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11. 发明申请

US20110124782A1 FLUORINATED ETHER COMPOUNDS AND METHODS OF USING THE SAME 失效
标题翻译：氟化醚化合物及其使用方法
公开(公告)号：US20110124782A1
公开(公告)日：2011-05-26
申请号：US13054601
申请日：2009-07-15
申请人： Rudolf J. Dams , Michael S. Terrazas , Klaus Hintzer , Zai-Ming Qiu , Miguel A. Guerra , Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Tilman C. Zipplies , Werner Schwertfeger
发明人： Rudolf J. Dams , Michael S. Terrazas , Klaus Hintzer , Zai-Ming Qiu , Miguel A. Guerra , Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Tilman C. Zipplies , Werner Schwertfeger
IPC分类号： C08K5/53 , C07F9/28 , C08K5/19 , C08K5/095 , C08K5/06 , C08K5/101 , C08K5/20 , C07C229/04 , C08K5/36 , C07C53/21 , C07C211/02 , C07F9/06 , C09K3/00
CPC分类号： C07C235/10 , C07C69/708 , C07C211/11 , C07C211/14 , C07C291/04 , C07C309/14 , C07F9/091 , C07F9/3808 , C08G65/007
摘要： Compounds represented by formula (Rf-Q-X)s—Z. Each Rf is independently a partially fluorinated or fully fluorinated group selected from Rfa-(O)r—CHF—(CF2)n—; [Rfb-(O)tC(L)H—CF2—O]m—W—; CF3CFH—O—(CF2)p—; CF3—(O—CF2)z—; and CF3—O—(CF2)3—O—CF2—. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compounds are also disclosed.
摘要翻译：由式（Rf-Q-X）s-Z表示的化合物。每个Rf独立地是选自Rfa-（O）r -CHF-（CF 2）n - 的部分氟化或完全氟化基团; [Rfb-（O）tC（L）H-CF2-O] m -W-; CF 3 CFH-O-（CF 2）p-; CF 3 - （O-CF 2）z - ; 和CF 3 -O-（CF 2）3 -O-CF 2 - 。还公开了降低液体的表面张力，制造泡沫以及使用该化合物处理表面的方法。

12. 发明申请

US20110124532A1 FLUORINATED ETHER SILANES AND METHODS OF USING THE SAME 审中-公开
标题翻译：氟化硅烷及其使用方法
公开(公告)号：US20110124532A1
公开(公告)日：2011-05-26
申请号：US13054579
申请日：2009-07-16
申请人： Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Michael S. Terrazas , Miguel A. Guerra , Rudolf J. Dams , Tilman C. Zipplies , Zai-Ming Qiu , Klaus Hintzer , Werner Schwertfeger
发明人： Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Michael S. Terrazas , Miguel A. Guerra , Rudolf J. Dams , Tilman C. Zipplies , Zai-Ming Qiu , Klaus Hintzer , Werner Schwertfeger
IPC分类号： C09K8/60 , C07F7/18 , C08G77/26
CPC分类号： C07F7/1804
摘要： Fluorinated compounds represented by formula Rf-Q-X—[Si(R)f(R1)3-f]g. Each Rf is independently a partially fluorinated or fully fluorinated group selected from Rfa-(O)r-CHF—(CF2)n-; [Rfb-(O)t-C(L)H—CF2—O]m-W—; CF3CFH—O—(CF2)p-; CF3—(O—CF2)z-; and CF3—O—(CF2)3—O—CF2—. Methods of treating a surface or a hydrocarbon-bearing formation using the fluorinated compounds and treated articles and treated hydrocarbon-bearing formations are also disclosed.
摘要翻译：由式Rf-Q-X- [Si（R）f（R 1）3-f] g表示的氟化合物。每个Rf独立地是选自Rfa-（O）r -CHF-（CF 2）n - 的部分氟化或完全氟化基团; [Rfb-（O）t -C（L）H-CF 2 -O] m -W-; CF 3 CFH-O-（CF 2）p-; CF 3 - （O-CF 2）z - ; 和CF 3 -O-（CF 2）3 -O-CF 2 - 。还公开了使用含氟化合物和经处理的制品和经处理的含烃地层处理表面或含烃地层的方法。

