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11. 发明授权

US07879224B2 Doped alumino-silicate catalyst and improved process for treatment of hydrocarbon feeds 有权
标题翻译：掺杂铝硅酸盐催化剂和改进的烃类进料处理方法
公开(公告)号：US07879224B2
公开(公告)日：2011-02-01
申请号：US11663497
申请日：2005-09-20
申请人： Patrick Euzen , Alexandra Chaumonnot , Magalie Roy-Auberger , Patrick Bourges , Tivadar Cseri , Maryline Delage , Nathalie Lett
发明人： Patrick Euzen , Alexandra Chaumonnot , Magalie Roy-Auberger , Patrick Bourges , Tivadar Cseri , Maryline Delage , Nathalie Lett
IPC分类号： C10G11/02 , B01J27/185
CPC分类号： B01J21/12 , B01J21/02 , B01J23/883 , B01J23/888 , B01J27/1853 , B01J27/188 , B01J35/0006 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/108 , B01J37/0201 , B01J37/20 , B01J37/28 , C10G49/02 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
摘要： The present invention concerns doped catalysts on an alumino-silicate support with an adapted macropore content and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table, a controlled quantity of phosphorus (optionally in combination with boron and/or silicon) as a doping element, and a non-zeolitic support based on alumina-silica containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
摘要翻译：本发明涉及具有适用的大孔含量和加氢裂化/加氢转化和使用它们的加氢处理方法的铝硅酸盐载体上的掺杂催化剂。该催化剂包含至少一种选自元素周期表第VIB族和第VIII族的元素形成的氢化脱氢元素，受控量的磷（任选与硼和/或硅组合）作为掺杂元素， - 基于含有大于5重量％和95重量％或更少的二氧化硅（SiO 2）的量的氧化铝 - 二氧化硅的硅铝石载体。

12. 发明授权

US06733657B2 Hydrocracking catalyst having a unique silica-alumina substrate 有权
标题翻译：具有独特二氧化硅 - 氧化铝底物的加氢裂化催化剂
公开(公告)号：US06733657B2
公开(公告)日：2004-05-11
申请号：US10045678
申请日：2002-01-15
申请人： Eric Benazzi , Tivadar Cseri , Magalie Roy-Auberger , Patrick Euzen
发明人： Eric Benazzi , Tivadar Cseri , Magalie Roy-Auberger , Patrick Euzen
IPC分类号： C10G4704
CPC分类号： C10G47/12 , B01J21/12 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/108 , B01J37/0009 , B01J37/20
摘要： A hydrocarbon conversion catalyst contains at least one silica-alumina having the following characteristics: A content by weight of silica SiO2 of between 10 and 60% by weight; an Na content less than 300 ppm by weight; a total pore volume of between 0.5 and 1.2 m/g measured by mercury porosimetry; a porosity of said silica-alumina wherein: the volume of mesopores whose diameter is between 40 Å and 150 Å, and whose mean diameter varies between 80 and 120 Å represents between 30 and 80% of the total pore volume, and (ii) the volume of macropores, whose diameter is greater than 500 Å and preferably between 1000 Å and 10,000 Å represents between 20 and 80% of the total pore volume; a specific surface area greater than 200 m2/g, and at least one hydro-dehydrogenating element selected metals of group VIB and group VIII, and optionally phosphorus, boron, silicon, or elements of group VIIA, VIIB or VB.
摘要翻译：烃转化催化剂含有至少一种具有以下特征的二氧化硅 - 氧化铝：二氧化硅SiO 2的重量含量为10至60重量％; Na含量小于300重量ppm; 通过水银孔率法测量的总孔体积为0.5-1.2m 2 / g; 所述二氧化硅 - 氧化铝的孔隙率，其中直径为介于40和150之间，其平均直径在80和120之间变化的介孔的体积占总孔体积的30至80％，和（ii）其直径大于500埃，优选在1000埃至10,000埃之间的大孔体积占总孔体积的20至80％; 比表面积大于200m 2 / g，以及至少一种加氢脱氢元素选择VIB族和VIII族的金属，以及任选的磷，硼，硅或VIIA，VIIB或VB族的元素。

