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11. 发明申请

US20110001084A1 ELECTRODE MATERIAL AND LITHIUM ION SECONDARY BATTERY 审中-公开
标题翻译：电极材料和锂离子二次电池
公开(公告)号：US20110001084A1
公开(公告)日：2011-01-06
申请号：US12828619
申请日：2010-07-01
申请人： Ryuji Shiozaki , Daisuke Maruyama , Yuya Mukainakano , Ken Baba
发明人： Ryuji Shiozaki , Daisuke Maruyama , Yuya Mukainakano , Ken Baba
IPC分类号： H01M4/58
CPC分类号： H01M10/0525 , B82Y30/00 , C01G31/00 , C01P2002/04 , C01P2002/72 , C01P2004/62 , C01P2004/64 , H01M4/131 , H01M4/485 , H01M2004/028 , Y02T10/7011
摘要： The electrode material according to the present invention has a crystal phase in the form of a lattice containing lithium vanadium oxide, such as Li0.3V2O5 with a primary particle diameter of 10 nm or more and 200 nm or less, wherein lithium is arranged in the lattice. Accordingly, when the electrode material is used as the positive electrode material, especially in the crystallized state containing an amorphous glass composition such as phosphor, lithium, antimony (or iron), a high battery capacity can be obtained. Further, even if the charging and discharging are repeated, the crystal structure is difficult to be collapsed, whereby the cycle characteristic is enhanced.
摘要翻译：根据本发明的电极材料具有含有锂钒氧化物的晶格形状的结晶相，例如一次粒径为10nm以上且200nm以下的Li 0.3 V 2 O 5，其中，锂配置在格子。因此，当电极材料用作正极材料时，特别是在含有诸如磷，锂，锑（或铁）的无定形玻璃组合物的结晶状态下，可以获得高电池容量。此外，即使重复充放电，晶体结构难以塌陷，从而提高了循环特性。

12. 发明申请

US20130071749A1 POSITIVE ELECTRODE ACTIVE MATERIAL PRODUCTION METHOD, POSITIVE ELECTRODE, AND STORAGE DEVICE 审中-公开
标题翻译：正极电极活性材料生产方法，正电极和存储装置
公开(公告)号：US20130071749A1
公开(公告)日：2013-03-21
申请号：US13613245
申请日：2012-09-13
申请人： Yuya MUKAINAKANO , Rikitaro Ishii , Ryuji Shiozaki
发明人： Yuya MUKAINAKANO , Rikitaro Ishii , Ryuji Shiozaki
IPC分类号： H01M4/58 , H01M4/583
CPC分类号： H01M4/136 , C01B25/455 , C01P2002/72 , H01M4/582 , H01M4/5825 , H01M4/625
摘要： There is provided a positive electrode active material production method, a positive electrode, and a storage device. A production method of a positive electrode active material having a LiVPO4F-type crystal structure and containing carbon, includes: a step of synthesizing a precursor that has VPO4 containing carbon, from a starting material in the form of vanadium pentoxide and a phosphate compound, and from a carbon material as an additive; and a step of synthesizing LiVPO4F containing carbon, from the precursor and LiF. The carbon material as an additive is conductive carbon black having a specific surface area of 700 to 1500 m2/g, and in the step of synthesizing the precursor, an addition amount of the conductive carbon black is less than 2 moles per mole of vanadium pentoxide.
摘要翻译：提供正极活性物质的制造方法，正极和存储装置。具有LiVPO 4 F型结晶结构并含有碳的正极活性物质的制造方法包括：从五氧化二钒和磷酸盐化合物的原料合成含有含有VPO 4的前体的工序，以及从碳材料作为添加剂; 以及从前体和LiF合成含有碳的LiVPO 4 F的工序。作为添加剂的碳材料是比表面积为700〜1500m 2 / g的导电性炭黑，在合成前体的步骤中，每摩尔五氧化二钒的导电性炭黑的添加量少于2摩尔。

13. 发明申请

US20110108760A1 ELECTRODE MATERIAL, PRODUCTION METHOD OF SAME AND LITHIUM ION SECONDARY BATTERY 审中-公开
标题翻译：电极材料，其生产方法和锂离子二次电池
公开(公告)号：US20110108760A1
公开(公告)日：2011-05-12
申请号：US12938734
申请日：2010-11-03
申请人： Yuya Mukainakano , Daisuke Maruyama , Ken Baba , Ryuji Shiozaki
发明人： Yuya Mukainakano , Daisuke Maruyama , Ken Baba , Ryuji Shiozaki
IPC分类号： H01M4/88 , H01M4/485
CPC分类号： H01M4/485 , H01M4/1391 , H01M10/0525
摘要： An electrode material uses, as an active material, sodium vanadium oxide represented by NaxV2O5 (0
摘要翻译：电极材料使用由NaxV2O5（0

