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11. 发明申请

US20130131251A1 X-RAY AND/OR METAL DETECTABLE ARTICLES AND METHOD OF MAKING THE SAME 有权
标题翻译： X射线和/或金属检测文章及其制备方法
公开(公告)号：US20130131251A1
公开(公告)日：2013-05-23
申请号：US13743560
申请日：2013-01-17
申请人： Christopher Luke Hein , Jan-Pleun Lens , Vandita Pai-Paranjape , Constant Peek , Robert Dirk van de Grampel
发明人： Christopher Luke Hein , Jan-Pleun Lens , Vandita Pai-Paranjape , Constant Peek , Robert Dirk van de Grampel
IPC分类号： C08L69/00
CPC分类号： C08L69/00 , C08G77/448 , C08L83/10 , Y10T428/25 , Y10T428/257 , C08L83/00
摘要： An article and thermoplastic composition including polycarbonate, a polysiloxane-polycarbonate and an x-ray detectable or metal detectable agent having good magnetic permeability and/or electrical conductivity wherein the composition may be used in articles for food preparation. The thermoplastic compositions are useful in forming molds for manufacturing a food product, such as chocolate molds.
摘要翻译：包括聚碳酸酯，聚硅氧烷 - 聚碳酸酯和具有良好磁导率和/或电导率的x射线可检测或金属可检测试剂的制品和热塑性组合物，其中所述组合物可用于食品制备用制品中。热塑性组合物可用于形成用于制造食品的模具，例如巧克力模具。

12. 发明申请

US20110160406A1 BLENDS OF ISOSORBIDE-BASED COPOLYCARBONATE, METHOD OF MAKING, AND ARTICLES FORMED THEREFROM 有权
标题翻译：基于异构体的共聚碳酸酯的混合物，制备方法和形成的制品
公开(公告)号：US20110160406A1
公开(公告)日：2011-06-30
申请号：US12893479
申请日：2010-09-29
申请人： Hans de Brouwer , Robert Dirk van de Grampel , Jan Henk Kamps , Jan Pleun Lens
发明人： Hans de Brouwer , Robert Dirk van de Grampel , Jan Henk Kamps , Jan Pleun Lens
IPC分类号： C08L69/00
CPC分类号： C08L69/00 , C08G64/0266 , C08G64/1666 , C08G64/186 , C08L83/10 , C08L2205/02 , C08L2666/18
摘要： Disclosed herein is are thermoplastic compositions comprising a blend of a homopolycarbonate comprising units derived from an aromatic dihydroxy compound and a copolymer comprising isosorbide units and siloxane units. The copolymer comprising isosorbide units and siloxane units can further comprise non-isosorbide aliphatic units derived from a C14-44 aliphatic diacid, a C14-44 aliphatic diol or combination of these, aromatic units, aliphatic units derived from an oligomer having a weight average molecular weight of 900 to 4000 or a combination of some or all of the foregoing additional units.
摘要翻译：本文公开的是包含均匀聚碳酸酯的共混物的热塑性组合物，其包含衍生自芳族二羟基化合物的单元和包含异山梨醇单元和硅氧烷单元的共聚物。包含异山梨醇单元和硅氧烷单元的共聚物还可以包含衍生自C14-44脂族二酸，C14-44脂族二醇或它们的组合的芳基单元，衍生自重均分子重量为900至4000，或者部分或全部上述附加单元的组合。

