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11. 发明申请

US20080318767A1 Novel Phosphazene-Supported Catalyst, Novel Compound Thereof and Use Thereof 审中-公开
标题翻译：新型磷腈载体催化剂，新型化合物及其用途
公开(公告)号：US20080318767A1
公开(公告)日：2008-12-25
申请号：US11631286
申请日：2005-06-28
申请人： Naritoshi Yoshimura , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
发明人： Naritoshi Yoshimura , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
IPC分类号： C07F9/06 , B01J31/02
CPC分类号： C08G63/823 , B01J31/0265 , B01J2231/12 , C07F9/065 , C07F9/224
摘要： A phosphazene-supported catalyst in which a support is bonded to a group represented by the general formula (1): wherein n, Zn−, a, b, c, d, R, R1 and D are all defined. The phosphazene-supported catalyst is highly effective to catalyze various organic reactions, and further has no reduction of activity even after recovery and reuse of the catalyst, thus it being economically advantageous. In addition, the polymerization of cyclic monomers, substitution of substituents, carbon-carbon bond forming reactions and the like can be conducted with extremely high efficiency.
摘要翻译：载体与由通式（1）表示的基团键合的磷腈担载催化剂：其中n，Zn-，a，b，c，d，R，R1和D全部定义。磷腈担载的催化剂对于催化各种有机反应是非常有效的，即使在回收和再利用催化剂之后也不会降低活性，因此在经济上是有利的。此外，可以极高效率进行环状单体的聚合，取代基的取代，碳 - 碳键形成反应等。

12. 发明申请

US20110288240A1 NOVEL PHOSPHAZENE-SUPPORTED CATALYST, NOVEL COMPOUND THEREOF AND USE THEREOF 审中-公开
标题翻译：新型磷酸盐载体催化剂，其新颖化合物及其用途
公开(公告)号：US20110288240A1
公开(公告)日：2011-11-24
申请号：US13198397
申请日：2011-08-04
申请人： Naritoshi YOSHIMURA , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
发明人： Naritoshi YOSHIMURA , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
IPC分类号： C08F8/40 , C07C45/45 , C07C41/16 , C07C41/02 , C07F9/06 , C07F9/22
CPC分类号： C08G63/823 , B01J31/0265 , B01J2231/12 , C07F9/065 , C07F9/224
摘要： A phosphazene-supported catalyst in which a support is bonded to a group represented by the general formula (1): wherein n, Zn−, a, b, c, d, R, R1 and D are all defined. The phosphazene-supported catalyst is highly effective to catalyze various organic reactions, and further has no reduction of activity even after recovery and reuse of the catalyst, thus it being economically advantageous. In addition, the polymerization of cyclic monomers, substitution of substituents, carbon-carbon bond forming reactions and the like can be conducted with extremely high efficiency.
摘要翻译：载体与由通式（1）表示的基团键合的磷腈担载催化剂：其中n，Zn-，a，b，c，d，R，R1和D全部定义。磷腈担载的催化剂对于催化各种有机反应是非常有效的，即使在回收和再利用催化剂之后也不会降低活性，因此在经济上是有利的。此外，可以极高效率进行环状单体的聚合，取代基的取代，碳 - 碳键形成反应等。

13. 发明申请

US20050085597A1 Polyether ketone and method for production thereof 失效
标题翻译：聚醚酮及其制备方法
公开(公告)号：US20050085597A1
公开(公告)日：2005-04-21
申请号：US10498096
申请日：2002-12-10
申请人： Masahiro Toriida , Takashi Kuroki , Takaharu Abe , Akira Hasegawa , Kuniyuki Takamatsu , Yoshiteru Taniguchi , Isao Hara , Setsuko Fujiyoshi , Tadahito Nobori , Shoji Tamai
发明人： Masahiro Toriida , Takashi Kuroki , Takaharu Abe , Akira Hasegawa , Kuniyuki Takamatsu , Yoshiteru Taniguchi , Isao Hara , Setsuko Fujiyoshi , Tadahito Nobori , Shoji Tamai
IPC分类号： C08G65/40 , C08G16/00
CPC分类号： C08G65/4093 , C08G65/40
摘要： There are disclosed, a polyether ketone having a primary particle size of 50 μm or less; and a method of producing a polyether ketone by a desalting polycondensation, which contains a step of conducting a polymerization reaction under a condition of deposition of the polymer. The polyether ketone obtained by the present invention has small particle size, high molecular weight and sufficiently small content of impurities such as alkali metal components.
摘要翻译：公开了一次粒径为50μm以下的聚醚酮，以及通过脱盐缩聚法制造聚醚酮的方法，该方法包括在聚合物沉积条件下进行聚合反应的步骤。通过本发明得到的聚醚酮具有粒径小，分子量高，杂质含量足够小的碱金属成分。

