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    • 18. 发明授权
    • Sealed alkaline-zinc storage battery
    • 密封碱性锌蓄电池
    • US06190801B1
    • 2001-02-20
    • US09274808
    • 1999-03-23
    • Mitsunori TokudaMutsumi YanoMitsuzou NogamiShin FujitaniKoji Nishio
    • Mitsunori TokudaMutsumi YanoMitsuzou NogamiShin FujitaniKoji Nishio
    • H01M442
    • H01M4/244H01M4/0497H01M4/26H01M4/32H01M4/48H01M4/52H01M10/24H01M10/283H01M10/30H01M2010/4292Y02E60/124
    • The invention provides a sealed alkaline-zinc storage battery including a tubular positive electrode containing, as an active material, a material having reversibility in a charge-discharge reaction; a separator; a negative electrode disposed within the tubular positive electrode with the separator sandwiched therebetween; and an alkaline electrolyte, in which the positive electrode has a capacity smaller than a capacity of the negative electrode at least in initial charge-discharge cycles, and the amounts of an uncharged active material and zinc to be packed in the negative electrode in manufacture of the sealed alkaline-zinc storage battery are set so that a theoretical capacity P of the uncharged active material existing in the negative electrode can be 0.3 through 1.8 times as large as a battery capacity in a completely charged state in the initial charge-discharge cycles, and that a theoretical capacity Q of zinc existing in the negative electrode can be 0.6 through 2.5 times as large as the battery capacity in a completely discharged state in the initial charge-discharge cycles. Thus, a sealed alkaline-zinc storage battery with high charge-discharge cycle performance is obtained.
    • 本发明提供一种密封的碱锌蓄电池,其包括管状正电极,其包含作为活性材料的充电 - 放电反应具有可逆性的材料; 分隔符 设置在管状正极内的负极,分隔件夹在其间; 和碱性电解质,其中至少在初始充放电循环中,正极具有小于负极容量的容量,以及在制造中要包装在负极中的不带电的活性材料和锌的量 密封的碱性锌蓄电池被设定为使得存在于负极中的不带电活性物质的理论容量P在初始充放电循环中可以是完全充电状态下的电池容量的0.3〜1.8倍, 在初始充放电循环中,存在于负极中的锌的理论容量Q可以是完全放电状态下的电池容量的0.6〜2.5倍。 因此,获得具有高充放电循环性能的密封的碱锌蓄电池。