13. 发明申请

US20090176894A1 PROCESS OF FISCHER-TROPSCH SYNTHESIS BY CONTROL OF THE PARTIAL PRESSURE OF WATER IN THE REACTION ZONE 有权
标题翻译：通过控制反应区水中部分压力进行FISCHER-TROPSCH合成的方法
公开(公告)号：US20090176894A1
公开(公告)日：2009-07-09
申请号：US12348044
申请日：2009-01-02
申请人： Marie-Claire MARION , Francois Hugues , Magalie Roy-Auberger
发明人： Marie-Claire MARION , Francois Hugues , Magalie Roy-Auberger
IPC分类号： C07C1/00
CPC分类号： B01J23/75 , B01J35/1061 , C10G2/32
摘要： The subject of the invention is a process for the synthesis of hydrocarbons based on a synthesis gas type feedstock in which said synthesis gas is brought into contact with a catalyst in a reactor under Fischer-Tropsch synthesis conditions and in which the partial pressure of water is controlled in order to keep it below a critical value ppH2Olimit defined by the formula: ppH2Olimit=exp(−7751/dp·T)·Ps(T) where T is the reaction temperature in K, dp is the average diameter of the catalyst pores in nm, determined by nitrogen adsorption-desorption (BJH method), Ps(T) is the saturating water vapour pressure at temperature T, in bar.
摘要翻译：本发明的主题是基于合成气类型原料合成烃的方法，其中所述合成气在费 - 托合成条件下在反应器中与催化剂接触，并且其中水的分压为控制以保持其低于由以下公式定义的临界值ppH2Olimit：ppH2Olimit = exp（-7751 / dp.T）.Ps（T）其中T是K中的反应温度，dp是催化剂孔的平均直径以氮气吸附 - 解吸（BJH法）测定，Ps（T）为温度T下的饱和水蒸汽压，单位为bar。

14. 发明申请

US20050211603A1 Doped spherically-shaped supported catalyst and process for hydrotreating and hydroconverting metal-containing oil fractions 有权
$Doped spherically-shaped supported catalyst and process for hydrotreating and hydroconverting metal-containing oil fractions$
标题翻译：掺杂球形载体催化剂和加氢处理和加氢转化含金属油馏分的方法
公开(公告)号：US20050211603A1
公开(公告)日：2005-09-29
申请号：US11086556
申请日：2005-03-23
申请人： Denis Guillaume , Stephane Kressmann , Magalie Roy-Auberger
发明人： Denis Guillaume , Stephane Kressmann , Magalie Roy-Auberger
IPC分类号： B01J21/04 , B01J21/12 , B01J23/16 , B01J23/24 , B01J23/28 , B01J23/85 , B01J23/88 , B01J23/883 , B01J35/02 , B01J35/10 , B01J37/00 , B01J37/02 , B01J37/08 , B01J37/20 , C10G45/00 , C10G45/04 , C10G45/06 , C10G45/08 , C10G47/12 , C10G65/02 , B01J21/02 , B01J27/06 , B01J27/14 , B01J27/19 , C10G47/02
CPC分类号： B01J23/24 , B01J21/04 , B01J23/85 , B01J23/883 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/108 , B01J37/0018 , B01J37/0207 , C10G45/00 , C10G45/04 , C10G65/02 , C10G2300/107 , C10G2300/1077 , C10G2300/703
摘要： The present invention concerns a catalyst for hydrotreating and/or hydroconverting heavy metal-containing hydrocarbon feeds, said catalyst comprising a support in the form of beads based on alumina, at least one catalytic metal or a compound of a catalytic metal from group VIB (column 6 in the new periodic table notation), optionally at least one catalytic metal or compound of a catalytic metal from group VIII (columns 8, 9 and 10 of the new periodic table notation), with a pore structure composed of a plurality of juxtaposed agglomerates, each formed by a plurality of acicular platelets, the platelets of each agglomerate being generally radially orientated with respect to each other and with respect to the center of the agglomerate. The catalyst also comprises at least one doping element selected from the group constituted by phosphorus, boron, silicon (or silica which does not belong to that which could be contained in the selected support) and halogens. The invention also concerns the use of said catalyst in converting metal-containing feeds.
摘要翻译：本发明涉及用于加氢处理和/或加氢转化含重金属的烃进料的催化剂，所述催化剂包括基于氧化铝的珠粒形式的载体，至少一种催化金属或来自VIB族的催化金属的化合物 6），任选的至少一种催化金属或来自第VIII族的催化金属（新的周期表符号的第8,9和10条）的化合物，其孔结构由多个并置的附聚物组成，每个由多个针状血小板形成，每个附聚物的血小板通常相对于彼此和相对于附聚物的中心径向取向。所述催化剂还包含至少一种选自磷，硼，硅（或二氧化硅）的掺杂元素，该组不属于所选载体中可包含的掺杂元素）和卤素。本发明还涉及所述催化剂在转化含金属的进料中的用途。

