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11. 发明授权

US08865789B2 Silicone hydrogel contact lenses 有权
标题翻译：硅胶水凝胶隐形眼镜
公开(公告)号：US08865789B2
公开(公告)日：2014-10-21
申请号：US13404035
申请日：2012-02-24
申请人： Li Yao , Ye Hong , Yuwen Liu , Charlie Chen , Charles A. Francis , Arthur Back
发明人： Li Yao , Ye Hong , Yuwen Liu , Charlie Chen , Charles A. Francis , Arthur Back
IPC分类号： C08L101/14 , B65B55/02 , G02C7/04 , C08G77/04 , G02B1/04
CPC分类号： G02B1/043 , C08L83/12 , C08L101/14 , C08L33/10 , C08L33/08
摘要： Silicone hydrogel contact lenses that have good dimensional stability, are ophthalmically-acceptable, and can be manufactured without the use of alcohol solvents are formed from the reaction product of a polymerizable composition comprising at least one mono-functional acrylate-containing siloxane monomer having a molecular weight of less than 2,000; at least one bi-functional acrylate-containing siloxane monomer having a molecular weight of at least 3,000; and at least one hydrophilic vinyl-containing monomer, wherein the polymerizable composition has a molar ratio of total amount of mono-functional acrylate-containing siloxane monomer to total amount of bi-functional acrylate-containing siloxane monomer of at least 30:1, respectively.
摘要翻译：由可聚合组合物的反应产物形成具有良好的尺寸稳定性的眼科学可接受的硅酮水凝胶隐形眼镜，并且可以制造不含醇溶剂的可聚合组合物，该可聚合组合物包含至少一种含单分子丙烯酸酯的含有单官能丙烯酸酯的硅氧烷单体重量小于2000; 至少一种分子量至少为3,000的含二官能丙烯酸酯的硅氧烷单体; 和至少一种亲水性含乙烯基单体，其中所述可聚合组合物的含单体官能丙烯酸酯的硅氧烷单体的总量与含二官能丙烯酸酯的硅氧烷单体的总量的摩尔比分别为至少30:1 。

12. 发明申请

US20140018465A1 High Water Content Silicone Hydrogel Contact Lenses 有权
标题翻译：高含水硅胶水凝胶隐形眼镜
公开(公告)号：US20140018465A1
公开(公告)日：2014-01-16
申请号：US13985109
申请日：2012-02-23
申请人： Yuwen Liu , Charlie Chen , Ye Hong , Charles A. Francis , Li Yao , Arthur Back
发明人： Yuwen Liu , Charlie Chen , Ye Hong , Charles A. Francis , Li Yao , Arthur Back
IPC分类号： G02B1/04
CPC分类号： G02B1/043 , C08F283/065 , C08L51/085 , C08L101/14
摘要： Silicone hydrogel contact lenses having a high water content are described. The lenses are derived from a polymerizable composition including a first siloxane monomer represented by formula (1): wherein m of formula (1) represents one integer from 3 to 10, n of formula (1) represents one integer from 1 to 10, R1 of formula (1) is an alkyl group having from 1 to 4 carbon atoms, and each R2 of formula (1) is independently either a hydrogen atom or a methyl group; the lenses also include units derived from a second siloxane monomer having a number average molecular weight of at least 7,000 daltons, and at least one vinyl-containing cross-linking agent. The lenses have average equilibrium water contents from about 30% wt/wt to about 70% wt/wt when fully hydrated. Batches of silicone hydrogel contact lenses and methods of making silicone hydrogel contact lenses are also described.
摘要翻译：描述了具有高水含量的硅氧烷水凝胶隐形眼镜。透镜衍生自包含由式（1）表示的第一硅氧烷单体的可聚合组合物：其中式（1）的m表示3至10的一个整数，式（1）的n表示1至10的整数，R 1 式（1）的烷基是碳原子数为1〜4的烷基，式（1）的各R 2独立地为氢原子或甲基。透镜还包括衍生自数均分子量为至少7,000道尔顿的第二硅氧烷单体的单元和至少一种含乙烯基交联剂。当完全水合时，透镜具有约30重量％至约70重量％的平均水含量。还描述了硅胶水凝胶隐形眼镜的批次和制造硅酮水凝胶隐形眼镜的方法。

