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11. 发明授权

US09540491B2 Organic-inorganic composite, composition for formation of organic-inorganic composite, and ink 有权
标题翻译：有机 - 无机复合材料，有机 - 无机复合材料的形成用组合物和油墨
公开(公告)号：US09540491B2
公开(公告)日：2017-01-10
申请号：US13576571
申请日：2011-01-27
申请人： Takeshi Otsuka , Yoshiki Chujo
发明人： Takeshi Otsuka , Yoshiki Chujo
IPC分类号： C09K11/06 , C09K11/08 , C08G83/00 , C09D11/037 , C09D11/10
CPC分类号： C08G83/001 , C09D11/037 , C09D11/10
摘要： An organic-inorganic composite of the present invention includes metal oxide particles and an organic polymer compound including a monomer containing organic ligands and a vinyl-based monomer having organic ligands which are bonded to a polymer chain through covalent bonds and the organic polymer compound is bonded to the metal oxide particles by the organic ligands forming a complex with metal atoms on the surface of the metal oxide particles. According to the organic-inorganic composite, the metal oxide particles and the organic polymer compound containing the organic ligands can be chemically bonded, therefore, light emission characteristics such as light emission intensity or stabilization of light emission wavelength can be improved, and transparency and mechanical characteristics such as thermal stability or hardness can also be improved.
摘要翻译：本发明的有机 - 无机复合体包括金属氧化物粒子和含有有机配体的单体和具有有机配体的乙烯基类单体的有机高分子化合物，所述有机配体通过共价键与聚合物链结合，有机高分子化合物键合通过与金属氧化物颗粒的表面上的金属原子形成络合物的有机配体与金属氧化物颗粒结合。根据有机 - 无机复合体，金属氧化物粒子和含有有机配体的有机高分子化合物可以进行化学键合，因此可以提高发光强度等发光特性或发光波长稳定化等发光特性，透明性和机械性也可以提高热稳定性，硬度等特性。

12. 发明申请

US20130331506A1 ORGANIC-INORGANIC COMPOSITE, COMPOSITE COMPOSITIONS OF ORGANIC AND INORGANIC COMPOUNDS, AND INK 有权
标题翻译：有机无机复合材料，有机和无机化合物的复合组合物和油墨
公开(公告)号：US20130331506A1
公开(公告)日：2013-12-12
申请号：US13979754
申请日：2012-01-18
申请人： Takeshi Otsuka , Yoshiki Chujo
发明人： Takeshi Otsuka , Yoshiki Chujo
IPC分类号： C09K11/07
CPC分类号： C09K11/07 , C08K5/0091 , C08L33/14 , C09D11/101 , C09K11/02 , C09K11/025 , C09K11/06 , C09K2211/1029 , C09K2211/183
摘要： Provided is an organic-inorganic composite having two or more kinds of light emission sites. When the organic-inorganic composite is caused to emit light, each of emission colors in each of light emission sites is independently maintained as a emission color that is shown when each of the light emission sites is independently caused to emit light.
摘要翻译：提供了具有两种以上发光位置的有机 - 无机复合体。当使有机 - 无机复合材料发光时，每个发光部位的发光颜色各自独立地保持为当各个发光部位独立地发光时示出的发光颜色。

13. 发明申请

US20130026416A1 ORGANIC-INORGANIC COMPOSITE, COMPOSITION FOR FORMATION OF ORGANIC-INORGANIC COMPOSITE, AND INK 有权
标题翻译：有机无机复合材料，有机无机复合材料的组合物和油墨
公开(公告)号：US20130026416A1
公开(公告)日：2013-01-31
申请号：US13576571
申请日：2011-01-27
申请人： Takeshi Otsuka , Yoshiki Chujo
发明人： Takeshi Otsuka , Yoshiki Chujo
IPC分类号： C08F8/42 , C09K11/06 , C08F36/20 , C08F226/06 , C08G64/40
CPC分类号： C08G83/001 , C09D11/037 , C09D11/10
摘要： An organic-inorganic composite of the present invention includes metal oxide particles and an organic polymer compound including a monomer containing organic ligands and a vinyl-based monomer having organic ligands which are bonded to a polymer chain through covalent bonds and the organic polymer compound is bonded to the metal oxide particles by the organic ligands forming a complex with metal atoms on the surface of the metal oxide particles. According to the organic-inorganic composite, the metal oxide particles and the organic polymer compound containing the organic ligands can be chemically bonded, therefore, light emission characteristics such as light emission intensity or stabilization of light emission wavelength can be improved, and transparency and mechanical characteristics such as thermal stability or hardness can also be improved.
摘要翻译：本发明的有机 - 无机复合体包括金属氧化物粒子和含有有机配体的单体和具有有机配体的乙烯基类单体的有机高分子化合物，所述有机配体通过共价键与聚合物链结合，有机高分子化合物键合通过与金属氧化物颗粒的表面上的金属原子形成络合物的有机配体与金属氧化物颗粒结合。根据有机 - 无机复合体，金属氧化物粒子和含有有机配体的有机高分子化合物可以进行化学键合，因此可以提高发光强度等发光特性或发光波长稳定化等发光特性，透明性和机械性也可以提高热稳定性，硬度等特性。

