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11. 发明授权

US07592064B2 Highly repellent carpet protectants 有权
标题翻译：高驱蚊地毯保护剂
公开(公告)号：US07592064B2
公开(公告)日：2009-09-22
申请号：US10913914
申请日：2004-08-06
申请人： Patrick Henry Fitzgerald , Andrew Hen Liu , Peter Michael Murphy , Charles L. Strickler
发明人： Patrick Henry Fitzgerald , Andrew Hen Liu , Peter Michael Murphy , Charles L. Strickler
IPC分类号： B32B3/02 , B32B5/02 , B32B27/00 , B32B27/02 , B32B27/04 , B32B27/12 , B32B27/40 , D03D27/00 , D04H11/00 , D05C17/00 , D02G3/00 , B05D3/02 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/7831 , C08G18/2885 , D06M15/576 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T428/249991 , Y10T428/2938 , Y10T428/2967 , Y10T428/31551 , Y10T428/31562 , Y10T442/2189 , Y10T442/2197 , Y10T442/2238 , Y10T442/2246 , Y10T442/2893
摘要： Carpet protectants comprising an aqueous dispersion comprising A. a partially fluorinated urethane polymer having at least one urea linkage, which compound is the product of the reaction of: (1) at least one organic polyisocyanate containing at least three isocyanate groups; (2) at least one fluorochemical compound which contains per molecule (a) a single functional group having one or more Zerewitinoff hydrogen atoms and (b) at least two carbon atoms, each of which is attached to at least two fluorine atoms; and (3) water in an amount sufficient to react with from about 5% to about 60% of the isocyanate groups in said polyisocyanate; B. a non-fluorinated cationic surfactant; and C. a non-fluorinated nonionic surfactant are disclosed.
摘要翻译：地毯保护剂包含水分散体，其包含A.具有至少一个脲键的部分氟化的聚氨酯聚合物，该化合物是以下物质的反应产物：（1）至少一种含有至少三个异氰酸酯基团的有机多异氰酸酯; （2）至少一种含氟化合物，其每分子含有（a）具有一个或多个Zerewitinoff氢原子的单官能团和（b）至少两个碳原子，每个碳原子连接至少两个氟原子; 和（3）足以与所述多异氰酸酯中的约5％至约60％的异氰酸酯基反应的水; B.非氟化阳离子表面活性剂; 和C.一种非氟化非离子表面活性剂。

