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    • 11. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US5376522A
    • 1994-12-27
    • US111263
    • 1993-08-24
    • Hideki TakiguchiTomoyuki NakayamaNobuaki KagawaHakubun Ohashi
    • Hideki TakiguchiTomoyuki NakayamaNobuaki KagawaHakubun Ohashi
    • G03C1/09G03C1/34G03C1/035
    • G03C1/09G03C1/34
    • A silver halide photographic material having photographic constituent layers on a support, which photographic material is characterized in that at least one of said photographic constituent layers is a silver halide emulsion layer, at least 50% in number of the light-sensitive silver halide grains in said silver halide emulsion layer being grains that contain at least 60 mol % of silver bromide, and at least one of said photographic constituent layers containing at least one of the compounds represented by the following general formula (I):[HlAu.sub.m (L).sub.n (X).sub.p ].sub.q (I)where L is a 1igand in a 5- or 6-membered hetero ring; X is an anionic group; l is an integer of 0-2; m is an integer of 1 or 2; n is an integer of 1-3; p is an integer of 0-3; and q is an integer of 1-4. The silver halide photographic material has high sensitivity and yet it is improved in protection against deterioration in its photographic performance such as increased fog and degraded granularity due to storage after manufacture.
    • 一种卤化银照相材料,其在支持体上具有照相构成层,该照相材料的特征在于,所述照相构成层中的至少一个为卤化银乳剂层,至少50%的感光卤化银颗粒数 所述卤化银乳剂层是含有至少60mol%溴化银的颗粒,并且至少一个所述照相构成层含有至少一种由以下通式(I)表示的化合物:[HlAum(L)n (X)p] q(I)其中L是5或6元杂环的1配位; X是阴离子基团; l是0-2的整数; m为1或2的整数; n为1-3的整数; p是0-3的整数; q为1-4的整数。 卤化银照相材料具有高灵敏度,但是其防止其照相性能的劣化得到改善,例如由于制造后的储存而增加的雾和降低的颗粒度。