15. 发明授权

US06509382B1 Process for activating a fischer-tropsch synthesis catalyst 有权
标题翻译：活化托吡托合成催化剂的方法
公开(公告)号：US06509382B1
公开(公告)日：2003-01-21
申请号：US09717101
申请日：2000-11-22
申请人： Olivier Ducreux , Marie Claire Marion , Magalie Roy-Auberger , John Lynch
发明人： Olivier Ducreux , Marie Claire Marion , Magalie Roy-Auberger , John Lynch
IPC分类号： C07C2700
CPC分类号： C10G2/331 , B01J23/75 , B01J23/8913 , B01J23/94 , B01J23/96 , B01J37/16 , B01J37/18 , B01J38/04 , B01J38/58 , C07C1/0445 , C07C2523/40 , C07C2523/74 , Y02P20/584
摘要： Process for activating a Fischer-Tropsch synthesis catalyst that comprises at least two stages: at least one stage for activation in the presence of hydrogen, or a mixture of hydrogen and an inert gas, and at least one stage for activation in the presence of carbon monoxide or a mixture of carbon monoxide and an inert gas, and optionally a third activation stage that is carried out either in the presence of hydrogen or a mixture of hydrogen and an inert gas, or in the presence of carbon monoxide or a mixture of carbon monoxide and an inert gas.
摘要翻译：用于活化包含至少两个阶段的费 - 托合成催化剂的方法：用于在氢存在下活化的至少一个阶段，或氢和惰性气体的混合物，以及在一氧化碳存在下活化的至少一个阶段或一氧化碳和惰性气体的混合物，以及任选的第三活化阶段，其在氢气或氢气和惰性气体的混合物存在下，或在一氧化碳或一氧化碳和惰性气体。

16. 发明授权

US08618017B2 Irregularly shaped non-spherical supported catalyst, and a process for hydroconversion heavy oil fractions 失效
$Irregularly shaped non-spherical supported catalyst, and a process for hydroconversion heavy oil fractions$
标题翻译：不规则形状的非球形载体催化剂，以及加氢转化重油馏分的方法
公开(公告)号：US08618017B2
公开(公告)日：2013-12-31
申请号：US13463255
申请日：2012-05-03
申请人： Stephane Kressmann , Magalie Roy-Auberger , Jean Luc Le Loarer , Denis Guillaume , Jean Francois Chapat
发明人： Stephane Kressmann , Magalie Roy-Auberger , Jean Luc Le Loarer , Denis Guillaume , Jean Francois Chapat
IPC分类号： C10G45/06
CPC分类号： B01J21/04 , B01J23/85 , B01J23/883 , B01J27/19 , B01J35/0026 , B01J35/026 , B01J35/10 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/1066 , B01J35/1071 , B01J37/0018 , B01J37/0036 , B01J37/0063 , B01J37/10 , C10G49/04 , C10G49/12 , C10G2300/205 , C10G2300/4018
摘要： A catalyst for hydrotreating and/or hydroconverting heavy metal-containing hydrocarbon feeds, comprises a support in the form of mainly irregular and non-spherical alumina-based agglomerates the specific shape. The catalyst is prepared by a specific order of steps: crushing, calcining, acidic autoclaving, drying, further calcining and impregnation with catalytic metals.
摘要翻译：用于加氢处理和/或加氢转化含重金属的烃进料的催化剂包括主要为不规则和非球形的氧化铝基附聚物形式的支撑体。催化剂通过以下步骤的特定顺序制备：粉碎，煅烧，酸性高压灭菌，干燥，进一步煅烧和用催化金属浸渍。

