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11. 发明授权

US5296337A Process for retouching photographic images containing a dye having a cleavable ballast 失效
标题翻译：用于修饰含有具有可切割镇流器的染料的照相图像的方法
公开(公告)号：US5296337A
公开(公告)日：1994-03-22
申请号：US872473
申请日：1992-04-23
申请人： J. Ramon Vargas , John W. Harder , Phillip D. Knight , Paul A. Burns , Lynda D. Weber
发明人： J. Ramon Vargas , John W. Harder , Phillip D. Knight , Paul A. Burns , Lynda D. Weber
IPC分类号： G03C7/18 , G03C7/30 , G03C7/32 , G03C7/38 , G03C11/00 , G03C11/04 , G03C11/18 , G03G8/00 , G03G5/92 , G03G5/94 , G03G7/00
CPC分类号： G03C7/3835 , G03C11/04 , Y10S430/144 , Y10S430/159
摘要： There are described a method for retouching photographic images, compositions adapted for such retouching, and photographic elements containing dye-forming couplers that yield dye images that particularly lend themselves to retouching by this method. The method comprises contacting a photographic element containing a dye image with a defined retouching composition to solubilize and remove selected areas or amounts of dye. The composition comprises an aqueous basic solution of a dinucleophile and a water-soluble organic co-solvent. The preferred photographic element for application of this retouching method comprises a dye image formed from a pyrazoloazole magenta dye forming coupler having a cleavable ballast group joined to the remainder of the molecule by one or two electrophilic cleavage groups. The retouching composition cleaves the ballast from the dye and solubilizes the dye, allowing it to be washed from the element.
摘要翻译：描述了修饰照相图像的方法，适用于这种修饰的组合物，以及含有染料形成成色剂的照相元件，其产生特别适合于通过该方法进行修饰的染料图像。该方法包括将含有染料图像的照相元件与限定的润饰组合物接触以溶解并除去所选择的区域或数量的染料。所述组合物包含双亲核苷酸水溶液和水溶性有机共溶剂。用于这种修饰方法的优选的照相元件包括由具有可切割压载物的吡唑并噻唑品红色染料形成成色剂形成的染料图像，其通过一个或两个亲电裂解基团连接到分子的其余部分。修饰组合物从染料中切割镇流物并溶解染料，使其从元件中洗涤。

12. 发明授权

US5292631A Radiographic elements with improved covering power 失效
标题翻译：具有改善遮盖力的射线照相元件
公开(公告)号：US5292631A
公开(公告)日：1994-03-08
申请号：US892851
申请日：1992-06-03
申请人： Stephen A. Hershey , J. Ramon Vargas , Paul A. Burns
发明人： Stephen A. Hershey , J. Ramon Vargas , Paul A. Burns
IPC分类号： G03C1/035 , G03C1/005 , G03C1/35 , G03C1/43 , G03C5/16 , G03C1/06
CPC分类号： G03C5/16 , G03C1/0051 , G03C1/35 , Y10S430/167
摘要： Monocyclic and polycyclic azoles having the following formula enhance the covering power of a developed silver image formed from a radiographic element comprising a radiation sensitive tabular grain silver bromide, silver bromochloride or silver bromoiodide emulsion layer containing grains having a mean equivalent circular diameter of at least 0.3 .mu.m and a grain population wherein at least 50 percent of the total grain population projected area is accounted for by tabular grains having a tabularity of greater than 8, as determined by the relationship: ##EQU1## wherein T is tabularity; ECD is the mean effective circular diameter in .mu.m of the tabular grains; and t is the mean thickness in .mu.m of the tabular grains. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sup.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 is hydrogen, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 and R.sup.5 together complete a 5 or 6 membered heterocyclic nucleus containing 1 to 3 ring nitrogen atoms;L is a divalent aliphatic linking group containing 1 to 8 carbon atoms;T is an aliphatic terminal group containing 1 to 10 carbon atoms;m is 0 or 1;n is an integer of 0 to 4; andp is an integer of 2 to 4.
摘要翻译：具有下式的单环和多环唑增强了由包含辐射敏感的片状颗粒溴化银，溴氯化银或溴碘化银乳剂层形成的显影银图像的覆盖能力，该层含有平均当量圆直径至少为0.3的晶粒（我的）m和粮食人口，其中总粮食种群投资面积的至少50％是由具有大于8的平片状的片状颗粒占据的，由以下关系确定：（*化学结构*）其中T是片状 ; ECD是片状颗粒的（my）m的平均有效圆直径; t是片状颗粒的（my）m的平均厚度。唑类具有下列通式：（*化学结构*）（I）其中Z为-N =或-C（R5）=其中R5为氢，-NH2为1至8个碳原子的脂族或1至8个碳的芳族原子 R4是氢，1至8个碳原子的脂族或1至8个碳原子的芳族; R4和R5一起完成含有1至3个环氮原子的5或6元杂环核; L是含有1至8个碳原子的二价脂族连接基团; T是含有1至10个碳原子的脂肪族端基; m为0或1; n为0〜4的整数。 p为2〜4的整数。