13. 发明申请

US20120216489A1 Silicone Hydrogel Contact Lenses With High Freezable Water Content 审中-公开
标题翻译：硅胶水凝胶隐形眼镜具有高可冷冻含水量
公开(公告)号：US20120216489A1
公开(公告)日：2012-08-30
申请号：US13404041
申请日：2012-02-24
申请人： Paul Hungchaung Lee , Ronghua Liu , Xinfeng Shi , Yuwen Liu , Ye Hong , Charlie Chen , Li Yao , Arthur Back , Charles A. Francis
发明人： Paul Hungchaung Lee , Ronghua Liu , Xinfeng Shi , Yuwen Liu , Ye Hong , Charlie Chen , Li Yao , Arthur Back , Charles A. Francis
IPC分类号： B65B63/00 , C08L43/04
CPC分类号： B29D11/00038 , G02B1/043 , C08L101/14 , C08L83/04 , C08L33/10
摘要： Silicone hydrogel contact lenses that are derived from a polymerizable composition including at least one siloxane monomer and at least one hydrophilic monomer are described. These silicone hydrogel contact lenses have, when fully hydrated, has an equilibrium freezable water content of at least 25% wt/wt as determined by differential scanning calorimetry (DSC). Batches of silicone hydrogel contact lenses and methods of making silicone hydrogel contact lenses are also described.
摘要翻译：描述了衍生自包含至少一种硅氧烷单体和至少一种亲水单体的可聚合组合物的硅氧烷水凝胶隐形眼镜。当通过差示扫描量热法（DSC）测定时，这些硅氧水凝胶隐形眼镜在完全水合时具有至少25％wt / wt的平衡可冷冻水含量。还描述了硅胶水凝胶隐形眼镜的批次和制造硅酮水凝胶隐形眼镜的方法。

14. 发明授权

US09217813B2 Silicone hydrogel contact lenses 有权
标题翻译：硅胶水凝胶隐形眼镜
公开(公告)号：US09217813B2
公开(公告)日：2015-12-22
申请号：US13983307
申请日：2012-02-23
申请人： Yuwen Liu , Junhao Ge , Charlie Chen , Yuan Xu , Li Yao , Arthur Back , Charles A. Francis
发明人： Yuwen Liu , Junhao Ge , Charlie Chen , Yuan Xu , Li Yao , Arthur Back , Charles A. Francis
IPC分类号： G02B1/04 , B29D11/00 , G02C7/04 , C08L83/12
CPC分类号： G02B1/043 , B29D11/00125 , C08L83/12 , G02C7/04 , G02C7/049 , C08L101/14 , C08L83/04
摘要： Silicone hydrogel contact lenses are formed from the reaction product of a polymerizable composition comprising at least one acrylate-containing siloxane monomer, at least one hydrophilic vinyl-containing monomer, and at least one vinyl-containing cross-linking agent. The contact lenses have ophthalmically-acceptable ionoflux values and surface wettability, and can be manufactured without the use of volatile organic solvents.
摘要翻译：硅氧烷水凝胶隐形眼镜由包含至少一种含丙烯酸酯的硅氧烷单体，至少一种亲水性含乙烯基单体和至少一种含乙烯基交联剂的可聚合组合物的反应产物形成。隐形眼镜具有眼睛可接受的离子通量值和表面润湿性，并且可以在不使用挥发性有机溶剂的情况下制造。

15. 发明申请

US20140049746A1 Silicone Hydrogel Contact Lenses 有权
标题翻译：硅胶水凝胶隐形眼镜
公开(公告)号：US20140049746A1
公开(公告)日：2014-02-20
申请号：US13983307
申请日：2012-02-23
申请人： Yuwen Liu , Junhao Ge , Charlie Chen , Yuan Xu , Li Yao , Arthur Back , Charles A. Francis
发明人： Yuwen Liu , Junhao Ge , Charlie Chen , Yuan Xu , Li Yao , Arthur Back , Charles A. Francis
IPC分类号： G02B1/04
CPC分类号： G02B1/043 , B29D11/00125 , C08L83/12 , G02C7/04 , G02C7/049 , C08L101/14 , C08L83/04
摘要： Silicone hydrogel contact lenses are formed from the reaction product of a polymerizable composition comprising at least one acrylate-containing siloxane monomer, at least one hydrophilic vinyl-containing monomer, and at least one vinyl-containing cross-linking agent. The contact lenses have ophthalmically-acceptable ionoflux values and surface wettability, and can be manufactured without the use of volatile organic solvents.
摘要翻译：硅氧烷水凝胶隐形眼镜由包含至少一种含丙烯酸酯的硅氧烷单体，至少一种亲水性含乙烯基单体和至少一种含乙烯基交联剂的可聚合组合物的反应产物形成。隐形眼镜具有眼睛可接受的离子通量值和表面润湿性，并且可以在不使用挥发性有机溶剂的情况下制造。