12. 发明申请

US20090221200A1 COPOLYMERS FOR STAIN RESISTANCE 失效
标题翻译：共聚物耐腐蚀
公开(公告)号：US20090221200A1
公开(公告)日：2009-09-03
申请号：US12465155
申请日：2009-05-13
申请人： Timothy Edward Hopkins , Stephen Ernest Jacobson , Melea Rena Langley , Peter Michael Murphy
发明人： Timothy Edward Hopkins , Stephen Ernest Jacobson , Melea Rena Langley , Peter Michael Murphy
IPC分类号： B32B27/12 , D06M15/513
CPC分类号： D06M15/263 , C08F8/44 , C09D135/00 , D06M15/227 , D06M15/233 , D06M15/285 , D06M15/29 , D06M15/295 , D06M15/3562 , D06M2200/01 , Y10T428/23986 , Y10T428/2933 , Y10T428/2938 , Y10T428/2967 , Y10T428/3175 , Y10T428/31797 , Y10T428/31855 , Y10T428/3188 , Y10T428/31895 , Y10T428/31909 , Y10T428/31928 , Y10T442/2279 , C08F8/32 , C08F212/08 , C08F222/06 , C08F210/14
摘要： A method for imparting resistance to staining to a substrate comprising contacting the substrate with a copolymer comprising the monomers of Formula wherein D is at least one vinyl monomer selected from the group consisting of aryl olefin, alpha olefin and diene, each M is independently H, Ca, Mg, Al, Na, or K, each R1 is independently H, C1-C6 alkyl, or C1-C6 hydroxyalkyl, each R2 is independently linear or branched C1-C12 alkyl, C1-C6 hydroxyalkyl, C6F5, arylalkyl, C6H4OH, R3COOH, or R3SO3H, or R1 and R2 are linked together to form a morpholino or pyrrolidino ring, R3 is linear or branched C1-C12 alkyl, CH(COOH)CH2CH2, C6H4, or C6H3(OH), h1+h2 is h, h is a positive integer, k is zero or a positive integer, i and j are each independently zero or a positive integer, provided that the total of 1) h÷(k+h+i+j) is from about 0.005 to about 0.7, 2) k÷(k+h+i+j) is from about 0.3 to about 0.6, 3) [i+j]÷(k+h+i+j) is 0 to about 0.6, and provided that the sum of 1)+2)+3) is 1.0, said monomers occurring in any sequence.
摘要翻译：一种赋予对基材染色抗性的方法，包括使底物与包括式I的单体的共聚物接触，其中D为选自芳烯基烯烃，α-烯烃和二烯的至少一种乙烯基单体，每个M独立地为H， Ca，Mg，Al，Na或K，每个R 1独立地为H，C 1 -C 6烷基或C 1 -C 6羟基烷基，每个R 2独立地为直链或支链C 1 -C 12烷基，C 1 -C 6羟基烷基，C 6 F 5，芳基烷基，C 6 H 4 OH ，R 3 COOH或R 3 SO 3 H，或R 1和R 2连接在一起形成吗啉代或吡咯烷基环，R 3是直链或支链C 1 -C 12烷基，CH（COOH）CH 2 CH 2，C 6 H 4或C 6 H 3（OH），h1 + h2是h ，h是正整数，k是零或正整数，i和j各自独立为零或正整数，条件是1）h /（k + h + i + j）的总和为约0.005〜约0.7,2）k /（k + h + i + j）为约0.3至约0.6,3）[i + j] /（k + h + i + j）为0至约0.6，条件是 1）+2）+3）的总和为1.0，所述单体为卷曲任何顺序。

13. 发明申请

US20080202384A1 Fluoropolymer compositions and method of use 审中-公开
公开(公告)号：US20080202384A1
公开(公告)日：2008-08-28
申请号：US11712324
申请日：2007-02-28
申请人： Sheng Peng , Stephen James Getty , Patrick Henry Fitzgerald , Peter Michael Murphy , Ying Wang , Ernest Byron Wysong
发明人： Sheng Peng , Stephen James Getty , Patrick Henry Fitzgerald , Peter Michael Murphy , Ying Wang , Ernest Byron Wysong
IPC分类号： C09K3/18 , C08F10/00 , C08F14/18
CPC分类号： C08F214/18 , C08F214/186 , C08F220/18 , C08F220/24 , C08F220/28 , C08F220/58 , C09D133/16 , D06M15/263 , D06M15/267 , D06M15/277 , D06M2200/01 , D06M2200/11 , D06M2200/12
摘要： A composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): Rf—(CH2CF2)q(CH2CH2)r-Z-C(O)—C(R)═CH2 (I) wherein q and r are each independently integers of 1 to 3; Rf is a linear or branched perfluoroalkyl group having 2 to 6 carbon atoms; Z is —O—, —NR1— or —S—; R is hydrogen, Cl, F or CH3; R1 is hydrogen, or a C1 to C4 alkyl; and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of 6 to 18 carbons; or (ii) a monomer of formula (II): (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is as defined above; each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof; said composition providing oil repellency, water repellency, and stain resistance to substrates contacted therewith; and a method for treating substrates with such copolymer compositions; are disclosed.

