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    • 20. 发明授权
    • Preparation of amide-containing polyethers
    • 含酰胺聚醚的制备
    • US4324881A
    • 1982-04-13
    • US185606
    • 1980-09-09
    • Gerd BlinneRolf WurmbFranz Schmidt
    • Gerd BlinneRolf WurmbFranz Schmidt
    • C08J11/10C08G65/40
    • C08J11/10C08J2375/04Y02W30/702
    • A process for the preparation of an amide-containing polyether comprises polycondensing a dihalobenzene compound, preferably bis-(4-chlorophenyl) sulfone or 4,4'-bis-(4"-chlorobenzoyl)-diphenyl ether, with an amide-containing bis-phenol of the formula HO-Ar.sup.1 -NHCO-Ar.sup.2 -CONH-Ar.sup.1 -OH where Ar.sup.1 is an aromatic radical of 6 to 12 carbon atoms and Ar.sup.2 is an aromatic radical of 6 to 12 carbon atoms or has the formula II ##STR1## where A.sup.1 is --SO.sub.2 --, --CO--, --C(CH.sub.3).sub.2 -- or 0 and n is 0 or 1, preferably 1,4-bis(4-hydroxybenzamido)-benzene, in the presence of an anhydrous alkali metal carbonate, and optionally in the presence of a bisphenol of the formula III ##STR2## where Ar.sup.1 and A.sup.1 have the above meanings and n and m are 0 or 1. The polyethers may be used to produce moldings, fibers, films, adhesives and coating materials.
    • 制备含酰胺的聚醚的方法包括将二卤代苯化合物,优选双(4-氯苯基)砜或4,4'-双 - (4“ - 氯苯甲酰基) - 二苯醚与含酰胺的 式HO-Ar1-NHCO-Ar2-CONH-Ar1-OH的双酚,其中Ar1是6至12个碳原子的芳族基团,Ar2是6-12个碳原子的芳族基团,或具有式II 其中A 1是-SO 2 - , - CO - , - C(CH 3)2 - 或0,n是0或1,优选1,4-双(4-羟基苯甲酰氨基) - 苯,在无水碱金属 碳酸酯,并且任选地在式III的双酚存在下,其中Ar1和A1具有上述含义,n和m为0或1.聚醚可用于生产模制品,纤维,膜,粘合剂和涂料 材料