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11. 发明申请

US20090238744A1 Catalyst System for CO-Removal 审中-公开
标题翻译：用于CO去除的催化剂体系
公开(公告)号：US20090238744A1
公开(公告)日：2009-09-24
申请号：US12406647
申请日：2009-03-18
申请人： Albert N. Chigapov , Brendan Patrick Carberry
发明人： Albert N. Chigapov , Brendan Patrick Carberry
IPC分类号： B01D53/62
CPC分类号： B01J35/0006 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/1026 , B01D2255/1028 , B01D2255/206 , B01D2255/2073 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20761 , B01D2256/12 , B01D2256/16 , B01D2257/502 , B01J23/8892 , B01J23/8913 , B01J35/04 , C01B3/583 , C01B2203/044 , C01B2203/047 , H01M8/0668
摘要： The invention relates to a catalyst system for the removal of carbon monoxide from a hydrogen containing feed gas. The system includes a first catalyst optimised to selectively oxidize carbon monoxide in the feed gas at temperatures below 100° C. The system also includes a second catalyst, downstream from the first catalyst, optimised to selectively oxidize carbon monoxide in the feed gas at temperatures above 100° C., the second catalyst having a higher carbon monoxide conversion rate than the first catalyst at 100° C.
摘要翻译：本发明涉及一种用于从含氢原料气中除去一氧化碳的催化剂体系。该系统包括优化的第一催化剂，其在低于100℃的温度下选择性地氧化进料气体中的一氧化碳。该系统还包括在第一催化剂的下游的第二催化剂，其被优化以在进料气体中选择性地氧化一氧化碳 100℃，第二催化剂在100℃下的一氧化碳转化率高于第一催化剂。

12. 发明授权

US07030054B2 PGM-free washcoats for catalyzed diesel particulate filter applications 有权
标题翻译：用于催化柴油颗粒过滤器应用的无PGM的洗涂层
公开(公告)号：US07030054B2
公开(公告)日：2006-04-18
申请号：US10418767
申请日：2003-04-18
申请人： Albert N Chigapov , Alexei A Dubkov , Brendan Patrick Carberry , Robert Walter McCabe
发明人： Albert N Chigapov , Alexei A Dubkov , Brendan Patrick Carberry , Robert Walter McCabe
IPC分类号： B01J23/00 , B01J23/58 , B01J23/72 , B01J23/70 , B01J23/74
CPC分类号： F01N3/035 , B01D53/945 , B01D2255/104 , B01D2255/20746 , B01D2257/404 , B01D2257/502 , B01D2257/702 , B01J23/002 , B01J23/66 , B01J23/68 , B01J23/688 , B01J23/83 , B01J23/894 , B01J23/8986 , B01J37/0244 , B01J2523/00 , F01N3/023 , F01N2510/06 , Y02A50/2324 , Y02T10/22 , Y10S502/525 , B01J2523/18 , B01J2523/3706 , B01J2523/3737 , B01J2523/72
摘要： The present invention provides new platinum group metal (“PGM”) free catalytic compositions that comprise silver and/or cobalt stabilized ceria. These compositions facilitate soot oxidation during the regeneration of diesel particulate filters (DPF) thereby replacing PGM formulations. The compositions of the invention are particularly useful as washcoat compositions for DPFs as part of an automotive after-treatment system. Among the formulations tested, the silver-stabilized ceria and cobalt-stabilized ceria formulations e.g. can oxidize soot at 250–300° C. in the presence of NO2 and oxygen, while silver-stabilized ceria can oxidize diesel soot even in the presence of oxygen as the sole oxidizing agent at these temperatures. A perovshite composition containing Ag—La—Mn was very active at temperatures above 300° C.
摘要翻译：本发明提供了包含银和/或钴稳定的二氧化铈的新的铂族金属（“PGM”）催化组合物。这些组合物在柴油颗粒过滤器（DPF）的再生期间促进烟灰氧化，从而替代PGM制剂。作为汽车后处理系统的一部分，本发明的组合物特别可用作DPF的修补基面涂料组合物。在所测试的制剂中，银稳定的二氧化铈和钴稳定的二氧化铈制剂例如可以在NO 2 2和氧的存在下在250-300℃下氧化烟灰，而在这些温度下，即使在作为唯一氧化剂的氧的存在下，银稳定的二氧化铈也可以氧化柴油烟灰。含有Ag-La-Mn的钙钛矿组合物在高于300℃的温度下非常活泼