14. 发明授权

US5750445A Treatment of polyamide materials with partial fluoroesters or fluorothioesters of maleic acid polymers and sulfonated aromatic condensates 失效
标题翻译：用马来酸聚合物和磺化芳族缩合物的部分氟代酯或氟代硫代酯处理聚酰胺材料
公开(公告)号：US5750445A
公开(公告)日：1998-05-12
申请号：US854234
申请日：1997-05-09
申请人： Engelbert Pechhold , Peter Michael Murphy
发明人： Engelbert Pechhold , Peter Michael Murphy
IPC分类号： D06P5/02 , C08F8/20 , C08F8/34 , D06M15/263 , D06M15/267 , D06M15/277 , D06M15/356 , D06M15/41 , D06M101/34 , D06P5/08 , B32B7/00
CPC分类号： D06M15/412 , C08F8/20 , C08F8/34 , D06M15/263 , D06M15/267 , D06M15/277 , D06M15/3568 , D06M2101/12 , D06M2101/34 , Y10T442/2279 , Y10T442/2287 , Y10T442/2893 , Y10T442/2967
摘要： The present invention comprises a process for providing soil resistance and resistance to staining by acid dyes to fibers and textiles by simultaneous or sequential application of a sulfonated phenol-formaldehyde condensation product and partial fluoroesters or fluorothioesters formed from copolymers of maleic anhydride and perfluoroalkyl alcohols or perfluoroalkyl thiols.
摘要翻译：本发明包括通过同时或顺序施用磺化苯酚 - 甲醛缩合产物和由马来酸酐和全氟烷基醇或全氟烷基的共聚物形成的部分氟代酯或氟代酯，提供耐酸性和耐酸性染料对纤维和纺织品的污染的方法硫醇

15. 发明授权

US08318877B2 Ethylene tetrafluoroethylene (meth)acrylate copolymers 失效
标题翻译：乙烯四氟乙烯（甲基）丙烯酸酯共聚物
公开(公告)号：US08318877B2
公开(公告)日：2012-11-27
申请号：US12154082
申请日：2008-05-20
申请人： Weiming Qiu , Anilkumar Raghavanpillai , Peter Michael Murphy , Jessica Louise Flatter
发明人： Weiming Qiu , Anilkumar Raghavanpillai , Peter Michael Murphy , Jessica Louise Flatter
IPC分类号： C08F14/18
CPC分类号： C08F14/18 , C08F220/24 , C08F220/34 , C08F220/36 , C08F220/38 , C09D133/16 , C09D133/26 , Y10T428/2395 , Y10T428/23986 , Y10T428/3154
摘要： A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]m-L-C(O)—C(R)═CH2 (I) wherein R is H, Cl, F or CH3, L is O, S, NH, S—(CH2)rO, S—(CH2)rNH, OC(O)NH—CH2CH2O, NHC(O)NHCH2CH2O, S—(CH2)rOC(O)NHCH2CH2O, or S(CH2)rNHC(O)NHCH2CH2O, and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is H, Cl, F or CH3, each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.
摘要翻译：共聚物组合物，其包含以以下重量百分比共聚的单体：（a）约20％至约95％的式（I）的单体或单体混合物：CnF2n + 1（CH2）x [（CF2CF2） y（CH 2 CH 2）z] mLC（O）-C（R）= CH 2（I）其中R是H，Cl，F或CH 3，L是O，S，NH，S-（CH 2））R NH，OC（O）NH-CH 2 CH 2 O，NHC（O）NHCH 2 CH 2 O，S-（CH 2）r OC（O）NHCH 2 CH 2 O或S（CH 2）r NHC（O）NHCH 2 CH 2 O，和（b）约5％％的至少一种：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（II）式（II）的单体（R2）2N-R3-O-C（O）-C（R）= CH2（Ⅱ）其中R是H，Cl，F或CH3，每个R2独立地是 C1至C4烷基; 并且R 3是二价直链或支链C1至C4亚烷基; 并且其中所述氮为约40％至100％盐碱化; 或（iii）其混合物。

