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    • 11. 发明申请
    • CROSSLINKABLE POLYTETRAFLUOROETHYLENE COMPOSITION OF MATTER, POWDERED POLYTETRAFLUOROETHYLENE CROSSLINKED BODY, POLYTETRAFLUOROETHYLENE MOLDED BODY, RESIN BLEND COMPOSITION OF MATTER AND RESIN BLEND MOLDED BODY
    • 交联聚四氟乙烯组合物,粉末聚四氟乙烯交联体,聚四氟乙烯模塑体,树脂混合物和树脂混合物体的组合物
    • US20090306296A1
    • 2009-12-10
    • US11913276
    • 2006-04-24
    • Yoshinori NanbaMeiten KohYasuhiko Sawada
    • Yoshinori NanbaMeiten KohYasuhiko Sawada
    • C08L27/00
    • C08K5/16C08K5/18C08K5/37C08L27/18
    • The object of the present invention is to offer a PTFE resin that can be prepared by common molding methods such as compression molding and the like without the necessity for expensive equipment or hot coining methods or the like that are deleterious to productivity, and where harmful substances are not generated during manufacture, and convention strength, crystallinity and surface characteristics are preserved, and where there is neither anisotropy nor heterogeneity, and where the PTFE resin is more difficult to deform than is conventional PTFE resin. A crosslinkable polytetrafluoroethylene composition of matter contains polytetrafluoroethylene and a crosslinking agent. The polytetrafluoroethylene possesses at least one reactive functional group selected from the group consisting of cyano (—CN), carboxyl (—COOH), alkoxycarbonyl (—COOR (where R is a monovalent organic group)) and acid halide (—COX (where X is a halogen atom)) on at least one of the main chain and side chain terminal ends. The crosslinking agent reacts with one or a plurality of reactive functional groups and can form a cyclic structure.
    • 本发明的目的是提供一种PTFE树脂,其可以通过诸如压缩成型等的常规成型方法制备,而不需要对生产率有害的昂贵的设备或热压印方法等,并且其中有害物质 在制造过程中不产生,并且保留常规强度,结晶度和表面特性,并且其中既不具有各向异性也不具有异质性,并且其中PTFE树脂比常规PTFE树脂更难变形。 可交联聚四氟乙烯组合物含有聚四氟乙烯和交联剂。 聚四氟乙烯具有至少一种选自氰基(-CN),羧基(-COOH),烷氧基羰基(-COOR(其中R是一价有机基团))和酰卤(-COX(其中X 是卤素原子))在主链和侧链末端中的至少一个上。 交联剂与一个或多个反应性官能团反应并且可以形成环状结构。
    • 15. 发明授权
    • Modified polytetrafluoroethylene fine powder and method for the production of the same
    • 改性聚四氟乙烯细粉及其制备方法
    • US06531557B1
    • 2003-03-11
    • US09242272
    • 1999-03-12
    • Kazutaka HosokawaYoshinori NanbaTakahisa AoyamaTetsuo Shimizu
    • Kazutaka HosokawaYoshinori NanbaTakahisa AoyamaTetsuo Shimizu
    • C08F21426
    • C08F214/262
    • A modified polytetrafluoroethylene fine powder containing agglomerates of colloidal particles with an average particle size of from 0.05 to 0.5 &mgr;m which comprise a copolymer of tetrafluoroethylene and an olefin-monomer represented by X(CF2)nOCF═CF2 in which X is a hydrogen atom, a fluorine atom or a chlorine atom, and n is an integer of 1 to 6, and/or C3F7(OCF2CF2CF2)m[OCF(CF3)CF2]pOCF═CF2 in which m and p are independently an integer of 0 to 4, provided that the sum of m and p is not 0 (zero), a content of the olefin monomer being from 0.02 to 0.3 wt. %, wherein the copolymer has a molecular weight distribution Mw/Mn of from 1.5 to 4.5 and a standard specific gravity of from 2.135 to 2.175. This modified polytetrafluoroethylene has good paste extrudability, and provides molded articles having good mechanical properties, in particular, pressure resistance.
    • 一种改性聚四氟乙烯细粉末,其含有平均粒径为0.05〜0.5μm的胶体粒子的附聚物,其包含由X(CF 2)n OCF = CF 2(其中X为氢原子)表示的四氟乙烯与烯烃单体的共聚物, 氟原子或氯原子,n为1〜6的整数,和/或C 3 F 7(OCF 2 CF 2 CF 2)m [OCF(CF 3)CF 2] p OCF = CF 2,其中m和p分别为0〜4的整数, m和p的和不为0(零),烯烃单体的含量为0.02-0.3重量%。 %,其中共聚物的分子量分布Mw / Mn为1.5〜4.5,标准比重为2.135〜2.175。 该改性聚四氟乙烯具有良好的糊料挤出性,并提供具有良好机械性能,特别是耐压性的模制品。