14. 发明授权

US07217780B2 Polyether ketone and method of producing the same 失效
标题翻译：聚醚酮及其制备方法
公开(公告)号：US07217780B2
公开(公告)日：2007-05-15
申请号：US10498096
申请日：2002-12-10
申请人： Masahiro Toriida , Takashi Kuroki , Takaharu Abe , Akira Hasegawa , Kuniyuki Takamatsu , Yoshiteru Taniguchi , Isao Hara , Setsuko Fujiyoshi , Tadahito Nobori , Shoji Tamai
发明人： Masahiro Toriida , Takashi Kuroki , Takaharu Abe , Akira Hasegawa , Kuniyuki Takamatsu , Yoshiteru Taniguchi , Isao Hara , Setsuko Fujiyoshi , Tadahito Nobori , Shoji Tamai
IPC分类号： C08G14/04 , C08G14/12 , C08G8/28
CPC分类号： C08G65/4093 , C08G65/40
摘要： There are disclosed, a polyether ketone having a primary particle size of 50 μm or less; and a method of producing a polyether ketone by a desalting polycondensation, which contains a step of conducting a polymerization reaction under a condition of deposition of the polymer. The polyether ketone obtained by the present invention has small particle size, high molecular weight and sufficiently small content of impurities such as alkali metal components.
摘要翻译：公开了一次粒径为50μm以下的聚醚酮，以及通过脱盐缩聚法制造聚醚酮的方法，该方法包括在聚合物沉积条件下进行聚合反应的步骤。通过本发明得到的聚醚酮具有粒径小，分子量高，杂质含量足够小的碱金属成分。

15. 发明申请

US20080033154A1 Process for Producing 3-Aminomethyltetrahydrofuran Derivative 审中-公开
标题翻译：生产3-氨基甲基四氢呋喃衍生物的方法
公开(公告)号：US20080033154A1
公开(公告)日：2008-02-07
申请号：US11629517
申请日：2005-06-02
申请人： Yoshihisa Inoue , Setsuko Funaki , Tetsuya Hamada , Yoshihiro Yamamoto , Isao Hara , Takaomi Hayashi , Miyuki Konno , Shinobu Aoki
发明人： Yoshihisa Inoue , Setsuko Funaki , Tetsuya Hamada , Yoshihiro Yamamoto , Isao Hara , Takaomi Hayashi , Miyuki Konno , Shinobu Aoki
IPC分类号： C07D307/02 , C07H5/06
CPC分类号： C07D307/14
摘要： A 3-aminomethyltetrahydrofuran derivative is produced by preparing a 3-cyanotetrahydrofuran derivative in a high yield from a malic acid derivative, and reducing the cyano group of the 3-cyanotetrahydrofuran derivative. The process can produce the 3-cyanotetrahydrofuran derivative in a high yield from inexpensive industrial materials.
摘要翻译：通过从苹果酸衍生物制备高收率的3-氰基四氢呋喃衍生物，并还原3-氰基四氢呋喃衍生物的氰基，制备3-氨基甲基四氢呋喃衍生物。该方法可以从廉价的工业材料以高产率生产3-氰基四氢呋喃衍生物。

16. 发明申请

US20110082325A1 TRANSITION METAL COMPLEX COMPOUNDS, OLEFIN OLIGOMERIZATION CATALYSTS INCLUDING THE COMPOUNDS, AND PROCESSES FOR PRODUCING OLEFIN OLIGOMERS USING THE CATALYSTS 有权
标题翻译：过渡金属复合化合物，包括该化合物的烯烃低聚催化剂，以及使用催化剂生产烯烃低聚物的方法
公开(公告)号：US20110082325A1
公开(公告)日：2011-04-07
申请号：US12452438
申请日：2008-06-27
申请人： Yasuhiko Suzuki , Shinsuke Kinoshita , Atsushi Shibahara , Naritoshi Yoshimura , Isao Hara , Tetsuya Hamada , Kazumori Kawamura , Kou Tsurugi , Yasunori Saito , Seiichi Ishii , Yasushi Nakayama , Naoto Matsukawa , Susumu Murata
发明人： Yasuhiko Suzuki , Shinsuke Kinoshita , Atsushi Shibahara , Naritoshi Yoshimura , Isao Hara , Tetsuya Hamada , Kazumori Kawamura , Kou Tsurugi , Yasunori Saito , Seiichi Ishii , Yasushi Nakayama , Naoto Matsukawa , Susumu Murata
IPC分类号： C07C2/26 , C07F7/28 , C07F11/00 , B01J31/14
CPC分类号： C08F10/00 , B01J31/143 , B01J31/1616 , B01J31/2243 , B01J2231/122 , B01J2231/20 , B01J2531/46 , B01J2531/62 , C07C2/32 , C07C251/24 , C07C2521/08 , C07C2521/16 , C07C2531/14 , C07C2531/22 , C07F7/003 , C08F110/02 , C07C11/107 , C08F4/64048 , C08F2500/02 , C08F4/64124 , C08F4/6931 , C08F4/64117 , C08F4/02
摘要： The invention provides transition metal complex compounds, high-activity olefin oligomerization catalysts containing the compounds, and olefin oligomerization processes using the catalysts.A transition metal complex compound [A] according to the invention is represented by Formula (I) or Formula (I′) below. An olefin oligomerization catalyst includes the transition metal complex compound [A]. In an olefin oligomerization process of the invention, an olefin is oligomerized in the presence of the catalyst.
摘要翻译：本发明提供了过渡金属络合物，含有这些化合物的高活性烯烃低聚催化剂和使用该催化剂的烯烃低聚方法。根据本发明的过渡金属络合物[A]由下式（I）或式（I'）表示。烯烃低聚催化剂包括过渡金属络合物[A]。在本发明的烯烃低聚方法中，烯烃在催化剂存在下被低聚。