16. 发明授权

US08263800B2 Partially fluorinated sulfonated surfactants 失效
标题翻译：部分氟化磺化表面活性剂
公开(公告)号：US08263800B2
公开(公告)日：2012-09-11
申请号：US12165798
申请日：2008-07-01
申请人： Peter Michael Murphy , Tracy Hewat
发明人： Peter Michael Murphy , Tracy Hewat
IPC分类号： C07C69/34 , C11D3/50 , C11D1/12
CPC分类号： C07C309/17 , A61K8/466 , B01F17/0035 , C11D1/004
摘要： The present invention comprises a compound comprising Formula 1A, 1B, or 1C (Ra—O—CO—)2X Formula 1A Ra—O—CO—X—CO—O—(CH2CH2)Rf Formula 1B Ra—O—CO—X—CO—O—R Formula 1C wherein Ra is the group Rf(CH2CF2)d—(CgH2g)—; RfOCF2CF2—(CgH2g)—; RfOCFHCF2O(CH2CH2O)v—(CgH2g)—; RfOCFHCF2O(CwH2w); RfOCF(CF3)CONH—(CgH2g); or Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k; Rf is CcF(2c+1); d is 1 to about 3; g is 1 to 4; v is 1 to about 4; w is from about 3 to about 12; h is 1 to about 6; i, j, and k are each independently 1, 2, or 3, or a mixture thereof; provided that the total number of carbon atoms in group (vi) is from about 8 to about 22; X is a linear or branched difunctional alkyl sulfonate group —CeH(2e−1)(SO3M)-, wherein e is 2 or 3; M is a monovalent cation selected from the group consisting of hydrogen, ammonium, alkali metal, or alkaline earth metal; R is H or a linear or branched alkyl group CbH(2b+1)—; and b is from 1 to about 18.
摘要翻译：本发明包括式1A，1B或1C（Ra-O-CO-）2X式1A的化合物Ra-O-CO-X-CO-O-（CH2CH2）Rf式1B Ra-O-CO-X -CO-O-R式1C其中R a是基团R f（CH 2 CF 2）d - （C 1 H 2） RfOCF2CF2-（CgH2g） - ; RfOCFHCF2O（CH2CH2O）v-（CgH2g） - ; RfOCFHCF2O（CwH2w）; RfOCF（CF3）CONH-（CgH2g）; 或Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k; Rf为CcF（2c + 1）; d为1〜3; g为1〜4; v为1至约4; w为约3至约12; h为1〜6; i，j和k各自独立地为1,2或3，或其混合物; 组（vi）中的碳原子总数为约8至约22; X是直链或支链双官能烷基磺酸盐基-CeH（2e-1）（SO3M） - ，其中e是2或3; M是选自氢，铵，碱金属或碱土金属的一价阳离子; R是H或直链或支链烷基CbH（2b + 1） - ; b为1至约18。

17. 发明申请

US20110009668A1 POLYFLUOROSULFONAMIDO AMINE AND INTERMEDIATE 失效
标题翻译：聚氟虫胺和中间体
公开(公告)号：US20110009668A1
公开(公告)日：2011-01-13
申请号：US12500817
申请日：2009-07-10
申请人： Alexander Borisovich Shtarov , Peter Michael Murphy , Brent Ryan Gonska , Stephan James McLain
发明人： Alexander Borisovich Shtarov , Peter Michael Murphy , Brent Ryan Gonska , Stephan James McLain
IPC分类号： C07C311/01
CPC分类号： C07C311/09 , C07C303/38 , C07C303/40
摘要： Current methods for making polyfluorosulfonamido amines, which involve the use of a diamine reactant, provide low yields and produce an undesirable fluorine containing bis-sulfonamide by-product representing an economic loss. The bis-sulfonamide by-product is particularly undesirable because it shares very similar physical properties with the desired monoamine product thus making isolation of the desired polyfluorosulfonamido amine product difficult and costly. Furthermore, instead of the efficient incorporation of fluorine to make the desired polyfluorosulfonamido amine product, the bis-sulfonamide by-product constitutes a substantial loss of costly fluorinated starting material. The bis-sulfonamide by-product also constitutes an undesirable impurity that can worsen surfactancy, repellency, or other performance characteristics of the desired polyfluorosulfonamido amine product. The present invention provides a method of making a polyfluorosulfonamido amine without the production of a bis-sulfonamide by-product by reacting a polyfluoroalkylsulfonic compound with a monoamino amide rather than with a diamine reactant as in previously known methods.
摘要翻译：涉及使用二胺反应物的制备多氟磺酰氨基胺的现有方法提供低产率并产生表示经济损失的不希望的含氟双磺酰胺副产物。双磺酰胺副产物是特别不希望的，因为它与所需的单胺产物分享非常相似的物理性质，从而使所需的多氟磺酰胺胺产物的分离困难且昂贵。此外，代替有效地引入氟以制备所需的多氟磺酰氨基胺产物，双磺酰胺副产物构成昂贵的氟化原料的显着损失。双磺酰胺副产物也构成可恶化期望的多氟磺酰氨基胺产物的表面活性，排斥性或其它性能特征的不期望的杂质。本发明提供了如先前已知的方法，通过使多氟烷基磺酸化合物与单氨基酰胺而不是二胺反应物反应而制备多氟磺酰胺，不产生双磺酰胺副产物的方法。