13. 发明授权

US5110942A Dye derived from a pyrazolotriazole 失效
标题翻译：衍生自吡唑并三唑的染料
公开(公告)号：US5110942A
公开(公告)日：1992-05-05
申请号：US576031
申请日：1990-08-31
申请人： John W. Harder , Paul A. Burns
发明人： John W. Harder , Paul A. Burns
IPC分类号： G03C7/38 , G03C11/04
CPC分类号： G03C7/3835 , G03C11/04
摘要： A method of retouching a dye image comprises selective removal with an aqueous acidic organic solvent solution, as described in the application, of a portion of a dye image from an exposed and processed photographic silver halide element comprising a support bearing a dye image from a dye-forming coupler and a primary amine photographic color developing agent, wherein the dye-forming coupler: (a) contains so ionizable group that is retained as part of a dye formed upon oxidative coupling, (b) has a structure such that the Log P of the coupler is greater than 4 and is derived from a four-equivalent coupler that has a Log P less than 8, and (c) has a coupling reactivity that enables formation of maximum image density of at least 0.6. The method comprises the step of contacting the dye image with an aqueous acidic organic solvent solution, as described in the application, for a time and at a temperature sufficient to selectively dissolve and remove a portion of the dye image from the photographic element. A new photographic element designed for such retouching comprises new pyrazolotriazole couplers as described in the application.
摘要翻译：修饰染料图像的方法包括如本申请中所述的由酸性有机溶剂水溶液选择性地除去来自暴露和加工的照相卤化银元素的染料图像的一部分，其包含载体，染料图像来自染料成色成色剂和伯胺照相彩色显影剂，其中染料形成成色剂：（a）含有作为在氧化偶合时形成的染料的一部分保留的可离子化基团，（b）具有使得Log P 的耦合器大于4并且衍生自具有Log P小于8的四等效成色剂，并且（c）具有能够形成至少0.6的最大图像密度的偶联反应性。该方法包括如本申请中所述使染料图像与酸性有机溶剂水溶液接触的时间和温度足以从照相元件中选择性地溶解和除去一部分染料图像的步骤。设计用于这种修饰的新的照相元件包括如本申请中所述的新的吡唑并三唑成色剂。

14. 发明授权

US5021325A Photographic material and process comprising a pyrazolotriazole coupler 失效
标题翻译：包含吡唑并三唑成色剂的摄影材料和方法
公开(公告)号：US5021325A
公开(公告)日：1991-06-04
申请号：US452997
申请日：1989-12-19
申请人： Paul A. Burns , John W. Harder
发明人： Paul A. Burns , John W. Harder
IPC分类号： C07D487/04 , G03C7/38
CPC分类号： C07D487/04 , G03C7/3835
摘要： A pyrazolotriazole dye-forming coupler containing on a carbon atom in a non-coupling position a ballast group derived from and bonded through a carboxylic acid portion of an unsubstituted or substituted amino acid provides useful magenta dye images in a photographic material and process and enables simplification of manufacture of the coupler. Such couplers are useful in photographic silver halide materials and processes.