14. 发明授权

US5338431A Oxygen concentration detecting apparatus 失效
标题翻译：氧浓度检测装置
公开(公告)号：US5338431A
公开(公告)日：1994-08-16
申请号：US978076
申请日：1992-11-18
申请人： Hiroshi Yorita , Toshihiko Igashira , Michiyasu Moritsugu , Yoshiki Chujo
发明人： Hiroshi Yorita , Toshihiko Igashira , Michiyasu Moritsugu , Yoshiki Chujo
IPC分类号： G01N27/419 , F02D45/00 , F02M25/07 , G01N27/406 , G01N27/409 , G01N27/41
CPC分类号： G01N27/4065 , G01N27/419 , F02M2026/004
摘要： An oxygen concentration detecting apparatus having, a pumping cell and a sensing cell, electrodes formed on both surfaces of each of the pumping and sensing cells, a related support structure forming a closed space by being connected with the pumping and sensing cells, an opening communicating between the closed space and the surrounding environment, an electromotive force detector for detecting an electromotive force generated between the electrodes of the sensing cell, a voltage source for applying a voltage between the electrodes of the pumping cell, a current detector for detecting as a signal representing the oxygen concentration a current flowing in the pumping cell when a voltage is applied between the electrodes of the pumping cell, and a controller for controlling the voltage so that the electromotive force is constant at a specified value at which value the above-mentioned current is 70% or less of the limiting current.
摘要翻译：具有泵浦单元和感测单元的氧浓度检测装置，形成在每个泵浦和感测单元的两个表面上的电极，通过与泵送和感测单元连接而形成闭合空间的相关支撑结构，在闭合空间与周围环境之间的电动势检测器，用于检测在感测单元的电极之间产生的电动势，用于在泵浦单元的电极之间施加电压的电压源，用于检测作为信号的电流检测器表示当在泵浦单元的电极之间施加电压时在泵浦单元中流动的电流的氧浓度，以及用于控制电压的控制器，使得电动势恒定在上述电流值的规定值为极限电流的70％以下。

15. 发明授权

US4538575A Device for controllably heating oxygen sensor 失效
标题翻译：用于可控制加热氧气传感器的装置
公开(公告)号：US4538575A
公开(公告)日：1985-09-03
申请号：US511235
申请日：1983-07-06
申请人： Yoshiki Chujo , Hiroshi Noguchi
发明人： Yoshiki Chujo , Hiroshi Noguchi
IPC分类号： G01N27/419 , F02D41/14 , G01N27/409 , G01N27/41 , G05D23/00 , F02B3/00 , F02B33/00
CPC分类号： F02D41/1494 , F02D41/1456
摘要： Pulse current having a certain cycle is supplied to an electric heater in an oxygen sensor for exhaust gas. Duty ratio of this pulse current is controlled in relation to the amplitude of voltage and current applied to the heater to thereby maintain power consumption of the heater per unit time at a constant one. Also this duty may be corrected on the basis of parameters for running an internal combustion engine.
摘要翻译：具有一定周期的脉冲电流被供给到用于废气的氧传感器中的电加热器。相对于施加到加热器的电压和电流的幅度来控制该脉冲电流的占空比，从而将加热器的功率消耗保持在恒定值。也可以基于运行内燃机的参数来校正该责任。