18. 发明授权

US07829477B2 Fluorinated water soluble copolymers 失效
标题翻译：氟化水溶性共聚物
公开(公告)号：US07829477B2
公开(公告)日：2010-11-09
申请号：US11978290
申请日：2007-10-29
申请人： Peter Michael Murphy , Jessica Sinks , Ying Wang
发明人： Peter Michael Murphy , Jessica Sinks , Ying Wang
IPC分类号： B32B5/02
CPC分类号： C09D133/16 , C08F220/04 , C08F220/24 , C08F220/32 , C08F220/38 , C08F220/58 , Y10T428/23986 , Y10T428/31544 , Y10T442/2172 , Y10T442/2279 , Y10T442/2287
摘要： A method of providing water repellency, oil repellency, soil resistance, soil release, stain resistance and stain release to substrates comprising contacting said substrate with a composition comprising a copolymer having repeating units of Formula 1 in any sequence: wherein Rf is a straight or branched perfluoroalkyl group having from about 2 to about 8 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, Q is alkylene of 1 to about 15 carbon atoms, hydroxyalkylene of 2 to about 15 carbon atoms, —O(CnH2n)—, —(CH2CF2)m(CH2)n—, —CONR1(CnH2n)—, —(CnH2n)OCONR1(CnH2n)—, (—CONR1CH2)2CH—, —SO2N(R1)(CnH2n)—, or —(CnH2n)SO2N(R1)(CnH2n)—, each R1 is independently H or alkyl of 1 to about 4 carbon atoms, each n is independently 1 to about 15, each m is independently 1 to about 4, Z is hydrogen or methyl, x is a positive integer, y is zero or a positive integer, t is a positive integer, and M is H+, alkali metal cation, alkaline earth metal cation, or ammonium.
摘要翻译：提供防水性，拒油性，耐土壤性，污垢释放，耐污染性和对基材的污迹释放的方法，包括使所述底物与包含具有任何顺序的具有式1的重复单元的共聚物的组合物接触的组合物接触：其中Rf是直链或支链具有约2至约8个碳原子的全氟烷基或其混合物，其任选被至少一个氧原子间隔，Q为1至约15个碳原子的亚烷基，2至约15个碳原子的羟基亚烷基，-O （CnH2n） - ， - （CH2CF2）m（CH2）n-，-CONR1（CnH2n） - ， - （CnH2n）OCONR1（CnH2n） - ，（-CONR1CH2）2CH-，-SO2N（R1）（CnH2n）或 - （C n H 2n）SO 2 N（R 1）（C n H 2n） - ，每个R 1独立地为H或1至约4个碳原子的烷基，每个n独立地为1至约15，m各自独立地为1至约4，Z为氢或甲基，x为正整数，y为零或正整数，t为正整数，M为H +，碱金属阳离子，碱地球金属阳离子或铵。

