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11. 发明授权

US4575534A Styrene-butadiene copolymer rubber composition 失效
标题翻译：苯乙烯 - 丁二烯共聚物橡胶组合物
公开(公告)号：US4575534A
公开(公告)日：1986-03-11
申请号：US597635
申请日：1984-04-06
申请人： Noboru Oshima , Isamu Shimizu , Mikio Takeuchi , Tatsuo Fujimaki , Shinsuke Yamaguchi
发明人： Noboru Oshima , Isamu Shimizu , Mikio Takeuchi , Tatsuo Fujimaki , Shinsuke Yamaguchi
IPC分类号： C08L7/00 , C08C19/44 , C08L9/06 , C08L21/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L77/00 , C08L101/00 , C08L9/00 , C08L53/00
CPC分类号： C08C19/44 , C08L21/00
摘要： Disclosed herein is a rubber composition comprising at least 20% by weight of styrene-butadiene copolymer based on the total weight of the rubber content. The styrene-butadiene copolymer is obtained by randomly copolymerizing styrene with 1,3-butadiene in a hydrocarbon solvent in the presence of an organolithium compound as an initiator and then subjecting to a coupling reaction with a polyfunctional coupling agent, and contains 30-70% by weight of branched polymers therein, and has the following properties:(a) a content of bound styrene in the copolymer 3-15% by weight;(b) a content of vinyl bonds contained in the butadiene units is 15-30% by weight;(c) a Mooney viscosity (ML.sub.1+4.sup.100.degree. C.) is 15-50; and(d) a molecular weight distribution of the copolymer is bimodal at a ratio Mw/Mn of 1.4-2.2 in which Mw is a weight-average molecular weight and Mn is a number-average molecular weight.
摘要翻译：本文公开了一种橡胶组合物，其包含基于橡胶含量的总重量的至少20重量％的苯乙烯 - 丁二烯共聚物。苯乙烯 - 丁二烯共聚物通过在有机锂化合物作为引发剂的存在下在烃溶剂中将苯乙烯与1,3-丁二烯无规共聚而得到，然后与多官能偶联剂进行偶联反应，并含有30-70％（a）共聚物中结合苯乙烯含量3-15％（重量）; （b）丁二烯单元中所含的乙烯基键的含量为15〜30重量％（c）门尼粘度（ML1 + 4100℃）为15-50; 和（d）共聚物的分子量分布是双峰的，比率＆upbar＆Mw /＆lt;上升＆Mn为1.4-2.2，其中＆Upbar＆Mw为重均分子量，＆lt;上升＆Mn为数均分子量。

12. 发明申请

US20060030677A1 Modified polymers prepared with lanthanide-based catalysts 有权
公开(公告)号：US20060030677A1
公开(公告)日：2006-02-09
申请号：US11244999
申请日：2005-10-06
申请人： Yoichi Ozawa , H. Miller , Koji Masaki , Tatsuo Fujimaki , Takuo Sone , Iwakazu Hattori , Koichi Morita
发明人： Yoichi Ozawa , H. Miller , Koji Masaki , Tatsuo Fujimaki , Takuo Sone , Iwakazu Hattori , Koichi Morita
IPC分类号： C08F8/00
CPC分类号： C08C19/44 , C08F136/04 , C08K3/36 , C08L7/00 , C08L9/06 , C08L19/006 , C08F4/545 , C08L2666/08
摘要： A method for preparing a functionalized polymer comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with at least one functionalizing agent defined by the formula (I) where A is a substituent that will undergo an addition reaction with a pseudo-living polymer, R1 is a divalent organic group, R2 is a monovalent organic group, and each R4, which may be the same or different, is a monovalent organic group or a substituent defined by —OR5 where R5 is a monovalent organic group, with the proviso that A, R1, R2, R4, and R5 are substituents that will not protonate a pseudo-living polymer. Also, the functionalized polymer and a vulcanizable composition containing the polymer.