13. 发明授权

US08633288B2 Fluorinated ether compounds and methods of using the same 失效
标题翻译：氟化醚化合物及其使用方法
公开(公告)号：US08633288B2
公开(公告)日：2014-01-21
申请号：US13054601
申请日：2009-07-15
申请人： Rudolf J. Dams , Michael S. Terrazas , Klaus Hintzer , Zai-Ming Qiu , Miguel A. Guerra , Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Tilman C. Zipplies , Werner Schwertfeger
发明人： Rudolf J. Dams , Michael S. Terrazas , Klaus Hintzer , Zai-Ming Qiu , Miguel A. Guerra , Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Tilman C. Zipplies , Werner Schwertfeger
IPC分类号： C08F4/44
CPC分类号： C07C235/10 , C07C69/708 , C07C211/11 , C07C211/14 , C07C291/04 , C07C309/14 , C07F9/091 , C07F9/3808 , C08G65/007
摘要： Compounds represented by formula (Rf-Q-X)s—Z. Each Rf is independently a partially fluorinated or fully fluorinated group selected from Rfa-(O)r—CHF—(CF2)n—; [Rfb-(O)tC(L)H—CF2—O]m—W—; CF3CFH—O—(CF2)p—; CF3—(O—CF2)z—; and CF3—O—(CF2)3—O—CF2—. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compounds are also disclosed.
摘要翻译：由式（Rf-Q-X）s-Z表示的化合物。每个Rf独立地是选自Rfa-（O）r -CHF-（CF 2）n - 的部分氟化或完全氟化基团; [Rfb-（O）tC（L）H-CF2-O] m -W-; CF 3 CFH-O-（CF 2）p-; CF 3 - （O-CF 2）z - ; 和CF 3 -O-（CF 2）3 -O-CF 2 - 。还公开了降低液体的表面张力，制造泡沫以及使用该化合物处理表面的方法。

14. 发明授权

US07160850B2 Compositions of monomeric surfactants 失效
标题翻译：单体表面活性剂的组成
公开(公告)号：US07160850B2
公开(公告)日：2007-01-09
申请号：US11027410
申请日：2004-12-30
申请人： Rudolf J. Dams , Michael S. Terrazas , Michael J. Sierakowski , George G. I. Moore
发明人： Rudolf J. Dams , Michael S. Terrazas , Michael J. Sierakowski , George G. I. Moore
IPC分类号： C11D1/00 , C11D3/20 , C11D3/24 , C11D3/26 , C11D3/34
CPC分类号： C09D11/03 , C08K5/435 , C09D7/63
摘要： Described are monomeric fluorosurfactants having two perfluoro-lower-alkyl sulfonamido segments which are more efficient and effective in lowering the surface tension of organic solvents and water compared to other C4-based fluorosurfactants.
摘要翻译：描述了具有两个全氟低级烷基亚磺酰氨基链段的单体含氟表面活性剂，与其它基于C4的含氟表面活性剂相比，其降低有机溶剂和水的表面张力更有效和有效。