19. 发明授权

US07692035B2 Fluorinated esters 失效
标题翻译：氟化酯
公开(公告)号：US07692035B2
公开(公告)日：2010-04-06
申请号：US12165824
申请日：2008-07-01
申请人： Peter Michael Murphy , Tracy Hewat
发明人： Peter Michael Murphy , Tracy Hewat
IPC分类号： C07C69/34
CPC分类号： C07C69/65 , C07C69/657 , C07C235/08
摘要： A compound comprising Formula 2A, 2B, or 2C (Ra—O—CO—)2YFormula 2A Ra—O—CO—Y—CO—O—(CH2CH2)RfFormula 2B Ra—O—CO—Y—CO—O—RFormula 2C wherein Ra is the group (i) Rf(CH2CF2)d—(CgH2g)—; (ii) RfOCF2CF2—(CgH2g)—; (iii) Rf OCFHCF2O(CH2CH2O)v—(CgH2g)—; (iv) RfOCFHCF2O(CwH2w)—; (v) RfOCF(CF3)CONH—(CgH2g)—; or (vi) Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k; each Rf is independently CcF(2c+1); c is 2 to about 6; d is 1 to about 3; g is 1 to 4; v is 1 to about 4; w is from about 3 to about 12; h is 1 to about 6; i, j, and k are each independently 1, 2, or 3, or a mixture thereof; provided that the total number of carbon atoms in group (vi) is from about 8 to about 22; Y is a linear or branched diradical having olefinic unsaturation of the formula —CeH(2e-2)— wherein e is 2 or 3; R is H or a linear or branched alkyl group CbH(2b+1)—; and b is from 1 to about 18.
摘要翻译：包含式2A，2B或2C（Ra-O-CO-）2Y的化合物式2A Ra-O-CO-Y-CO-O-（CH2CH2）Rf式2B Ra-O-CO-Y-CO-O -R式2C其中Ra是基团（ⅰ）Rf（CH 2 CF 2）d - （C 1 H 2）（ⅱ）RfOCF2CF2-（CgH2g） - ; （iii）Rf OCFHCF2O（CH2CH2O）v-（CgH2g） - ; （iv）RfOCFHCF2O（CwH2w） - ; （v）RfOCF（CF 3）CONH-（CgH2g） - ; 或（vi）Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k; 每个Rf独立地为CcF（2c + 1）; c为2至约6; d为1〜3; g为1〜4; v为1至约4; w为约3至约12; h为1〜6; i，j和k各自独立地为1,2或3，或其混合物; 组（vi）中的碳原子总数为约8至约22; Y是具有式-CeH（2e-2） - 烯烃不饱和键的直链或支链双基，其中e为2或3; R是H或直链或支链烷基CbH（2b + 1） - ; b为1至约18。

20. 发明申请

US20090291222A1 Ethylene tetrafluoroethylene (meth)acrylate copolymers 失效
标题翻译：乙烯四氟乙烯（甲基）丙烯酸酯共聚物
公开(公告)号：US20090291222A1
公开(公告)日：2009-11-26
申请号：US12154082
申请日：2008-05-20
申请人： Weiming Qiu , Anilkumar Raghavanpillai , Peter Michael Murphy , Jessica Louise Flatter
发明人： Weiming Qiu , Anilkumar Raghavanpillai , Peter Michael Murphy , Jessica Louise Flatter
IPC分类号： B05D1/02 , C08G16/00 , C08G63/06 , C08G12/00 , C08G18/71 , C08G75/00 , C08G63/682 , B05D1/18 , B05D1/28 , C08F214/18 , C08L75/06 , C08G63/685 , C08L33/04 , C08L77/00
CPC分类号： C08F14/18 , C08F220/24 , C08F220/34 , C08F220/36 , C08F220/38 , C09D133/16 , C09D133/26 , Y10T428/2395 , Y10T428/23986 , Y10T428/3154
摘要： A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]m-L-C(O)—C(R)═CH2 (I) wherein R is H, Cl, F or CH3, L is O, S, NH, S—(CH2)rO, S—(CH2)rNH, OC(O)NH—CH2CH2O, NHC(O)NHCH2CH2O, S—(CH2)rOC(O)NHCH2CH2O, or S(CH2)rNHC(O)NHCH2CH2O, and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is H, Cl, F or CH3, each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.
摘要翻译：共聚物组合物，其包含以以下重量百分比共聚的单体：（a）约20％至约95％的式（I）的单体或单体混合物：CnF2n + 1（CH2）x [（CF2CF2）其中R为H，Cl，F或CH 3，L为O，S，NH，S-（CH 2）r O，S-（CH 2））R NH，OC（O）NH-CH 2 CH 2 O，NHC（O）NHCH 2 CH 2 O，S-（CH 2）r OC（O）NHCH 2 CH 2 O或S（CH 2）r NHC（O）NHCH 2 CH 2 O，和（b）约5％％的至少一种：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（II）式（II）的单体（R2）2N-R3-OC（O）-C（R）-CH2（Ⅱ）其中R是H，Cl，F或CH3，每个R2独立地是C1至 C4烷基; 并且R 3是二价直链或支链C1至C4亚烷基; 并且其中所述氮为约40％至100％盐碱化; 或（iii）其混合物。

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