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    • 15. 发明授权
    • Silver halide photographic element containing crosslinked copolymers
    • 含有交联共聚物的卤化银照相元件
    • US4677050A
    • 1987-06-30
    • US903888
    • 1986-09-04
    • Shigeki YokoyamaTakayuki InayamaNaohiko SugimotoTakashi Naoi
    • Shigeki YokoyamaTakayuki InayamaNaohiko SugimotoTakashi Naoi
    • G03C1/053G03C1/76
    • G03C1/053
    • A silver halide photographic material is described, comprising a support having thereon at least one layer containing a cross-linked polymer represented by formula (I) ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom or an unsubstituted or substituted alkyl group; R.sub.3 represents a hydrogen atom, an unsubstituted or substituted alkyl group, cycloalkyl group, aryl group, or acyl group; R.sub.4 represents a hydrogen atom or an unsubstituted or substituted alkyl group; or R.sub.3 and R.sub.4 together form a ring; L represents a divalent, trivalent or tetravalent connecting group; l represents 0 or 1; m represents an integer of 1 to 3; n represents an integer of 1 to 10; A represents a polymeric unit formed by copolymerizing an ethylenically unsaturated and copolymerizable monomer; B represents a polymeric unit formed by copolymerizing a copolymerizable cross-linking monomer containing at least two copolymerizable and ethylenically unsaturated groups; M represents a cation; w represetns 10 to 95 mol %; x represents 3 to 88 mol %; y represents 0 to 50 mol %, and z represents 2 to 30 mol %.
    • 描述了一种卤化银照相材料,其包括其上具有至少一层含有由式(I)表示的交联聚合物(I)的载体的载体,其中R 1和R 2各自表示氢原子或未取代或取代的烷基 组; R3表示氢原子,未取代或取代的烷基,环烷基,芳基或酰基; R4表示氢原子或未取代或取代的烷基; 或R3和R4一起形成环; L表示二价,三价或四价连接基团; l表示0或1; m表示1〜3的整数, n表示1〜10的整数, A表示通过烯键式不饱和和可共聚单体共聚形成的聚合单元; B表示通过共聚含有至少两个可共聚的和烯属不饱和基团的可共聚的交联单体形成的聚合物单元; M表示阳离子; w表示10〜95 mol%; x表示3〜88摩尔%。 y表示0〜50摩尔%,z表示2〜30摩尔%。
    • 18. 发明授权
    • Silver halide photographic light-sensitive element containing a u.v.
absorbing layer
    • US4431726A
    • 1984-02-14
    • US453657
    • 1982-12-27
    • Tetsuro KojimaTadashi IkedaShingo IshimaruNaohiko Sugimoto
    • Tetsuro KojimaTadashi IkedaShingo IshimaruNaohiko Sugimoto
    • G03C7/26C08F20/00C08F20/12C08F20/34C08F20/52C08F20/54C08F22/00C08F22/32G03C1/04G03C1/06G03C1/815G03C1/78
    • G03C1/815C08F20/12C08F20/54Y10S430/114
    • A silver halide photographic light-sensitive material is disclosed. The material is comprised of one or more light-sensitive silver emulsion layers and one or more light-insensitive layers. The silver halide layers or light-insensitive layers contain an ultraviolet ray absorbing polymer latex. The polymer latex is comprised of a homopolymer or copolymer having a repeating unit derived from monomers represented by the following general formula (I): ##STR1## wherein the substituents within a general formula (I) are defined within the specification. The polymer latex (I) contains a substituents Q which represents an ultraviolet ray absorbing group represented by the general formula (II): ##STR2## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an aryloxy group having 6 to 20 carbon atoms, an alkylthio group having 1 to 20 carbon atoms, an arylthio group having 6 to 20 carbon atoms, an amino group, an alkylamino group having 1 to 20 carbon atoms, an arylamino group having 6 to 20 carbon atoms, a hydroxyl group, a cyano group, a nitro group, an acylamino group, a carbamoyl group, a sulfonyl group, a sulfamoyl group, a sulfonamide group, an acyloxy group or an oxycarbonyl group, and R.sub.1 and R.sub.2, R.sub.2 and R.sub.3, R.sub.3 and R.sub.4 or R.sub.4 and R.sub.5 may form a 5 to 6 member ring by ring closure; R.sub.6 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R.sub.7 represents a cyano group, --COOR.sub.9, --CONHR.sub.9, --COR.sub.9 or --SO.sub.2 R.sub.9 ; and R.sub.8 represents a cyano group, --COOR.sub.10, --CONHR.sub.10, --COR.sub.10 or --SO.sub.2 R.sub.10 ; wherein R.sub.9 and R.sub.10 each represents an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms; wherein one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 bonds to the vinyl group through the linking group. The photographic material which includes the polymer latex of the invention has excellent absorption characteristics in the 300 to 400 nm range and does not cause static marks caused by ultraviolet rays. Furthermore, the material does not undergo deterioration of color reproduction and fading or discoloration of color images caused by light.