15. 发明授权

US08476385B2 Fluorinated ether compositions and methods of using the same 失效
标题翻译：氟化醚组合物及其使用方法
公开(公告)号：US08476385B2
公开(公告)日：2013-07-02
申请号：US12602877
申请日：2008-06-06
申请人： Rudolf J. Dams , Miguel A. Guerra , Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Zai-Ming Qiu , Werner Schwertfeger , Michael S. Terrazas , Tilman C. Zipplies
发明人： Rudolf J. Dams , Miguel A. Guerra , Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Zai-Ming Qiu , Werner Schwertfeger , Michael S. Terrazas , Tilman C. Zipplies
IPC分类号： C08F18/20
CPC分类号： C08F220/24 , C08F220/28 , C08F220/36 , C08F230/08 , C08G65/007 , C08L33/08 , C08L35/06 , C09D133/08 , C09D133/14 , C09D135/06 , C08L2666/04
摘要： A composition including at least one first divalent unit represented by formula: Each Rf is independently selected from the group consisting of Rfa—(O)t—CHF—(CF2)n—; [Rfa—(O)t—C(L)H—CF2—O]m—W—; Rfb-O—(CF2)p-; F(CkF2k)—(O—CkF2k)P—O—CF2—; and CF3—O—(CF2)3—(OCF(CF3)—CF2)Z—O-L1-. Each Q is independently selected from the group consisting of a bond, —C(O)—N(R1)—, and —C(O)—O—. Each X is independently selected from the group consisting of alkylene and arylalkylene, wherein alkylene and arylalkylene are each optionally interrupted by at least one ether linkage and optionally terminated by —N(R1)—C(O)— or —O—C(O)—. R and R1 are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. Rfa represents a partially or fully fluorinated alkyl group having from 1 to 10 carbon atoms and optionally interrupted with at least one oxygen atom. Rfb is selected from the group consisting of CF3CFH— and F(CjF2j)-. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compositions are also disclosed.
摘要翻译：包含至少一个由式表示的第一二价单元的组合物：每个Rf独立地选自Rfa-（O）t-CHF-（CF 2）n - ; [Rfa-（O）t -C（L）H-CF 2 -O] m -W-; Rfb-O-（CF2）p-; F（CkF2k） - （O-CkF2k）P-O-CF2-; 和CF 3 -O-（CF 2）3 - （OCF（CF 3）-CF 2）Z-O-L 1。每个Q独立地选自由键，-C（O）-N（R 1） - 和-C（O）-O-组成的组。每个X独立地选自亚烷基和芳基亚烷基，其中亚烷基和芳基亚烷基各自任选地被至少一个醚键中断，并且任选地被-N（R 1）-C（O） - 或-OC（O） - 。 R和R 1各自独立地选自氢和具有1至4个碳原子的烷基。 Rfa表示具有1至10个碳原子并且任选被至少一个氧原子中断的部分或完全氟化的烷基。 Rfb选自CF 3 CFH-和F（C 1 F 2）） - 。还公开了降低液体的表面张力，制造泡沫和使用组合物处理表面的方法。

16. 发明申请

US20100270021A1 METHODS FOR TREATING HYDROCARBON-BEARING FORMATIONS WITH FLUORINATED POLYMER COMPOSITIONS 有权
标题翻译：用氟化聚合物组合物处理碳氢化合物载体的方法
公开(公告)号：US20100270021A1
公开(公告)日：2010-10-28
申请号：US12809683
申请日：2008-12-18
申请人： Jimmie R. Baran, JR. , Michael S. Terrazas , Rudolf J. Dams , George G.I. Moore
发明人： Jimmie R. Baran, JR. , Michael S. Terrazas , Rudolf J. Dams , George G.I. Moore
IPC分类号： E21B43/16 , C09K8/60
CPC分类号： C09K8/80 , C09K8/604
摘要： A method of treating a hydrocarbon-bearing formation and treated hydrocarbon-bearing formations. The method includes contacting the hydrocarbon-bearing formation with a composition having solvent and a fluorinated polymer. The fluorinated polymer has units having formula (I): A method for making a composition containing these units is also disclosed.
摘要翻译：一种处理含烃地层和经处理的含烃地层的方法。该方法包括使含烃地层与具有溶剂和含氟聚合物的组合物接触。氟化聚合物具有式（I）的单元：还公开了制备含有这些单元的组合物的方法。

17. 发明申请

US20100270020A1 METHODS FOR TREATING HYDROCARBON-BEARING FORMATIONS WITH FLUORINATED ANIONIC SURFACTANT COMPOSITIONS 审中-公开
标题翻译：用氟化阴离子表面活性剂组合物处理碳氢化合物载体的方法
公开(公告)号：US20100270020A1
公开(公告)日：2010-10-28
申请号：US12809615
申请日：2008-12-18
申请人： Jimmie R. Baran, Jr. , Michael S. Terrazas , Rudolf J. Dams
发明人： Jimmie R. Baran, Jr. , Michael S. Terrazas , Rudolf J. Dams
IPC分类号： E21B43/16 , C09K8/68 , E21B43/00
CPC分类号： C09K8/80 , C09K8/604
摘要： Methods of treating a hydrocarbon-bearing formation having brine and liquid hydrocarbons and treated hydrocarbon-bearing formations. The methods include contacting the hydrocarbon-bearing formation with a composition comprising solvent and a fluorinated anionic surfactant. In some embodiments, the solvent solubilizes the brine in the hydrocarbon-bearing formation without causing the fluorinated anionic surfactant to precipitate. In some embodiments, the solvent includes at least one of a polyol or polyol ether independently having from 2 to 25 carbon atoms and at least one of water, a monohydroxy alcohol, an ether, or a ketone, wherein the monohydroxy alcohol, the ether, and the ketone each independently have up to 4 carbon atoms.
摘要翻译：处理具有盐水和液态烃和经处理的含烃地层的含烃地层的方法。所述方法包括使含烃地层与包含溶剂和氟化阴离子表面活性剂的组合物接触。在一些实施方案中，溶剂将盐水溶解在含烃地层中，而不会使氟化阴离子表面活性剂沉淀。在一些实施方案中，溶剂包括独立地具有2至25个碳原子的多元醇或多元醇醚和至少一种水，单羟基醇，醚或酮，其中所述单羟基醇，醚，并且酮各自独立地具有至多4个碳原子。