17. 发明授权

US08258361B2 Transition metal complex compounds, olefin oligomerization catalysts including the compounds, and processes for producing olefin oligomers using the catalysts 有权
标题翻译：过渡金属络合物，包括该化合物的烯烃低聚催化剂，以及使用该催化剂生产烯烃低聚物的方法
公开(公告)号：US08258361B2
公开(公告)日：2012-09-04
申请号：US12452438
申请日：2008-06-27
申请人： Yasuhiko Suzuki , Shinsuke Kinoshita , Atsushi Shibahara , Naritoshi Yoshimura , Isao Hara , Tetsuya Hamada , Kazumori Kawamura , Kou Tsurugi , Yasunori Saito , Seiichi Ishii , Yasushi Nakayama , Naoto Matsukawa , Susumu Murata
发明人： Yasuhiko Suzuki , Shinsuke Kinoshita , Atsushi Shibahara , Naritoshi Yoshimura , Isao Hara , Tetsuya Hamada , Kazumori Kawamura , Kou Tsurugi , Yasunori Saito , Seiichi Ishii , Yasushi Nakayama , Naoto Matsukawa , Susumu Murata
IPC分类号： C07C2/22 , C07F7/28 , B01J31/18
CPC分类号： C08F10/00 , B01J31/143 , B01J31/1616 , B01J31/2243 , B01J2231/122 , B01J2231/20 , B01J2531/46 , B01J2531/62 , C07C2/32 , C07C251/24 , C07C2521/08 , C07C2521/16 , C07C2531/14 , C07C2531/22 , C07F7/003 , C08F110/02 , C07C11/107 , C08F4/64048 , C08F2500/02 , C08F4/64124 , C08F4/6931 , C08F4/64117 , C08F4/02
摘要： The invention provides transition metal complex compounds, high-activity olefin oligomerization catalysts containing the compounds, and olefin oligomerization processes using the catalysts.A transition metal complex compound [A] according to the invention is represented by Formula (I) or Formula (I′) below. An olefin oligomerization catalyst includes the transition metal complex compound [A]. In an olefin oligomerization process of the invention, an olefin is oligomerized in the presence of the catalyst.
摘要翻译：本发明提供了过渡金属络合物，含有这些化合物的高活性烯烃低聚催化剂和使用该催化剂的烯烃低聚方法。根据本发明的过渡金属络合物[A]由下式（I）或式（I'）表示。烯烃低聚催化剂包括过渡金属络合物[A]。在本发明的烯烃低聚方法中，烯烃在催化剂存在下被低聚。

