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11. 发明授权

US4336403A Preparation of methyl methacrylate by reaction of methyl propionate and methanol 失效
标题翻译：通过丙酸甲酯和甲醇的反应制备甲基丙烯酸甲酯
公开(公告)号：US4336403A
公开(公告)日：1982-06-22
申请号：US228284
申请日：1981-01-26
申请人： Franz Merger , Gerd Fouquet
发明人： Franz Merger , Gerd Fouquet
IPC分类号： B01J27/00 , C07B61/00 , C07C69/54 , C07C67/343
CPC分类号： C07C69/54 , Y02P20/582
摘要： Methyl methacrylate is prepared by reacting methyl propionate and methanol at 200.degree.-550.degree. C. over a catalyst mixture which has a condensing action and is capable of dehydrogenating methanol to formaldehyde.
摘要翻译：甲基丙烯酸甲酯是通过使甲酸丙酯和甲醇在200-550℃下反应制得的，该催化剂混合物具有冷凝作用并且能够将甲醇脱氢成甲醛。

12. 发明授权

US4354045A Preparation of formaldehyde 失效
标题翻译：甲醛的制备
公开(公告)号：US4354045A
公开(公告)日：1982-10-12
申请号：US221822
申请日：1980-12-31
申请人： Franz Merger , Gerd Fouquet
发明人： Franz Merger , Gerd Fouquet
IPC分类号： B01J23/80 , B01J27/057 , C07C45/00 , C07C47/052 , C07C45/51 , C07C45/65
CPC分类号： B01J27/0576 , B01J23/80 , C07C45/002
摘要： Formaldehyde is prepared by dehydrogenation of methanol in the presence of a catalyst containing copper, zinc and tellurium, at from 300.degree. to 750.degree. C.The formaldehyde obtainable by the process of the invention is a disinfectant, tanning agent, reducing agent and valuable starting material for the preparation of synthetic resins, adhesives, plastics and auxiliaries in numerous sectors of industry.
摘要翻译：甲醛通过甲醇在含有铜，锌和碲的催化剂存在下在300℃至750℃下脱氢而制备。通过本发明方法获得的甲醛是消毒剂，鞣剂，还原剂和有价值的起始物用于制造许多行业的合成树脂，粘合剂，塑料和助剂的材料。

13. 发明授权

US4560822A Preparation of dienes by dehydration of aldehydes 失效
标题翻译：通过醛脱水制备二烯
公开(公告)号：US4560822A
公开(公告)日：1985-12-24
申请号：US730687
申请日：1985-05-03
申请人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Gerd Fouquet
发明人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Gerd Fouquet
IPC分类号： C07C11/12 , B01J29/00 , C07B61/00 , C07C1/00 , C07C1/24 , C07C11/18 , C07C13/21 , C07C13/23 , C07C45/50 , C07C67/00
CPC分类号： C07C1/24 , C07C2101/16 , C07C2529/06 , C07C2529/86 , C07C2529/88
摘要： Dienes are prepared by dehydration of aldehydes at elevated temperatures by a method in which the dehydration is carried out using a zeolite as a catalyst.
摘要翻译：二烯通过使用沸石作为催化剂进行脱水的方法在升高的温度下脱醛而制备。

14. 发明授权

US4118588A Manufacture of methacrylic acid and methyl methacrylate 失效
标题翻译：制造甲基丙烯酸和甲基丙烯酸甲酯
公开(公告)号：US4118588A
公开(公告)日：1978-10-03
申请号：US781149
申请日：1977-03-25
申请人： Gerd Fouquet , Franz Merger , Rolf Platz , Karl Baer
发明人： Gerd Fouquet , Franz Merger , Rolf Platz , Karl Baer
IPC分类号： C07C69/54 , B01J21/00 , B01J23/00 , B01J27/00 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/353 , C07C57/04 , C07C67/00 , C07C69/52
CPC分类号： C07C51/353
摘要： Methacrylic acid and methyl methacrylate are manufactured by reacting, respectively, propionic acid and methyl propionate with dimethoxymethane in the presence of catalysts based on phosphates and/or silicates of magnesium, calcium, aluminum, zirconium, thorium and/or titanium, and in the presence of from 0 to 0.5 mole of water per mole of the acetal.
摘要翻译：甲基丙烯酸和甲基丙烯酸甲酯通过在基于镁，钙，铝，锆，钍和/或钛的磷酸盐和/或硅酸盐的催化剂存在下，分别使丙酸和丙酸甲酯与二甲氧基甲烷反应制备，并且在存在下每摩尔缩醛为0至0.5摩尔水。