15. 发明授权

US5006448A Photographic material and process 失效
标题翻译：摄影材料和工艺
公开(公告)号：US5006448A
公开(公告)日：1991-04-09
申请号：US366730
申请日：1989-06-15
申请人： Richard P. Szajewski , Paul A. Burns , Jerrold N. Poslusny , Norma B. Platt , Timothy D. Norden
发明人： Richard P. Szajewski , Paul A. Burns , Jerrold N. Poslusny , Norma B. Platt , Timothy D. Norden
IPC分类号： G03C7/305
CPC分类号： G03C7/305 , Y10S430/158
摘要： A photographic recording material is disclosed which contains a compound capable of releasing a development inhibitor moiety during photographic processing which enhances development inhibition and reduces interlayer interimage effects without adversely affecting photographic properties.

16. 发明授权

US06291152B1 Photographic element having improved dye stability, compound, and imaging process 失效
标题翻译：具有改善的染料稳定性，化合物和成像方法的摄影元件
公开(公告)号：US06291152B1
公开(公告)日：2001-09-18
申请号：US09707636
申请日：2000-11-07
申请人： Paul A. Burns , Robert F. Romanet , Susan M. Fischer , David G. Lincoln , Paul P. Spara
发明人： Paul A. Burns , Robert F. Romanet , Susan M. Fischer , David G. Lincoln , Paul P. Spara
IPC分类号： G03C108
CPC分类号： G03C7/3825 , G03C7/3212 , G03C7/3835
摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a bicyclic azole dye-forming coupler, having appended to a ring carbon at a non-coupling position thereof a substituent group represented by the formula: wherein the arrow represents the point of attachment of the substituent group to a non-coupling position of the coupler; R1, R2, R3 and R4 are independently selected hydrogen or substituent groups, provided that any two of R1, R2, R3 and R4 may join to form a ring; Ra and Rb are independently hydrogen or a substituent; each Rc and Rd is an independently selected hydrogen or an alkyl or aryl group, provided that any two of them may join to form a ring and n is 1 to 10; Re is hydrogen or an alkyl or aryl group; each Y is an independently selected substituent group and m is from 0 to 4; and Z is a substituent selected from the group consisting of —C(O)R5, —S(O)2R5, —SOR5, —P(═O)(R6)2 and —P(═O)(OR6)2 in which R5 is selected from the group consisting of alkyl, aryl, heterocyclic, alkoxy, aryloxy, alkylamino, and arylamino groups and each R6 is independently selected from the group consisting of alkyl and aryl groups; provided that Z can form a ring with any one of Rc and Rd. Such an element provides improved image dye stability.
摘要翻译：公开了一种照相元件，其包含感光卤化银乳剂层，该感光卤化银乳剂层具有与其相连的双环唑形染料形成成色剂，其在非偶合位置附加有环碳，由下式表示的取代基：其中箭头表示取代基与偶联剂的非偶联位置的连接点; R 1，R 2，R 3和R 4独立地选自氢或取代基，条件是R 1，R 2，R 3和R 4中的任何两个可以连接形成 R a和R b独立地是氢或取代基;每个R c和R d是独立选择的氢或烷基或芳基，条件是它们中的任何两个可以连接形成环，n是1至10; Re是氢或烷基或芳基;每个Y是独立选择的取代基，m是0-4; 并且Z是选自-C（O）R 5，-S（O）2 R 5，-SOR 5，-P（= O）（R 6）2和-P（= O）（OR 6）2的取代基，其中 R5选自烷基，芳基，杂环，烷氧基，芳氧基，烷基氨基和芳基氨基，每个R6独立地选自烷基和芳基; 只要Z可以与Rc和Rd中的任何一个形成环。这样的元素提供了改进的图像染料稳定性。