14. 发明授权

US07691535B2 Active substance of positive electrode and non-aqueous electrolyte battery containing the same 有权
标题翻译：含有正极和非水电解质电池的活性物质
公开(公告)号：US07691535B2
公开(公告)日：2010-04-06
申请号：US10500819
申请日：2003-03-26
申请人： Ryuji Shiozaki , Akihiro Fujii , Tokuo Inamasu , Hiroe Nakagawa , Suguru Kozono , Toshiyuki Nukuda
发明人： Ryuji Shiozaki , Akihiro Fujii , Tokuo Inamasu , Hiroe Nakagawa , Suguru Kozono , Toshiyuki Nukuda
IPC分类号： H01M4/52 , H01M4/50
CPC分类号： H01M4/505 , C01G45/1242 , C01G51/42 , C01G53/50 , C01P2002/52 , C01P2006/40 , H01M4/525 , H01M10/0525
摘要： A positive active material is provided which can give a battery having a high energy density and excellent high-rate discharge performance and inhibited from decreasing in battery performance even in the case of high-temperature charge. Also provided is a non-aqueous electrolyte battery employing the positive active material. The positive active material contains a composite oxide which is constituted of at least lithium (Li), manganese (Mn), nickel (Ni), cobalt (Co), and oxygen (O) and is represented by the following chemical composition formula: LiaMnbNicCodOe (wherein 0
摘要翻译：提供一种正极活性材料，其可以给出具有高能量密度的电池和优异的高速率放电性能，并且即使在高温充电的情况下也可以抑制电池性能的降低。还提供了使用正极活性物质的非水电解质电池。正极活性物质含有至少由锂（Li），锰（Mn），镍（Ni），钴（Co）和氧（O）构成的复合氧化物，由以下化学组成式表示：LiaMnbNicCodOe （其中0

15. 发明申请

US20060257743A1 Nonaqueous electrolyte cell 审中-公开
标题翻译：非水电解质电池
公开(公告)号：US20060257743A1
公开(公告)日：2006-11-16
申请号：US10558887
申请日：2004-03-17
申请人： Junichi Kuratomi , Takaaki Iguchi , Akinori Ito , Ryuji Shiozaki , Kenji Kohno
发明人： Junichi Kuratomi , Takaaki Iguchi , Akinori Ito , Ryuji Shiozaki , Kenji Kohno
IPC分类号： H01M4/52 , H01M4/50 , H01M10/40 , H01M4/58
CPC分类号： H01M4/505 , H01M4/525 , H01M6/164 , H01M10/0525 , H01M10/0569
摘要： An object of the present invention is to provide a nonaqueous electrolyte battery which restrains swelling of the battery during high-temperature storage and is excellent in battery performance after storage. The invention is characterized by a specific constitution of a nonaqueous electrolyte and a combination thereof with a positive active material having specific crystal structure and composition. Namely, it is characterized by a nonaqueous electrolyte battery containing a positive electrode, a negative electrode, and a nonaqueous electrolyte, wherein the above nonaqueous electrolyte contains at least a cyclic carbonate having a carbon-carbon π bond and the above positive electrode contains a positive active material comprising a composite oxide represented by a composite formula: LixMnaNibCOcO2 (wherein 0≦x≦1.1, a+b+c=1, |a-b|
摘要翻译：本发明的目的是提供一种非水电解质电池，其在高温保存期间抑制电池膨胀，并且在储存后具有优异的电池性能。本发明的特征在于非水电解质的具体结构及其与具有特定晶体结构和组成的正极活性物质的组合。也就是说，其特征在于包含正极，负极和非水电解质的非水电解质电池，其中上述非水电解质至少含有具有碳 - 碳p键的环状碳酸酯，上述正极含有正极包含复合氧化物的活性材料，所述复合氧化物由以下复合式表示：Li x Mn x N a （其中0 <= x <= 1.1，a + b + c = 1，| ab | <0.05,0 型晶体结构。