13. 发明申请

US20080227629A1 OXIDATION CATALYSTS 失效
标题翻译：氧化催化剂
公开(公告)号：US20080227629A1
公开(公告)日：2008-09-18
申请号：US12044578
申请日：2008-03-07
申请人： Albert N. Chigapov , Brendan Patrick Carberry
发明人： Albert N. Chigapov , Brendan Patrick Carberry
IPC分类号： B01J29/068 , B01J23/10 , B05D3/00
CPC分类号： B01J23/894 , B01D53/944 , B01D2255/1021 , B01D2255/1023 , B01D2255/206 , B01D2255/20738 , B01D2255/20746 , B01J23/63 , B01J23/8913 , B01J37/0203 , B01J37/0248 , F01N3/10 , F01N2510/06
摘要： The present invention relates to an oxidation catalyst comprising a substrate and an oxidation coating of platinum (Pt), palladium (Pd), cobalt (Co), iron (Fe) and cerium (Ce) applied to the substrate. Furthermore the invention relates to a method for producing such an oxidation catalyst and an internal combustion engine using such an oxidation catalyst.
摘要翻译：本发明涉及一种氧化催化剂，其包含基材和施加到基材上的铂（Pt），钯（Pd），钴（Co），铁（Fe）和铈（Ce）的氧化涂层。此外，本发明涉及使用这种氧化催化剂制造这种氧化催化剂和内燃机的方法。

14. 发明授权

US06813884B2 Method of treating diesel exhaust gases 有权
标题翻译：处理柴油机废气的方法
公开(公告)号：US06813884B2
公开(公告)日：2004-11-09
申请号：US09683642
申请日：2002-01-29
申请人： Albert Nazipovich Shigapov , Brendan Patrick Carberry , Robert Walter McCabe
发明人： Albert Nazipovich Shigapov , Brendan Patrick Carberry , Robert Walter McCabe
IPC分类号： F01N300
CPC分类号： B01D53/9418 , B01D2251/2062 , B01D2251/2067 , B01D2251/208 , B01D2255/1021 , F01N3/0231 , F01N3/035 , F01N3/206 , F01N13/009 , F01N2570/14 , F01N2610/02 , F01N2610/08
摘要： A diesel exhaust treatment system and method of oxidizing NO to NO2 at low temperatures are provided. The system utilizes a platinum catalyst on a zirconia-stabilized silica support which oxidizes NO in the exhaust gas to NO2 and uses the NO2 in an amount sufficient to oxidize particulate trapped on a particulate filter. The catalyst is preferably pre-treated at a temperature of between about 500 to 650° C. in a NO-oxygen-nitrogen mixture to increase conversion at low temperatures. The catalyst preferably includes an additional oxide component selected from the group consisting of TiO2, P2O5, WO3, B2O3, and Al2O3. or a heteropolyacid component to further increase activity at low temperatures or to decrease platinum loading at the same level of performance.

15. 发明授权

US08833060B2 Method for operating a spark-ignition internal combustion engine with exhaust gas aftertreatment 有权
标题翻译：用排气后处理操作火花点火式内燃机的方法
公开(公告)号：US08833060B2
公开(公告)日：2014-09-16
申请号：US13402797
申请日：2012-02-22
申请人： Helmut Hans Ruhland , Moritz Klaus Springer , Brendan Patrick Carberry
发明人： Helmut Hans Ruhland , Moritz Klaus Springer , Brendan Patrick Carberry
IPC分类号： F01N3/00 , F01N3/10 , F01N3/02 , F01N9/00 , F02D37/02 , F01N3/023 , F02D41/02 , F02D41/14 , F02D41/40 , F02D41/00
CPC分类号： F01N9/002 , F01N3/023 , F01N3/101 , F01N2430/06 , F02D37/02 , F02D41/0055 , F02D41/0245 , F02D41/029 , F02D41/1448 , F02D41/405 , F02D2200/0812 , Y02T10/22 , Y02T10/26 , Y02T10/44 , Y02T10/47
摘要： Embodiments for regenerating a particle filter are provided. In one example, a method includes operating a spark-ignition internal combustion engine having a particle filter for collecting and burning soot particles in exhaust gas comprises in order to initiate regeneration of the particle filter. The method may include, in response to a regeneration condition, increasing exhaust temperature by retarding spark timing and once regeneration is reached, operating the engine with lean combustion to regenerate the particle filter, where a degree of leanness is based on each of a state of the filter and an upstream three-way catalyst.
摘要翻译：提供了用于再生颗粒过滤器的实施例。在一个实例中，一种方法包括操作具有用于收集和燃烧废气中的烟灰颗粒的颗粒过滤器的火花点火内燃机，以便启动颗粒过滤器的再生。该方法可以包括响应于再生条件，通过延迟火花正时而增加排气温度，并且一旦达到再生，则以稀燃燃烧来操作发动机以再生颗粒过滤器，其中一级的稀薄度基于过滤器和上游三通催化剂。