17. 发明授权

US07666296B2 Process for the hydroconversion in a slurry of heavy hydrocarbonaceous feedstocks in the presence of a dispersed phase and an alumina-based oxide 有权
标题翻译：在分散相和氧化铝基氧化物存在下，在重质烃原料的浆液中加氢转化的方法
公开(公告)号：US07666296B2
公开(公告)日：2010-02-23
申请号：US11961688
申请日：2007-12-20
申请人： Magalie Roy-Auberger
发明人： Magalie Roy-Auberger
IPC分类号： C07C4/06
CPC分类号： B01J27/043 , B01J21/04 , B01J27/04 , B01J27/047 , B01J27/051 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/108 , B01J37/0018 , B01J37/0036 , B01J37/0203 , B01J37/0207 , B01J37/10 , B01J37/20 , C10G2300/107
摘要： The invention relates to a process for converting heavy hydrocarbonaceous feedstocks carried out in a slurry reactor in the presence of hydrogen and in the presence of a catalytic composition obtained by: injecting a catalytic precursor of at least one metal of Group VIB and/or Group VIII in at least part of the feedstock to be treated in the absence of an oxide substrate, thermal treatment at a temperature of 400° C. or below, in the presence of H2S so as to form the dispersed sulphur-containing catalyst, bringing said catalyst into contact with particles of alumina oxide free from silica, said oxide particles having a polymodal porous structure composed of a plurality of juxtaposed agglomerates and each formed from a plurality of acicular platelets, the platelets of each agglomerate being oriented radially in relation to one another and relative to the centre of the agglomerate, said particles having an irregular non-spherical shape and being mainly in the form of fragments obtained by crushing with alumina balls, introducing the catalyst composition obtained into the reactor.
摘要翻译：本发明涉及一种在氢气存在下，在淤浆反应器中进行的重质烃类原料的转化和催化剂组合物的存在下进行转化的方法，所述催化组合物通过以下方法获得：注入至少一种VIB族金属和/或VIII族金属的催化前体在不存在氧化物底物的待处理原料的至少一部分中，在H 2 S存在下在400℃或更低的温度下进行热处理，以形成分散的含硫催化剂，使所述催化剂与不含二氧化硅的氧化铝颗粒接触，所述氧化物颗粒具有由多个并置的附聚物组成并且由多个针状血小板形成的多模多孔结构，每个附聚物的血小板相对于彼此径向取向，相对于附聚物的中心，所述颗粒具有不规则的非球形并且主要以所获得的碎片的形式通过用氧化铝球破碎，将得到的催化剂组合物引入反应器。

18. 发明授权

US07807044B2 Process for slurry phase hydroconversion of heavy hydrocarbon feeds and/or coal using a supported catalyst 有权
标题翻译：使用负载型催化剂对重质烃进料和/或煤的浆料相加氢转化的方法
公开(公告)号：US07807044B2
公开(公告)日：2010-10-05
申请号：US11961132
申请日：2007-12-20
申请人： Magalie Roy-Auberger , Denis Guillaume
发明人： Magalie Roy-Auberger , Denis Guillaume
IPC分类号： C10G47/04
CPC分类号： B01J37/0063 , B01J21/04 , B01J23/24 , B01J23/40 , B01J23/74 , B01J23/85 , B01J23/883 , B01J27/19 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/108 , B01J37/0018 , B01J37/10 , C10G45/08 , C10G49/04 , C10G2300/301
摘要： The invention concerns a process for converting heavy feeds carried out in a slurry reactor in the presence of hydrogen and in the presence of a catalyst comprising at least one catalytic metal or a compound of a catalytic metal from group VIB and/or VIII supported on alumina, the pore structure of which is composed of a plurality of juxtaposed agglomerates each formed by a plurality of acicular platelets, the platelets of each agglomerate being generally radially oriented with respect to the others and with respect to the center of the agglomerate, the catalyst having an irregular and nonspherical shape and being mainly in the form of fragments. The process of the invention employs a catalyst with a specific pore texture, shape and granulometry, resulting in improved performances.
摘要翻译：本发明涉及一种在氢气存在下，在含有至少一种催化金属或催化金属化合物的催化剂存在下，在淤浆反应器中进行重质进料的方法，所述催化剂金属或载体在氧化铝上的VIB族和/或VIII族的催化剂金属化合物其孔结构由多个并列聚集体组成，每个团聚体由多个针状血小板形成，每个附聚物的血小板通常相对于其它凝聚块大致径向取向，并且相对于附聚物的中心，催化剂具有形状不规则和非球形，主要以片段的形式。本发明的方法采用具有特定孔结构，形状和粒度的催化剂，从而提高了性能。