16. 发明授权

US06444751B1 Process for producing vinyl alcohol polymer composition 失效
标题翻译：制备乙烯醇聚合物组合物的方法
公开(公告)号：US06444751B1
公开(公告)日：2002-09-03
申请号：US09554594
申请日：2000-05-26
申请人： Yoshiki Chujo , Ryo Tamaki , Kanenori Itoh , Yukiatsu Komiya
发明人： Yoshiki Chujo , Ryo Tamaki , Kanenori Itoh , Yukiatsu Komiya
IPC分类号： C08G6348
CPC分类号： C08F8/12 , C08F8/42 , C08F218/08
摘要： A solution containing a metal alkoxide or oligomers thereof, a vinyl carboxylate polymer and an organic solvent is used, and, while low boiling substances containing the organic solvent is removed, both polycondensation of the metal alkoxide or oligomers thereof and saponification of the vinyl carboxylate polymer are conducted in parallel with each other and in the same reaction zone. On the occasion, the metal alkoxide or oligomers thereof is used in an amount of the metal atom present in the metal alkoxide or oligomers thereof of 0.01 to 100 moles based on 100 moles of the acyl group originating from the vinyl carboxylate unit present in the vinyl carboxylate polymer. This process can produce vinyl alcohol polymer compositions comprising a metal oxide without causing property unevenness, the compositions being capable of maintaining their excellent gas-barrier properties when exposed to high-temperature and high-humidity conditions or after being repeatedly bent. The process thus can produce, commercially advantageously, materials useful as food-packaging materials and the like.
摘要翻译：使用含有金属醇盐或其低聚物，羧酸乙烯酯聚合物和有机溶剂的溶液，并且除去含有有机溶剂的低沸点物质，金属醇盐或其低聚物的缩聚和羧酸乙烯酯聚合物的皂化在相同的反应区中彼此平行进行。在这种情况下，金属醇盐或其低聚物的使用量是金属醇盐或其低聚物中存在的金属原子的量为0.01至100摩尔，基于100摩尔源自乙烯基羧酸酯单元的酰基羧酸盐聚合物。该方法可以生产包含金属氧化物的乙烯醇聚合物组合物，而不会引起性能不均匀，该组合物在暴露于高温高湿条件下或在反复弯曲之后能够保持其优异的气体阻隔性能。因此，该方法可以商业上有利地生产用作食品包装材料等的材料。

17. 发明授权

US4491921A Method and apparatus for controlling the air fuel ratio in an internal combustion engine 失效
标题翻译：用于控制内燃机中的空燃比的方法和装置
公开(公告)号：US4491921A
公开(公告)日：1985-01-01
申请号：US333319
申请日：1981-12-22
申请人： Shinichi Sugiyama , Yoshiki Chujo , Takehisa Yaegashi
发明人： Shinichi Sugiyama , Yoshiki Chujo , Takehisa Yaegashi
IPC分类号： F02D41/14 , F02D41/26 , F02B3/00 , F02D33/00
CPC分类号： F02D41/1479 , F02D41/26
摘要： An output voltage from an O.sub.2 sensor is intermittently sampled and the sampled voltage is converted into a binary signal. The binary signal is applied to an electrical digital computer, and therein the following operations are carried out. First, the maximum value and minimum value of the applied binary signal are detected, then the difference between the maximum and minimum values and the sum of the maximum and minimum values are calculated. A reference value is calculated using the calculated difference and sum and the minimum value from a predetermined algebraic function. Thereafter, the applied binary signal is compared with the calculated reference value to generate a binary signal indicative of the comparison result. Then, the air-fuel ratio of the engine is adjusted in response to this binary signal calculated by the digital computer.
摘要翻译：来自O2传感器的输出电压被间歇地采样，采样电压被转换为二进制信号。二进制信号被应用于电子数字计算机，其中执行以下操作。首先，检测所应用的二进制信号的最大值和最小值，然后计算最大值和最小值之差以及最大和最小值之和。使用计算的差值和来自预定代数函数的和和最小值来计算参考值。此后，将所应用的二进制信号与计算的参考值进行比较，以生成表示比较结果的二进制信号。然后，根据由数字计算机计算出的二进制信号来调节发动机的空燃比。

18. 发明授权

US09006354B2 Composite composition of inorganic oxide particles and silicone resin, method of manufacturing the same, transparent composite, and method of manufacturing the same 有权
标题翻译：无机氧化物颗粒和硅树脂的复合组合物，其制造方法，透明复合材料及其制造方法
公开(公告)号：US09006354B2
公开(公告)日：2015-04-14
申请号：US13809560
申请日：2011-07-12
申请人： Takeshi Otsuka , Yoshiki Chujo
发明人： Takeshi Otsuka , Yoshiki Chujo
IPC分类号： C08L83/08 , B82Y30/00 , C01G25/02 , C09C1/00 , C09C1/30 , C09C3/12 , C09D183/06 , C08G77/38 , C08G77/14
CPC分类号： C08G77/398 , B82Y30/00 , C01G25/02 , C01P2004/64 , C08G77/14 , C08G77/38 , C08L83/08 , C09C1/00 , C09C1/3063 , C09C1/3081 , C09C1/309 , C09C3/12 , C09D183/06
摘要： A method of manufacturing a composite composition, having: bonding a dispersant to the surfaces of inorganic oxide particles to provide dispersibility in a hydrophobic solvent to the inorganic oxide particles, and then dispersing the inorganic oxide particles in a hydrophobic solvent; substituting the dispersant bonded to the surfaces of the inorganic oxide particles with a surface modifier, which is a polydimethylsiloxane-skeleton polymer having one functional group at one terminal end, in the hydrophobic solvent in which the organic oxide particles are dispersed to bond the functional group of the polydimethylsiloxane-skeleton polymer to the surfaces of the inorganic oxide particles; and conjugating a silicone resin and the inorganic oxide particles obtained in the previous step, wherein the surface thereof is modified by bonding the polydimethylsiloxane-skeleton polymer having one functional group at one terminal end thereof, to obtain a composite composition.
摘要翻译：一种复合组合物的制造方法，其特征在于，具有：将分散剂粘合到无机氧化物粒子的表面，在疏水性溶剂中赋予无机氧化物粒子的分散性，然后将无机氧化物粒子分散在疏水性溶剂中; 将分散有有机氧化物颗粒的疏水性溶剂中的表面改性剂（其末端具有一个官能团的聚二甲基硅氧烷 - 骨架聚合物）的表面改性剂与无机氧化物颗粒表面接合的分散剂代替键合官能团的聚二甲基硅氧烷 - 骨架聚合物的无机氧化物颗粒的表面; 并与上述工序中得到的硅氧烷树脂和无机氧化物粒子共轭，其表面通过在一个末端键合具有一个官能团的聚二甲基硅氧烷骨架聚合物而得到复合组合物。