18. 发明申请

US20100179262A1 FLUORINATED ETHER COMPOSITIONS AND METHODS OF USING THE SAME 失效
标题翻译：氟化醚组合物及其使用方法
公开(公告)号：US20100179262A1
公开(公告)日：2010-07-15
申请号：US12602877
申请日：2008-06-06
申请人： Rudolf J. Dams , Miguel A. Guerra , Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Zai-Ming Qiu , Worner Schwertfeger , Michael S. Terrazas , Tilman C. Zipplies
发明人： Rudolf J. Dams , Miguel A. Guerra , Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Zai-Ming Qiu , Worner Schwertfeger , Michael S. Terrazas , Tilman C. Zipplies
IPC分类号： C07C69/52 , C08K5/10 , C09K3/00 , C07F7/08
CPC分类号： C08F220/24 , C08F220/28 , C08F220/36 , C08F230/08 , C08G65/007 , C08L33/08 , C08L35/06 , C09D133/08 , C09D133/14 , C09D135/06 , C08L2666/04
摘要： A composition including at least one first divalent unit represented by formula: Each Rf is independently selected from the group consisting of Rfa—(O)t—CHF—(CF2)n—; [Rfa—(O)t—C(L)H—CF2—O]m—W—; Rfb-O—(CF2)p-; F(CkF2k)—(O—CkF2k)P—O—CF2—; and CF3—O—(CF2)3—(OCF(CF3)—CF2)Z—O-L1-. Each Q is independently selected from the group consisting of a bond, —C(O)—N(R1)—, and —C(O)—O—. Each X is independently selected from the group consisting of alkylene and arylalkylene, wherein alkylene and arylalkylene are each optionally interrupted by at least one ether linkage and optionally terminated by —N(R1)—C(O)— or —O—C(O)—. R and R1 are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. Rfa represents a partially or fully fluorinated alkyl group having from 1 to 10 carbon atoms and optionally interrupted with at least one oxygen atom. Rfb is selected from the group consisting of CF3CFH— and F(CjF2j)-. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compositions are also disclosed.
摘要翻译：包含至少一个由式表示的第一二价单元的组合物：每个Rf独立地选自Rfa-（O）t-CHF-（CF 2）n - ; [Rfa-（O）t -C（L）H-CF 2 -O] m -W-; Rfb-O-（CF2）p-; F（CkF2k） - （O-CkF2k）P-O-CF2-; 和CF 3 -O-（CF 2）3 - （OCF（CF 3）-CF 2）Z-O-L 1。每个Q独立地选自由键，-C（O）-N（R 1） - 和-C（O）-O-组成的组。每个X独立地选自亚烷基和芳基亚烷基，其中亚烷基和芳基亚烷基各自任选地被至少一个醚键中断，并且任选被-N（R 1）-C（O） - 或-O-C（O ） - 。 R和R 1各自独立地选自氢和具有1至4个碳原子的烷基。 Rfa表示具有1至10个碳原子并且任选被至少一个氧原子中断的部分或完全氟化的烷基。 Rfb选自CF 3 CFH-和F（C 1 F 2）） - 。还公开了降低液体的表面张力，制造泡沫和使用组合物处理表面的方法。

