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    • 12. 发明授权
    • Process for dyeing, in the gel state, fiber material composed of wet
spun acrylonitrile polymers using dyes with two basic groups
    • 在凝胶状态下染色的方法是使用具有两个碱性基团的染料由湿纺丙烯腈聚合物组成的纤维材料
    • US4563191A
    • 1986-01-07
    • US647269
    • 1984-09-04
    • Manfred HahnkeReinhard MohrKurt Hohmann
    • Manfred HahnkeReinhard MohrKurt Hohmann
    • D06P3/76C09B69/00D01F1/06D01F6/18D06P3/70C09B23/16D06F1/06D06P1/41
    • D06P3/702C09B69/001D01F1/06D01F6/18Y10S8/927
    • Fiber material composed of acid-modified homopolymers or copolymers of acrylonitrile (PAC fibers) which has been obtained by a wet spinning process, has not been dried and is still in a swollen condition (gel form), can be dyed advantageously and in fast colors by means of soluble dyes, the molecule of which contains several groups, namely more than one quaternary grouping and/or a strongly basic grouping carrying no charge, which exert a basic action towards the acid groups of the fiber substance. The chromophore of this colorant can belong to the category of monoazo or diazo dyes, methine, azamethine or diazamethine dyes or naphthalactam dyes.In accordance with the invention, after substantially removing the non-aqueous spinning solvent by washing, the spun material, as a moist gel, is dyed continuously or discontinuously from an aqueous dyebath; the fibers can be stretched before the dye is applied, during the dyeing process itself or immediately afterwards.By virtue of their special nature, the dyes of the type designated above, which have a strong fixing action, produce optimum fixing rates when dyeing PAC gels and, in the subsequent production stages, do not cause any noticeable soiling, as a result of dye which has bled out, on components of machines and operating baths, such as stretching or after-treatment baths. Investigations of penetration of the fiber by the dye, of the fixing rate and of the resulting fastness properties, such as fastness to wet processing, have shown no disadvantages compared with conventional dyes.
    • 由湿法纺丝法得到的酸改性均聚物或丙烯腈共聚物(PAC纤维)所组成的纤维材料未经干燥,仍处于溶胀状态(凝胶形式),可以有利地以快速染色 通过可溶性染料,其分子含有几个基团,即多于一个四元组和/或不带电荷的强碱基,其对纤维物质的酸基发挥基本作用。 这种着色剂的发色团可以属于单偶氮或重氮染料,次甲基,氮杂酮或二氮杂吗啉染料或萘胺染料。 根据本发明,通过洗涤基本上除去非水性纺丝溶剂后,作为湿凝胶的纺丝材料从水性染浴中连续或不连续地染色; 在染色过程本身之前或之后,纤维可以在施加染料之前被拉伸。 由于其特殊性质,具有强固定作用的上述类型的染料在染色PAC凝胶时产生最佳定影率,并且在随后的生产阶段中不会引起明显的污染,因为染料 已经排出了机器和操作浴的部件,如拉伸或后处理浴。 通过染料对纤维的渗透性,定影率和所得到的坚牢度性能的研究,例如湿法加工的坚牢度,与常规染料相比,没有显示出缺点。
    • 14. 发明授权
    • Substituted pyridine compounds
    • 取代的吡啶化合物
    • US3956294A
    • 1976-05-11
    • US521443
    • 1974-11-06
    • Erwin EleckensteinErnst HeinrichReinhard Mohr
    • Erwin EleckensteinErnst HeinrichReinhard Mohr
    • C07D401/06C07D401/12C07D413/04C07D295/12
    • C07D413/04C07D401/06C07D401/12
    • Compounds of the formula ##SPC1##Wherein X is aliphatic, cycloaliphatic, aromatic, aralkyl, hetaryl, hetarylalkyl or hydrogen; Y is aliphatic, aromatic, aralkyl, --COOR.sub.2, --COR.sub.2, ##EQU1## --CN, --NH.sub.2, --NO, --NO.sub.2 or hydrogen with the proviso that when Y is hydrogen, X is other than hydrogen; Z.sub.1 is cyano, ##EQU2## --OR.sub.12, --SR.sub.12 or --SO.sub.2 R.sub.12 and Z.sub.2 is chlorine, bromine, cyano, hydroxy, mercapto, ##EQU3## R.sub.1 is aliphatic; R.sub.2 is aliphatic, cycloaliphatic, aromatic, aralkyl or heterocyclic; R.sub.3 and R.sub.4 when taken separately are hydrogen, aliphatic, cycloaliphatic, aromatic or aralkyl; R.sub.3 and R.sub.4 when taken together with the nitrogen atom to which they are attached form a heterocyclic moiety; R.sub.5 and R.sub.6 when taken separately are aliphatic, aromatic, aralkyl, heterocyclic or hydrogen; R.sub.5 and R.sub.6 when taken together with the nitrogen atom to which they are attached are heterocyclic; R.sub.7 is hydrogen; aliphatic or aromatic; R.sub.8 and R.sub.9 are aliphatic or aromatic, R.sub.10 is hydrogen, aliphatic or aralkyl, R.sub.11 is aliphatc and R.sub.12 is aliphatic, aromatic or aralkyl; R.sub.10 and R.sub.11 when taken together with the nitrogen atom to which they are attached are heterocyclic.
