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    • 14. 发明授权
    • Silica-reinforced tire tread rubber
    • 二氧化硅增强轮胎胎面橡胶
    • US06350807B1
    • 2002-02-26
    • US09616270
    • 2000-07-14
    • Edward John BlokPaul Harry SandstromWen-Liang HsuAdel Farhan HalasaJohn Joseph Andre VertheRaymond Robert DiRossi
    • Edward John BlokPaul Harry SandstromWen-Liang HsuAdel Farhan HalasaJohn Joseph Andre VertheRaymond Robert DiRossi
    • C08K334
    • C08L9/00B60C1/0016C08K3/04C08K3/36C08K5/0016C08L7/00C08L15/00Y02T10/862C08L2666/08
    • The present invention relates to a tire tread compound that is highly loaded with silica. This compound offers the advantages of silica compounding without the need for solution SBR. More specifically, the tire tread rubber formulations of this invention offer an excellent combination of traction, treadwear and rolling resistance characteristics. The subject invention discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of (1) 5 phr to 40 phr of a polyisoprene rubber selected from the group consisting of natural rubber and synthetic polyisoprene, (2) 20 phr to 60 phr of high vinyl polybutadiene rubber having a glass transition temperature which is within the range of −40° C. to 10° C., (3) 20 phr to 60 phr of tin-coupled isoprene-butadiene rubber having a glass transition temperature which is within the range of −90° C. to −70° C., (4) 30 phr to 90 phr of silica, (5) 5 phr to 50 phr of carbon black, (6) 2 phr to 50 phr of processing oil and (7) 0.5 phr to 15 phr of a silica coupling agent.
    • 本发明涉及高度负载二氧化硅的轮胎胎面胶。 该化合物具有二氧化硅复合的优点,无需溶液SBR。 更具体地,本发明的轮胎胎面橡胶配方提供牵引力,胎面磨损和滚动阻力特性的优异组合。 本发明公开了一种轮胎,其由具有外圆周胎面的大致环形胎体,两个间隔开的胎圈,从胎圈到胎圈延伸的至少一个帘布层以及从所述胎面径向延伸并将所述胎面连接到所述胎圈的侧壁构成; 其中所述胎面适于与地面接触; 其中胎面由(1)5phr至40phr的选自天然橡胶和合成聚异戊二烯的聚异戊二烯橡胶,(2)20phr至60phr的玻璃化转变温度为20phr至60phr的高乙烯基聚丁二烯橡胶 在-40℃至10℃的范围内,(3)20phr至60phr的锡偶合异戊二烯 - 丁二烯橡胶,其玻璃化转变温度在-90℃至-70℃的范围内 (4)30phr至90phr的二氧化硅,(5)5phr至50phr的炭黑,(6)2phr至50phr的加工油和(7)0.5phr至15phr的二氧化硅 偶联剂。
    • 19. 发明授权
    • High performance tire tread rubber composition
    • 高性能轮胎胎面胶组成
    • US5994448A
    • 1999-11-30
    • US133503
    • 1998-08-12
    • Edward John BlokPaul Harry SandstromWen-Liang HsuAdel Farhan Halasa
    • Edward John BlokPaul Harry SandstromWen-Liang HsuAdel Farhan Halasa
    • B60C1/00C08C19/44C08L9/00C08K3/00
    • C08C19/44B60C1/0016C08L9/00C08K3/36C08L7/00C08L9/06
    • This invention relates to a tire tread compound that can be used in manufacturing tires having outstanding traction characteristics without compromising treadwear and rolling resistance. The tire tread compounds of this invention are made utilizing an isoprene-butadiene rubber having a high glass transition temperature and having SnR.sub.3 end groups, wherein R represents an alkyl group, such as a tertiary-butyl group. These isoprene-butadiene rubbers are made by reacting an isoprene-butadiene rubber having a glass transition temperature which is within the range of about -50.degree. C. to about 0.degree. C. with a tin compound of the formula SnR.sub.3 X, wherein R represents an alkyl group and wherein X represents a halogen. This invention more specifically discloses a tire tread rubber composition which is comprised of (1) about 60 phr to about 95 phr of an isoprene-butadiene rubber having a glass transition temperature which is within the range of about -50.degree. C. to about 0.degree. C. and having --SnR.sub.3 end groups, (2) about 5 phr to about 30 phr of natural rubber and (3) up to about 25 phr of a rubbery polymer having a low glass transition temperature which is within the range of about -85.degree. C. to about -55.degree. C., with the proviso that the total amount of the natural rubber and the rubbery polymer having a low glass transition temperature does not exceed about 40 phr. The rubbery polymer having a low glass transition temperature will typically be high cis-1,4-polybutadiene, isoprene-butadiene rubber, styrene-butadiene rubber or styrene-isoprene-butadiene rubber.
