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    • 13. 发明授权
    • Four layer cation exchange fluoropolymer membrane
    • 四层阳离子交换氟聚合物膜
    • US4983264A
    • 1991-01-08
    • US173041
    • 1988-03-28
    • Haruhisa MiyakeHiroaki ItoKoji SuzukiRyoji Yamada
    • Haruhisa MiyakeHiroaki ItoKoji SuzukiRyoji Yamada
    • C25B13/08C08J5/22C25B1/46
    • C25B1/46C08J5/2281C08J2327/18
    • A cation exchange fluoropolymer membrane comprising at least three integrally laminated layers including a main layer made of a perfluorocarbon polymer having carboxylic acid groups as its ion exchange groups with an ion exchange capacity of from 1.4 to 2.0 meq/g dry resin and having a thickness of from 50 to 250 .mu.m, a sulfonic acid film surface layer formed on one side of said main layer, made of a perfluorocarbon polymer having sulfonic acid groups as its ion exchange groups with an ion exchange capacity of from 0.5 to 1.5 meq/g dry resin and having a thickness of from 5 to 50 m, and a carboxylic acid film surface layer formed on the other side of said main layer, made of a perfluorcarbon polymer having carboxylic acid groups as its ion exchange groups with an ion exchange capacity of from 0.5 to 1.3 meq/g dry resin and having a thickness of from 5 to 50 .mu.m, said sulfonic acid film surface layer and carboxylic acid film surface layer constituting the outer-most layers, respectively.
    • 一种阳离子交换含氟聚合物膜,其包含至少三个整体层叠的层,所述层包括由具有羧酸基的全氟化碳聚合物制成的主层作为离子交换基团,离子交换容量为1.4-2.0meq / g干树脂,并且具有 50〜250μm,形成在所述主层一侧的磺酸膜表面层,由具有磺酸基的全氟化碳聚合物作为其离子交换容量为0.5〜1.5meq / g的离子交换基团 树脂,并且具有5至50μm的厚度,以及形成在所述主层的另一侧上的羧酸膜表面层,其由具有羧酸基团的全氟碳聚合物作为离子交换容量的离子交换容量 0.5〜1.3meq / g干树脂,厚度为5〜50μm,所述磺酸膜表面层和构成最外层的羧酸膜表面层各自 呃
    • 14. 发明授权
    • Process for producing potassium hydroxide
    • 生产氢氧化钾的方法
    • US4586992A
    • 1986-05-06
    • US733870
    • 1985-05-14
    • Haruhisa MiyakeHiroaki ItoKoji SuzukiRyoji Yamada
    • Haruhisa MiyakeHiroaki ItoKoji SuzukiRyoji Yamada
    • C08J5/22C25B1/46C25B9/00C25B9/08C25B13/02C25B13/08C25B1/10
    • C08J5/2281C25B1/46
    • A process for producing potassium hydroxide by electrolysis of potassium chloride in an electrolytic cell comprising an anode compartment and a cathode compartment partitioned by a cation exchange membrane, which process comprises supplying potassium chloride to the anode compartment for the electrolysis to form potassium hydroxide in the cathode compartment, characterized in that said cation exchange membrane is a multi-layer membrane comprising at least two layers including a main layer made of a perfluorocarbon polymer having carboxylic acid groups as its ion exchange groups with an ion exchange capacity of from 0.9 to 1.6 meq/g dry resin and having a thickness of from 80 to 300 .mu.m and a sulfonic acid film surface layer on the anode compartment side, made of a perfluorocarbon polymer having sulfonic acid groups as its ion exchange groups with an ion exchange capacity of from 0.5 to 1.5 meq/g dry resin and having a thickness of from 5 to 50 .mu.m.
    • 一种通过电解槽中电解氯化钾生产氢氧化钾的方法,该电解槽包括由阳离子交换膜分隔的阳极室和阴极室,该方法包括向阳极室供应氯化钾用于电解以在阴极中形成氢氧化钾 其特征在于,所述阳离子交换膜是包含至少两层的多层膜,所述层包括由具有羧酸基的离子交换基团的全氟化碳聚合物制成的主层,离子交换容量为0.9至1.6meq / g干树脂,厚度为80〜300μm,阳极室侧的磺酸膜表面层由具有磺酸基的离子交换容量为0.5〜 1.5meq / g干树脂,厚度为5至50μm。