16. 发明申请

US20120210699A1 METHOD FOR OPERATING A SPARK-IGNITION INTERNAL COMBUSTION ENGINE WITH EXHAUST GAS AFTERTREATMENT 有权
标题翻译：使用排气后处理的火花点火内燃机的方法
公开(公告)号：US20120210699A1
公开(公告)日：2012-08-23
申请号：US13402797
申请日：2012-02-22
申请人： Helmut Hans Ruhland , Moritz Klaus Springer , Brendan Patrick Carberry
发明人： Helmut Hans Ruhland , Moritz Klaus Springer , Brendan Patrick Carberry
IPC分类号： F01N3/035
CPC分类号： F01N9/002 , F01N3/023 , F01N3/101 , F01N2430/06 , F02D37/02 , F02D41/0055 , F02D41/0245 , F02D41/029 , F02D41/1448 , F02D41/405 , F02D2200/0812 , Y02T10/22 , Y02T10/26 , Y02T10/44 , Y02T10/47
摘要： Embodiments for regenerating a particle filter are provided. In one example, a method for operating a spark-ignition internal combustion engine having a particle filter for collecting and burning soot particles in exhaust gas comprises in order to initiate regeneration of the particle filter, increasing a particle filter temperature Tfilter to such an extent that Tfilter≧TReg, wherein TReg is a predefinable minimum regeneration temperature, and operating the internal combustion engine superstoichiometrically (λ>1).
摘要翻译：提供了用于再生颗粒过滤器的实施例。在一个示例中，用于操作具有用于在废气中收集和燃烧烟灰颗粒的颗粒过滤器的火花点火内燃机的方法包括为了开始颗粒过滤器的再生，将颗粒过滤器温度Tfilter增加到如下程度的程度： Tfilter≧TReg，其中TReg是预定义的最小再生温度，并且在超分子量（λ> 1）下操作内燃机。

17. 发明授权

US07797931B2 Catalyst composition for diesel particulate filter 有权
标题翻译：柴油颗粒过滤器的催化剂组成
公开(公告)号：US07797931B2
公开(公告)日：2010-09-21
申请号：US11766397
申请日：2007-06-21
申请人： Alexei A Dubkov , Albert N Chigapov , Brendan Patrick Carberry
发明人： Alexei A Dubkov , Albert N Chigapov , Brendan Patrick Carberry
IPC分类号： F01N3/10 , F01N3/021 , B01J23/40 , B01J21/00 , B01J8/02
CPC分类号： B01D53/944 , B01D2255/102 , B01D2255/206 , B01D2255/20761 , B01D2255/40 , B01J23/894 , B01J37/0201 , B01J37/038 , F01N3/0231 , Y02A50/2345
摘要： A catalyst composition is provided for use on a diesel particulate filter which facilitates the oxidation of soot from diesel engine exhaust and which generates low NO2 emissions during regeneration of the filter. The catalyst composition includes a catalytic metal comprising a platinum group metal selected from Pt, Pd, Pt—Pd, or combinations thereof, an active metal oxide component containing Cu and La; and an oxide component selected from oxides of Co, Fe, or combinations thereof. The catalyst composition includes a support selected from alumina, silica, zirconia, or combinations thereof. The catalyst composition may be provided on a diesel particulate filter by impregnating the filter with an alumina, silica or zirconia sol solution modified with glycerol and/or saccharose, impregnating the filter with a stabilizing solution, and impregnating the filter with a solution containing the catalyst metal precursor(s), the active metal oxide precursor(s) and the Co or Fe oxide(s). The resulting catalyst coated diesel particulate filter provides effective soot oxidation, exhibits good thermal stability, has a high BET surface area, exhibits minimal backpressure, and produces low NO2 emissions during filter regeneration.
摘要翻译：提供了一种用于柴油微粒过滤器的催化剂组合物，该柴油颗粒过滤器有利于烟灰从柴油发动机排气中氧化并且在过滤器再生期间产生低NO 2排放。催化剂组合物包括含有选自Pt，Pd，Pt-Pd或其组合的铂族金属的催化金属，含有Cu和La的活性金属氧化物组分; 和选自Co，Fe的氧化物或其组合的氧化物组分。催化剂组合物包括选自氧化铝，二氧化硅，氧化锆或其组合的载体。可以通过用用甘油和/或蔗糖改性的氧化铝，二氧化硅或氧化锆溶胶溶液浸渍过滤器，将催化剂组合物提供在柴油机微粒过滤器上，用稳定溶液浸渍过滤器，并用含有催化剂的溶液浸渍过滤器金属前体，活性金属氧化物前体和Co或Fe氧化物。所得催化剂涂覆的柴油颗粒过滤器提供有效的烟灰氧化，显示出良好的热稳定性，具有高的BET表面积，表现出最小的背压，并且在过滤器再生期间产生低的NO 2排放。