16. 发明申请

US20050019659A1 Active substance of positive electrode and nonaqueous electrolyte battery containing the same 有权
标题翻译：含有正极和非水电解质电池的活性物质
公开(公告)号：US20050019659A1
公开(公告)日：2005-01-27
申请号：US10500819
申请日：2003-03-26
申请人： Ryuji Shiozaki , Akihiro Fujii , Tokuo Inamasu , Hiroe Nakagawa , Suguru Kozono , Toshiyuki Nukuda
发明人： Ryuji Shiozaki , Akihiro Fujii , Tokuo Inamasu , Hiroe Nakagawa , Suguru Kozono , Toshiyuki Nukuda
IPC分类号： C01G45/12 , C01G51/04 , C01G53/00 , C01G53/04 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M10/0525 , H01M10/36
CPC分类号： H01M4/505 , C01G45/1242 , C01G51/42 , C01G53/50 , C01P2002/52 , C01P2006/40 , H01M4/525 , H01M10/0525
摘要： A positive active material is provided which can give a battery having a high energy density and excellent high-rate discharge performance and inhibited from decreasing in battery, performance even in the case of high-temperature charge. Also provided is a non-aqueous electrolyte battery employing the positive active material. The positive active material contains a composite oxide which is constituted of at least lithium (Li), manganese (Mn), nickel (Ni), cobalt (Co), and oxygen (O) and is represented by the following chemical composition formula: LiaMnbNicCodOe (wherein 0
摘要翻译：提供一种正极活性物质，即使在高温充电的情况下也能够提供具有高能量密度和优异的高倍率放电性能的电池，并且可以抑制电池性能的降低。还提供了使用正极活性物质的非水电解质电池。正极活性物质含有至少由锂（Li），锰（Mn），镍（Ni），钴（Co）和氧（O）构成的复合氧化物，由以下化学组成式表示：LiaMnbNicCodOe （其中0

17. 发明授权

US08153295B2 Positive electrode active material and its manufacturing method, positive electrode for lithium secondary cell using same, and lithium secondary cell 有权
标题翻译：正极活性物质及其制造方法，使用其的锂二次电池用正极和锂二次电池
公开(公告)号：US08153295B2
公开(公告)日：2012-04-10
申请号：US10564742
申请日：2004-07-13
申请人： Daisuke Endo , Akihiro Fujii , Ryuji Shiozaki , Tokuo Inamasu , Hiroe Nakagawa , Toshiyuki Nukuda
发明人： Daisuke Endo , Akihiro Fujii , Ryuji Shiozaki , Tokuo Inamasu , Hiroe Nakagawa , Toshiyuki Nukuda
IPC分类号： H01M4/13
CPC分类号： H01M4/525 , H01M4/485 , H01M4/505
摘要： A positive active material is provided which can inhibit side reactions between the positive electrode and an electrolyte even at a high potential and which, when applied to a battery, can improve charge/discharge cycle performance without impairing battery performances even in storage in a charged state. Also provided are: a process for producing the active material; a positive electrode for lithium secondary batteries which employs the active material; and a lithium secondary battery which has improved charge/discharge cycle performance while retaining intact battery performances even after storage in a charged state and which can exhibit excellent charge/discharge cycle performance even when used at a high upper-limit voltage. The positive active material comprises: base particles able to dope and release lithium ions; and an element in Group 3 of the periodic table present on at least part of that part of the base particles which is able to come into contact with an electrolyte. It is produced by, e.g., a process which comprises: producing base particles containing lithium and able to dope and release lithium ions; and then imparting an element in Group 3 of the periodic table to the base particles so that the element can be present on at least part of that part of the base particles which is able to come into contact with an electrolyte.
摘要翻译：提供一种正极活性物质，即使在高电位下也可以抑制正电极和电解质之间的副反应，并且当应用于电池时，即使在带电状态下的存储中也可以改善充电/放电循环性能而不损害电池性能。还提供了：生产活性材料的方法; 使用活性物质的锂二次电池用正极; 以及锂二次电池，即使在充电状态下保存后也能够保持完整的电池性能而具有改善的充放电循环性能，并且即使在高上限电压下使用也能表现出优异的充放电循环性能。正极活性物质包括：能够掺杂和释放锂离子的基础颗粒; 并且周期表的组3中的元素存在于能够与电解质接触的基础颗粒的该部分的至少一部分上。它通过例如包括：生产含锂的碱性颗粒并能够掺杂和释放锂离子的方法生产; 然后将元素在元素周期表的第3组中赋予基础颗粒，使得元素可以存在于能够与电解质接触的基础颗粒的那部分的至少一部分上。