16. 发明申请

US20120220744A1 Wettable Silicone Hydrogel Contact Lenses 有权
标题翻译：可湿性硅胶水凝胶隐形眼镜
公开(公告)号：US20120220744A1
公开(公告)日：2012-08-30
申请号：US13404037
申请日：2012-02-24
申请人： Yuwen Liu , Charlie Chen , Charles A. Francis , Junhao Ge , Yuan Xu , Li Yao , Arthur Back , Ying Zheng
发明人： Yuwen Liu , Charlie Chen , Charles A. Francis , Junhao Ge , Yuan Xu , Li Yao , Arthur Back , Ying Zheng
IPC分类号： C08F230/08
CPC分类号： G02C7/04 , B65B5/04 , G02B1/043 , C08L83/12 , C08L33/08 , C08L33/10
摘要： Ophthalmically acceptably wettable silicone hydrogel contact lenses are described. The lenses are derived from a polymerizable composition including a first siloxane monomer. The lenses have ophthalmically acceptably wettable lens surfaces when fully hydrated. Batches of silicone hydrogel contact lenses and methods of making silicone hydrogel contact lenses are also described.
摘要翻译：描述了眼科可接受的可湿性硅氧水凝胶隐形眼镜。透镜衍生自包含第一硅氧烷单体的可聚合组合物。当完全水合时，镜片具有眼科可接受的可润湿透镜表面。还描述了硅胶水凝胶隐形眼镜的批次和制造硅酮水凝胶隐形眼镜的方法。

17. 发明授权

US08487058B2 Wettable silicone hydrogel contact lenses 有权
标题翻译：可湿性硅酮水凝胶隐形眼镜
公开(公告)号：US08487058B2
公开(公告)日：2013-07-16
申请号：US13404037
申请日：2012-02-24
申请人： Yuwen Liu , Charlie Chen , Charles A. Francis , Junhao Ge , Yuan Xu , Li Yao , Arthur Back , Ying Zheng
发明人： Yuwen Liu , Charlie Chen , Charles A. Francis , Junhao Ge , Yuan Xu , Li Yao , Arthur Back , Ying Zheng
IPC分类号： C08F230/06 , C08F290/06 , G02B1/04
CPC分类号： G02C7/04 , B65B5/04 , G02B1/043 , C08L83/12 , C08L33/08 , C08L33/10
摘要： Ophthalmically acceptably wettable silicone hydrogel contact lenses are described. The lenses are derived from a polymerizable composition including a first siloxane monomer. The lenses have ophthalmically acceptably wettable lens surfaces when fully hydrated. Batches of silicone hydrogel contact lenses and methods of making silicone hydrogel contact lenses are also described.
摘要翻译：描述了眼科可接受的可湿性硅氧水凝胶隐形眼镜。透镜衍生自包含第一硅氧烷单体的可聚合组合物。当完全水合时，镜片具有眼科可接受的可润湿透镜表面。还描述了硅胶水凝胶隐形眼镜的批次和制造硅酮水凝胶隐形眼镜的方法。

18. 发明授权

US09164298B2 Wettable silicone hydrogel contact lenses 有权
标题翻译：可湿性硅酮水凝胶隐形眼镜
公开(公告)号：US09164298B2
公开(公告)日：2015-10-20
申请号：US13983577
申请日：2012-02-23
申请人： Ye Hong , Li Yao , Yuwen Liu , Charlie Chen , Arthur Back
发明人： Ye Hong , Li Yao , Yuwen Liu , Charlie Chen , Arthur Back
IPC分类号： G02C7/04 , G02B1/04 , C08L83/12
CPC分类号： G02C7/049 , C08L83/12 , G02B1/043 , C08L101/14 , C08L83/04 , C08L51/085
摘要： Silicone hydrogel contact lenses are formed from the reaction product of a polymerizable composition comprising at least one acrylate-containing siloxane monomer, at least one hydrophilic vinyl-containing monomer, and at least one vinyl-containing cross-linking agent, wherein the polymerizable composition has a molar ratio of total amount of hydrophilic vinyl-containing monomer to total amount of acrylate-containing siloxane monomer of from 5:1 to 30:1, respectively. The silicone hydrogel contact lenses have good manufacturing processability, can be manufactured without the use of alcohol solvents, and have excellent surface wettability.
摘要翻译：硅氧烷水凝胶隐形眼镜由包含至少一种含丙烯酸酯的硅氧烷单体，至少一种亲水性含乙烯基单体和至少一种含乙烯基交联剂的可聚合组合物的反应产物形成，其中可聚合组合物具有亲水性含乙烯基单体的总量与含丙烯酸酯的硅氧烷单体的总量的摩尔比分别为5:1至30:1。硅酮水凝胶隐形眼镜具有良好的制造加工性，可以在不使用醇溶剂的情况下制造，并且具有优异的表面润湿性。