18. 发明授权

US06497095B2 Regeneration of diesel engine particulate filter only above low fuel levels 有权
标题翻译：柴油发动机颗粒过滤器的再生仅在燃油水平以上
公开(公告)号：US06497095B2
公开(公告)日：2002-12-24
申请号：US09745359
申请日：2000-12-21
申请人： Brendan Patrick Carberry , David Arthur Ketcher , Paul Eduard Moraal
发明人： Brendan Patrick Carberry , David Arthur Ketcher , Paul Eduard Moraal
IPC分类号： F01N300
CPC分类号： F01N3/0842 , F01N3/023 , F01N3/035 , F01N9/002 , F01N2250/02 , F02B37/00 , F02D41/0007 , F02D41/0055 , F02D41/024 , F02D41/029 , F02D41/1448 , F02D41/1456 , F02D41/187 , F02D41/405 , F02D2009/0237 , F02D2200/0404 , F02D2200/0414 , F02D2200/0812 , F02M26/05 , Y02T10/144 , Y02T10/26 , Y02T10/44 , Y02T10/47
摘要： A filter used to remove particulates from a diesel engine exhaust is regenerated by increasing the exhaust temperature to achieve burn off of the accumulated particulates. Regeneration of the filter is inhibited when the sensed level of fuel in a diesel fuel tank for the engine falls below a first threshold level. Optionally, filter regeneration may be initiated when the sensed fuel level is between the first threshold and a higher threshold, and the load level of particulates accumulated in said filter is above a preselected, relatively high load level. Increase of the exhaust temperature to achieve burn off may be achieved by a variety of techniques, including throttling the intake of said engine, reducing the oxygen content in the exhaust gases delivered to said engine, closing an EGR valve of said engine, or performing post injection of fuel in the engine's combustion cylinders.
摘要翻译：用于从柴油发动机排气中去除颗粒物的过滤器通过增加废气温度来再生，以实现累积的颗粒物的燃尽。当用于发动机的柴油机油箱中感测到的燃料水平低于第一阈值水平时，过滤器的再生被抑制。可选地，当感测到的燃料水平处于第一阈值和较高阈值之间时，可以启动过滤器再生，并且累积在所述过滤器中的微粒的负载水平高于预选的相对较高的负载水平。可以通过各种技术实现排气温度的提高，包括节流所述发动机的进气，减少输送到所述发动机的废气中的氧含量，关闭所述发动机的EGR阀或执行后处理在发动机的燃烧缸中喷射燃料。

19. 发明授权

US06405528B1 Method for determining load on particulate filter for engine exhaust, including estimation of ash content 有权
标题翻译：确定发动机排气微粒过滤器负荷的方法，包括灰分估计
公开(公告)号：US06405528B1
公开(公告)日：2002-06-18
申请号：US09716650
申请日：2000-11-20
申请人： Urs Christen , Brendan Patrick Carberry , Paul Eduard Moraal
发明人： Urs Christen , Brendan Patrick Carberry , Paul Eduard Moraal
IPC分类号： F01N300
CPC分类号： F01N11/002 , F01N3/035 , F01N9/002 , F01N13/0097 , F01N2550/04 , F01N2560/08 , F02B29/0406 , F02B37/22 , F02D2200/0812 , F02M26/05 , F02M26/23 , Y02T10/47
摘要： A method for determining the load on an internal combustion engine exhaust particulate filter optimizes filter regeneration by determining the portion of the filter load constituted by accumulated ash. In one technique, the ash load is determined by recording the lowest value of DPF load over a time or distance interval. In another technique, an estimate is made of the amount of load remaining at each of a plurality of DPF regeneration events; the amount of remaining load immediately following the regeneration event corresponds to the amount of accumulated ash in the DPF. DPF load estimation is performed using equations for laminar or turbulent flow in pipes. These equations establish a linear or quadratic relationship between the flow through the DPF and the pressure drop measured across it.
摘要翻译：用于确定内燃机排气微粒过滤器上的载荷的方法通过确定由累积灰分构成的过滤器负载的部分来优化过滤器再生。在一种技术中，通过在时间或距离间隔上记录DPF负载的最低值来确定灰载荷。在另一种技术中，估计在多个DPF再生事件中的每一个处剩余的负载量; 紧接在再生事件之后的剩余负荷量对应于DPF中积累的灰分量。 DPF负荷估计使用管道中层流或湍流的方程来执行。这些方程在通过DPF的流量与在其间测量的压降建立了线性或二次关系。

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