人： Naritoshi Yoshimura , Shinji Kiyono , Tetsuya Hamada , Eiji Watanabe , Saiko Sawada
IPC分类号： C07C209/00 , C07C253/34 , C07C209/48 , C07C253/22 , B01J23/44 , B01J25/00 , B01J25/02
CPC分类号： C07C209/48 , B01J23/44 , B01J25/00 , B01J25/02 , C07B2200/09 , C07C253/22 , C07C253/34 , C07C2601/14 , C07C255/46 , C07C211/18
摘要： A method for producing trans-1,4-bis(aminomethyl)cyclohexane includes a nuclear hydrogenation step of producing a hydrogenated terephthalic acid or terephthalic acid derivative by nuclear hydrogenation of a terephthalic acid or terephthalic acid derivative, the terephthalic acid or terephthalic acid derivative being at least one selected from the group consisting of terephthalic acid, terephthalic acid ester, and terephthalic acid amide; a cyanation step of treating the hydrogenated terephthalic acid or terephthalic acid derivative with ammonia, thereby producing 1,4-dicyanocyclohexane, and producing trans-1,4-dicyanocyclohexane from the obtained 1,4-dicyanocyclohexane; and an aminomethylation step of treating the trans-1,4-dicyanocyclohexane with hydrogen, thereby producing trans-1,4-bis(aminomethyl)cyclohexane. Metal oxide is used as a catalyst in the cyanation step, and the obtained trans-1,4-dicyanocyclohexane has a metal content of 3000 ppm or less.
摘要翻译：反式-1,4-双（氨基甲基）环己烷的制造方法包括通过对苯二甲酸或对苯二甲酸衍生物的核氢化制造氢化对苯二甲酸或对苯二甲酸衍生物的核氢化工序，对苯二甲酸或对苯二甲酸衍生物为选自对苯二甲酸，对苯二甲酸酯和对苯二甲酸酰胺中的至少一种; 用氨处理氢化对苯二甲酸或对苯二甲酸衍生物的氰化步骤，从而得到1,4-二氰基环己烷，由所得1,4-二氰基环己烷生产反式-1,4-二氰基环己烷; 和用氢处理反式-1,4-二氰基环己烷的氨基甲基化步骤，从而产生反式-1,4-双（氨基甲基）环己烷。在氰化步骤中使用金属氧化物作为催化剂，得到的反式-1,4-二氰基环己烷的金属含量为3000ppm以下。

20. 发明申请

US20130197269A1 METHOD FOR PRODUCING BIS(AMINOMETHYL)CYCLOHEXANES 有权
标题翻译：生产双（氨基甲基）环己烷的方法
公开(公告)号：US20130197269A1
公开(公告)日：2013-08-01
申请号：US13877595
申请日：2011-10-05
申请人： Naritoshi Yoshimura , Shinji Kiyono , Tetsuya Hamada , Eiji Watanabe , Saiko Sawada
发明人： Naritoshi Yoshimura , Shinji Kiyono , Tetsuya Hamada , Eiji Watanabe , Saiko Sawada
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , C07C253/22 , C07C2601/14 , C07C255/46 , C07C211/18
摘要： A method for producing bis(aminomethyl)cyclohexanes includes a nuclear hydrogenation step of producing hydrogenated phthalic acids or phthalic acid derivatives by nuclear hydrogenation of phthalic acids or phthalic acid derivatives of at least one selected from the group consisting of phthalic acids, phthalic acid esters, and phthalic acid amides; a cyanation step of treating the hydrogenated phthalic acids or phthalic acid derivatives obtained in the nuclear hydrogenation step with ammonia, thereby producing dicyanocyclohexanes; and an aminomethylation step of treating the dicyanocyclohexanes obtained in the cyanation step with hydrogen, thereby producing bis(aminomethyl)cyclohexanes. In the cyanation step, metal oxide is used as a catalyst, and the obtained dicyanocyclohexanes have a metal content of 3000 ppm or less.
摘要翻译：制备双（氨基甲基）环己烷的方法包括核氢化步骤，其通过邻苯二甲酸或邻苯二甲酸衍生物的核氢化制备氢化邻苯二甲酸或邻苯二甲酸衍生物，所述邻苯二甲酸或邻苯二甲酸衍生物选自邻苯二甲酸，邻苯二甲酸酯，和邻苯二甲酸酰胺; 氰化步骤，用氨处理在核氢化步骤中得到的氢化邻苯二甲酸或邻苯二甲酸衍生物，从而产生二氰基环己烷; 和在氰化步骤中用氢处理二氰基环己烷的氨基甲基化步骤，从而产生双（氨基甲基）环己烷。在氰化步骤中，使用金属氧化物作为催化剂，所得到的二氰基环己烷的金属含量为3000ppm以下。

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