    • 式WH的化合物是脂族,脂环族,芳族,芳烷基,杂芳基,杂芳基烷基或氢; Y是脂族,芳族,芳烷基,-COOR 2,-COR 2,R 3,R 3 -COOR 1,-COR 2,-CO-N ANGLE,-SO 2 R 2,-SO 2 -N取代基,R 4 R 4 -CN,-NH 2,-NO,-NO 2 或氢,条件是当Y是氢时,X不是氢; Z 1是氰基,R 5 R 7 R 8 OR 10 -N角,角NN,-NH-OR 10,-N角,R 6 R 11 R 11 -OR 12,-SR 12或-SO 2 R 12,Z 2是氯,溴,氰基,羟基,巯基, OR 12,-SR 12,-SO 2 R 12,-N ANGLE,R 6 R 7 R 8 OR 10 ANGLE NN ANGLE,-NH-OR 10或-N ANGLE R 9 R 11 R 1是脂族基; R2是脂族,脂环族,芳族,芳烷基或杂环; 单独使用时,R 3和R 4为氢,脂族,脂环族,芳族或芳烷基; 当与它们所连接的氮原子一起形成杂环部分时,R 3和R 4; R5和R6分别为脂族,芳族,芳烷基,杂环或氢时; 当与它们所连接的氮原子一起取代时,R 5和R 6是杂环的; R7是氢; 脂肪族或芳香族; R 8和R 9是脂族或芳族,R 10是氢,脂族或芳烷基,R 11是脂族基,R 12是脂族,芳族或芳烷基; 当与它们所连接的氮原子一起取代时,R 10和R 11是杂环的。
    • 16. 发明授权
    • Water-insoluble monoazo-dyestuffs for synthetic fibrous materials
    • 用于合成纤维材料的水不溶性单偶氮染料
    • US4160764A
    • 1979-07-10
    • US894177
    • 1978-04-06
    • Peter MischkeErwin FleckensteinReinhard Mohr
    • Peter MischkeErwin FleckensteinReinhard Mohr
    • C09B29/08C09B31/043C09B29/26C09B31/08
    • C09B29/0834C09B31/043
    • Azo-dyestuff of the formula ##STR1## in which D represents nitrophenylene, ##STR2## DINITRO-PHENYLENE, NITRO-CYANO-PHENYLENE, NITRO-CHLORO-PHENYLENE, NITRO-BROMO-PHENYLENE, TRICHLORO-PHENYLENE, NITRO-DICHLORO-PHENYLENE, DINITRO-CHLORO-PHENYLENE, DINITRO-CYANO-PHENYLENE, NITRO-BROMO-CYANO-PHENYLENE, DINITRO-BROMO-PHENYLENE, PHENYLAZO-PHENYLENE, ##STR3## R represents hydrogen, chlorine, lower alkyl, lower alkoxy, --O--CH.sub.2 --CN, --NH--CO--lower alkyl, --NH--COO lower alkyl or ##STR4## n stands for the integer 1 or 2, X represents cyano, --CO--NH.sub.2 or --COO-lower alkyl, R.sub.1 represents hydrogen, lower alkyl, lower alkylene-OH, lower alkylene-CN, lower alkylene-OCO-lower alkyl or lower alkenyl, and R.sub.2 represents lower alkyl, lower alkylene-O-CO-lower alkyl or lower alkylene-COO-lower alkyl, said dyestuffs being suitable for the dyeing or printing of synthetic fibrous materials, such as fibers of cellulose-di-, -21/2- or -triacetat, polyamides, polyurethanes, polyolefines, polycarbonates and particularly of linear polyesters, the dyeings or prints obtained being distinguished by a very good build up, tinctorial strength and a series of very good fastness properties.