    • 本发明涉及一种轮胎胎面胶,其可用于制造具有优异牵引特性的轮胎,而不损害胎面和滚动阻力。 本发明的轮胎胎面胶料采用高玻璃化转变温度的异戊二烯 - 丁二烯橡胶制成,并具有SnR 3端基,其中R表示烷基,如叔丁基。 这些异戊二烯 - 丁二烯橡胶通过使玻璃化转变温度在约-50℃至约0℃范围内的异戊二烯 - 丁二烯橡胶与式SnR 3 X的锡化合物反应制备,其中R表示 烷基,其中X表示卤素。 本发明更具体地公开了一种轮胎胎面橡胶组合物,其包含(1)约60phr至约95phr的玻璃化转变温度在约-50℃至约0的范围内的异戊二烯 - 丁二烯橡胶 具有-SnR 3端基,(2)约5phr至约30phr的天然橡胶和(3)至多约25phr的玻璃化转变温度低于约 - 约25phr的橡胶状聚合物, 85℃至约-55℃,条件是具有低玻璃化转变温度的天然橡胶和橡胶状聚合物的总量不超过约40phr。 具有低玻璃化转变温度的橡胶状聚合物通常是高顺式-1,4-聚丁二烯,异戊二烯 - 丁二烯橡胶,苯乙烯 - 丁二烯橡胶或苯乙烯 - 异戊二烯 - 丁二烯橡胶。
    • 20. 发明授权
    • Silica-reinforced tire tread rubber
    • 二氧化硅增强轮胎胎面橡胶
    • US06378582B1
    • 2002-04-30
    • US09665863
    • 2000-09-20
    • Paul Harry SandstromAdel Farhan HalasaWen-Liang HsuEdward John Blok
    • Paul Harry SandstromAdel Farhan HalasaWen-Liang HsuEdward John Blok
    • B60C1100
    • B60C1/0016Y02T10/862
    • The present invention relates to a tire tread compound that is highly loaded with silica. This compound offers the advantages of silica compounding without the need for solution SBR. More specifically, the tire tread rubber formulations of this invention offer an excellent combination of traction, treadwear and rolling resistance characteristics. The subject invention discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of (1) 10 phr to 35 phr of high vinyl polybutadiene rubber having a glass transition temperature which is within the range of −40° C. to 10° C., (2) 65 phr to 90 phr of tin-coupled isoprene-butadiene rubber having a glass transition temperature which is within the range of −90° C. to −70° C., (3) 30 phr to 90 phr of silica, (4) 5 phr to 50 phr of carbon black, (5) 2 phr to 50 phr of processing oil and (6) 0.5 phr to 15 phr of a silica coupling agent.
    • 本发明涉及高度负载二氧化硅的轮胎胎面胶。 该化合物具有二氧化硅复合的优点,无需溶液SBR。 更具体地,本发明的轮胎胎面橡胶配方提供牵引力,胎面磨损和滚动阻力特性的优异组合。 本发明公开了一种轮胎,其由具有外圆周胎面的大致环形胎体,两个间隔开的胎圈,从胎圈到胎圈延伸的至少一个帘布层以及从所述胎面径向延伸并将所述胎面连接到所述胎圈的侧壁构成; 其中所述胎面适于与地面接触; 其中所述胎面由(1)10phr至35phr的玻璃化转变温度在-40℃至10℃范围内的高乙烯基聚丁二烯橡胶组成,(2)65phr至90phr至 具有玻璃化转变温度在-90℃至-70℃范围内的锡偶联异戊二烯 - 丁二烯橡胶,(3)30phr至90phr二氧化硅,(4)5phr至50phr的 炭黑,(5)2phr至50phr的加工油和(6)0.5phr至15phr的二氧化硅偶联剂。