13. 发明授权

US07829632B2 Polyester polycarbonate compositions, methods of making, and articles formed therefrom 有权
标题翻译：聚酯聚碳酸酯组合物，制造方法和由其形成的制品
公开(公告)号：US07829632B2
公开(公告)日：2010-11-09
申请号：US11741835
申请日：2007-04-30
申请人： Shreyas Chakravarti , Bernardus Antonius Gerardus Schrauwen , Robert Dirk van de Grampel
发明人： Shreyas Chakravarti , Bernardus Antonius Gerardus Schrauwen , Robert Dirk van de Grampel
IPC分类号： C08L75/00 , C08L37/00 , C08F8/00
CPC分类号： C08L67/02 , C08L69/005 , C08L2205/02 , C08L2666/18
摘要： A composition comprises a polyester-polycarbonate polymer comprising isophthalate-terephthalate-resorcinol ester units and carbonate units, a poly(C4-alkylene) ester, and a polyester comprising cyclohexanedimethylene terephthalate units, or a combination of cyclohexanedimethylene terephthalate and ethylene terephthalate. The composition can be extruded into pellets that are clear and colorless. The composition can further be molded into articles having a percent haze value less than or equal to 10 percent, and total luminous transmittance value of greater than or equal to 70 percent, measured in accordance with ASTM D1003-00. Also disclosed is a method for forming the compositions, and articles prepared therefrom.
摘要翻译：组合物包含含有间苯二甲酸酯 - 对苯二甲酸酯 - 间苯二酚酯单元和碳酸酯单元的聚酯 - 聚碳酸酯聚合物，聚（C 4 - 亚烷基）酯和包含环己烷二亚甲基对苯二甲酸酯单元的聚酯，或对苯二甲酸环己烷二甲酯和对苯二甲酸乙二醇酯的组合。该组合物可以挤出成为澄清和无色的颗粒。根据ASTM D1003-00测量，组合物可以进一步模塑成具有小于或等于10％的雾度值百分比，总透光率值大于或等于70％的制品。还公开了形成组合物的方法及其制备的制品。

14. 发明申请

US20100124644A1 X-RAY AND/OR METAL DETECTABLE ARTICLES AND METHOD OF MAKING THE SAME 有权
标题翻译： X射线和/或金属检测文章及其制备方法
公开(公告)号：US20100124644A1
公开(公告)日：2010-05-20
申请号：US12570421
申请日：2009-09-30
申请人： Christopher Luke Hein , Jan-Pleun Lens , Vandita Pai-Paranjape , Constant Peek , Robert Dirk van de Grampel
发明人： Christopher Luke Hein , Jan-Pleun Lens , Vandita Pai-Paranjape , Constant Peek , Robert Dirk van de Grampel
IPC分类号： G21F1/10 , B32B27/00 , H01F1/09
CPC分类号： C08L69/00 , C08G77/448 , C08L83/10 , Y10T428/25 , Y10T428/257 , C08L83/00
摘要： An article and thermoplastic composition including polycarbonate, a polysiloxane-polycarbonate and an x-ray detectable or metal detectable agent having good magnetic permeability and/or electrical conductivity wherein the composition may be used in articles for food preparation. The thermoplastic compositions are useful in forming molds for manufacturing a food product, such as chocolate molds.
摘要翻译：包括聚碳酸酯，聚硅氧烷 - 聚碳酸酯和具有良好磁导率和/或电导率的x射线可检测或金属可检测试剂的制品和热塑性组合物，其中所述组合物可用于食品制备用制品中。热塑性组合物可用于形成用于制造食品的模具，例如巧克力模具。

15. 发明授权

US07687583B2 Polyester polycarbonate compositions, methods of making, and articles formed therefrom 有权
标题翻译：聚酯聚碳酸酯组合物，制造方法和由其形成的制品
公开(公告)号：US07687583B2
公开(公告)日：2010-03-30
申请号：US11741959
申请日：2007-04-30
申请人： Shreyas Chakravarti , Bernardus Antonius Gerardus Schrauwen , Robert Dirk van de Grampel
发明人： Shreyas Chakravarti , Bernardus Antonius Gerardus Schrauwen , Robert Dirk van de Grampel
IPC分类号： C08G63/16
CPC分类号： C08L67/02 , C08K3/01 , C08K5/0008 , C08L69/00 , C08L69/005 , C08L2666/02 , C08L2666/18
摘要： A composition comprises a polyester-polycarbonate polymer comprising isophthalate-terephthalate-resorcinol ester units and carbonate units, a first polyester selected from poly(ethylene terephthalate), poly(ethylene isophthalate), or a combination thereof, and a second polyester comprising butylene terephthalate units, cyclohexanedimethylene terephthalate units, or a combination of cyclohexanedimethylene terephthalate units and ethylene terephthalate units. The composition can be extruded into pellets that are clear and colorless. The composition can further be molded into articles having a percent haze value less than or equal to 10 percent, and total luminous transmittance value of greater than or equal to 70 percent, measured in accordance with ASTM D1003-00. Also disclosed is a method for forming the compositions, and articles prepared therefrom.
摘要翻译：组合物包含含有间苯二甲酸酯 - 对苯二甲酸酯 - 间苯二酚酯单元和碳酸酯单元的聚酯 - 聚碳酸酯聚合物，选自聚（对苯二甲酸乙二醇酯），聚（乙烯间苯二甲酸酯）或其组合）的第一聚酯和包含对苯二甲酸丁二醇酯单元，对苯二甲酸环己烷二甲酸酯单元，或环己烷二亚甲基对苯二酸酯单元和对苯二甲酸乙二醇酯单元的组合。该组合物可以挤出成为澄清和无色的颗粒。根据ASTM D1003-00测量，组合物可以进一步模塑成具有小于或等于10％的雾度值百分比，总透光率值大于或等于70％的制品。还公开了形成组合物的方法及其制备的制品。