15. 发明授权

US4487962A Preparation of methacrylic acid by gas phase oxidation of methacrolein 失效
标题翻译：甲基丙烯醛气相氧化制备甲基丙烯酸
公开(公告)号：US4487962A
公开(公告)日：1984-12-11
申请号：US424553
申请日：1982-09-27
申请人： Richard Krabetz , Franz Merger , Matthias Schwarzmann
发明人： Richard Krabetz , Franz Merger , Matthias Schwarzmann
IPC分类号： B01J23/887 , B01J23/89 , B01J27/19 , B01J27/198 , B01J27/199 , C01B25/45 , C07B61/00 , C07C51/00 , C07C51/235 , C07C51/25 , C07C57/055 , C07C67/00
CPC分类号： B01J23/002 , B01J23/8877 , B01J23/8993 , B01J27/199 , C07C51/252 , B01J2523/00
摘要： An oxidation catalyst wherein the catalytically active component has the general formulaMo.sub.12 P.sub.a Rh.sub.b Cu.sub.c V.sub.d Cs.sub.e X.sub.f Y.sub.g Z.sub.h O.sub.x,where X is Cr and/or Fe, Y is Nb, Z is Na, Li, K and/or Rb, a is 0.1-4, b is 0.001-1, c is 0.05-2, d is 0.05-4, e is 0.1-5, f is 0-2, g is 0-3 and h is 0-2, and x is the number of oxygen atoms required to saturate the valencies of the other constituents, is very suitable for the preparation of methacrylic acid by gas phase oxidation of methacrolein with an oxygen-containing and steam-containing gas mixture.
摘要翻译：一种氧化催化剂，其中催化活性组分具有通式Mo 12 PaRhbCucVdCseXfYgZhOx，其中X是Cr和/或Fe，Y是Nb，Z是Na，Li，K和/或Rb，a是0.1-4，b是0.001-1 ，c为0.05-2，d为0.05-4，e为0.1-5，f为0-2，g为0-3，h为0-2，x为饱和化合物所需的氧原子数的其它成分非常适合用含氧和含蒸汽的气体混合物气相氧化甲基丙烯醛来制备甲基丙烯酸。

16. 发明授权

US4409128A Oxidation catalyst, especially for the preparation of methacrylic acid by gas phase oxidation of methacrolein 失效
标题翻译：氧化催化剂，特别是通过气相氧化甲基丙烯醛制备甲基丙烯酸
公开(公告)号：US4409128A
公开(公告)日：1983-10-11
申请号：US283633
申请日：1981-07-15
申请人： Richard Krabetz , Franz Merger , Matthias Schwarzmann
发明人： Richard Krabetz , Franz Merger , Matthias Schwarzmann
IPC分类号： B01J23/887 , B01J23/89 , B01J27/19 , B01J27/198 , B01J27/199 , C01B25/45 , C07B61/00 , C07C51/00 , C07C51/235 , C07C51/25 , C07C57/055 , C07C67/00 , B01J27/14
CPC分类号： B01J23/002 , B01J23/8877 , B01J23/8993 , B01J27/199 , C07C51/252 , B01J2523/00
摘要： An oxidation catalyst wherein the catalytically active component has the general formulaMo.sub.12 P.sub.a Rh.sub.b Cu.sub.c V.sub.d Cs.sub.e X.sub.f Y.sub.g Z.sub.h O.sub.x,where X is Cr and/or Fe, Y is Nb, Z is Na, Li, K and/or Rb, a is 0.1-4, b is 0.001-1, c is 0.05-2, d is 0.05-4, e is 0.1-5, f is 0-2, g is 0-3 and h is 0-2, and x is the number of oxygen atoms required to saturate the valencies of the other constituents, is very suitable for the preparation of methacrylic acid by gas phase oxidation of methacrolein with an oxygen-containing and steam-containing gas mixture.
摘要翻译：一种氧化催化剂，其中催化活性组分具有通式Mo 12 PaRhbCucVdCseXfYgZhOx，其中X是Cr和/或Fe，Y是Nb，Z是Na，Li，K和/或Rb，a是0.1-4，b是0.001-1 ，c为0.05-2，d为0.05-4，e为0.1-5，f为0-2，g为0-3，h为0-2，x为饱和化合物所需的氧原子数的其它成分非常适合用含氧和含蒸汽的气体混合物气相氧化甲基丙烯醛来制备甲基丙烯酸。