18. 发明授权

US07393476B2 Positive electrode active material for lithium secondary cell and lithium secondary cell 有权
标题翻译：锂二次电池和锂二次电池用正极活性物质
公开(公告)号：US07393476B2
公开(公告)日：2008-07-01
申请号：US10486080
申请日：2002-11-12
申请人： Ryuji Shiozaki , Akihiro Fujii , Kazuya Okabe , Toshiyuki Nukuda
发明人： Ryuji Shiozaki , Akihiro Fujii , Kazuya Okabe , Toshiyuki Nukuda
IPC分类号： H01B1/00 , H01B1/12 , H01M4/02 , H01M4/58
CPC分类号： H01M4/131 , B82Y30/00 , C01G45/1228 , C01G51/44 , C01G51/50 , C01G53/44 , C01G53/50 , C01P2002/54 , C01P2002/60 , C01P2002/72 , C01P2002/74 , C01P2004/03 , C01P2004/04 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/40 , H01M4/1391 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/0525
摘要： A positive active material for lithium secondary batteries, includes a composite oxide including an oxide which is represented by the composite formula LixMnaNibCocO2 and has an α-NaFeO2 structure, and an impurity phase including Li2MnO3. The values a, b, and c are within such a range that in a ternary phase diagram showing the relationship among these, (a, b, c) is present on the perimeter of or inside the quadrilateral ABCD defined by point A (0.5, 0.5, 0), point B (0.55, 0.45, 0), point C (0.55, 0.15, 0.30), and point D (0.15, 0.15, 0.7) as vertexes, and 0.95
摘要翻译：锂二次电池用正极活性物质包括由复合氧化物构成的复合氧化物，该复合氧化物由复合氧化物Li x Mn 具有α-NaFeO 2 N 2结构，并且包含Li 2 MnO 2的杂质相， SUB> 3 。值a，b和c在这样的范围内，即在表示这些之间的关系的三元相图中，（a，b，c）存在于由点A（0.5， 0.5，0,0），点B（0.55,0.45,0），点C（0.55,0.15,0.30）和点D（0.15,0.15,0.7）作为顶点，并且0.95

19. 发明申请

US20060177739A1 Positive electrode active material and its manufacturing method, positive electrode for lithium secondary cell using same, and lithium secondary cell 有权
标题翻译：正极活性物质及其制造方法，使用其的锂二次电池用正极和锂二次电池
公开(公告)号：US20060177739A1
公开(公告)日：2006-08-10
申请号：US10564742
申请日：2004-07-13
申请人： Daisuke Endo , Akihiro Fujii , Ryuji Shiozaki , Tokuo Inamasu , Hiroe Nakagawa , Toshiyuki Nukuda
发明人： Daisuke Endo , Akihiro Fujii , Ryuji Shiozaki , Tokuo Inamasu , Hiroe Nakagawa , Toshiyuki Nukuda
IPC分类号： H01M4/58 , H01M4/52 , H01M4/50
CPC分类号： H01M4/525 , H01M4/485 , H01M4/505
摘要： A positive active material is provided which can inhibit side reactions between the positive electrode and an electrolyte even at a high potential and which, when applied to a battery, can improve charge/discharge cycle performance without impairing battery performances even in storage in a charged state. Also provided are: a process for producing the active material; a positive electrode for lithium secondary batteries which employs the active material; and a lithium secondary battery which has improved charge/discharge cycle performance while retaining intact battery performances even after storage in a charged state and which can exhibit excellent charge/discharge cycle performance even when used at a high upper-limit voltage. The positive active material comprises: base particles able to dope and release lithium ions; and an element in Group 3 of the periodic table present on at least part of that part of the base particles which is able to come into contact with an electrolyte. It is produced by, e.g., a process which comprises: producing base particles containing lithium and able to dope and release lithium ions; and then imparting an element in Group 3 of the periodic table to the base particles so that the element can be present on at least part of that part of the base particles which is able to come into contact with an electrolyte.
摘要翻译：提供一种正极活性物质，即使在高电位下也可以抑制正电极和电解质之间的副反应，并且当应用于电池时，即使在带电状态下的存储中也可以改善充电/放电循环性能而不损害电池性能。还提供了：生产活性材料的方法; 使用活性物质的锂二次电池用正极; 以及锂二次电池，即使在充电状态下保存后也能够保持完整的电池性能而具有改善的充放电循环性能，并且即使在高上限电压下使用也能表现出优异的充放电循环性能。正极活性物质包括：能够掺杂和释放锂离子的基础颗粒; 并且周期表的组3中的元素存在于能够与电解质接触的基础颗粒的该部分的至少一部分上。它通过例如包括：生产含锂的碱性颗粒并能够掺杂和释放锂离子的方法生产; 然后将元素在元素周期表的第3组中赋予基础颗粒，使得元素可以存在于能够与电解质接触的基础颗粒的那部分的至少一部分上。

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