19. 发明申请

US20140022506A1 Wettable Silicone Hydrogel Contact Lenses 有权
标题翻译：可湿性硅胶水凝胶隐形眼镜
公开(公告)号：US20140022506A1
公开(公告)日：2014-01-23
申请号：US13983577
申请日：2012-02-23
申请人： Ye Hong , Li Yao , Yuwen Liu , Charlie Chen , Arthur Back
发明人： Ye Hong , Li Yao , Yuwen Liu , Charlie Chen , Arthur Back
IPC分类号： G02C7/04
CPC分类号： G02C7/049 , C08L83/12 , G02B1/043 , C08L101/14 , C08L83/04 , C08L51/085
摘要： Silicone hydrogel contact lenses are formed from the reaction product of a polymerizable composition comprising at least one acrylate-containing siloxane monomer, at least one hydrophilic vinyl-containing monomer, and at least one vinyl-containing cross-linking agent, wherein the polymerizable composition has a molar ratio of total amount of hydrophilic vinyl-containing monomer to total amount of acrylate-containing siloxane monomer of from 5:1 to 30:1, respectively. The silicone hydrogel contact lenses have good manufacturing processability, can be manufactured without the use of alcohol solvents, and have excellent surface wettability.
摘要翻译：硅氧烷水凝胶隐形眼镜由包含至少一种含丙烯酸酯的硅氧烷单体，至少一种亲水性含乙烯基单体和至少一种含乙烯基交联剂的可聚合组合物的反应产物形成，其中可聚合组合物具有亲水性含乙烯基单体的总量与含丙烯酸酯的硅氧烷单体的总量的摩尔比分别为5:1至30:1。硅酮水凝胶隐形眼镜具有良好的制造加工性，可以在不使用醇溶剂的情况下制造，并且具有优异的表面润湿性。

20. 发明申请

US20120220743A1 Dimensionally Stable Silicone Hydrogel Contact Lenses 有权
标题翻译：尺寸稳定的硅胶水凝胶隐形眼镜
公开(公告)号：US20120220743A1
公开(公告)日：2012-08-30
申请号：US13404034
申请日：2012-02-24
申请人： Charles A. Francis , Ying Zheng , Yuan Xu , Li Yao , Arthur Back , Ye Hong , Charlie Chen
发明人： Charles A. Francis , Ying Zheng , Yuan Xu , Li Yao , Arthur Back , Ye Hong , Charlie Chen
IPC分类号： C08F230/08
CPC分类号： C08F230/08 , C08F222/1006
摘要： Dimensionally stable silicone hydrogel contact lenses are described. The lenses are derived from a polymerizable composition including a first siloxane monomer represented by formula (1): wherein m of formula (1) represents one integer from 3 to 10, n of formula (1) represents one integer from 1 to 10, R1 of formula (1) is an alkyl group having from 1 to 4 carbon atoms, and each R2 of formula (1) is independently either a hydrogen atom or a methyl group; the lenses also include units derived from a second siloxane monomer represented by formula (2): wherein R1 of formula (2) is selected from either hydrogen atom or a methyl group; R2 of formula (2) is selected from either of hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms; m of formula (2) represents an integer of from 0 to 10; n of formula (2) represents an integer of from 4 to 100; a and b represent integers of 1 or more; a+b is equal to 20-500; b/(a+b) is equal to 0.01-0.22; the configuration of siloxane units includes a random configuration, the second siloxane monomer having a number average molecular weight of at least 3,000 daltons that is present in the polymerizable composition in an amount such that ratio of the first siloxane monomer to the second siloxane monomer is at least 2:1 based on unit parts by weight. Batches of silicone hydrogel contact lenses and methods of making silicone hydrogel contact lenses are also described.
摘要翻译：描述了尺寸稳定的硅酮水凝胶隐形眼镜。透镜衍生自包含由式（1）表示的第一硅氧烷单体的可聚合组合物：其中式（1）的m表示3至10的一个整数，式（1）的n表示1至10的整数，R 1 式（1）的烷基是碳原子数为1〜4的烷基，式（1）的各R 2独立地为氢原子或甲基。透镜还包括衍生自由式（2）表示的第二硅氧烷单体的单元：其中式（2）的R 1选自氢原子或甲基; 式（2）的R2选自氢原子或碳原子数为1〜4的烃基; 式（2）的m表示0〜10的整数，式（2）的n表示4〜100的整数， a和b表示1以上的整数; a + b等于20-500; b /（a + b）等于0.01-0.22; 硅氧烷单元的构型包括随机构型，第二硅氧烷单体的数均分子量为至少3,000道尔顿，其存在于可聚合组合物中，其量使得第一硅氧烷单体与第二硅氧烷单体的比率在至少2：1，单位重量份。还描述了硅胶水凝胶隐形眼镜的批次和制造硅酮水凝胶隐形眼镜的方法。

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