17. 发明授权

US06190849B1 Photographic element containing ballasted tetrazole derivative and inhibitor releasing coupler 有权
标题翻译：含有镇流四唑衍生物和抑制剂释放成色剂的照相元件
公开(公告)号：US06190849B1
公开(公告)日：2001-02-20
申请号：US09358500
申请日：1999-07-21
申请人： Paul A. Burns , Louis E. Friedrich , Stephen P. Singer
发明人： Paul A. Burns , Louis E. Friedrich , Stephen P. Singer
IPC分类号： G03C108
CPC分类号： G03C7/3926 , G03C1/346 , G03C7/3005 , G03C7/30541 , G03C7/30552 , G03C7/30558 , Y10S430/156 , Y10S430/158
摘要： The invention provides a color photographic element comprising: a) a first light sensitive silver halide emulsion layer containing a tetrazole compound of Formula I: wherein when R1 is hydrogen, then R2 is an alkyl, aryl, alkoxy , aryloxy, alkylthio or arylthio, sulfoxyl, sulfonyl, sulfamoyl, —O—CO—, —O—SO2—, a heterocyclic group, a carbonyl group or an amino group or when R2 is a thiol (—SH) group, then R1 is an alkyl, aryl or heterocyclic group provided further that the ClogP for the compound of Formula I is at least 2.0 and less than 7.8; and b) a second light sensitive silver halide emulsion layer, having a spectral sensitivity different from that of the first light sensitive silver halide emulsion layer, containing a compound of Formula II: COUP—(TIME)j—INH II wherein: 1) COUP is a coupler parent group capable of forming a dye upon reaction with an oxidized developer; 2) TIME is a timing group bonded to the coupling position of COUP and j is 0 or 1; and 3) INH is a mild silver development inhibitor fragment. The invention provides improved color reproduction.
摘要翻译：本发明提供了一种彩色照相元件，其包括：a）含有式I的四唑化合物的第一感光卤化银乳剂层：其中当R 1为氢时，R 2为烷基，芳基，烷氧基，芳氧基，烷硫基或芳硫基，，磺酰基，氨磺酰基，-O-CO-，-O-SO 2 - ，杂环基，羰基或氨基，或者当R 2为硫醇（-SH））时，R 1为烷基，芳基或杂环基进一步提供式I化合物的ClogP为至少2.0且小于7.8; 和b）具有不同于第一感光卤化银乳剂层的光谱灵敏度的第二感光卤化银乳剂层，其含有式II化合物：其中：1）COUP是能够形成染料的成色剂母体基团与氧化的显影剂反应; 2）TIME是键合到COUP的偶联位置的定时基团，j是0或1; 和3）INH是温和的银开发抑制剂片段。本发明提供了改进的色彩再现。

18. 发明授权

US6043013A Color photographic element containing elemental silver and heterocyclic thiol in a non-light sensitive layer 失效
标题翻译：在非光敏层中含有元素银和杂环硫醇的彩色照相元件
公开(公告)号：US6043013A
公开(公告)日：2000-03-28
申请号：US186855
申请日：1998-11-05
申请人： Paul A. Burns , Louis E. Friedrich , Stephen P. Singer , J. R. Vargas
发明人： Paul A. Burns , Louis E. Friedrich , Stephen P. Singer , J. R. Vargas
IPC分类号： G03C1/30 , G03C1/34 , G03C1/825 , G03C7/392
CPC分类号： G03C1/346 , G03C1/8255 , G03C7/3924 , G03C1/306
摘要： Disclosed is a photographic element comprising a non-light sensitive layer containing elemental silver and a heterocyclic thiol compound having a Clog P of at least 2.0 but less than 12.0, provided that the ring system of the compound comprises a --N.dbd.C--S--H group or its tautomer and does not react with an oxidized developer. The invention provides improved minimum densities in imaging layers.
摘要翻译：公开了一种照相元件，其包含含有元素银的非光敏层和Clog P为至少2.0且小于12.0的杂环硫醇化合物，条件是该化合物的环系包含-N = CSH基团或其互变异构体，并且不与氧化显影剂反应。本发明提供了成像层中改进的最小密度。