13. 发明授权

US06992147B1 Modified polymers prepared with lanthanide-based catalysts 有权
标题翻译：用镧系元素催化剂制备的改性聚合物
公开(公告)号：US06992147B1
公开(公告)日：2006-01-31
申请号：US10296084
申请日：2000-11-10
申请人： Yoichi Ozawa , H. Jerrold Miller , Koji Masaki , Tatsuo Fujimaki , Takuo Sone , Iwakazu Hattori , Koichi Morita
发明人： Yoichi Ozawa , H. Jerrold Miller , Koji Masaki , Tatsuo Fujimaki , Takuo Sone , Iwakazu Hattori , Koichi Morita
IPC分类号： C08C19/00 , C08F8/00
CPC分类号： C08C19/44 , C08F136/04 , C08K3/36 , C08L7/00 , C08L9/06 , C08L19/006 , C08F4/545 , C08L2666/08
摘要： A method for preparing a functionalized polymer comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with at least one functionalizing agent defined by the formula (I) where A is a substituent that will undergo an addition reaction with a pseudo-living polymer, R1 is a divalent organic group, R2 is a monovalent organic group, and each R4, which may be the same or different, is a monovalent organic group or a substituent defined by —OR5 where R5 is a monovalent organic group, with the proviso that A, R1, R2, R4, and R5 are substituents that will not protonate a pseudo-living polymer. Also, the functionalized polymer and a vulcanizable composition containing the polymer.
摘要翻译：一种制备官能化聚合物的方法，包括以下步骤：通过使共轭二烯单体与镧系元素基催化剂聚合制备假活性聚合物，并使假活性聚合物与至少一种由式（I）定义的官能化试剂反应，其中 A是将与假活性聚合物进行加成反应的取代基，R 1是二价有机基团，R 2是一价有机基团，并且每个R 可以相同或不同的一价有机基团或由-OR 5定义的取代基，其中R 5是一价有机基团，条件是A，R 1，R 2，R 4和R 5都是不会将假活性聚合物质子化的取代基。此外，官能化聚合物和含有聚合物的可硫化组合物。

14. 发明授权

US5011888A Vulcanized rubber composition 失效
标题翻译：硫化橡胶组合物
公开(公告)号：US5011888A
公开(公告)日：1991-04-30
申请号：US449308
申请日：1989-12-06
申请人： Fumio Tsutsumi , Akihiko Morikawa , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuro Hamada , Tatsuo Fujimaki , Masayuki Ohashi
发明人： Fumio Tsutsumi , Akihiko Morikawa , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuro Hamada , Tatsuo Fujimaki , Masayuki Ohashi
IPC分类号： C08L9/06 , B60C1/00 , C08F297/04 , C08G18/69 , C08L21/00 , C08L53/00 , C08L53/02
CPC分类号： C08L53/02 , B60C1/0016 , C08G18/69 , C08L21/00 , C08G2380/00
摘要： A rubber composition is disclosed which contains not less than 20% by weight in a rubber component of a block copolymer composed of polymer or copolymer block units (A) and a random copolymer block units (B). The polymer or copolymer block units (A) are obtained by singly polymerizing a conjugated diolefine or copolymerizing the conjugated diolefine and a monovinyl aromatic hydrocarbon with use of a lithium initiator and contains not more than 10% by weight of the bound monovinyl aromatic hydrocarbon. The random copolymer block unit (B) are obtained by copolymerizing the conjugated diolefine and the monovinyl aromatic hydrocarbon and contain 15 to 80% by weight of the bound monovinyl aromatic hydrocarbon. In the block copolymer, (i) the block copolymer contains not less than 10% by weight of each of the block units (A) and the block units (B); (ii) the total content of the bound monovinyl aromatic hydrocarbon is from 10 to 40% by weight; (iii) the average content of the vinyl bonds in the conjugated diolefine portions is from 20 to 70%; and (iv) polymerizable terminals of the block copolymer are reacted with an isocyanate compound.
摘要翻译：公开了在由聚合物或共聚物嵌段单元（A）和无规共聚物嵌段单元（B）组成的嵌段共聚物的橡胶组分中不少于20重量％的橡胶组合物。聚合物或共聚物嵌段单元（A）是通过使共轭二烯烃单独聚合或使用锂引发剂共轭共轭二烯和单乙烯基芳族烃而得到的，并且含有不超过10重量％的结合的单乙烯基芳烃。无规共聚物嵌段单元（B）通过使共轭二烯烃和单乙烯基芳族烃共聚而得到，并含有15〜80重量％的结合的单乙烯基芳烃。在嵌段共聚物中，（i）嵌段共聚物含有不少于块单元（A）和嵌段单元（B）的10重量％。（ii）结合的单乙烯基芳烃的总含量为10〜40重量％（iii）共轭二烯烃部分中的乙烯基键的平均含量为20〜70％。和（iv）嵌段共聚物的可聚合端与异氰酸酯化合物反应。