    • 其中D表示硝基亚苯基,偶氮苯基,硝基 - 苯基,硝基 - 苯基,硝基 - 溴 - 苯基,三氯苯基,硝基 - 二氯苯,苯并噻吩, 四甲基氯苯,十一烷基 - 苯乙烯,硝基 - 溴 - 氰基 - 苯乙烯,十一烷基 - 苯乙烯,苯基 - 苯乙烯,<图像> <图像>&lt; IMA&gt;&gt;&gt; R代表氢,氯, 低级烷基,低级烷氧基,-O-CH 2 -CN,-NH-CO-低级烷基,-NH-COO低级烷基或n代表整数1或2,X代表氰基,-CO-NH 2或 - 低级烷基,R 1表示氢,低级烷基,低级亚烷基-OH,低级亚烷基-CN,低级亚烷基-OCO-低级烷基或低级烯基,R 2表示低级烷基,低级亚烷基-O-CO-低级烷基或低级烷基 亚烷基-COO-低级烷基,所述染料适用于合成纤维材料的染色或印刷,例如纤维素二 - ,二 - 或2-三乙酸纤维,聚酰胺,聚氨酯,聚烯烃,聚碳酸酯 特别是线性聚酯,所获得的染色或印花的特征在于非常好的聚集度,着色强度和一系列非常好的坚牢度性质。
    • 18. 发明授权
    • 2,6-Hydrazino-3-pyridine carboxyamides
    • 2,6-二肼-3-吡啶羧酰胺
    • US3954782A
    • 1976-05-04
    • US521408
    • 1974-11-06
    • Erwin FleckensteinErnst HeinrichReinhard Mohr
    • Erwin FleckensteinErnst HeinrichReinhard Mohr
    • C07D401/06C07D401/12C07D413/04C07D295/12
    • C07D413/04C07D401/06C07D401/12
    • Compounds of the formula ##SPC1##Wherein X is aliphatic, cycloaliphatic, aromatic, aralkyl, hetaryl, hetarylalkyl or hydrogen; Y is aliphatic, aromatic, aralkyl, --COOR.sub.1, --COR.sub.2, ##EQU1## --SO.sub.2 R.sub.2, ##EQU2## --CN, --NH.sub.2, --NO, --NO.sub.2 or hydrogen with the proviso that when Y is hydrogen, X is other than hydrogen; Z.sub.1 is cyano, ##EQU3## --NH--OR.sub.10, ##EQU4## --OR.sub.12, --SR.sub.12 or --SO.sub.2 R.sub.12 and Z.sub.2 is chlorine, bromine, cyano, hydroxy, mercapto, --OR.sub.12, --SR.sub.12, --SO.sub.2 R.sub.12, ##EQU5## --NH--OR.sub.10 or ##EQU6## R.sub.1 is aliphatic; R.sub.2 is aliphatic, cycloaliphatic, aromatic, aralkyl or heterocyclic; R.sub.3 and R.sub.4 when taken separately are hydrogen, aliphatic, cycloaliphatic, aromatic or aralkyl; R.sub.3 and R.sub.4 when taken together with the nitrogen atom to which they are attached form a heterocyclic moiety; R.sub.5 and R.sub.6 when taken separately are aliphatic, aromatic, aralkyl, heterocyclic or hydrogen; R.sub.5 and R.sub.6 when taken together with the nitrogen atom to which they are attached are heterocyclic; R.sub.7 is hydrogen, aliphatic or aromatic; R.sub.8 and R.sub.9 are aliphatic or aromatic, R.sub.10 is hydrogen, aliphatic or aralkyl, R.sub.11 is aliphatic and R.sub.12 is aliphatic, aromatic or aralkyl; R.sub.10 and R.sub.11 when taken together with the nitrogen atom to which they are attached are heterocyclic.
    • 式WH的化合物是脂族,脂环族,芳族,芳烷基,杂芳基,杂芳基烷基或氢; Y是脂族的,芳族的,芳烷基,-COOR 1,-COR 2,R 3 -CO-N角,R 4 -SO 2 R 2,R 3 -SO 2 -N取代基,R 4 -CN,-NH 2,-NO,-NO 2或氢,条件是 当Y是氢时,X不是氢; Z 1是氰基,R 5 -N ANGLE,R 6 R 7 R 8 ANGLE NN ANGLE,R 9 -NH-OR 10,OR 10 -N ANGLE,R 11 -OR 12,-SR 12或-SO 2 R 12,Z 2是氯,溴,氰基,羟基,巯基,-OR 12 ,-SR 12,-SO 2 R 12,R 5 -N,G 6,R 7 R 8, R11 R1是脂肪族的; R2是脂族,脂环族,芳族,芳烷基或杂环; 单独使用时,R 3和R 4为氢,脂族,脂环族,芳族或芳烷基; 当与它们所连接的氮原子一起形成杂环部分时,R 3和R 4; R5和R6分别为脂族,芳族,芳烷基,杂环或氢时; 当与它们所连接的氮原子一起取代时,R 5和R 6是杂环的; R7是氢,脂族或芳族; R8和R9是脂族或芳族的,R10是氢,脂族或芳烷基,R11是脂族的,R12是脂族的,芳族的或芳烷基; 当与它们所连接的氮原子一起取代时,R 10和R 11是杂环的。
    • 19. 发明授权
    • Process for spin-dyeing of acid-modified polymers of acrylonitrile by
the wet-spinning procedure using quaternary ammonium or cyclammonium
dyestuffs of low M value and high cation weight having two or three
said ammonium or cyclammonium groups
    • 使用具有低M值和高阳离子重量的季铵或环状铵染料通过湿法纺丝方法将丙烯腈的酸改性聚合物进行纺丝染色的方法,其具有两个或三个所述铵或环铵基团
    • US4557732A
    • 1985-12-10
    • US538800
    • 1983-10-04
    • Manfred HahnkeReinhard MohrKurt Hohmann