16. 发明申请

US20080269526A1 METHODS OF MAKING AN ANTISTATIC AGENT 审中-公开
标题翻译：制造抗静电剂的方法
公开(公告)号：US20080269526A1
公开(公告)日：2008-10-30
申请号：US12170097
申请日：2008-07-09
申请人： Theodorus Lambertus Hoeks , Chiel Albertus Leenders , Robert Dirk van de Grampel
发明人： Theodorus Lambertus Hoeks , Chiel Albertus Leenders , Robert Dirk van de Grampel
IPC分类号： C07F9/54
CPC分类号： C07C303/32 , C07F9/5407 , C07C309/06 , C07C309/10
摘要： Disclosed are methods for making the phosphonium sulfonate salt of generic formula (1): wherein each X is independently a halogen or hydrogen, provided that the molar ratio of halogen to hydrogen is greater than about 0.90; p is 0 or 1 and q and r are integers of 0 to about 7 provided that q+r is less than 8 and that if p is 1 then r is greater than zero; and each R is the same or different hydrocarbon radical containing 1 to about 18 carbon atoms, the method comprising the steps of combining in an aqueous medium, a compound of the generic formula (2): wherein M is K, and X, q, p, and r are as defined above, with a compound of the generic formula (3): (R)4P-Z (3) wherein Z is a halogen and R is as defined above; and separating the phosphonium sulfonate of formula (1) from the aqueous medium. Also disclosed is an antistatic composition comprising phosphonium sulfonate (1), and articles prepared therefrom.
摘要翻译：公开了制备通式（1）的鏻磺酸盐的方法：其中每个X独立地是卤素或氢，条件是卤素与氢的摩尔比大于约0.90; p为0或1，q和r为0至约7的整数，条件是q + r小于8，如果p为1，则r大于零; 并且每个R是含有1至约18个碳原子的相同或不同的烃基，该方法包括以下步骤：在水性介质中混合通式（2）的化合物：其中M是K，X，q， p和r如上所定义，与通式（3）的化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？（R） PZ（3）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中Z是卤素，R如上所定义; 并将式（1）的磺酸鏻与水性介质分离。还公开了包含磺酸鏻（1）和由其制备的制品的抗静电组合物。

17. 发明申请

US20080269400A1 POLYESTER POLYCARBONATE COMPOSITIONS, METHODS OF MAKING, AND ARTICLES FORMED THEREFROM 有权
标题翻译：聚酯聚碳酸酯组合物，制备方法和形成的制品
公开(公告)号：US20080269400A1
公开(公告)日：2008-10-30
申请号：US11741835
申请日：2007-04-30
申请人： Shreyas Chakravarti , Bernardus Antonius Gerardus Schrauwen , Robert Dirk van de Grampel
发明人： Shreyas Chakravarti , Bernardus Antonius Gerardus Schrauwen , Robert Dirk van de Grampel
IPC分类号： C08F283/00 , C08G18/42
CPC分类号： C08L67/02 , C08L69/005 , C08L2205/02 , C08L2666/18
摘要： A composition comprises a polyester-polycarbonate polymer comprising isophthalate-terephthalate-resorcinol ester units and carbonate units, a poly(C4-alkylene) ester, and a polyester comprising cyclohexanedimethylene terephthalate units, or a combination of cyclohexanedimethylene terephthalate and ethylene terephthalate. The composition can be extruded into pellets that are clear and colorless. The composition can further be molded into articles having a percent haze value less than or equal to 10 percent, and total luminous transmittance value of greater than or equal to 70 percent, measured in accordance with ASTM D1003-00. Also disclosed is a method for forming the compositions, and articles prepared therefrom.
摘要翻译：组合物包含含有间苯二甲酸酯 - 对苯二甲酸酯 - 间苯二酚酯单元和碳酸酯单元的聚酯 - 聚碳酸酯聚合物，聚（C 4 - 亚烷基）酯和包含环己烷二亚甲基对苯二酸酯单元的聚酯或环己烷二亚甲基对苯二甲酸酯和对苯二甲酸乙二醇酯。该组合物可以挤出成为澄清和无色的颗粒。根据ASTM D1003-00测量，组合物可以进一步模塑成具有小于或等于10％的雾度值百分比，总透光率值大于或等于70％的制品。还公开了形成组合物的方法及其制备的制品。