19. 发明授权

US07803266B2 Doped spherically-shaped supported catalyst and process for hydrotreating and hydroconverting metal-containing oil fractions 有权
$Doped spherically-shaped supported catalyst and process for hydrotreating and hydroconverting metal-containing oil fractions$
标题翻译：掺杂球形载体催化剂和加氢处理和加氢转化含金属油馏分的方法
公开(公告)号：US07803266B2
公开(公告)日：2010-09-28
申请号：US11086556
申请日：2005-03-23
申请人： Denis Guillaume , Stéphane Kressmann , Magalie Roy-Auberger
发明人： Denis Guillaume , Stéphane Kressmann , Magalie Roy-Auberger
IPC分类号： C10G11/00 , C10G45/04 , C10G45/08 , C10G45/60 , C10G47/00 , B01J35/08 , B01J35/10
CPC分类号： B01J23/24 , B01J21/04 , B01J23/85 , B01J23/883 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/108 , B01J37/0018 , B01J37/0207 , C10G45/00 , C10G45/04 , C10G65/02 , C10G2300/107 , C10G2300/1077 , C10G2300/703
摘要： A catalyst and process for hydrotreating and/or hydroconverting heavy metal-containing hydrocarbon feeds, said catalyst comprising a support in the form of beads based on alumina, at least one catalytic metal or a compound of a catalytic metal from group VIB (column 6 in the new periodic table notation), optionally at least one catalytic metal or compound of a catalytic metal from group VIII (columns 8, 9 and 10 of the new periodic table notation), with a pore structure composed of a plurality of juxtaposed agglomerates, each formed by a plurality of acicular platelets, the platelets of each agglomerate being generally radially orientated with respect to each other and with respect to the center of the agglomerate. The catalyst also comprises at least one doping element selected from the group constituted by phosphorus, boron, silicon (or silica which does not belong to that which could be contained in the selected support) and halogens.
摘要翻译：用于加氢处理和/或加氢转化含重金属的烃进料的催化剂和方法，所述催化剂包含基于氧化铝的珠粒形式的载体，至少一种催化金属或来自VIB族的催化金属的化合物新的周期表符号），任选的至少一种催化金属或来自第VIII族的催化金属（新的周期表符号的第8,9和10条）的化合物，具有由多个并置的附聚物组成的孔结构，每个由多个针状血小板形成，每个附聚物的血小板通常相对于彼此和相对于附聚物的中心径向取向。所述催化剂还包含至少一种选自磷，硼，硅（或二氧化硅）的掺杂元素，该组不属于所选载体中可包含的掺杂元素）和卤素。

20. 发明授权

US07662865B2 Process of Fischer-Tropsch synthesis by control of the partial pressure of water in the reaction zone 有权
标题翻译：通过控制反应区中水的分压来进行费 - 托合成的方法
公开(公告)号：US07662865B2
公开(公告)日：2010-02-16
申请号：US12348044
申请日：2009-01-02
申请人： Marie-Claire Marion , Francois Hugues , Magalie Roy-Auberger
发明人： Marie-Claire Marion , Francois Hugues , Magalie Roy-Auberger
IPC分类号： C07C27/00
CPC分类号： B01J23/75 , B01J35/1061 , C10G2/32
摘要： The subject of the invention is a process for the synthesis of hydrocarbons based on a synthesis gas type feedstock in which said synthesis gas is brought into contact with a catalyst in a reactor under Fischer-Tropsch synthesis conditions and in which the partial pressure of water is controlled in order to keep it below a critical value ppH2O-limit defined by the formula: ppH2Olimit=exp(−7751/dp·T)·Ps(T) where T is the reaction temperature in K, dp is the average diameter of the catalyst pores in nm, determined by nitrogen adsorption-desorption (BJH method), Ps(T) is the saturating water vapour pressure at temperature T, in bar.
摘要翻译：本发明的主题是基于合成气类型原料合成烃的方法，其中所述合成气在费 - 托合成条件下在反应器中与催化剂接触，并且其中水的分压为控制以使其低于由以下公式定义的临界值ppH2O限制：ppH2Olimit = exp（-7751 / dp.T）.Ps（T）其中T是K中的反应温度，dp是通过氮吸附 - 解吸（BJH法）确定的催化剂孔隙，P（T）是在温度T下的饱和水蒸汽压力，单位为bar。

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