19. 发明申请

US20130211016A1 COMPOSITE COMPOSITION OF INORGANIC OXIDE PARTICLES AND SILICONE RESIN, METHOD OF MANUFACTURING THE SAME, TRANSPARENT COMPOSITE, AND METHOD OF MANUFACTURING THE SAME 有权
公开(公告)号：US20130211016A1
公开(公告)日：2013-08-15
申请号：US13809560
申请日：2011-07-12
申请人： Takeshi Otsuka , Yoshiki Chujo
发明人： Takeshi Otsuka , Yoshiki Chujo
IPC分类号： C08L83/08
CPC分类号： C08G77/398 , B82Y30/00 , C01G25/02 , C01P2004/64 , C08G77/14 , C08G77/38 , C08L83/08 , C09C1/00 , C09C1/3063 , C09C1/3081 , C09C1/309 , C09C3/12 , C09D183/06
摘要： A method of manufacturing a composite composition, having: bonding a dispersant to the surfaces of inorganic oxide particles to provide dispersibility in a hydrophobic solvent to the inorganic oxide particles, and then dispersing the inorganic oxide particles in a hydrophobic solvent; substituting the dispersant bonded to the surfaces of the inorganic oxide particles with a surface modifier, which is a polydimethylsiloxane-skeleton polymer having one functional group at one terminal end, in the hydrophobic solvent in which the organic oxide particles are dispersed to bond the functional group of the polydimethylsiloxane-skeleton polymer to the surfaces of the inorganic oxide particles; and conjugating a silicone resin and the inorganic oxide particles obtained in the previous step, wherein the surface thereof is modified by bonding the polydimethylsiloxane-skeleton polymer having one functional group at one terminal end thereof, to obtain a composite composition.

20. 发明授权

US08299283B2 Contrast agent containing silsesquioxane 失效
标题翻译：含有倍半硅氧烷的对比剂
公开(公告)号：US08299283B2
公开(公告)日：2012-10-30
申请号：US12733464
申请日：2008-09-03
申请人： Yoshiki Chujo , Kazuo Tanaka , Kensuke Naka
发明人： Yoshiki Chujo , Kazuo Tanaka , Kensuke Naka
IPC分类号： C07F7/18 , C07F7/00
CPC分类号： C07F7/21 , A61K49/124
摘要： The present invention provides a contrast agent which ensures 1) high contrast performance, 2) low toxicity, and 3) a simple production process.The present invention provides a contrast agent containing a silsesquioxane represented by General Formula (I), wherein R1, the same or different, is a substituent bonded to Si through a carbon atom, the substituent having, at its terminal, a group represented by General Formula (II), wherein p represents an integer of from 1 to 5; q is the same or different, and represents an integer of from 1 to 5; R2 is the same or different, and represents hydrogen atom, alkyl group, aralkyl group or acyl group, or a group represented by General Formula (III), wherein p, q and R2 are the same as above.
摘要翻译：本发明提供了一种造影剂，其确保1）高对比度性能，2）低毒性，和3）简单的生产过程。本发明提供含有通式（I）表示的倍半硅氧烷的造影剂，其中R1，相同或不同，是通过碳原子与Si键合的取代基，该取代基在其末端具有由通式式（II），其中p表示1〜5的整数; q相同或不同，表示1〜5的整数， R2相同或不同，表示氢原子，烷基，芳烷基或酰基，或由通式（III）表示的基团，其中p，q和R2与上述相同。

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