18. 发明授权

US08389662B2 Isosorbide-based polycarbonates, method of making, and articles formed therefrom 有权
标题翻译：基于异山梨醇的聚碳酸酯，制造方法和由其形成的制品
公开(公告)号：US08389662B2
公开(公告)日：2013-03-05
申请号：US12893457
申请日：2010-09-29
申请人： Hans de Brouwer , Robert Dirk van de Grampel , Jan Henk Kamps , Jan-Pleun Lens , Hendrik Theodurus van de Grampel
发明人： Hans de Brouwer , Robert Dirk van de Grampel , Jan Henk Kamps , Jan-Pleun Lens , Hendrik Theodurus van de Grampel
IPC分类号： C08G64/18 , C08G64/02 , C08G63/64 , C08G77/448
CPC分类号： C08L69/00 , C08G64/0266 , C08G64/1666 , C08G64/186 , C08L83/10 , C08L2205/02 , C08L2666/18
摘要： Disclosed herein is a polycarbonate polymer comprising: an isosorbide unit, a polysiloxane unit, and an aliphatic unit different from the isosorbide unit, wherein the isosorbide unit, polysiloxane unit, and aliphatic unit are each carbonate, or a combination of carbonate and ester units, the aliphatic unit different from the isosorbide unit is derived from an aliphatic oligomer having a molecular weight of 900 to 4000, and the calculated bio-content is greater than or equal to 40 weight percent, based on the total weight of the polycarbonate polymer.
摘要翻译：本文公开了一种聚碳酸酯聚合物，其包含：异山梨醇单元，聚硅氧烷单元和不同于异山梨醇单元的脂肪族单元，其中所述异山梨醇单元，聚硅氧烷单元和脂肪族单元各自为碳酸酯，或碳酸酯和酯单元的组合，与异山梨醇单元不同的脂肪族单元来自分子量为900〜4000的脂肪族低聚物，计算出的生物含量为聚碳酸酯聚合物总重量的40重量％以上。