18. 发明授权

US09370589B2 Switching fluorescent nanoparticle probe and fluorescent particle imaging method using same 有权
标题翻译：开关荧光纳米粒子探针和荧光颗粒成像方法使用相同
公开(公告)号：US09370589B2
公开(公告)日：2016-06-21
申请号：US13818392
申请日：2011-08-08
申请人： Isao Hara , Eiichi Ozeki , Hideo Saji , Shunsaku Kimura , Masahiro Ono , Takashi Temma
发明人： Isao Hara , Eiichi Ozeki , Hideo Saji , Shunsaku Kimura , Masahiro Ono , Takashi Temma
IPC分类号： A61K9/14 , A61K49/00
CPC分类号： A61K49/0089 , A61K49/0032 , A61K49/0093 , Y10S977/773 , Y10S977/927
摘要： The present invention provides a novel fluorescent nanoparticle imaging probe having a switching function (a function to quench a fluorescent dye during nanoparticle preparation, and emit fluorescence during imaging). A switching fluorescent nanoparticle probe comprising: a molecular assembly composed of an amphiphilic block polymer having a hydrophilic block chain and a hydrophobic block chain; and a fluorescent dye encapsulated in the molecular assembly, wherein (a) the hydrophilic block chain comprises, as an essential hydrophilic structural unit, a unit selected from a sarcosine unit and an alkylene oxide unit, (b) the hydrophobic block chain comprises, as an essential hydrophobic structural unit, a unit selected from the group consisting of an amino acid unit and a hydroxylic acid unit, and (c) the fluorescent dye is a cyanine compound represented by the formula (I): and two or more molecules of the fluorescent dye are encapsulated in the single molecular assembly.
摘要翻译：本发明提供了具有开关功能（在纳米颗粒制备期间淬灭荧光染料并在成像期间发射荧光的功能）的新型荧光纳米颗粒成像探针。一种开关荧光纳米颗粒探针，包括：由具有亲水嵌段链和疏水性嵌段链的两亲嵌段聚合物组成的分子组合; 以及包封在分子组合中的荧光染料，其中（a）所述亲水性嵌段链包含作为必需亲水性结构单元的选自肌氨酸单元和烯化氧单元的单元，（b）所述疏水性嵌段链包含：必需的疏水结构单元，选自氨基酸单元和羟基酸单元的单元，和（c）荧光染料是由式（I）表示的花青化合物：和荧光染料被封装在单分子组装中。

19. 发明授权

US4908472A Preparation process of cinnamate ester 失效
标题翻译：肉桂酸酯的制备方法
公开(公告)号：US4908472A
公开(公告)日：1990-03-13
申请号：US291207
申请日：1988-12-28
申请人： Usaji Takaki , Shinobu Aoki , Yoshihiro Yamamoto , Isao Hara
发明人： Usaji Takaki , Shinobu Aoki , Yoshihiro Yamamoto , Isao Hara
IPC分类号： B01J23/44 , B01J10/00 , B01J19/00 , B01J27/122 , B01J27/13 , B01J31/04 , B01J31/22 , C07B61/00 , C07C67/36 , C07C69/618
CPC分类号： B01J19/0013 , B01J19/0066 , C07C67/36 , B01J2219/00094 , B01J2219/00108
摘要： The invention relates to a process for preparing a cinnamate ester comprising forming a reaction mixture of a styrene compound, an alcohol and a catalyst in a reactor; blowing a feed gas mixture of carbon monoxide, oxygen and an inert gas into the reaction mixture through at least one feed port; collecting a discharge gas flowing from the reactor and passing the gas through a condenser to form a condensate; recirculating the condensate into the reactor; blowing into the reaction mixture through at least one feed port other than the feed port(s) for the feed gas mixture, a gas selected from the groups consisting of the discharge gas and an inert gas; and isolating the cinnamate ester from the mixture.

20. 发明授权

US09849197B2 Switching-type fluorescent nanoparticle probe, and fluorescent molecular imaging method using same 有权
公开(公告)号：US09849197B2
公开(公告)日：2017-12-26
申请号：US14002327
申请日：2012-03-01
申请人： Hideo Saji , Shunsaku Kimura , Masahiro Ono , Takashi Temma , Isao Hara , Eiichi Ozeki
发明人： Hideo Saji , Shunsaku Kimura , Masahiro Ono , Takashi Temma , Isao Hara , Eiichi Ozeki
IPC分类号： A61K9/00 , A61K49/00
CPC分类号： A61K49/0054 , A61K49/0032 , A61K49/0034 , A61K49/0069 , A61K49/0093
摘要： [Problem] To provide a novel fluorescent nanoparticle imaging probe having a switching function (a function to quench a fluorescent dye in a blood component and emit fluorescence in a tumor or an inflamed site to be imaged).[Solution] A fluorescent nanoparticle probe comprising: a molecular assembly composed of an amphiphilic block polymer having a hydrophilic block chain and a hydrophobic block chain; and a fluorescent dye encapsulated in the assembly, wherein (a) the hydrophilic block chain comprises, as an essential hydrophilic structural unit, a unit selected from a sarcosine unit and an alkylene oxide unit, (b) the hydrophobic block chain comprises, as an essential hydrophobic structural unit, a unit selected from the group consisting of an amino acid unit and a hydroxylic acid unit, and (c) the fluorescent dye is a polylactic acid-bound cyanine compound comprising: a fluorescent group represented by the formula (I): and a polylactic acid group having 5 to 50 lactic acid units, and two or more molecules of the fluorescent dye are encapsulated in the single molecular assembly.

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