17. 发明授权

US5689010A Preparation of higher aldehydes 失效
标题翻译：制备较高级的醛
公开(公告)号：US5689010A
公开(公告)日：1997-11-18
申请号：US638592
申请日：1996-04-29
申请人： Rocco Paciello , Franz Merger , Michael Roper , Heinz-Josef Kneuper
发明人： Rocco Paciello , Franz Merger , Michael Roper , Heinz-Josef Kneuper
IPC分类号： B01J31/22 , C07B61/00 , C07C45/50 , C07C45/62 , C07C45/73 , C07C45/74 , C07C47/02 , C07C47/21 , C07C45/49
CPC分类号： C07C45/50 , C07C45/62 , C07C45/74
摘要： Aldehydes with a higher number of carbon atoms and high selection are prepared by reacting olefins, in particular from petrochemical refinery products, by a hydroformylation with aldol condensation using a mixed catalyst of rhodium-carbonyl-phosphines and Mannich catalyst.
摘要翻译：通过使用铑 - 羰基膦和Mannich催化剂的混合催化剂通过使醛醇缩合的加氢甲酰化反应，使烯烃，特别是石油化学品炼油产物反应，制备具有较高碳原子数和高选择性的醛。

18. 发明授权

US5416240A Preparation of poloxy-alkylene glycols 失效
标题翻译：烷氧基 - 亚烷基二醇的制备
公开(公告)号：US5416240A
公开(公告)日：1995-05-16
申请号：US24903
申请日：1993-03-02
申请人： Hans-Juergen Weyer , Rolf Fischer , Gerhard Jeschek , Franz Merger , Herbert Mueller
发明人： Hans-Juergen Weyer , Rolf Fischer , Gerhard Jeschek , Franz Merger , Herbert Mueller
IPC分类号： C08G65/02 , C08G65/08 , C08G65/16 , C08G65/20 , C07C41/01 , C07C41/02
CPC分类号： C08G65/20
摘要： Polyoxyalkylene glycols are prepared by a process in which tetrahydrofuran is polymerized with a total of not more than 95 mol %, based on the amount of tetrahydrofuran used, of one or more comonomers from the group consisting of the cyclic ethers and acetals in the absence of water and in the presence of a monohydric alcohol or of a monocarboxylic acid with the aid of an anhydrous heteropoly acid catalyst, and the polyoxyalkylene glycol is liberated from the resulting polyoxyalkylene glycol monoethers or polyoxyalkylene glycol monoesters by cleavage of the monoether or monoester bond.
摘要翻译：聚氧亚烷基二醇通过以下方法制备，其中四氢呋喃基于所用四氢呋喃的总量不超过95摩尔％，在不存在共聚单体的情况下聚合来自由环醚和缩醛组成的组中的一种或多种共聚单体水和一元醇或单羧酸存在下，借助于无水杂多酸催化剂，通过裂解单醚或单酯键，从所得聚氧亚烷基二醇单醚或聚氧亚烷基二醇单酯中释放出聚氧亚烷基二醇。