15. 发明授权

US4782119A Rubber composition comprising a styrene-butadiene block copolymer having two kinds of blocks 失效
标题翻译：包含具有两种嵌段的苯乙烯 - 丁二烯嵌段共聚物的橡胶组合物
公开(公告)号：US4782119A
公开(公告)日：1988-11-01
申请号：US769923
申请日：1985-08-27
申请人： Fumio Tsutsumi , Akio Iakashima , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuo Fujimaki , Yoshiyuki Morimoto
发明人： Fumio Tsutsumi , Akio Iakashima , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuo Fujimaki , Yoshiyuki Morimoto
IPC分类号： C08L7/00 , B60C1/00 , C08F297/04 , C08L1/00 , C08L9/06 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L53/00 , C08L53/02 , C08L77/00 , C08L101/00
CPC分类号： B60C1/0016 , C08F297/044 , Y10S525/914
摘要： A rubber composition containing at least 20% by weight of a styrene-butadiene block copolymer consisting of a block (A) and a block (B) characterized in that: (i) the block (A) is a styrene-butadiene copolymer block having the content of styrene of 10-80% by weight and the average content of the vinyl bonds in the butadiene portion of 30-70% by weight; (ii) the block (B) is a polybutadiene block with the average content of the vinyl bonds in the butadiene portion being not more than 60% by weight (iii) the styrene-butadiene block copolymer contains at least 20% by weight of each of the block (A) and the block (B); (iv) the average content of the vinyl bonds in the butadiene portion of the block (A) is greater by at least 5% by weight than that of the block (B); (v) the glass transition temperature of the block (A) is higher by at least 30.degree. C. than that of the block (B); (vi) the whole content of the bound styrene in the above block copolymer is 5-40% by weight; (vii) the ratio Mw/Mn between the weight average molecular weight Mw and the number average molecular weight Mn of the block copolymer is 1.8-5.0 when calculated as polystyrene according to the gel permeation chromatogram; and (viii) the Mooney's viscosity (ML.sub.1+4.sup.100.degree. C.) of the block copolymer is 20-150.
摘要翻译：一种含有至少20重量％由嵌段（A）和嵌段（B）组成的苯乙烯 - 丁二烯嵌段共聚物的橡胶组合物，其特征在于：（i）嵌段（A）是苯乙烯 - 丁二烯共聚物嵌段，其具有苯乙烯含量为10-80重量％，丁二烯部分中乙烯基键的平均含量为30-70重量％; （ii）嵌段（B）是丁二烯部分中乙烯基键的平均含量不大于60重量％的聚丁二烯嵌段（iii）苯乙烯 - 丁二烯嵌段共聚物含有至少20重量％（A）和块（B）; （iv）嵌段（A）的丁二烯部分中的乙烯基键的平均含量比块（B）的平均含量高至少5重量％。（v）嵌段（A）的玻璃化转变温度比嵌段（B）的玻璃化转变温度高至少30℃; （vi）上述嵌段共聚物中的结合苯乙烯的全部含量为5-40重量％（vii）根据凝胶渗透色谱法计算，当以聚苯乙烯计算时，嵌段共聚物的重均分子量Mw与数均分子量Mn之比Mw / Mn为1.8-5.0; 和（viii）嵌段共聚物的门尼粘度（ML1 + 4100℃）为20-150℃。