19. 发明授权

US08318851B2 Weatherable resinous compositions 有权
标题翻译：耐候性树脂组合物
公开(公告)号：US08318851B2
公开(公告)日：2012-11-27
申请号：US11873084
申请日：2007-10-16
申请人： Franciscus Maria Huijs , Robert Dirk van de Grampel , Ronald Akkermans
发明人： Franciscus Maria Huijs , Robert Dirk van de Grampel , Ronald Akkermans
IPC分类号： C08L51/00
CPC分类号： C08L53/00 , C08L25/02 , C08L25/12 , C08L25/14 , C08L33/04 , C08L33/20 , C08L51/003 , C08L55/02 , C08L69/005 , C08L2205/03 , C08L2666/02 , C08L2666/24 , C08L2666/14 , C08L2666/04
摘要： Disclosed are compositions comprising: (i) 5-45 wt. % of an acrylonitrile-styrene-acrylate (ASA) graft copolymer or acrylate-modified ASA, (ii) 2-82 wt. % of at least one polyestercarbonate which is a block polyestercarbonate comprising organic carbonate blocks alternating with arylate blocks, said arylate blocks comprising ester structural units derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid, and having a degree of polymerization of at least about 4; and (iii) 5-60 wt. % of at least one rigid thermoplastic polymer comprising structural units derived from styrene and acrylonitrile; alpha-methylstyrene and acrylonitrile; alpha-methylstyrene, styrene, and acrylonitrile; styrene, acrylonitrile, and methyl methacrylate; alpha-methyl styrene, acrylonitrile, and methyl methacrylate; or alpha-methylstyrene, styrene, acrylonitrile, and methyl methacrylate, or mixtures thereof, wherein wt. % values are based on the weight of components (i)-(iii) and wherein a molded article made from the composition has a notched Izod impact strength of at least 5 kilojoules per square meter (kJ/m2) as determined according to ISO 180 at room temperature and a Vicat B value of at least 101° C. determined at 120° C. according to ISO 306. Articles made from said compositions are also disclosed.
摘要翻译：公开的组合物包含：（i）5-45wt。丙烯腈 - 苯乙烯 - 丙烯酸酯（ASA）接枝共聚物或丙烯酸酯改性的ASA的％，（ii）2-82wt。至少一种聚酯碳酸酯，其是包含与芳基化物嵌段交替的有机碳酸酯嵌段的嵌段聚酯碳酸酯，所述芳基化物嵌段包含衍生自至少一种1,3-二羟基苯部分和至少一种芳族二羧酸的酯结构单元，的聚合度至少约4; 和（iii）5-60重量％至少一种含有衍生自苯乙烯和丙烯腈的结构单元的刚性热塑性聚合物的％ α-甲基苯乙烯和丙烯腈; α-甲基苯乙烯，苯乙烯和丙烯腈; 苯乙烯，丙烯腈，甲基丙烯酸甲酯; α-甲基苯乙烯，丙烯腈和甲基丙烯酸甲酯; 或α-甲基苯乙烯，苯乙烯，丙烯腈和甲基丙烯酸甲酯，或其混合物。％值基于组分（i） - （iii）的重量，并且其中由组合物制成的模制品具有根据ISO 180测定的至少5千焦/平方米（kJ / m 2）的缺口伊佐德冲击强度并且根据ISO 306在120℃下测定至少101℃的维卡B值。还公开了由所述组合物制成的制品。

20. 发明申请

US20110160408A1 ISOSORBIDE-BASED POLYCARBONATES, METHOD OF MAKING, AND ARTICLES FORMED THEREFROM 有权
标题翻译：基于异构体的聚碳酸酯，其制备方法和形成的制品
公开(公告)号：US20110160408A1
公开(公告)日：2011-06-30
申请号：US12893457
申请日：2010-09-29
申请人： Hans de Brouwer , Robert Dirk van de Grampel , Jan Henk Kamps , Jan-Pleun Lens , Hendrik Theodurus van de Grampel
发明人： Hans de Brouwer , Robert Dirk van de Grampel , Jan Henk Kamps , Jan-Pleun Lens , Hendrik Theodurus van de Grampel
IPC分类号： C08L67/04 , C08L67/00 , C08L83/06
CPC分类号： C08L69/00 , C08G64/0266 , C08G64/1666 , C08G64/186 , C08L83/10 , C08L2205/02 , C08L2666/18
摘要： Disclosed herein is a polycarbonate polymer comprising: an isosorbide unit, a polysiloxane unit, and an aliphatic unit different from the isosorbide unit, wherein the isosorbide unit, polysiloxane unit, and aliphatic unit are each carbonate, or a combination of carbonate and ester units, the aliphatic unit different from the isosorbide unit is derived from an aliphatic oligomeric polyester polyol having a molecular weight of 900 to 4000, and the calculated bio-content is greater than or equal to 40 weight percent, based on the total weight of the polycarbonate polymer.
摘要翻译：本文公开了一种聚碳酸酯聚合物，其包含：异山梨醇单元，聚硅氧烷单元和不同于异山梨醇单元的脂肪族单元，其中所述异山梨醇单元，聚硅氧烷单元和脂肪族单元各自为碳酸酯，或碳酸酯和酯单元的组合，与异山梨醇单元不同的脂肪族单元来自分子量为900〜4000的脂族低聚聚酯多元醇，计算出的生物含量大于或等于40重量％，基于聚碳酸酯聚合物的总重量。

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