19. 发明授权

US5268499A Preparation of mixtures of 3-aminopropionitrile and ethylene cyanohydrin 失效
标题翻译：制备3-氨基丙腈和乙烯氰醇的混合物
公开(公告)号：US5268499A
公开(公告)日：1993-12-07
申请号：US47303
申请日：1993-04-19
申请人： Franz Merger , Martin Brudermueller , Wolfgang Harder , Juergen Hartig , Dieter Franz
发明人： Franz Merger , Martin Brudermueller , Wolfgang Harder , Juergen Hartig , Dieter Franz
IPC分类号： C07C253/30
CPC分类号： C07C253/30
摘要： A process for preparing mixtures of 3-aminopropionitrile of the formula IH.sub.2 N--CH.sub.2 --CH.sub.2 --CN (I)and ethylene cyanohydrin of the formula IIHO--CH.sub.2 --CH.sub.2 --CN (II)comprises reacting bis(2-cyanoethyl) ether of the formula IIINC--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --CN (III)with ammonia at from 50 to 170.degree. C. and under from 1 to 500 bar thermally or in the presence of a heterogeneous catalyst.
摘要翻译：制备式I H 2 N-CH 2 -CH 2 -N（I）的3-氨基丙腈和式II HO-CH2-CH2-CN（Ⅱ）的乙烯氰醇的混合物的方法包括使双（2-氰乙基）醚式III NC-CH2-CH2-O-CH2-CH2-CN（III）与氨在50至170℃下和在1至500巴下加热或在多相催化剂存在下反应。

20. 发明授权

US5256813A 3-substituted 2-hydroxy-3-formylpropionic esters, the preparation thereof and the use thereof for preparing 3-substituted 3-formylacrylic esters 失效
标题翻译： 3-取代的2-羟基-3-甲酰基丙酸酯，其制备及其用于制备3-取代的3-甲酰基丙烯酸酯的用途
公开(公告)号：US5256813A
公开(公告)日：1993-10-26
申请号：US883342
申请日：1992-05-15
申请人： Franz Merger , Juergen Frank
发明人： Franz Merger , Juergen Frank
IPC分类号： C07C69/675 , C07C69/732
CPC分类号： C07C69/675
摘要： A 3-substituted 2-hydroxy-3-formylpropionic ester of the formula I ##STR1## where R.sup.1 is lower alkyl, and R.sup.2 is straight-chain or branched alkyl of 1 to 10 carbon atoms, is obtained by adding an alkanal of the fomrula II ##STR2## and an alkyl glyoxylate of the formula III ##STR3## simultaneously to a catalyst system composed of a salt or a mixture of a secondary amine and a carboxylic acid in such a way that the temperature does not exceed 90.degree. C., preferably 80.degree. C., or else adding one of the reactants of the formula II or III to a mixture of the catalyst system described above and the other reactant in such a way that the temperature does not exceed 90.degree. C. The 2-hydroxy-3-formylpropionic eater of the formula I can be converted by treatment with dehydrating agents, especially acetic anhydride, into good yields of the corresponding 3-substituted 3-formylacrylic ester.
摘要翻译：其中R1是低级烷基，R2是具有1-10个碳原子的直链或支链烷基的式Ⅰ的3-取代的2-羟基-3-甲酰基丙酸酯是通过将烷基的II型和式III（III）的烷基乙醛酸盐同时与由仲胺和羧酸的盐或混合物组成的催化剂体系，使得温度不超过90℃，优选80℃，或者将一种式II或III的反应物加入到上述催化剂体系和另一种反应物的混合物中，使得温度不超过90℃。式I的2-羟基-3-甲酰基丙酸酯可以通过用脱水剂，特别是乙酸酐处理转化成相应3-取代的3-甲酰基丙烯酸酯的良好产率。

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