16. 发明授权

US08618199B2 Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents 有权
公开(公告)号：US08618199B2
公开(公告)日：2013-12-31
申请号：US13711701
申请日：2012-12-12
申请人： Yoichi F. Ozawa , H. Jerrold Miller , Koji Masaki , Koichi Morita , Tatsuo Fujimaki , Tetsuya Omura , Takuo Sone , Iwakazu Hattori
发明人： Yoichi F. Ozawa , H. Jerrold Miller , Koji Masaki , Koichi Morita , Tatsuo Fujimaki , Tetsuya Omura , Takuo Sone , Iwakazu Hattori
IPC分类号： C08K5/13 , C08C19/22
CPC分类号： C08F136/14 , C08C19/00 , C08C19/22 , C08C19/44 , C08F36/04 , C08F136/06 , C08K3/04 , C08K3/045 , C08K3/36 , C08L21/00 , C08L91/00 , C08F4/545 , C08L15/00
摘要： A method for preparing a functionalized polymer comprising the steps of preparing a polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, wherein the lanthanide-based catalyst comprises (a) a lanthanide compound, (b) an alkylating agent, and (c) a source of halogen, and reacting the pseudo-living polymer with at least one amide-containing functionalizing agent.

17. 发明授权

US5066721A Tires made of silica filled, silane modified rubber 失效
标题翻译：硅胶填充的轮胎，硅烷改性橡胶
公开(公告)号：US5066721A
公开(公告)日：1991-11-19
申请号：US202658
申请日：1988-05-31
申请人： Tatsuro Hamada , Hiromi Fukuoka , Hideki Komatsu , Tatsuo Fujimaki
发明人： Tatsuro Hamada , Hiromi Fukuoka , Hideki Komatsu , Tatsuo Fujimaki
IPC分类号： B60C1/00 , C08C19/44 , C08F8/42 , C08K3/36 , C08L15/00 , C08L21/00 , C08L25/18
CPC分类号： B60C1/0016 , C08C19/44
摘要： There is a tire having tire performances such as wear resistance, cut resistance, heat build-up and the like and a processability simultaneously and economically improved by the application of a rubber composition containing a rubbery polymer modified with a silane compound and silica. The rubbery polymer modified with the silane compound is obtained by reacting an active terminal of a living polymer, which is obtained by polymerizing a monomer in the presence of an organic alkali metal catalyst, with a silane compound represented by the following general formula:X.sub.n Si(OR).sub.m R'.sub.4-m-n(where X is a halogen atom selected from a chlorine atom, a bromine atom and an iodine atom, OR is a non-hydrolyzable alkoxy group having a carbon number of 4.about.20, an aryloxy group or a cycloalkoxy group, R' is an alkyl group having a carbon number of 1.about.20, an aryl group, a vinyl group or a halogenated alkyl group, m is an integer of 1.about.4, n is an integer of 0.about.2, and a sum of n and m is 2.about.4), which is contained in an amount of not less than 10% by weight as a rubber ingredient, and silica is contained in an amount of 5.about.200 parts by weight based on 100 parts by weight of the rubber ingredient.

18. 发明授权

US5017636A Rubber compositions from modified trans-polybutadiene and rubber for tires 失效
标题翻译：来自改性反式聚丁二烯和轮胎橡胶的橡胶组合物
公开(公告)号：US5017636A
公开(公告)日：1991-05-21
申请号：US521008
申请日：1990-05-10
申请人： Iwakazu Hattori , Noboru Shimada , Noboru Oshima , Mitsuhiko Sakakibara , Hiroshi Mouri , Tatsuo Fujimaki , Tatsuro Hamada
发明人： Iwakazu Hattori , Noboru Shimada , Noboru Oshima , Mitsuhiko Sakakibara , Hiroshi Mouri , Tatsuo Fujimaki , Tatsuro Hamada
IPC分类号： C08C19/44 , C08L15/00
CPC分类号： C08C19/44 , C08L15/00 , C08K3/04 , C08K5/01 , C08K5/09 , C08L7/00 , C08L9/00 , C08L9/06
摘要： A rubber composition for tire having improved processability, wear resistance, rebound resilience and heat build-up comprises 20.about.70 parts by weight of a specified butadiene polymer, 30.about.80 parts by weight of at least one rubber selected from natural rubber, high cis-1,4 polyisoprene rubber and styrene-butadiene copolymer rubber, and 0.about.30 parts by weight of high cis-1,4 polybutadiene and/or low cis-1,4 polybutadiene, and contains 35.about.100 parts by weight of carbon black, 0.about.50 parts by weight of process oil, 0.5.about.5 parts by weight of aliphatic carboxylic acid and 0.1.about.3 parts by weight of sulfur based on 100 parts by weight of the above rubber components.
摘要翻译：具有改善的加工性，耐磨性，回弹性和发热性的轮胎用橡胶组合物包含20重量份指定的丁二烯聚合物，30重量份至少一种选自天然橡胶，高顺式 -1,4-聚异戊二烯橡胶和苯乙烯 - 丁二烯共聚物橡胶，和0分钟30重量份的高顺式-1,4聚丁二烯和/或低顺-1,4聚丁二烯，并含有35重量％的炭黑，0差异基于100重量份的上述橡胶组分，加工油50重量份，0.5重量份脂肪族羧酸和0.1重量份3重量份的硫。