    • Manfred HahnkeReinhard MohrKurt Hohmann
    • D06P1/41C08K5/00C09B69/06D01F6/54D06P3/76D06P7/00D06P3/70
    • D01F6/54C08K5/0041C09B69/06Y10S534/01
    • Improvement of a process for spin-dyeing acid-modified polymers or copolymers of acrylonitrile in which cationic quaternary dyestuffs are added to the spinning mass and spun according to the wet-spinning procedure. The improvement is characterized by using dyestuffs characterized by a migration factor M of 20 or less than 20, by a combination index K of less than 2.5 and a cation weight of more than 310. Migration factor M and combination index K are known values in the dyestuff field or can be determined. The dyestuff to be used according to the invention can belong to the most different classes of dyestuffs; they fix rapidly on the polymer, and thus they do not color, or color only to a minor extent, the coagulation, stretching and washing baths although they are soluble in water and aqueous solutions of these baths. The fibers and filaments obtained by the process of the invention have outstanding fastnesses to wet processing and, owing to the absence of dyestuff aggregates at the surface of the fiber such as occur when spin-dyeing with pigments, very good fastnesses to dry and wet rubbing. The fibers are intense, absolutely transparent and free from specks.
    • 改进将染色酸改性聚合物或丙烯腈的共聚物的方法改进,其中将阳离子季染料加入到纺丝织物中并根据湿纺丝方法纺丝。 改进的特征在于使用迁移因子M为20或小于20的染料,组合指数K小于2.5,阳离子重量大于310.迁移因子M和组合指数K为 染料领域或可以确定。 根据本发明使用的染料可以属于最不同类型的染料; 它们快速固定在聚合物上,因此它们不会在凝固,拉伸和洗涤浴中颜色不浅或仅在较小程度上着色,尽管它们可溶于水和这些浴的水溶液。 通过本发明的方法获得的纤维和细丝具有优异的湿法加工牢度,并且由于在用颜料旋转染色时在纤维表面没有染料聚集体,因此具有非常好的干湿摩擦牢度 。 纤维是强烈的,绝对透明的,没有斑点。
    • 20. 发明授权
    • Process for dyeing uniformly polyacrylonitrile fiber materials
    • 均匀地染色聚丙烯腈纤维材料的方法
    • US4252535A
    • 1981-02-24
    • US16300
    • 1979-02-28
    • Norbert KollodzeiskiRudolf LowenfeldEberhard MundlosReinhard MohrKurt Hohmann
    • Norbert KollodzeiskiRudolf LowenfeldEberhard MundlosReinhard MohrKurt Hohmann
    • D06P3/76D06P3/70C09B27/00
    • D06P3/76Y10S534/01Y10S8/927
    • A dyeing process has been found which enables to dye uniformly polyacrylonitrile fiber materials, by using as dyestuffs basic azo dyestuffs being non-quarternized and containing neither cationic quaternary ammonium groups nor cationic N-substituted or N-unsubstituted iminium groups, said azo dyestuffs containing on the other hand at least one unsubstituted or substituted amino group, hydrazino group, amidino group or guanidino group capable of forming salts. The very dyeing process as such is carried out according to usual processing data for dyeing polyacrylonitriles in a slightly acid medium. Especially with the use of several of these dyestuffs for polychromic dyeing, such as trichromic dyeing, special advantages are obtained, insofar that even at cut-rate dyeing periods and for preparing light color shades, there are obtained even dyes with constant color shades, when using these dyestuffs having good migrating properties.
    • 已经发现染色工艺能够均匀地染色聚丙烯腈纤维材料,通过使用染色剂,碱性偶氮染料不被季铵化并且既不含阳离子季铵基团也不含阳离子N-取代或N-未取代的亚胺基团,所述偶氮染料含有 另一方面至少一个能够形成盐的未取代或取代的氨基,肼基,脒基或胍基。 根据通常的加工数据,在微酸性介质中染色聚丙烯腈进行染色。 特别是使用这些染料中的几种用于多色染色,如三色染色,得到了特殊的优点,即使在切割染色期间和用于制备浅色色调的情况下,甚至获得具有恒定色调的均匀染料,当 使用具有良好迁移性能的这些染料。