19. 发明申请

US20100168300A1 AQUEOUS COMPOSITIONS OF FLUORINATED SURFACTANTS AND METHODS OF USING THE SAME 失效
标题翻译：氟化表面活性剂的水性组合物及其使用方法
公开(公告)号：US20100168300A1
公开(公告)日：2010-07-01
申请号：US12601143
申请日：2008-05-21
申请人： Rudolf J. Dams , Michael S. Terrazas
发明人： Rudolf J. Dams , Michael S. Terrazas
IPC分类号： C08K5/42 , C08K5/09
CPC分类号： C11D1/004 , C09D5/027 , C09D7/45 , C09D7/47 , C09G1/04 , C11D3/37
摘要： Aqueous compositions comprising surfactant represented by a formula selected from the group consisting of: [Rf—(O)t—CHF—(CF2)n—COO−]iXi+; {[Rf—(O)t—CQH—CF2—O]m—R—COO−}iXi+; {[Rf—(O)t—CQH—CF2—O]m—R—SO3−)i, Xi+; and [CF3CFH—O—(CF2)p—COO−]iXi+; wherein Rf represents a partially or fully fluorinated aliphatic group optionally interrupted with at least one oxygen atom; Q is selected from the group consisting of F and CF3; R is selected from the group consisting of alkylene and arylene; X1+ represents a cation having a valence i, wherein i is 1, 2 or 3; t is O or 1; m is 1, 2, or 3; n is O or 1; and p is an integer from 1 to 6. In some aspects, the aqueous composition comprises a non-fluorinated polymer and is essentially free of fluoropolymers. In another aspect, the aqueous composition has a pH of greater than 11. In another aspect, the aqueous composition has a pH of at least 8 and is essentially free of fluorinated olefins. Methods of coating a surface and an article having a surface in contact with the composition are provided. Methods of cleaning a surface, and methods of lowering the surface tension of a liquid having a pH greater than 11 using aqueous compositions comprising the surfactants are also provided.
摘要翻译：包含由选自以下的式的表面活性剂组成的水性组合物：[Rf-（O）t-CHF-（CF 2）n -CO 2 - ] i X i + {[Rf-（O）t-CQH-CF2-O] m -R-COO-} iXi +; {[Rf-（O）t-CQH-CF2-O] m -R-SO3-）i，Xi + 和[CF 3 CFH-O-（CF 2）p-COO-] i X i +; 其中Rf表示任选被至少一个氧原子间断的部分或完全氟化的脂族基团; Q选自F和CF 3; R选自亚烷基和亚芳基; X1 +表示具有i价的阳离子，其中i为1,2或3; t为O或1; m为1,2或3; n为0或1; 并且p是1至6的整数。在一些方面，水性组合物包含非氟化聚合物，并且基本上不含含氟聚合物。另一方面，水性组合物的pH值大于11.另一方面，水性组合物的pH值至少为8，基本上不含氟化烯烃。提供涂覆表面和具有与组合物接触的表面的制品的方法。还提供了使用包含表面活性剂的水性组合物来清洁表面的方法和降低pH大于11的液体的表面张力的方法。

20. 发明授权

US07495118B2 Compositions containing C4-swallow tail silanes 失效
标题翻译：含C4-燕尾硅烷的组合物
公开(公告)号：US07495118B2
公开(公告)日：2009-02-24
申请号：US11027404
申请日：2004-12-30
申请人： Rudolf J. Dams , Michael S. Terrazas , George G. I. Moore
发明人： Rudolf J. Dams , Michael S. Terrazas , George G. I. Moore
IPC分类号： C07F7/10
CPC分类号： C04B41/009 , C04B41/4933 , C04B41/84 , C07F7/1804 , C04B41/4922 , C04B33/00
摘要： Described are perfluoro lower alkyl derived silanes having two perfluoroalkyl groups in close proximity to one another which in an organic solvent are useful in treating siliceous substrates; the compositions may optionally contain an additional non-fluorinated compound in a mixture or condensation product.
摘要翻译：描述了具有两个彼此紧邻的全氟烷基的全氟低级烷基衍生硅烷，其在有机溶剂中可用于处理硅质底物; 组合物可以任选地在混合物或缩合产物中含有另外的非氟化化合物。

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