19. 发明授权

US4894409A Rubber composition 失效
标题翻译：橡胶组成
公开(公告)号：US4894409A
公开(公告)日：1990-01-16
申请号：US218797
申请日：1988-07-14
申请人： Noboru Shimada , Iwakazu Hattori , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuro Hamada , Hiromi Fukuoka , Tatsuo Fujimaki
发明人： Noboru Shimada , Iwakazu Hattori , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuro Hamada , Hiromi Fukuoka , Tatsuo Fujimaki
IPC分类号： C08K3/36 , C08C19/44 , C08F4/00 , C08K3/00 , C08L15/00 , C08L21/00
CPC分类号： C08C19/44 , C08L21/00
摘要： A rubber composition comprising not less than 20% by weight of an amino group-containing diene based polymer in a rubber component, and 10 to 100 parts by weight of silica as a filler with respect to 100 parts by weight of the rubber component. The amino group-containing diene based polymer is obtained by polymerizing a monomer or copolymerizing the monomer in an organic solvent in the presence of at least one of an organic alkali metal and an organic alkaline earth metal.
摘要翻译：橡胶组合物，相对于100重量份的橡胶组分，包含不少于20重量％的在橡胶组分中含氨基的二烯基聚合物和10至100重量份作为填料的二氧化硅。含有氨基的二烯系聚合物通过在有机碱金属和有机碱土金属中的至少一种的存在下，使单体聚合或在有机溶剂中共聚而得到。

20. 发明授权

US4812525A Polybutadiene rubber composition 失效
标题翻译：聚丁二烯橡胶组合物
公开(公告)号：US4812525A
公开(公告)日：1989-03-14
申请号：US74172
申请日：1987-07-16
申请人： Noboru Oshima , Yoshishige Chikatsu , Toshiaki Fukuhori , Tatsuro Hamada , Tatsuo Fujimaki
发明人： Noboru Oshima , Yoshishige Chikatsu , Toshiaki Fukuhori , Tatsuro Hamada , Tatsuo Fujimaki
IPC分类号： B60C1/00 , C08C19/44 , C08F8/42 , C08L9/00 , C08L21/00
CPC分类号： C08C19/44 , C08L9/00
摘要： A rubber composition is disclosed which contains, as a rubber component, 20-100% by weight of (A) polybutadiene polymerized by using a lithium initiator and 80 to 0% by weight of (B) another rubber component. The polybutadiene has the following physical properties (i)-(v):(i) The molecular weight distribution of Mw/Mn is 1.4 to 3.0 in which Mw and Mn are a weight average molecular weight and a number average molecular weight, respectively;(ii) A polymer component having the molecular weight being not more than 10.sup.5 when calculated as polystyrene is from 7 to 25%;(iii) The content of bound vinyl groups is from 10 to 25%;(iv) The content of tin atoms bonded to the polymer by tin-carbon bonds is not less than 50 ppm;(v) Mooney viscosity (ML.sub.1+4, 100.degree. C.) is from 20 to 70.
摘要翻译：公开了一种橡胶组合物，其包含作为橡胶组分的20-100重量％的（A）使用锂引发剂聚合的聚丁二烯和80至0重量％的（B）另一种橡胶组分的橡胶组合物。聚丁二烯具有以下物理性质（i） - （v）：（i）Mw / Mn的分子量分布分别为1.4〜3.0，其中Mw和Mn分别为重均分子量和数均分子量; （ii）当以聚苯乙烯计算时分子量不大于105的聚合物组分为7至25％; （iii）结合乙烯基的含量为10〜25％。（iv）通过锡 - 碳键与聚合物键合的锡原子的含量不小于50ppm; （v）门尼粘度（ML1 + 4,100℃）为20〜70。

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