19. 发明授权

US5985533A Photographic element having improved magenta dye light stability and process for its use 失效
标题翻译：具有改善的品红染料光稳定性的照相元件及其使用方法
公开(公告)号：US5985533A
公开(公告)日：1999-11-16
申请号：US24034
申请日：1998-02-16
申请人： Robert F. Romanet , Paul A. Burns , Susan M. Fischer , Paul P. Spara , Rajiv P. Balasubramanian , David G. Lincoln , Daniel L. Kapp
发明人： Robert F. Romanet , Paul A. Burns , Susan M. Fischer , Paul P. Spara , Rajiv P. Balasubramanian , David G. Lincoln , Daniel L. Kapp
IPC分类号： G03C7/38 , G03C1/08 , G03C7/26 , G03C7/32
CPC分类号： G03C7/3835
摘要： The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula II: whereinX is hydrogen or a coupling-off group;R.sup.1, R.sup.2, and R.sup.3 are independently selected alkyl groups, provided that any two of R.sup.1, R.sup.2, and R.sup.3 may join to form a ring;R.sup.4 is hydrogen or a substituent, provided that R.sup.3 and R.sup.4 may join to form a ring when R.sup.4 is a substituent;R.sup.a is hydrogen or a substituent;Y is a substituent with at least one Y substituent having a formula selected from the group consisting of --CONR.sup.b R.sup.c, --NHCOR.sup.d, and --SO.sub.2 R.sup.e, wherein R.sup.b, R.sup.c, and R.sup.d are independently selected from the group consisting of H, alkyl, aryl, and heterocyclic groups and R.sup.e is selected from the group consisting of an alkyl group, an aryl group, a heterocyclic group, --NR.sup.g R.sup.h, and --OR.sup.i wherein R.sup.g, R.sup.h, and R.sup.i are selected from the same group as R.sup.a and n is from 1 to 5.The element exhibits improved magenta dye light stability.
摘要翻译：本发明提供了一种照相元件，其包含卤化银乳剂层，其具有与式II所代表的染料形成成色剂：其中X为氢或偶合离去基团; R 1，R 2和R 3是独立选择的烷基，条件是R 1，R 2和R 3中的任何两个可以连接形成环; R4是氢或取代基，条件是当R 4为取代基时，R 3和R 4可以连接形成环; Ra是氢或取代基; Y是具有至少一个具有选自-CONRbRc，-NHCORd和-SO2Re的Y取代基的取代基，其中Rb，Rc和Rd独立地选自H，烷基，芳基，和杂环基，并且Re选自烷基，芳基，杂环基，-NRgRh和-ORi，其中R g，Rh和R i选自与Ra相同的基团，n为1 该元件表现出改善的品红染料光稳定性。

20. 发明授权

US5972587A Photographic element having improved magenta dye light stability and process for its use 失效
标题翻译：具有改善的品红染料光稳定性的照相元件及其使用方法
公开(公告)号：US5972587A
公开(公告)日：1999-10-26
申请号：US024032
申请日：1998-02-16
申请人： Robert F. Romanet , Paul A. Burns , Susan M. Fischer , Paul P. Spara , Rajiv P. Balasubramanian , David G. Lincoln
发明人： Robert F. Romanet , Paul A. Burns , Susan M. Fischer , Paul P. Spara , Rajiv P. Balasubramanian , David G. Lincoln
IPC分类号： G03C7/384 , G03C7/38 , G03C1/08 , G03C7/26 , G03C7/32
CPC分类号： G03C7/3835
摘要： The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula II: ##STR1## wherein X is hydrogen or a coupling-off group;R.sup.1, R.sup.2, and R.sup.3 are independently selected alkyl groups, provided that any two of R.sup.1, R.sup.2 and R.sup.3 may join to form a ring;R.sup.4 is hydrogen or a substituent, provided that R.sup.3 and R.sup.4 may join to form a ring when R.sup.4 is a substituent;R.sup.a is hydrogen or a substituent;each Y is an independently selected substituent with at least one Y substituent in the 2-position (relative to oxygen) having the formula --NHSO.sub.2 R.sup.f, wherein R.sup.f is an alkyl or aryl group, and n is from 1 to 5.The element exhibits improved magenta dye light stability.
摘要翻译：本发明提供了一种照相元件，其包含卤化银乳剂层，其具有与式II所代表的染料形成成色剂：其中X为氢或偶合离去基团; R 1，R 2和R 3是独立选择的烷基，条件是R 1，R 2和R 3中的任何两个可以连接形成环; R4是氢或取代基，条件是当R 4为取代基时，R 3和R 4可以连接形成环; Ra是氢或取代基; 每个Y是在具有式-NHSO 2 R f的2-位（相对于氧）中具有至少一个Y取代基的独立选择的取代基，其中Rf是烷基或芳基，n是1至5.元素表现出改进品红染料光稳定。

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